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By J. W. Town

This report summarizes the results of laboratory investigations conducted by the Federal Bureau of Mines to obtain hydrometallurgical information on the dissolution of mercury sulfides from ores, flotation concentrates, and pure mercuric sulfides. Statistical methods were used to design the experiments and evaluate the resulting data. Studies demonstrated that cinnabar is readily soluble in sodium sulfide, partly soluble in potassium sulfide, and essentially insoluble in ammonium sulfide. Additions of sodium hydroxide or potassium hydroxide to sodium sulfide solutions increased mercury extraction slightly; when either was added to potassium sulfide or ammonium sulfide solutions, mercury extraction was equal to that of sodium sulfide. Tests at the Albany Metallurgy Research Center showed that sodium sulfide would completely dissolve chemically pure mercuric sulfide, more than 95 percent of the cinnabar in 5-percent mercury flotation concentrates, and 60 to 90 percent of the cinnabar in low-grade ores. The double-leach tests showed that potassium sulfide would dissolve over 90 percent of the arsenic in mercury-arsenic products and 1 to 10 percent of the mercury; then sodium sulfide-hydroxide solutions would dissolve 80 to 90 percent of the remaining mercury and 5 to 10 percent of the arsenic.

Jan 1, 1961

By David Schlain

A small alumina reduction cell with a graphite crucible and boron nitride liner was developed by the Bureau of Mines as the initial phase of a study of the reactions which occur in the reduction of alumina by the Hall-Heroult process. Operating conditions in the cell such as temperature, time, current density, electrolyte composition, and electrode materials may be varied easily. Aluminum was produced in the cell at a current efficiency of about 75 percent and a cell voltage of 2.7 volts. Although the data are not wholly conclusive, the operation of the cell did not appear to be greatly affected by large changes in temperature, electrode spacing, current density, and alumina concentration in the electrolyte.

Jan 1, 1963

By J. F. McIlwain

Cobalt-base hardfacing alloys used for wear resistance consist almost entirely of metals largely imported into the United States. As part of an overall research program to help alleviate this foreign dependency, the Bureau of Mines has been investigating an iron-base alloy system as a potential replacement for cobalt-base alloys for some uses. To ascertain the melting ranges, thermal analyses were made of cast heats of alloys containing, in weight percent, 59-61 Fe, 16-19 Cr, 8-9 Ni, 1 Mn, 1 W, 1 Mo, 0.5 Cb, 0.6 Si, 0.3 C, and 0-12 stoichiometric TiB2. Powder alloys within this range of composition, prepared by mechanical alloying, were sized and applied to mild steel test coupons by nontrans-ferred-arc plasma spraying. The resulting thin coatings were >95 pet dense, with bond strengths of 35 MPa and hardness of 400 to 840 DPH. Abrasive and adhesive wear test data were compared to those of a plasma-sprayed cobalt-base alloy. A range of boride contents resulting in most promising properties was determined for further research.

Jan 1, 1985

By R. E. Lindstrom

A study of ion-exchange resin crosslinkage and eluant flow rate, resin-bed shape, and addition of separating ions to feed stock was undertaken to determine their effect on the separation efficiency of ion-exchange on bastna-site-rare-earth elements. Results show that 12-percent divinylbenzene (DVB) crosslinkage resin is detrimental to separation efficiency at flow rates over 2 to 5 ml./min./sq. cm.; whereas, separation with 4-percent DVB crosslinkage resin is relatively unaffected by flow rates between 2 and 10 m1./min./sq.cm.

Jan 1, 1959

By T. F. Mitchell

During the investigation or the occurrence of manganese deposits in western United States, Bureau of Mines' examining engineers collected samples from four manganese properties in the Death Valley region, California. These were supplemented by samples submitted by owners of two other properties in the same area. Extensive laboratory tests were made to determine the, amenability of the ores to standard ore-dressing concentration methods. A small sample of high-grade oxide manganese ore from the McWhinney property, San Bernardino County, Calif., was submitted by the owner. Although the sample would sinter directly to plus 48 percent manganese grade, it appeared probable that the ore, if mined in quantity, would be lower in grade and would require beneficiation. Therefore, testing was conducted to remove the chief gangue constituent, calcite. The National Resources, Inc., property (also known as the old Owl Hole mine) is in the Owl Hole Springs district, I mile from Owl Hole Springs, San Bernardino County, Calif., near the southwest corner of Death Valley National Monument. The ore deposits occur as small lenses or ,pockets, evidently .replacements in limestone and granite. Laboratory work was done on a representative sample of orb procured by Bureau engineers.

Jan 1, 1949

By H. W. Kilau

The Bureau of Mines evaluated synthetic fluorspar as a substitute for natural fluorspar flux in basic cupola ironmaking. The synthetic fluor-spars tested were prepared from waste fluosilicic acid generated during the processing of fluorapatite ore. The cupola trials showed the synthetic products to be the equivalent of natural fluorspar from an operational standpoint. However, wet scrubber sampling showed that substantial losses of volatilized fluorine occurred from the cupola during operation. The losses during synthetic fluorspar trials considerably exceeded those from natural fluorspar trials. Laboratory viscosity testing, using a high-temperature rotational viscometer, confirmed this finding and indicated that fluorspar volatility in slags is related to slag basicity. Synthetic fluorspar is accordingly recommended more for highly basic cupola operation (>1.3 basicity) than for neutral or acid operation, because of the increased potential for pollution and baghouse filter detezioration"

Jan 1, 1989

By John Paul Gries

During World. War II, when the curtailment of imports led to an unprecedented demand for domestic mica, beryl, spodumene, and other pegmatite minerals, the Bureau of Mines and the Geological Survey entered upon a program designed to expedite mining of these minerals from the Black Hills area of South Dakota. The program involved napping, sampling, and drilling of many pegmatite dikes in the southern portion of the Black Hills and beneficiation conducted in the field and in the Bureau of Mines laboratories at Rapid City, S. Dak., Rolla, Mo., Salt Lake City, Utah, and College Park, Md. This report describes the occurrence and sampling of the Beecher No. 2 pegmatite, which was investigated as part of the general pegmatite study in South Dakota. Investigation of the Beecher No. 2 pegmatite was started on November 20, 1943, and terminated in the spring of 1944. During this period, the Bureau of Mines took a series of trench samples across the pegmatite at the surface for grain-count studies and chemical analyses. The Geological Survey mapped the geology of the deposit after it was exposed by trenching and stripping.

Jan 1, 1950

By L. E. Cardwell

This publication contains routine analyses and related source data for 299 natural gas samples from 22 States and three foreign countries. All of the samples were collected during calendar year 1972 as part of a continuous survey of the free world for occurrences of helium in natural gas. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863 and 576.4 Fourteen previous publications have presented the results of 9,902 gas analyses prior to 1972. The first three, Bulletins 486,5 576,6 and 617,7 contain analyses and related source data on 5,218 gas samples collected from

Jan 1, 1973

By T. E. Gray

This report describes preparation characteristics of the significant coalbeds in Marion County, W. Va., as determined by the Bureau of Mines. It is one in a series telling what coals are suitable for producing metallurgical coke, either as mined or after beneficiation. Over 9.4 million tons of coal was produced in Marion County, W. Va., in 1958, of which almost 6 million tons was cleaned mechanically in nine cleaning plants. All of the coal mechanically cleaned came from the Pittsburgh bed. The Bureau of Mines estimated that 1,578 million tons of recoverable coal remained in the county in beds 28 inches or more thick as of January 1, 1955.

Jan 1, 1960

By T. E. Gray

This report describes the preparation characteristics of the more significant coals in Dickenson County, Va. It is one in a series planned to determine which coals are suitable for the production of metallurgical coke either as mined or after beneficiation. Nearly 4 million tons of coal was produced in Dickenson County in 1955, of which approximately 2.7 million tons was cleaned mechanically in 5 cleaning plants. The Federal Geological Survey has estimated that nearly 1,300 million tons of measured and indicated coal reserves remained in the county as of January 1, 1951.

Jan 1, 1958

By Robert S. Warfield

The Bureau of Mines investigated a geologically favorable area in the Beluga River coalfield in south-central Alaska to determine if there were sufficient minable coal reserves for onsite utilization to meet the projected thermal power needs of the Anchorage area. A program of diamond core drilling and sampling delimited a shallow saucerlike structure estimated to contain indicated reserves of more than 20 million tons of subbitminous coal in a seam over 50 feet thick that could be mined by opencut methods. A large sample of fresh coal was taken across the full width of the seam for washability studies. This sample, with 4 volume-percent of clay partings eliminated, contained 24.4 percent moisture and 16.8 percent ash and had a calorific value of 7,162 Btu per pound. The studies indicated that mechanical cleaning would be of doubtful value.

Jan 1, 1963

By W. A. Stickney

This report summarizes the results of laboratory tests of five samples of low-grade phosphate ores from Idaho. The laboratory test work has demonstrated that by grinding, desliming, and flotation a portion of the siliceous gangue can be removed. The highly carbonaceous ores responded successfully to treatment after preroasting, to produce a plus-30-percent-P205 product. It has been found that highly siliceous ores, as represented by the samples treated, are more readily amenable to concentration than ores high in calcium carbonate. Of the five samples tested, four were amenable to concentration to a product containing over 30 percent P205. One sample, from the Conda, second bed, was not amenable to mineral-dressing treatment to produce a plus-25-percent-P205 product.

Jan 1, 1955

By Oliver Q. Leone

Three electrorefining cells were designed to investigate various factors associated with the electrorefining of reject - grade titanium sponge . Operation of the cells provided information on cell design as well as on how design and operating variables affected the quality of the titanium product . A sodium chloride - titanium chloride electrolyte was used , and the electrolyte chambers had capacities ranging from 400 to 3,500 pounds of molten salt . Major factors investigated were electrolyte composition , temperature and useful life , effect of various cathode shapes and materials of construction , methods for removing cathode deposits , effect of current density and cell potential , and the mechanics of deposit growth and crystal morphology . One of the cells was in intermittent operation over a 4 - year period and produced 2 tons of refined titanium . A product with a hardness of 80 or less Bhn (Brinell hardness number ) was consistently and easily obtained . Some metal with a hardness of less than 60 Bhn was produced . In one of the cells in which the electrolyte was held at operating temperature with an internal heater an ac input of 25 kw maintained 3,500 pounds of electrolyte at 850 ° C , but with an external heater 35 kw was required to maintain 400 pounds at 850° C.

Jan 1, 1964

By R. O. Dannenberg

A metallic displacement process, utilizing easily available steel wool or steel window screen, was devised and successfully used for the recovery of silver from waste photographic fixing solutions. Laboratory and prolonged commercial-scale testing established that the iron filament type unit will efficiently precipitate silver, as a high-grade sludge, from acidic waste photographic fixing solutions ranging in grade from less than 1 to over 10 grams of silver per liter. Data and design information are presented to facilitate the construction and operation of a practical unit of any desired size. A smelting process for recovering pure silver from precipitated sludge containing 27 to 80 percent silver was devised.

Jan 1, 1968

By Jon C. Volkwein

The Bureau of Mines conducted a series of tests to evaluate the effectiveness of mixing a compressed-air-generated foam with dried whole-grain silica sand to suppress dust in minerals processing plants. Dust at downstream transfer points was monitored with personal gravimetric samplers and with Real-Time Aerosol Monitors (RAM's) that were connected to strip' chart recorders. Results showed dust reductions of 80 to 90 pct on three separate occasions at two different plants. The mechanism by which foam suppresses dust is discussed, as are the constraints on the use of foam, which may include incompatibility of the foam with the mineral product, difficulty in controlling the foam generator, and cost.

Jan 1, 1983

By Walter R. Storms

This paper, which describes the mining methods of the Potash Co. of America in Eddy County, N. Mex., is one of a series being prepared by the Mining Branch, of the Bureau of Mines on mining practices and methods in various mining districts of the United States. 4, T. The mine and plant of Potash Co. of America are situated in sec. 20 S., R.. 30, E.,. N. M. P. M., about 22 miles by paved road northeast of Carlsbad (fig. 1). A spur line of the Atchison, Topeka & Santa Fe Railroad also connects the mine with Carlsbad.

Apr 1, 1948

By J. B. Gayle

The removal of coal particles from a slurry by flotation is made possible by the formation of stable aggregates with air bubbles of suitable sizes. The formation of such aggregates is theoretically possible only for certain favorable combinations of the solid-liquid-gas interfacial tensions. Because interfacial tensions involving solid phases are not conveniently measurable, a related variable, the contact angle, frequently is used as a measure of the floatability of various materials. Zero angles indicate nonfloatable substances, and large angles indicate substances having a high degree of floatability. During a study of contact angles for coal and substances related to coal in their similarity of response to various physical and chemical treatments, particularly flotation, carbonization, and oxidation, the reproducibility of replicate determinations taken within a 4-hour period was found to be much better than that for comparable results taken over a longer period of time. Consideration of possible causes for these differences led to an investigation of the effects of temperature variations on contact angles. References to literature revealed only a small amount of information, some of it apparently conflicting. Specifically, Sutherland and Wark4/ found that temperature variations "within limits" did not appreciably influence the angles measured for galena conditioned with potassium ethyl xanthate. On the other hand, McGlashan and McLeod5/ presented preliminary data showing that for sphalerite conditioned with potassium ethyl xanthate the angle is maximum at 25° to 35° C., depending on the pH of the system.

Jan 1, 1960

By James S. Wroth

The Act of Congress approved June 25, 1926 (Public Act 424, 69th Congress), authorized joint investigations by the U. S. Geological Survey and the U. S. Bureau of Mines to determine "the location, extent, and mode of occurrence of potash deposits in the United States." The particular deposits selected for exploration were the extensive rock-salt formations underlying large areas in western Texas and southeastern New Mexico, from which potash salts had been identified in the cuttings and sludges from oil wells drilled with cable tools. The evidence of these sludge samples was qualitative only and beyond definitely proving the presence of potash salts in the salt beds, gave little clue to the possible size, richness, or extent of the potash occurrences.

Jan 1, 1929

By Thomas J. Peters

In 1987, at the request of the U.S. Bureau of Land Management, the Bureau of Mines studied the 350-acre Henry?s Lake Wilderness Study Area (ID-035-077) in order to evaluate its identified mineral resources. The Wilderness Study Area is located in northern Fremont County, ID, approximately 140 air miles north-northeast of Pocatello and 3 miles south of the Montana border. The Wilderness Study Area is near the north shore of Henry's Lake at the foot of the southwest-facing slope of Black Mountain. Archean hornblende gneiss, the main rock type present, crops out northeast of the Madison Range Fault, which trends northwest across the southwest corner of the Wilderness Study Area.

Jan 1, 1988

In this U.S. Bureau of Mines report, two drill-split mechanical excavation mining system concepts are described, casted, and cost compared with conventional drill-blast mining systems. The concepts for the two drill-split mechanical excavation mining systems presented are (1) a method for steeply dipping narrow veins 0.6 to 1.2 m wide and (2) a longwall method for fiat-lying tabular ores. In the proposed systems, 70 to 80 pet of the ore is disposed of underground as backfill. For sortable ores, face area crushing, sorting, and direct stowage of run-of-mine waste and low-grade ores are proposed. The underground sorting and stowing of waste reduce materials handling, processing, and waste disposal costs by reducing the quality of ore transported to the surface by 70 to 80 pet (by volume). Because many of the tools and techniques proposed for use in these systems have little or no historical mining industry use, cost assignations are heavily influenced by engineering judgments and presented as prefeasibility-level cost estimates. These estimates, presented as discounted-cash-flow-rate-of-return (DCFROR) values, show the proposed systems to be at least as profitable as, and in some cases 50 pet more profitable than, conventional drill-blast mining.

Jan 1, 1994