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By L. H. Adami

This paper reports the results of solution calorimetry conducted to obtain the heats of formation of crystalline FeS04?6.952H20 and FeS04?1.008H20, from. which values were derived for the stoichiometric compounds FeS04?H20 and FeS04?H20. Also included are derived values of the free energies of formation and dehydration. This work was undertaken primarily to fill a need for data for pure, easily obtainable ferrous compounds that are suitable for use as calorimetric intermediates, The ferrous sulfate hydrates meet the essential requirements for this use.

Jan 1, 1963

By G. R. Hopkins

The average quantity of heat needed to refine a barrel of crude oil in 1934 was 638,000 B.t.u., or about as much heat energy as contained in 5 gallons of fuel oil. Although the total heat utilized in 1934 was slightly above 1933, crude runs to stills increased 4 percent, hence the average requirement per barrel declined from 660,000 B.t.u. in 1933 to 638,000 B.t.u. in 1934 (see fig. 1). The average for 1934 constitutes a new record for firing efficiency, being just under the previous low of 1929. Heat consumption at refineries depends on many factors, of which the trends in yields of gasoline and lubricating oils are probably most important. The yield of gasoline is indicative of activity at cracking plants, which type of plant utilizes more than the average amount of heat per gallon of product. The yield of lubricating oils is indicative of the extent to which credo oil is refined; that is, it takes considerably more heat to refine a barrel of crude through lubricating oils than it does to separate only gasoline and kerosene. The yield of gasoline decreased from 43.7 percent in 1933 to 43.4 percent in 1934; on the other hand, the yield of gas oil and fuel oil increased. Although the yield of lubricating oils increased slightly in 1934 the theoretical increase in fuel requirements probably was offset by technical improvements, such as solvent refining.

Jan 1, 1935

By G. R. Hopkins

The average quantity of heat needed to refine a barrel of crude oil in 1934 was 638,000 B.t.u., or about as much heat energy as contained in 5 gallons of fuel.oil. Although the total heat utilized in 1934 was slightly above 1933, crude runs to stills increased 4 percent, hence the average requirement per barrel declined from 660,000 B.t.u. in 1933 to 638,000 B.t.u. in 1934 (see fig. 1). The average for 1934 constitutes a new record for firing efficiency, being just under the previous low of 1929. Heat consumption at refineries depends on many factors, of which the trends in yields of gasoline and lubricating oils are probably most important. The yield of gasoline is indicative of activity at cracking plants, which typo of plant utilizes more thou the average amount of heat per gallon of product. The yield of lubricating oils is indicative of the extent to which crude oil is refined; that is, it takes considerably more heat to refine a barrel of crude through lubricating oils than it does to separate only gasoline and kerosene. The yield of gasoline decreased from 43.7 percent in 1933 to 43.4 percent in 1934; on the other hand, the yield of gas oil and fuel oil increased. Although the yield of lubricating oils increased slightly in 1934 the theoretical increase in fuel requirements probably was offset by technical improvements, such as solvent refining. Although no outstanding technical developments of a fuel-saving nature were made in 1934, some progress undoubtedly was recorded. Heat exchangers, an effective fuel-saving device, wore enlarged, and some refiners now take off several cuts before the crude reaches the pipe stills. The total capacity of pipe stills increased 2.5 percent in 1934, and many of the less efficient shell stills were torn out.

Jan 1, 1935

By R. H. King

A very simple cold-bend test was devised and tested for evaluating thermoplastic jackets used on mine-power-feeder cables. A test sample is bent into a semi-circle whose radius is equal to the minimum bend radius recommended by IPCEA and then cooled to the, desired test temperature (-35°C). While at temperature, the sample is straightened by pulling the cable ends with a winch arrangement. The results show that of the jackets tested, those which cannot withstand the test literally burst when the sample is straightened.

Jan 1, 1978

By R. W. Freedman

The gas chromatographic method, devised by the Bureau of Mines for analyzing routine mine air samples, was compared with the infrared method used for confirmatory determination of methane in mine air. While maintaining the specificity of the infrared method for methane determination, the gas chromatographic method is more precise, much more rapidly performed, and more convenient.

Jan 1, 1968

By A. W. Ambrose

A few years ago, (March 3, 1915) Congress passed a law providing for the establishments of ten mining experiment stations under the supervision of the Bureau of Mines. In 1917 the Secretary of the Interior decided that one of these stations should be devoted to Petroleum, and in the early part of 1918, approved the establishment of the Petroleum Experiment Station at Bartlesville, Oklahoma, upon the condition that the city furnish the site for the buildings and guarantee $50,000. for the erection of the buildings. A building site of 5 acres and the necessary building fund was furnished by the Bartlesville Chamber of Commerce.The buildings consist of an administration and laboratory building, both of brick construction. The former is a two-story structure of eight rooms. A large room occupying over half of the main floor is devoted to the library, reception room, and clerical force. The remaining rooms comprise a drafting room and six offices occupied by the staff assigned to this station. The laboratory is a one-story brick building and contains a well-equipped chemical and physical laboratory, also a machine shop and mechanical laboratory. In addition to the main buildings there now are on the property an experimental refinery, a blue-print house, and a store house. These latter buildings are all of sheet-iron construction.

Oct 1, 1920

By R. R. Schehl

The Bureau of Mines has developed a quantitative Analysis for pyrite in coal by X-ray diffraction that can be accomplished in little more than 1 hour. To minimize the sample analysis time, data processing has been completely computerized with pertinent output information displayed on a VR12 cathode-ray tube display. Use of this computerized system is not only advantageous during the experimental stages of the pyrite analysis project but would also be essential if the X-ray diffraction procedure is accepted as a standard method of analysis.

Jan 1, 1973

By C. H. Gorski

Evaluation of raw materials for mineral wool is one phase of the Bureau of Mines broad program for the more effective utilization: of our mineral resources. The experimental work and test-evaluation results on several raw materials as useful components for the production of mineral wool are presented in this report. Samples from all sections of the United States, including copper slag from Tacoma, Wash., pebble phosphate slime from Florida, and granites from Massachusetts and Minnesota, have been blown into mineral wool successfully in the laboratory tests. Maximum conservation of the Nation's mineral and manpower resources requires maximum utility of those resources. Al though the domestic reserves of oil, gas, and coal are tremendous, judicious use of these fuels through the use of proper insulation will insure the highest thermal efficiency. The effectiveness of mineral wool as a heat-insulating material has assumed an increasingly important role in the national economy, and it has become a fuel saver in countless applications. The most immediate concern to many is the use of mineral wool in the home, which promotes uniform temperature and minimizes drafts by reducing heat transfer through the walls, ceiling, and floors. There are, however, many industrial and commercial uses that require large volumes of mineral wool each year.

Jan 1, 1951

By A. R. Rule

This report describes preliminary studies by the Bureau of Mines to develop a procedure for extracting the fluorine from low-grade fluorspar ores in which the CaF2 particles are finely locked in the calcite matrix. A combination of flotation beneficiation and pyrohydrolysis is applied to recover and to liberate the fluorine. Flotation of a finely locked high-calcite fluorspar ore containing only 11.7 pct CaF2 recovered over 92 pct of the fluorspar at a grade of 51 to 52 pct CaF2. Pyrohydrolysis of the flotation concentrate liberated nearly 90 pct of the fluorine as aqueous HF. By this procedure over 80 pct of the fluorine contained in the original ore was extracted.

Jan 1, 1974

By C. S. ROBINSON, T. M. Romslo

This investigation was conducted jointly by the Bureau of Mines and the Geological Survey to obtain further information on the source and economic possibilities of the copper mineralization exposed on the Copper Giant group of claims, Ajo mining district, Pima County, Ariz. The Copper Giant group of claims was first brought to the attention of the Bureau of Mines by Joseph Hunter (deceased), Phoenix, Ariz., part owner of the claims. In December 1942 these claims, and an adjoining group, were investigated by T. C. Denton, mining engineer, formerly with the Bureau of Mines, and Nels P. Peterson, geologist, Federal Geological Survey. It was concluded the area could not be considered as a source of copper for immed- iate emergency needs and that further investigation of the area, at the time, was not warranted. In the spring of 1948 the lessee, J. H. Greenway Albert, requested Bureau of Mines assistance in developing the property. J. H. Hedges, former chief, Tucson Branch, Mining Division, and Lincoln A. Stewart, mining engineer, Bureau of Mines, made a cursory examination of the property and noted that at numerous places, low-grade copper mineralization appeared on fractures and bedding of the Locomotive fanglomerate and Ajo volcanics, which are thought to be of Tertiary age. During the period of May 11 through 14, 1949, Bureau of Mines engineers3 mapped and sampled two areas of mineral- ization. On June 2 and 3, 1949, the areas selected by the Bureau and three other nearby mineralized areas were investigated by C. A. Anderson and R. S. Cannon, Jr., of the Federal Geological Survey. As a result of these examina- tions, further investigation of certain areas was believed to be merited. The Copper Giant area was selected as the most favorable in which to carry out exploratory and development work. The field work on the project was started in October 1949 and completed in December 1949. It consisted of road building, trenching, sampling, topo- graphic and geologic mapping, diamond drilling, and logging of core. Samples taken on the project and during preliminary examinations totaled 64, of which 63 were surface samples. Diamond drilling, started October 10 and completed December 7, consisted of two holes for a total depth of 1,542 feet.

Mar 1, 1952

By Howard E. Parkinson

In 1969, new coal mine health and safety legislation was enacted in the United States. As a result of this legislation, the Department of Interior, Bureau of Mines has carried out communications research aimed at developing whole mine communications for increased safety and efficient operation. The research has advanced and many promising results are now being demonstrated to the mining industry. However, there remains a challenge to further improve wireless communications within the mine workings, and through the overburden above the workings. The objectives for future research and development will be discussed, together with the physical and operational constraints that new mine communication systems must face.

Jan 1, 1973

By W. W. Culter

"This paper is the outcome of thorough investigation into the value of the previous methods used for deriving production decline curves. It is highly important that methods be employed that are fundamentally sound and also practicably applicable. Six methods commonly used were studied. Some of these were found to be fundamentally in error; some save reliable curves but involved much work and time in the preparation; others gave reliable curves with less time and effort.It was found that of the methods previously employed the ""family curve"" method described in Bull. 134 Amer. Inst. Feb. 1918, pp. 499-500 by Lewis and Beal, was probably the most satisfactory. The now method given in this paper ploys the same principles as the ""family curve"" method, but is mathematical instead of graphical,The engineer and the oil man should carefully boar in mind both the use and the limitations of the average production curve such as is derived by the ""family curve"" method or other methods mentioned. Estimations of future productions or of underground oil reserves of a particular tract or well should be made from the production records of the tract or the well itself wherever such records are satisfactory. The use of the average curve of a district or field should be applied only to those properties or wells where there are not sufficient data to construct individual or tract production records, or where the productive life so short that a satisfactory individual record can not be obtained."

Jul 1, 1920

By Daryl E. Radcliffe

The Bureau of Mines, as part of an agreement with the Bear Coal Co., Somerset, Col o., evaluated the response of a coal mine roof to time lapse. Time lapse, the interval between exposure and support of the roof, was studied using both instrumentation and statistics. Instrumentation studies were designed to equate displacement and rates of displacement with areas of roof left unsupported from 15 minutes to more than 4 days. A statistical study was completed to compare roof fall occurrence with time lapse intervals encountered during normal room-and-pillar mining. Results from this investigation show time lapse, in the Bear mine, to he insignificant with respect to roof stability after installation of permanent support.

Jan 1, 1980

By Larry R. Wilson

The development effort described herein was directed toward the design and development of a flexible communication system to provide two-way section communications between any telephone on an MCM-101 telephone FDM exchange and a miner provided with a uhf walkie-talkie transceiver. The system also provides normal communication between miners within a working section through the uhf coupler interface repeater.

Jan 1, 1976

By D. G. Kesterke

The electrolytic reduction of uranium dioxide to molten uranium in fluoride baths at approximately 1,200° C was demonstrated. Electrolyte constituents were BaF2, UF4, and either MgF2 or LiF. Preliminary laboratory-scale experiments were made in which the uranium oxide was added continuously for 3 to 5 hours to the cell during electrolysis. Over 1,000 grams of metal of 99-8 percent purity was made in some tests, Major impurities were aluminum, barium, iron, silicon, carbon, and oxygen. The effects of cell design, geometry, and bath composition were investigated. Electrode arrangement was the most important factor in cell performance.

Jan 1, 1963

By H. V. Makar

An aluminizing dross which is accumulating as a waste material in substantial quantities was tested for possible use as a steel deoxidizer. This material, consisting mainly of aluminum, silicon, and iron, was used to deoxidize laboratory-scale melts ranging from 7 to 100 pounds. Oxygen analysis showed that the aluminizing dross was effective in reducing oxygen levels in steel. A direct comparison with aluminum wire showed the dross material to be at least as effective. Under similar test conditions with 7-pound melts, 3 grams of aluminum reduced the oxygen concentration from 210 to 175 ppm, while 4 grams of aluminizing dross (equivalent to approximately 2 grams aluminum) reduced the oxygen concentration from 250 to 170 ppm. An additional 4 grams of aluminizing dross produced a final oxygen concentration of 140 ppm.

Jan 1, 1972

By F. W. Brown

In 1942 the Explosives Division investigated electrostatic hazards associated with the manufacture, storage, and use of explosives. A report was issued in 19454/ presenting the data on the spark sensitivities of explosives. In 1948, the apparatus was redesigned and rebuilt to make the routine testing of explosives safer and more convenient. The rebuilt apparatus is described in this re-issue of the former report. Included are details of construction and a list of parts. PRINCIPLES OF METHOD In normal procedures without special precautions, it is possible for static charges to be accumulated on individuals or on ungrounded equipment or structures.5/ Static charges may be produced in many ways, but they are most commonly produced by rubbing or successive contact and separation of unlike surfaces, at least one of which is usually an insulator.

Jan 1, 1953

By Arnold B. Hubbard

This report describes a method of concentrating the insoluble organic material (kerogen) in a rich Colorado oil shale without any apparent alteration of its original chemical form. The method involved treating finely pulverized shale with dilute acetic acid at room temperature to remove the carbonates, which act as a cementing agent for the shale, and cause the shale particles to partly disintegrate into the organic and inorganic components. The acid-treated shale then was centrifuged in different liquid mediums ranging from 1.4 to 1.15 gravity to effect a mechanical separation. From a Colorado oil shale containing 48.0 percent ash, kerogen concentrates containing 43.3 to 8.7 percent ash were obtained. The carbon:hydrogen ratios of the kerogen in the original shale and the different concentrates were essentially the same. The oil:kerogen ratios calculated from Fischer assays of the above samples were essentially the same, regardless of the organic or inorganic contents. This was also true of the assay water:kerogen ratios of the same samples. These data indicate that no significant change occurred in the kerogen during the concentration process.

Jan 1, 1952

By Bruce D. Sartwell

A program was written which utilizes a remote teletype input to a time- sharing computer to plot charged particle or X-ray energy spectra which are stored in the memory of multichannel analyzers. The program, written in FORTRAN V, accepts the data printed out by the pulse height analyzer on paper tape and then, after reading these data tapes into the computer, plots on the teletype the desired energy spectra on a scale automatically adjusted for the maximum number occurring in the data. The program is flexible enough so that the researcher can subsequently expand or contract the vertical (intensity) or horizontal (energy) scales. With a slight modification, the program will accept data printouts from scalers or analog to digital converters. The program also includes a feature for integrating the energy peaks obtained by pulse height analysis.

Jan 1, 1970

By Raymond B. Ladoo

"The recent discovery and exploitation of petroleum territory have resulted in the enactment of new petroleum laws in most of the South American Republics. The activities in the discovery of these new fields were engendered by the knowledge of the fact that present producing fields must within well defined periods be exhausted. Oil operators were willing to take the initial steps in exploitation in the absence of legislation that applied strictly to petroleum operations. The enactment of modern legislation in many of these Republics encouraging and protect¬ing exploitations may cause tremendous oil activities in these countries, and the results may be comparable with the magnitude of the undertakings and the prestige of the companies now entering this territory.These, oil fields are admirably located for convenient distribution of petroleum by water to all the Nations using oil as fuel for shipping and industrial concerns. The oil markets of the western coast of South America will derive immense benefits from the Panama Canal. This navigation route brings these markets into direct ocean shipment with the Atlantic coasts of the Western and Eastern Hemispheres.One deterrent to oil production in the Republics of South America is the want of inland. transportation facilities, but the recent laws of these Republics without exception provide for acquiring rights of way for pipe lines and other modes of transportation; and doubtless the great interests and. syndicates already operating in these regions will, as production increases, provide ample pipe line transportation sufficient to convey to the coast the oil produced. It way be assumed, from the legal guarantees afforded, and from operating equipment and machinery that are now being concentrated that refineries will be erected at shipping points for the purpose of making these petroleum products accessible to the world."

May 1, 1921