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By Johann Engelbrecht, Stéfan de Bruyn, Petrus van den Heever

A system for the on-stream X-ray diffractometric determination of mineral phases in slurries was developed in response to the mining industry's need for process control during the beneficiation of industrial minerals. The instrumentation for and results from testwork conducted at a phosphate rock beneficiation plant in Florida are discussed. Results show that the concentrations of the minerals apatite (var. francolite) and quartz can be accurately determined every few minutes, so that adjustments to the flotation circuit can be timeously executed from the control room. The on-stream measurements can ultimately be integrated into an automated plant control strategy. Estimates of savings on reagent and staffing costs, as well as the benefits from consistent grades and greater recoveries, have shown that the investment in such a system could often be recovered in less than a year.

Jan 1, 1999

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, the pH decreased and metals increased. Output pH increased from 4 to more than 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long-term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2002

By G. A. Munoz, J. D. Miller

Gold leaching of an auriferous pyrite ore from the Portovelo deposit in Ecuador indicates that noncyanide leaching systems, such as thiocyanate and thiourea, are not as effective as the traditional cyanide system. For example, whereas approximately 95% of the gold can be leached from the ore with cyanide, only about 50% gold dissolution can be achieved with a thiocyanate leaching system. Electrochemical measurements indicate that gold is not cathodically protected by pyrite in these systems. Based on the results of preliminary diagnostic experiments, it appears that gold dissolution in thiocyanate and thiourea systems is limited by passivation due to the formation of either elemental sulfur or sulfur compounds on the gold surface.

Jan 1, 2000

By Gun Berglund, Eric Forssberg

Sulphide mineral flotation is known to be affected by oxidation-reduction conditions in the pulp, although there is some doubt as to whether it is the oxidizing environment or the type of oxidant which influences flotation. Variations in the oxidizing conditions of the pulp and their subsequent effect on flotation were examined for two types of natural sulphide ore, a galenasphalerite ore and a complex pyrite ore. Different gas mixtures ranging from pure nitrogen to pure oxygen were used to control the oxidizing conditions. Zinc recovery increased with a more oxidizing environment, and nitrogen gas acted almost as a depressant for sphalerite in the flotation of the Pb-Zn ore. For the complex pyrite ore, the selectivity between chalcopyrite and both gangue and pyrite improved when the environment was oxidizing, resulting in higher Cu recovery in the copper rougher concentrate. The use of an oxygen rich flotation gas was found to be a suitable method for changing the oxidizing conditions and improving flotation under controlled conditions. The flotation results were correlated to the oxygen content and the redox potential, parameters which describe the pulp chemistry conditions.

Jan 1, 1989

By W. K. Tolley, D. G. Kotlyar

Oxidized sulfide minerals, commonly formed by weathering, are becoming increasingly important resources as primary sulfide deposits are depleted. Oxidation, in general, reduces selectivity and recovery in flotation. The objective of this research was to determine the mechanisms of oxidation and collector adsorption in sulfide systems as a step towards developing improved technologies for beneficiation of oxidized sulfides. Data from microcell flotation tests are combined with electrochemical and spectrophotometric measurements. The adsorption of ethyl xanthate (EX) on oxidized sulfides was characterized using AC impedance and voltammetry techniques, and correlated to flotation response. Oxidation resulted in an electrically resistive, nonporous surface layer. The floatability of chalcocite, chalcopyrite and pyrite was dependent on the extent of oxidation. Oxidation for one day or more at 65ºC suppressed chalcocite flotation. Oxidized chalcocite also inhibited flotation of chalcopyrite and pyrite. Oxidation caused decreased chalcopyrite flotation. Pyrite flotation, however, increased after oxidation.

Jan 1, 1995

By A. B. Cecala

The US Bureau of Mines performed a study to determine optimal locations for longwall face methane monitoring equipment. Longwall face ignitions continue to be a concern to the US coal mining industry. Gains in ignition control technology have been somewhat negated by advances in longwall productivity. More reliable, heavy duty longwall face systems generate higher production rates and increase methane liberation rates. These rates will likely continue to rise as further coal production increases occur. Efforts will continue in the areas of methane drainage, methane containment and methane dilution. In addition, more effective face methane monitoring is needed. As technology continues toward automated longwall panels, the importance of monitoring for methane at the shearer becomes even more significant. Since the primary face ignition source is the shearer mining machine, the Bureau ran tests to determine the best location to take methane readings on the shearer. This information, in conjunction with data obtained from field studies, provides a knowledge base for selecting optimum face methane monitoring locations.

Jan 1, 1995

By G. E. Mellor, R. E. Lippoth, T. B. Faddies

The Little Rocky Mountains host epithermal- gold-silver bearing vein and stockwork deposits in a syenite intrusive complex. Pegasus Gold Ltd. is currently mining these oxidized deposits by open-pit methods and recovering gold and silver by heap-leach processes. A geologic program has been designed to effectively determine the basic ore characteristics; 1) mineralization; 2) oxidation; 3) structural setting; 4) lithology; 5) alteration; and ultimately, 6) the leachability of the ore. Geologic mapping, sampling, drilling, assaying, and testing are routinely used in exploration, development, production control, mine planning, and ore reserve estimations. Timely and accurate assay results are essential for the program's success.

Jan 1, 1992

By Simona Markic

With the aim of environment protection the program package HOMOGEN is used for realizing the planning and noxious components control in the coal produced. Using the program package PRIPREMA the division in levels and transformation (Hermite polynoms) in the N (0,1) distribution are made. By separated kriging 50 m x 50 m blocks are estimated on the levels and detailed distributions of the estimated component content are obtained. The face - longwall face is built in the blocks estimated in this way, and the direction of mining is determined. Using the stochastic simulation the distribution of the estimated production component (e.g. sulfur) on the face is obtained. Simulating the production of all faces in operation the distribution of the estimated daily mine production component is obtained. The estimated depot component is obtained in the same way. This procedure is used in the short-term planning of the estimated component movement for a given period in advance, and also in the daily production control in the case of changing conditions, e.g. the increased atmospheric pressure. The technology is successfully applied to the Velenje Lignite Mine Slovenia.

Jan 1, 1992

By S. Svoronos, B. Moudgil, R. Stana, A. El-Midany

Due to their similar surface properties, it is not always easy to separate carbonate minerals from other salt type minerals by froth flotation. A particular example is the difficulty of separating dolomite impunities from phosphate minerals. Such challenging fundamental and practical problems have inspired several research efforts in various laboratories around the globe to find methods for economically removing the dolomite. However, a universal and cost effective process is not in commercial use. In this paper, a new process for separation of carbonate minerals (dolomite or calate) from other associated minerals is presented. Differential solubility of carbonates in slightly acidic solution is utilized to generate micro GO, bubbles at the carbonate mineral/ water interface. Particle (e.g., dolomite)/ bubble aggregates float to the surface leaving phosphate concentrate with low MgO content. Interestingly, up to 6.0 mm particles can be floated by such micro bubble/particle aggregates. Different sutface-active agents were tested to stabilize the bubbles. Results of these tests are presented and the mechanisms involved are discussed.

Jan 1, 2005

By Edward F. Divers, J. Drew Potts

Powered dust-filtering helmets (dust helmets) have become increasingly prevalent in the underground mine environment in recent years. Many longwall operations use dust helmets to reduce the respirable dust exposures of miners required to work downwind of crusher, roof support and shearer operations. While continuous mining sections are usually less dusty, use of diesel equipment represents a new potential health problem. The U.S. Bureau of Mines recently conducted a study to determine the efficiency of a dust helmet on diesel-size particulate. Two underground evaluations were conducted on continuous mining sections that were using diesel haulage vehicles. Model No. AH21 Racal airstream helmets equipped with AS22-3 prefilters, AS23-3 main filters and AS60476 tyvek full-face seals were tested. Helmets were placed on mannequin heads and mounted in the ram car cabs. Andersen Model 298 (eight-stage) personal cascade impactors were used to sample air inside and outside of the helmet. Impactor stages 8 and the final filters were analyzed to determine submicrometer (0 - 0.93 µm) particle concentrations. Results from this study showed that the dust helmet was 94% (± 3% at 95% confidence level) efficient on submicrometer particles. Typically, very little coal dust is observed in the submicrometer size range, therefore, these particles were assumed to be from diesel exhaust. Results from this study indicate that proper use of the dust helmet on continuous mining sections that are using diesel haulage vehicles may be beneficial to the health of miners.

Jan 1, 1991

By A. R. Zambrano

Equations for power draft, capacity and work input for predicting the performance of industrial grinding mills are derived based on torque measurements using a laboratory instrumented mill. These derivations are based on mechanical principles and on the first-order kinetics of the grinding process. Rittinger's, Kick's and Bond's laws express work input as work index (Wi) times a particle size function. It is proposed that these laws are only particular cases of more general expressions having the particle size function raised to an exponent, i.e., the work exponent (We). Case studies illustrate the excellent prediction of the Wi - We models compared to the three mentioned laws, and, from the data, the corresponding general mill-sizing equation is derived. Key words: Grinding mills, Comminution, Work index, Mill sizing

Jan 1, 2003

By Henrique Garcia Pereira

In a large scale mining project, the global feasibility study must take into account the interdependence of three sub systems: the geological subsystem, represented by the orebody model; the technological subsystem, consisting .of mining and ore dressing models; and the economic subsystem, including the selling price of final product, production costs and investments. In cases where the ore is heterogeneous, the interdependence between geological and technological subsystems may be assessed by a Data Analysis technique such as Correspondence Analysis (CA). This technique was applied by David and Dagbert (1975) on examples of data from geochemistry and geology. In the approach used in this paper, CA is used to create the basic framework for defining different types of ore. The final definitions of ore types take into account the mi¬ning method and the results of applying beneficiation processes to the ore.

Jan 1, 1982

By A. T. Weber, G. T. Adel

Earlier studies on the hydrodynamic interactions between fine particles and air bubbles have shown that fine particle flotation can be improved by using small air bubbles. In the present work, microbubbles ranging in size from 70 to 250 microns have been used in a flotation column for the processing of fine coal. The performance of the microbubble column has been studied as a function of wash water addition rate, aeration rate, feed rate and column length to diameter (L/D) ratio. The information collected from these tests has been used to analyze column behavior and to develop scale-up criteria. The results of this investigation suggest that mixing within the column may not be as significant as bubble size and residence time in determining column performance. Improved recovery can be obtained by decreasing bubble size which increases the flotation rate constant, and also by increasing L/D which increases residence time for a fixed column volume. The increase in residence time with L/D is due to a decrease in the volumetric flow rate of wash water with column diameter.

Jan 1, 1988

By Frank X. Bellini, Marc Saidman, Allen J. Hulshizer, Anthony J. Stewart

The cooling water system for the Seabrook Nuclear Station involves 10.25 Km (33,623 ft.) of 6.7 m (22 ft.) OD hard rock tunnels, over one third of which is under and terminating over 1.6 Km (a mile) out in the Atlantic Ocean. The major excavation is accomplished by two TBM's concurrently driving the intake and discharge tunnels which by mid-January, 1981, completed 92% of the excavation. This paper presents the case history of the excavation work and describes a computer program developed to evaluate major activities of TBM excavation on a shift-by-shift basis. Details and summaries of the production efforts are computer plotted in different forms to facilitate the evaluation of production performance, trouble spots and trends.

Jan 1, 1981

By E. H. Cho, P. K. Dai

An acid mine drainage sludge sample, containing 3.6% Mn, 0.18% Ni, 0.15% Co and 0.39% Zn, was obtained from central West Virginia. The sample was leached at room temperature with a pH 3 sulfuric acid solution. Air was then bubbled through the leach solution at pH 4.5 to precipitate the iron. The leach solution contained 258 ppm Zn, 105 ppm Ni, 90 ppm Co and 2050 ppm Mn. Three solvent extraction studies were performed to selectively extract these metal ions in a sequential operation with DEHPA. Cyanex 272 and Lix 84. The A/O ratio was one, and the extractants were diluted ten times with kerosene. A study of solvent extraction with DEHPA showed that Zn could be extracted without Ni or Co up to a pH of 2.75. A pH of 2.75 is considered to be the optimum pH to maximize the selective separation of Zn from Mn. The separation factor of Co over manganese suggests that the two metal ions should be extracted together by Cyanex 272. The separation factor of Co over Ni indicates that these two metal ions can be separated most effectively around pH 5.3. Also, Ni can be effectively extracted by Lix 84 above pH 5.5.

Jan 1, 1995

By R. N. Rothan, V. Khunova, C. M. Liauw, G. C. Lees

The interphase modification activity of 1,3-phenylene dimaleimide (also known as m-phenylene bismaleimide (BMI)) has been studied in composites based on magnesium hydroxide (60% w/w) and a polypropylene block copolymer (PPBC) that featured an ethylene-rich elastomeric impact modifier phase. BMI was found to be a unique product that led to significant simultaneous improvements in composite strength and toughness, even at the high filler levels. BMI modification was found to promote encapsulation of filler particles with the elastomeric phase of the PPBC together with formation of a PP boundary layer of increased crystalline content.

Jan 1, 2003

By D. J. Shields

This paper describes a dynamic short-nun mineral supply model that incorporates secondary processing, transportation, mineral market structure, and direct mining and milling costs. The method employed is network flow programming. Empirical tests utilizing domestic phosphate industry data have been conducted by the Bureau of Mines, U.S. Department of the Interior. In the model, nodes represent physical locations such as a mine or port. Arcs represent either a process, such as mining, or movement, such as rail or barge transport. Each arc is described by lower or minims allowable flow bounds, upper or maximum possible flow bands, and variable cost. Mines and previous period inventories represent potential supply. The model is optimized via a cost minimizing algorithm, which attempts to fulfill stated total demand at the minimum possible system cost given the arc constraints. An optimal solution of the model will predict production patterns by mineral property for each prespecified level of demand. A mineral property is defined as a separate accounting entity such as a mine. The results of serial optimizations are used to construct the short-run supply curve. Dynamic policy analysis can be conducted by altering the arc constraints.

Jan 1, 1986

By M. H. H. Mahmoud, T. A. El-Barbary, E. A. Abdel Aal, I. A. Ibrahim, A. K. Ismail

Fertilizer-grade phosphoric acid with a P2O5 concentration of 50% should contain less than 1.5% Fe2O3, otherwise, the P2O5 water solubility of the fertilizers prepared from high-iron acids will be low. High-iron Egyptian phosphate concentrates fromAbu-Tartur and Sebaiya- West were leached with sulfuric acid and recycled phosphoric acid to produce 50%-P2O5 phosphoric acids containing 4.0% and 2.7% Fe2O3, respectively. The high iron contents were reduced to the industrially accepted limit of 1.5% Fe2O3 by precipitation with potassium sulfate. The factors affecting the effi¬ciency of the precipitation process, e.g., temperature, time and K2O/Fe2O3 ratio, were systematically studied, and the optimum conditions were achieved. The clarification of the prepared phosphoric acid from iron-containing sludges was also investigated by varying the time and temperature. The utilization of the separated sludges as fertilizer and recovery of P205 by pulping in water were also evaluated.

Jan 1, 2000

By D. Armour, E. R. Bauer, D. R. Zuchelli, T. M. Durr, E. R. Reeves

A team of noise specialists from the National Institute for Occupational Safety and Health (NIOSH), Mine Safety and Health Administration (MSHA), and Joy Manufacturing attempted to evaluate an engineering noise control on a Joy longwall stageloader. The team developed and executed a test plan to evaluate the noise attenuation of the engineering control in an underground coal-mining environment. An evaluation of the long-term noise effects and durability of the engineering control were also a focus of the research effort. Pre- and postcontrol measurements consisting of a combination of worker dosimetry and task observations, tape recordings, and sound level measurements were used to evaluate the engineering control. A description of the engineering noise control, pre- and post-control sound level measurements, and an evaluation of control success is presented. In the end, no evaluation was possible due to mining practices, miner task variations, and inconclusive data.

Jan 1, 2005

By V. G. Papangelakis, G. P. Demopoulos

The high temperature (180-200 OC ) pressure oxidation (02 - HzSO4) process for the recovery of gold from refractory concentrates (FeS2/FeA8S) is simulated with the aid of a computer model. The model centers on the continuous operation of a multi-stage horizontal autoclave. In particular the effects of key process parameters controlling the autogenous operation of the autoclave are critically examined. The building elements of the model are (i) the continuous particle size distribution function of the concentrate, (ii) the residence time distribution function of the slurry and (iii) the shrinking core kinetics. Conversion is calculated on the basis of the segregated flow model. For the calculation of the particle size distribution at the exit of each compartment the population balance model is employed. The effects of feed rate, feed preheating, cooling, autoclave configuration and rate limiting regime (chemical reaction vs. gas-liquid mass transfer) on the autogenous steady state operation are discussed. Finally optimum reactor design and operation criteria are indicated.

Jan 1, 1990