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The dissolution kinetics of gold in iodide solutions with oxygen in an autoclave was investigated. The leaching process was described by a gas-liquid-solid heterogeneous reaction. The effect of stirring speed, temperature, partial pressure of oxygen, and concentration of lixiviants on the overall leaching rate was investigated. It was found that the dissolution of gold was limited by a heterogeneous chemical reaction. The apparent activation energy was measured to be 34.7-54.3 kJ/mol under the conditions studied. Experimental findings were in good agreement with the kinetic model proposed.

Jan 1, 1996

By Marshall D. Himes

The Pima mine, 39,000 ton per day copper mine, is located 17 miles south of Tucson, Arizona. The mine is in a sequence of Paelozoic and Mesozoic sediments striking east-northeast and dipping southeasterly intruded by a Tertiary quartz monzonite porphyry. The Paleozoic Permian(?) dolo¬mites, limestones, and sandstones have been altered to talc-silicate skarn, marble and quartzite. The overlying Mesozoic Triassic(?) clastic sediments have undergone some recrystallization and hydro¬thermal alteration. The clastic metasediments are divided into three distinct lithologic units, lithic arenite, arkose, and inter¬bedded and overlying black argillite. Three types of hydrothermal alteration in the clastic rocks are propylitic alteration (epidote, chlorite and quartz, with or without sericite), quartz-sericite alteration, and potassic alteration (K-feldspar and quartz, with or without sericite and chlorite). The porphyry has undergone potassic alteration. Dominant structures are an east-west post mineral fault in the western part of the pit, and strong low angle faulting and shearing which truncates the ore body at depth. Two joint sets, one parallel to bedding and the other at right angles to bedding are prominent in the mine. Faulting is in two dominant directions, one striking northwest, dipping northeast and the other striking northeast, dipping northwest. Mineralization is predominantly disseminated pyrite and chalcopyrite, and molybdenite-quartz veinlets. There are lens important amounts of magnetite, hematite, sphalerite, galena, tennantite and bornite. Mineralization is believed to be both structurally and chemically controlled.

Jan 1, 1972

A parametric study was conducted to establish the optimum operating conditions for the column flotation of fine coal. The parameters examined in this investigation included collector and frother dosages, feed solids content, and the volumetric flow rates of feed slurry, air and wash water. Despite the wide range of conditions studied the experimental data were found to fall along single grade-recovery curves, just below the maximum separation predicted by the release analysis technique. The deviation of the parametric test data from the release curve was attributed to the nonselective entrainment of mineral matter associated with poor froth washing. The operating point on the characteristic recovery-grade curve was found to be primarily determined by feed rate and aeration rate.

Jan 1, 1992

By E. Martinez

A heavy mineral sand sample was tested containing 13% heavy mineral consisting of rutile, zircon, and ilmenite. Eleven tests were run at a mill site with a Mineral Deposit Limited MG 4 spiral to determine the effect of the addition 0; magnets to the spiral compared to conventional gravity separation. Different magnet configurations and field strengths were tested. Optimum results were obtained with the spiral retrofitted with magnets. The heavy mineral content of the concentrate was increased from 55.5% in the control to 64.2% with the magnets. The 8.7% improvement in heavy mineral recovery was due not only to the weakly-magnetic ilmenite, but also to increased recoveries if the non-magnetic zircon and rutile. The increased recoveries were achieved with no loss of concentrate grade.

Jan 1, 1992

By J. Zhai, Z. Yin

"The electrokinetic and flotation behaviors of ilmenite using lead ions as the activator and sodium oleate as the collector were studied. The results of microflotation show that the flotability of ilmenite can be improved by lead ions obviously. The isoelectric point of ilmenite increases from 5.32 to 7.7 after the addition of lead ions because of the adsorption of Pb2+ and Pb(OH)+. The results of zeta potential measurements and the collector adsorption density calculation show that the adsorption of sodium oleate on the ilmenite surface via chemisorptions in addition to electrostatic interactions. Besides, the adsorption density calculation results show that as the addition of lead ions as the activator, the adsorption amounts of collector are greater than those without activation which is in aggrement with the flotation behaviors. INTRODUCTION Ilmenite, as an oxide mineral of formula FeTiO3, is usually used as the main resource of the extraction of titanium (Bulatovic and Wyslouzil, 1999). There are many researches showing that the conventional methods, such as gravity separation, magnetic separation and flotation, do not work efficiently as expected (Mehdilo et al., 2015; Zhu et al., 2011). Nowadays, to produce ilmenite concentration feasibly and efficiently, these separation methods above are combined for a reason that the raw ilmenite ores are characteristic of poor, fine and complicated. Moreover, surface modification, such as surface dissolution method, microwave irradiation and oxidation roasting, is applied to improve the flotability of ilmenite currently (Welham and Llewellyn, 1998; Zhang and Ostrovski, 2002). Generally, fatty acid salts are used as the collector for the flotation of oxide minerals and sodium oleate is usually used as the collector for the flotation of imenite ores (Fuerstenau and Pradip, 2005). The mechanism, such as individual ion electrostatic adsorption, chemical adsorption, ion–molecule dimeric complex adsorption, and the coadsorption of ion and molecule, have not been discussed systematically using sodium oleate as the collector in the flotation of ilmenite (Somasundaran, 1983). Under the activation circumstance using the lead ion as the activator and sodium oleate as the collector, the interaction mechanism seems to be still unclear. In the present study, the interaction mechanism between ilmenite and sodium oleate using lead ion as the activator are studied by microflotation, zeta potential measurements and adsorption density calculation. EXPERIMENTAL Materials and reagents Pure ilmenite minerals were obtained from Panzhihua, Sichuan province, China. The minerals were ground in a porcelain mill with an agate ball. Following that, the prosucts were sieved, and the samples of -0.074+0.038 mm size fraction were used for the microflotation experiments. The results of XRF show that the content of titanium element is 30.58%, showing that the purity of ilmenite is above 90%. On the basis of the results of XRF, it is determined that the purity of ilmenite is very high and meets the needs of microflotation"

Jan 1, 2017

By R. Mensah-Biney

The kinetics of loading of gold from bromide solution onto an anion exchange resin, PAZ-4, were investigated in a batch stirred reactor. The initial loading rate was described mathematically by a first-order reaction rate equation. The effect of agitation speed, temperature, resin particle size, resin concentration, initial concentration of gold and bromine in solution on the rate was investigated. The model described fairly accurately the loading process in terms of the variables investigated. The rate constant for the initial loading ranged from 0.5 to 1.3 x10-3 sec-1 and the half-time was 9.3 to 56 minutes. The initial rate constant increased with increasing temperature with an activation energy of 15.7 kJ/mole (3.8 kcal/mole). The rate constant was directly proportional to the concentration of the resin in solution. The subsequent reduction reaction was also modeled by the first-order rate equation and the apparent rate constant was estimated to be 3.0 x 10-6 sec-1 with a half-time of about 44 hours.

Jan 1, 1994

By T. G. Carnahan

The U.S. Department of the Interior, Bureau of Mines, performed a laboratory-scale investigation of technique for recovering silver from pregnant solutions generated in the hydrometallurgical treatment of complex base-metal sulfide concentrates with oxidizing chloride media. This provides a means for recovery and simplified reduction of accessory silver to metal from ions. The method consists of adding NaI or KI to the solution to precipitate AgI, which is then contacted with Na2S to produce Ag2S and to regenerate the iodide salt solution. Silver recoveries range from 99 pct with 20 pct excess iodide precipitant, to-92 pct when the theoretical stoichiometric amount of precipitant is employed. The Ag2S product can be reduced to silver metal by contact with aluminum chips in NaOH solution followed by purification with conventional fire refining techniques.

Jan 1, 1980

By S. K. Kawatra, V. Claremboux, S. Valluri

Carbon dioxide capture from coal-fired power plant flue gas and subsequent sequestration is expected to play a vital role in mitigating global climate change. To meet the growing need for CO2 capture Technology, Michigan Technological University is researching CO2 capture and Utilization. We have successfully converted CO2 into oxalic acid using an electrochemical approach. If oxalic acid can be produced in bulk from CO2, it can be used to leach rare earth minerals at low cost. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. In this paper, we will present an idea of how the factors mentioned above will effect the electrochemical reduction of CO2 to Oxalic acid. INTRODUCTION. CO2 is thermodynamically quite stable, as shown by its highly negative heat of formation. Thus, it is expected that the formation of any useful chemical from CO2 will require the input of at least as much energy as geological sequestration. However, to be more effective the resulting economic value of the chemical need only pass the cost of the additional energy required beyond geological sequestration. This lends itself to two extremes: one where the quantity of energy required is low and one where the economic value of the additional energy is low. It is expected that CO2 can be reduced via electrolysis to several compounds. Of particular interest are formic acid, oxalic acid, methanol, ethanol, formaldehyde, and carbon monoxide (as a component to syn-gas). These chemicals have been reported as electrolytic products previously in literature and have considerable potential for application. EXPERIMENTAL Electrocatalytic Production of Oxalate from CO2 We are using membrane electrolysis cell to produce oxalate from CO2. A membrane electrolysis cell is a 2-chamber electrolysis cell where the chambers are separated by a selectively permeable membrane. To produce oxalate, a cation exchange membrane (which selectively exchanges cations) was used. Previous literature suggests that in the cathode chamber an organic electrolyte, such as tetraethylammonium perchlorate or tetraethylammonium bromide in dimethylformamide, are preferred3. In the anode chamber, a sodium hydroxide solution water is used. Carbon dioxide is then bubbled into the cathode chamber as a current is applied.

Jan 1, 2019

By A. E. Halim, J. F. Brune

The 2006 Sago, Darby, and Aracoma mine disasters in the United States (US) forced the US government to implement the 2006 MINER Act and additional regulations that require all US underground coal mines to install and maintain refuge chambers to manage entrapment emergencies, in particular, fires and explosions. However, there is a debate on whether barricading in refuge chambers is a good strategy to survive such emergencies. Australian coal mines are not required to use refuge chambers and, instead, have adopted a strategy that focuses on instructing and training miners to self-escape to the surface. This paper analyzes merits and problems of using refuge chambers and self-escape to the surface to manage emergencies in fires or explosions in an underground coal mine. The authors found that the use of refuge chambers may not be the best strategy during extensive fires or when multiple explosions happen. In these situations, mine rescuers are unlikely able to extract miners who are sheltered in chambers and conversely, self-escape may save more lives than sheltering. Chances for successful self-escape are further improved by regular, externally assessed training such as Level 1 Emergency Exercises required in the Australian State of Queensland. These exercises put pressure on mine operators to ensure and maintain the effectiveness of their emergency management system.

By Jonathan G. Price

Silver-copper-lead deposlts in Precambrian, Permian, and Cretaceous red-bed sequences near Van Horn, Texas, have the following features In common: (1) mineralization controlled by steeply dipping fractures in sandstones, (2) lack of ore In overlying and interbedded limestones, (3) absence of igneous intrusions, (4) sulfide ores without typical hydrothermal gangue minerals, and (5) associated arsenic, molybdenum, zinc, and cadmium but not gold. Ore was probably deposited along fractures by reaction between low-temperature, oxidizing, metal-rich ground waters and sulfide-bearing waters or rocks. Detailed mapping and studies of fracture patterns indicate that mineralization occurred during Basin and Range extensional deformation, thereby postdating major Trans-Pecos igneous activity.

Jan 1, 1983

By John B. Gustavson

Gold was first discovered in Alabama in 1830. Before a decade had passed more than 20,000 people were employed in the various gold districts scattered across east-central Alabama. By 1849 most of the presently defined gold districts were known with such towns as Arbacoochee, Chulafinnee, Goldville, Pinetucky, and Idaho being the principal mining camps. The California gold rush of 1849 signaled the end of intensive prospecting in the Alabama Piedmont for the precious metal. Reactivation of many of the old gold districts has been attempted several times since 1849. Significant activity and development took place between 1874 and 1880, 1888 and 1916, and 1929 and 1936. Locally, some of the development met with moderate succes. The last productive gold mine in Alabama ceased production in 1935. The sharp increase in gold prices since 1973 has caused renewed interest in the potential values of gold of the Alabama gold districts. Most of the gold workings have been abandoned for nearly 75 years and are for the most part inaccessible for convential property evaluation. The early gold miners and prospectors in Alabama were more intent upon finding and mining the valuable metal than in recording their activities for future generations. No matter how interesting or historically significant these records might have been the miners kept no records and left behind them few maps as clues to their activities. Inasmuch as most of the old gold districts have been extensively mined and prospected during the past 150 years, there is very little chance of finding large deposits through conventional outcrop prospecting methods. Similarly, the present geologic knowledge of the various districts is insufficient to launch successful exploration programs looking for large blind lode deposits in new locations within the general gold bearing region.

Jan 1, 1975

By Jan Wolski

Increasing interest in the Bucket Wheel Excavator (BWE) technology calls for a universally understandable definition of suitable performance factors which would reflect the unique features of this technology. The importance of properly designed and calculated performance factors for the BWE systems cannot be overemphasised. They are used by all levels of management in any mining organization for a wide variety of purposes, in particular for budgeting, for selecting new equipment, for monitoring current equipment and for comparison with other operations.

Jan 1, 1984

By Dan S. Nilsson

When an open pit mine is deepened, more and more waste rock must normally be removed. Techniques for optimization of open pit design are well-established within the mining industry. The recommended method is to choose the open pit alternative with the highest net present capital value of open pit and future underground mining. When the open pit is mined out, the operation must be closed, or, if it is profitable, mining must start underground. When planning an underground operation we experience the same type of optimization problem that occurs when determining the optimal depth for open pit mining. When mining underground the ore body is often divided into a number of areas, blocks or slices, each containing a transportation system with trains, trucks, conveyors, etc. When all the ore within such a part of the deposit is extracted, the operation must be closed, or, if it is profitable, a new transportation must be developed. The question that now arises is: how large a pan of a deposit shall be included in the first development and how much shall be left for future consideration?

Jan 1, 1981

By M. Tamlin

The state of the lithium mineral industry is closely linked to the performance of the glass and ceramic industries and to the overall economy. Demand for the glass/ceramic products in Europe, Asia and North America remained strong during 1999. This was due to a slight improvement in the economy during the latter half of the year. Consequently, demand for lithium minerals was firm, with a positive outlook. The major economic minerals for lithium are spodumene, petalite and lepidolite. The latter was once the primary mineral. But its importance hasdeclined since the 1960s. The lithium industry consists of two different segments: •The lithium minerals segment mines from hard-rock deposits and physically processes the material to high-grade concentrates. •The lithium chemicals and metal industry segment. The major feedstock for specialty lithium chemicals was previously high-grade spodumene ore converted to lithium carbonate. However, most lithium carbonate is now sourced from salars in North and South America.

Jan 1, 2000

By Richard M. Crowell

"As thorough sampling is usually expensive, the cost of a complete job is often unwarranted, and a cheaper approximation must be substituted. The engineer should, however, weigh the situation thoroughly before subscribing to an alternative other than an accurate assay basis on which to build his conclusion." Examination and Valuation of Mineral Property. R. Parks, 1949

Jan 1, 1994

By Thomas R. Kuesel

Just south of the L'Enfant Station in Seventh Street, the WMATA system splits into two branches, each comprising twin single-track soft ground tunnels. Immediately at the beginning of the section, Interstate Route 95 crosses transversely over the alignment in open cut, removing most of the cover over the tunnels. Seventh Street spans I-95 on a bridge whose abutments and pier also cross transversely over the four tunnels, with their footings as little as 7 feet above the tunnel crown (Figure 1). Soil investigations revealed that the tunnels would have to be driven through mixed face, with a clay invert and a waterlogged sand crown. Thus, there was a good chance that the roof would fall in, leaving 1-95 and the Seventh Street Bridge in a crater. Since there was no roof that could be counted on, these were figuratively (and potentially truly) Washington Metro's Topless Tunnels (Figures 2 and 3). DESIGN ALTERNATIVES Faced with this situation, the designers considered several options, including temporary detours that would permit demolition of the bridge and building tunnels under the 1-95 Freeway by cut-and-cover methods. They also investigated structural underpinning of the bridge and freeway pavement, and strengthening the bridge abutments and center pier by post-tensioning to enable them to span over any subsidence trough.

Jan 1, 1976

By J. P. H. Steele, T. Vincent, C. Debrunner, M. Whitehorn

For a variety of reasons, the need for automation of underground mining equipment is growing dramatically, e.g., improved safety and health, availability of labor, deeper mines, and desire for more focused excavation. While there has been tremendous progress made in this direction, much needs to be done to reach the holy grail of an autonomous mining machine. This paper reviews a number of technological developments and presents research and development needs for future development. A report on our current project for the Western Mining Resource Center at CSM is included.

Jan 1, 2000

By HONGWEI YANG, Lili Zhang

The oxidation behavior of copper smelting slag under non-isothermal conditions was studied by thermal analysis. The results indicate that the copper slag is mainly composed of fayalite ( Fe2SiO4) and magnetite ( Fe3O4). The oxidation behavior can be divided into two reaction stages with the increase in temperature; the first stage is the oxidation of fayalite to magnetite, and the second stage is the oxidation of magnetite to hematite. The two reaction stages cannot be strictly separated; that is, the reaction of fayalite is not complete, and magnetite has begun to transform into hematite. Based on the TG (thermogravimetric) curves, the ABS (Achar–Brindley–Sharp–Wendworth) differential and the Coats–Redfern integral methods were employed to investigate the oxidation kinetics of copper slag during the continuous heating process. The oxidation of fayalite into magnetite and amorphous silica phases occurs mainly in the temperature range of 673 to 1083 K. The activation energies calculated by the two methods are 193.69 and 195.52 kJ mol− 1, respectively. The reaction is consistent with Avrami–Erofeev equation, and the mechanism of oxidation is random nucleation and growth. The oxidation of magnetite to hematite occurs at 1083–1303 K. The activation energies are 308.79 and 328.77 kJ mol− 1, respectively. The mechanism conforms to the Jander equation and is controlled by the two-dimensional diffusion.

May 16, 2022

By Orville D. Mussey

During, 1956 the water used in mining iron ore in the United States amounted to about 2 billion gallons and the water used in producing iron concentrates-amounted to about 166 billion gallons. By 1980 an increase of about 65 percent is anticipated in the amount of water used for mining and beneficiating iron ore. Except for boiler-feed makeup water the quality requirements for water, for mining and beneficiating iron ores are not stringent. Adequate supplies. of water for development should be available at reasonable cost with the possible exception of some in arid regions.

Jan 1, 1961

By J. D. Vincent

The Mission By-Products Plant at the Mission Concentrator of the American Smelting and Refining Company, some 20 miles south of Tucson, Arizona in the Twin Buttes mining area, has been in operation slightly over a year. The plant produces a molybdenite concentrate a copper concentrate and, at times, a zinc concentrate. An intensive test program of over three years was conducted at Mission to make the recovery of molybdenum economic. Briefly it was found necessary to make a scavenger concentrate in the copper mill before it was possible to recover economic quantities of molybdenite. By so doing there were resulting additional recoveries of copper, silver and zinc. This program resulted in the design and construction of the existing plant. A paper by the authors discussing the test work and the design was presented at the, October 1965 meeting of the American Mining Congress in Las Vegas, Nevada, by Mr. Wayne Bossard.

Jan 1, 1966