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By Paul S. Korinko, Simona E. Hunyadi Murph

To address a radiological contamination event, a materials and process project was initiated. During the course of this project, processes and materials were developed that successfully captured zinc vapors physically and chemically, respectively. However, the physical traps were placed in an undesirable area and it was determined that the chemically captured zinc reactions was reversible. Consequently, advanced nanomaterials are being developed to capture zinc vapors. The current state of the art of the science and engineering of these materials and their efficacy for zinc capture and retention is discussed in this paper.

Jan 1, 2015

Kosaka Smelter & Refinery has a history of more than a century as a metallurgical department belonging to Kosaka mine. It has treated for a long time the "Black Ore" or the complicated concentrates dressed from it. The "Black Ore" is composed of black sulfides. It contains not only valuable metals such as gold, silver, copper, lead and zinc but also some impurities like arsenic, antimony and bismuth. With the development of Kosaka's floatation technology, five kinds of concentrates (copper, zinc, lead, pyrite and barite) have been separated from the "Black Ore" but the separation was not complete and each concentrate contained some unfavorable impuritie. In 1980s the highly appreciated yen and the drop of the metals priees forced many domestic mines to close their operations. Since then Kosaka Smelter has changed its way of operation to a custom smelter. Now more than 95% of copper concentrates are imported to take advantage of this technology of "Black Ore" treatment. It mainly treats the raw materials that contain high gold and silver like the "Black Ore". Recently, Kosaka has been working on the recycling of the metals from the printed circuit board scraps and sludge which contain some precious metals. The volume of the recycled metal is continuously increasing.

Jan 1, 2003

By C. M. F. Vieira

The main characteristics and physical and mechanical properties of clays from the county of Campos dos Goytacazes, located at the northern part of the State of Rio de Janeiro, Brazil, are presented. The characterization included mineralogical composition, chemical composition and particle size distribution. The properties related to water absorption, linear shrinkage and flexural rupture strength were obtained in samples that were prepared by 20 MPa uniaxial pressing and fired at 950 and 1100oC. The results showed that the clays are predominantly kaolinitic with high percentage of clay minerals. The kaolinitic structure associated with a small amount of fluxes confers a refractory behavior which makes difficult the sinterization and impairs the ceramic consolidation.

Jan 1, 2009

By Batric Pesic

The interactions of mineral-pyrite with T. ferrooxidans were studied by using a cyclic voltametry technique. The interactions with bacteria were carefully examined during the entire growth stage of bacteria (fermentation). Several very important discoveries were made. For example, the pyrite surface invariably drastically changed its properties at the second day of fermentation. Beyond two days of fermentation, the cyclic voltamograms were insensitive to convective diffusion produced by stirring. The SEM study revealed that bacteria populated the pyrite surface at an extremely high density levels. The high density of bacteria, and the solid reaction products formed on the pyrite surface created conditions for pore diffusion which explained why the CVs became insensitive to convective diffusion in solution (stirring).

Jan 1, 1990

By Cynthia Belt

"Before energy can be saved in the materials industry, the process must be understood. At the same time, baby boomers are starting to retire. New people are entering the field without experience and training especially in methods to save energy. Various classroom courses, seminars, books, software, and websites are available for the professional to better understand the industry with the ultimate goal to reduce energy use. This paper is a review of what is currently available with some comments on potential needs.IntroductionEnergy use is high within the materials industry. For the United States, the primary metal industry uses 8% of all energy used in manufacturing (Figure 1 )1 or 1, 736 trillion BTUs per year. Sadly, while energy use is high, energy management is not universal within the industry. Counting both internal programs and external such as the utility supplier, equipment manufacturers, federal and state programs, only 66% of primary metals companies participate in an energy management activity1.For the materials field, process heating is the majority of the energy use in a plant2. Understanding and optimizing process heating is a critical need for materials energy professionals. Surprisingly, process heating is not necessarily the work addressed within an energy program. The U.S. 2006 Manufacturing Energy Consumption Survey (see Table 1) found more primary metal companies addressing lighting with 31 % participation versus 15% with process heating work even though energy used in lighting tends to be a minor (in the range ofl-3% ofa typical plant's energy use)."

Jan 1, 2013

By Nobuo Takahashi

Effective solvent extraction media have been investigated for purification of rare earths. At first, a quaternary ammonium compound was studied. The counter anions of rare earths and organic dielectric substances were tested to improve separation factors,. And second, crown ethers were selected for extractant. Several diluents of crown-adducts were tested to improve solubility and distribution coefficient as well as the counter anions of rare earths. Especially, in the presence of strong reducing agents, highly selective extraction of europium from other rare earths was observed. The third extactnts were ß -diketones. Presence of organic dielectric substances was very effective to improve separation factors. Though those. three groups of extractants were suitable for mutual separation of light rare earths, alkyl esters of alkyl-phosphonic acids were suitable for mutual separation of heavy rare earths because of their high separation factors. To keep proper pH value was necessary for acidic extractants, so control method of the solution pH was studied with high molecule insoluble amines or salts of those.

Jan 1, 1995

By C. Ramasamy

The tariff reductions on imports, as a part of on-going liberalisation process in India, has fueled competition within and outside India and has, in turn provided an opportunity to reach global markets. This change calls for quality upgrades and cost-competitiveness without impairing the environment. In this context, gas based processes, contributing to improvement in quality and environment as well as processes where controls are applied when gases inimical to environment are involved, are discussed in a remelt/cast-house scenario. The impact of such processes on fabrication cost of sheet ingot is seen alongwith consumption and cost of materials and compared with a world class standard plant in North America.

Jan 1, 1996

By George A. Calboreanu

In order to overcome drilling and tapping of high hardness wear resistent material in slurry pumps, most of time mild steel inserts are mounted in the mold and after pouring they become an integrated part of the casting. This process is limiting the size and design possibilities of slurry pumps and efforts were made to drill and tap the hard iron itself. The paper will present practical results obtained in drilling and tapping Cr-Mo wear resistent material with hardness in excess of 700 HBN. The life time of the slurry pump parts used in hazardous waste fuel transportation with high slurry velocity and 15% solid loading some of it being quartz, increased 2.5 to 6 times.

Jan 1, 1996

By Andrzej Warczok

Intensive smelting of copper concentrate in Teniente Converter (CT) leads to the production of high grade matte and highly oxidized slag. Smelting slag is processed in Teniente vascular slag cleaning furnace. The slag composition and forms of copper affect the slag cleaning process and final copper content. Converting of high grade matte in Pierce-Smith converter faces some difficulties in proper slagging of iron oxides. Overblowing in copper making stage allows for slag liquidation but leads to high content of copper oxide in converter slag. Converter slag recycling into CT results in the increase of the participation of oxidic copper. Separate treatment of converter slag and its impact on the forms of copper in CT slag has been analyzed. Thermodynamic properties of a system and kinetic limitations pointed out the negative effect of converter slag recycling on the forms of copper and copper recovery in slag cleaning stage. Experimental results of slag cleaning tests in a crucible scale as well as microscopic examination of laboratory and industrial slag samples supported the above analysis and permitted to formulate recommendations of separate processing of converter slag. Keywords: copper, losses, slag, recycling

Jan 1, 2001

By Vinod K. Sikka, René Cooper

"Cohoes, New York 12047 Intermetallics are an attractive class of advanced materials. The aluminide intermetallics offer advantages including: (1) lower density, (2) oxidation resistance, (3) carburization resistance, and (4) interesting mechanical properties because of their ordered crystal structure. Even though the attractive properties of the aluminides and other intermetallics have been known for nearly four decades, their practical applications have not been developed for two reasons: (1) the poor ductility (in some cases, both ambient and high temperatures) and (2) the lack of processability into meaningful components. Recent advances such as ductilization of Ni3Al by small additions of boron and the knowledge that environmental effects are the major cause of poor ductility in Fe3Al and FeAl systems have brought the intelmetallics into the forefront of research and their commercial applications. This paper has described a method for melting Ni3AI-based alloys that successfully utilize the exotherrn for the formation of NiAl from the elemental materials. The reaction-synthesis method has also been utilized for the production of NiAI and NiAI-based alloy powders from the elemental powders. The reaction-synthesized powders of NiAI and NiAI-based alloys were consolidated by hot extrusion and evaluated for tensile properties over a temperature range from room temperature to 1050ºC. The powder-processing conditions have been found to have more influence on the ductile-to-brittle transition temperature of NiAI than the powder-production method.IntroductionIntermetallics are an attractive class of advanced materials [1-11]. The alum in ide interrnetallics offer advantages including: (1) lower density, (2) oxidation resistance, (3) carburization resistance, and (4) interesting mechanical properties because of their ordered crystal structure. Even though the attractive properties of the aluminides and other interrnetallics have been known for nearly four decades, their practical applications have not been developed for two reasons: (I) the poor ductility (in some cases, both ambient and high temperatures) and (2) the lack of processability into meaningful components. Recent advances such as ductilization of Ni3Al by small additions of boron and the knowledge that environmental effects are the major cause of poor ductility in Fe3Al and FeAl systems have brought the intermetallics into the forefront of research and their commercial applications. The paper will briefly review the processing techniques being pursued for the commercial applications of Ni3Al-based intermetallics. The major emphasis of the paper will deal with synthesis of Ni3Al and NiAI intelmetallics."

Jan 1, 1994

By D. M. Jones

Dust generation data have been obtained from 19 industrial Outokumpu flash furnaces. Statistical analyses of the data have been carried out and the most significant factors affecting dust generation evaluated. The results indicate that dust production may most effectively be minimized by: 1) Minimizing the distance between the molten slag and the furnace roof 2) Optimizing burner design and combustion parameters.

Jan 1, 1996

By Masanori Abe, Yoshitaka Kitamoto, Kazuhiro Nishimura

"Ferrite plating is a chemical processing which utilizes Fe2+ - Fe3+ oxidation to synthesizing polycrystalline films of ferromagnetic spinels (MFe20 4, M = Fe, Co, Ni, Zn, Al, Cr, TI, etc:) directly from an aqueous solution at 24 - 100°C. This low temperature process allows us to fabricate new ferrite film devices on · substrates of such non-heat-resistant materials as plastics, GaAs integrated circuits, and biomaterials. Synthesized from an aqueous solution the ferrite plated ·films are highly biocompatible. Thus various magnetic device and biomedical applications have been proposed and realized using ferrite-plated films. Ferrite-encapsulated polymer microspheres are applied to antibody carries for enzyme immunoassay, and also to toners/carriers for photocopying. Perpendicular magnetic recording media utilizing plated CoNi ferrite films are proposed. The low-temperature synthesized films of NiZn and Co ferrites are potentially used as soft-magnetic and/or insulating layers, respectively at high/microwave frequencies.IntroductionFerrite plating is a processing which facilitates the formation of crystalline spinel ferrite films with various compositions, (Fe, M)30 4 (M = Fe, Co, Ni, Zn, Al, Cr, TI, etc.), directly from an aqueous solution at 60 - 100°C [1]. This opened the door to fabricating novel ferrite-film devices using substrates of such non-heat-resistant materials as plastics and GaAs integrated circuits [2-4]; conventional ferrite film preparation techniques such as sputtering, vacuum evaporation, MBE, LPE, etc., require high temperatures(> -600°C) for crystallization of ferrites, which deteriorates the non-heat-resistant substrates. Recently we extended ferrite plating to be preformed at room temperature [5, 6]. This enables us to use as substrates such organic materials as biomaterials (e.g. enzymes) having very low heat-resistance."

Jan 1, 2000

By Thais Cristina da Costa Caldas, Alline Sardinha Cordeiro Morais, Carlos Maurício Fontes Vieira, Sergio Neves Monteiro

"This work has as its objective to evaluate the firing behavior of a kaolinitic clayey body from Campos dos Goytacazes-RJ incorporated with flat glass waste (FGW) from civil construction. Incorporations of the waste, with a particle size less than 74 µm (200 mesh), were performed in the red ceramic in the following amounts: 0, 2.5, 5 and 10 wt%. Specimens were prepared by uniaxial press-molding and then fired at 850 and 1050°C. The characterization of FGW was done by X-ray Fluorescence. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural rupture strength. The microstructure of the fired ceramics was evaluated by optical microscopy (OM). The obtained results showed that the flat glass waste can be used as a component of ceramic bodies once it was noticed tolerable modifications of technological behavior.IntroductionBrazil is one of the world’s largest producers and consumers of clayey ceramic. Campos dos Goytacazes is located in the north of the State of Rio de Janeiro, southeast of Brazil, it’s known as a large producer of red ceramics. It is estimated that the production of bricks can reach 1 billion pieces per year [1].Nowadays, recycling processes became more and more important, due the generation of wastes in large scale and the preoccupation with environmental. The amount of glass waste has been exponentially growing with the growth of the population. It is estimated that the amount of discarded glass as bottles, construction windows, packing and other glass waste represented in 2006 an amount of 7.5% of the total weight of the world´s domestic garbage [2]."

Jan 1, 2012

By Kathryn C. Sole

A novel solvent-extraction process for the refining of gold was recently commercialised, with the commissioning in May 1997 of a 24 t a-' refinery at Harmony Gold Mine in Virginia, South Africa. The MinataurTM Process (Mintek Alternative Technology for Au Refining) uses solvent-extraction technology to produce gold of 99.99% purity from the cathode sludge arising from a conventional carbon-in-pulp / electrowinning circuit. Implementation of this process introduces significant cost benefits compared with the conventional dore smelting / toll-refining route previously followed. This paper outlines the process, presents selected operating results obtained during the first few months of operation, and provides some details of the associated techno-economic advantages.

Jan 1, 1998

By M. L. Cunha

The lack of control of As and Sb compounds from copper smelters and converters has rendered some chalcopyrite containing arsenopyrite, stibnite and tetrahedrite minerals unusable for metal extraction. In the present investigation, we have studied the carbothennic reduction of Portuguese chalcopyrite mineral concentrate in the presence of lime/CaS04 and CaS04/Si02. Thermodynamic equilibrium calculations were performed to study the distribution of As and Sb between metal and the CaO-Si02-FeO slag phase. The phase equilibrium calculations also show the effect of oxygen partial pressure on the increase in the volume of the slag phase, which helps in lowering the copper metal formation temperature and facilitates a better separation between metal, matte and slag. The reduction reaction kinetics was studied between 850°C and 1100 °C, and the phases formed were identified by X-ray powder diffraction and scanning electron microscopy techniques. The importance of this research for using recycled matte, lean and rich minerals with As and Sb is also explained.

Jan 1, 2001

By R. E. Moore

The lining systems currently in use in BOF furnaces, certain steel ladles, and the slag line of electric are furnaces were developed during the late seventies through the mid-eighties using a trial and error method of combining aggregate, carbon sources, additives and binders. They are currently based on magnesia, graphite, metal additives and resin binders, the selections of each being tied to the anticipated intensity of the use conditions. The general functions of the respective constituents are well appreciated, however, there is still a great deal that is not known about how the socalled antioxidants protect the graphite nor how impurities from the graphite and the aggregate enter into the wear processes. In a simplified assessment of wear processes, it appears that if the deoxidized layer can be kept very thin, less than 810 mm in depth, and if the viscosity and quantity of the matrix glassy phases can be controlled to resist erosion of the deoxidized layer, lining life can be maximized for the various applications. This paper will discuss the characteristics of the starting materials systems currently being employed for applications requiring a deoxidation function to realize extended wear. It will not attempt to explain all the complex interrelationships between the respective constituents but will point to the potential for improvements through the use of improved constituents.

Jan 1, 1991

By T. T. Nguyen, D. R. Gunasegaram, D. Celentano

"Heat transfer rates at the casting-mold interface are believed to be substantially reduced by the formation of an interfacial gap during the course of solidification of aluminum alloys in permanent molds. In the current work, the effect of force-cooling a permanent composite mold on (i) the initiation and growth characteristics of the gap and (ii) interfacial heat transfer rates are studied. Interesting comparisons are made with the case where no cooling is employed. Casting and mold displacements are measured using L VDTs, and the mold is force-cooled by air jets.IntroductionIn a gravity casting situation where an aluminum alloy solidifies in a permanent mold, a gap initiates and grows between the shrinking casting and the expanding mold (1). It is widely believed that the formation of this gap, customarily referred to as an 'air gap', results in a substantial reduction in the heat transfer coefficient at the casting-mold interface (2), and hence is an important factor in solidification studies.The nature of the air gap formation process is thermo-mechanical. The rate of heat loss from the casting first determines the rate of solidification, which, in turn, decides when the gap initiates. The reason for this is the requirement for the solidified casting surface 'skin' to gain sufficient thickness, and hence strength, to be self-supporting. Once the gap initiates, the gap width controls the rate of heat loss from the casting, which, again, determines the rate at which the gap expands."

Jan 1, 1997

By Norihiro Murayama

Syntheses of zeolitic materials were carried out from coal fly ash by alkali hydrothermal treatment as part of the reuse and recycle technologies of coal ash, For the obtained zeolites, the cation exchange capacity and acid resistance, which are very important in the practical use of cation exchanger in aqueous solution, are investigated during this stufY, The cation exchange amounts of the NaP, CaP and K-CHA zeolites are measured for various cations such as K+, Na +, NH4+ Ca2+, Mg2+, Pb2+, Cd2+ and so on. The change in crystallization degree are researched as a function of pH. The simultaneous removal ability of NH4+ and PO43- in solution is examined for an example of the water purification with CaP zeolite. From these results, the characteristic and its mechanism of cation exchange are clarified for the various zeolitic materials obtained from coal fly ash.

Jan 1, 2003

By Thais Cristina da Costa Caldas, Carlos Mauricio Fontes Vieira, Alline Sardinha Cordeiro Morais, Sergio Neves Monteiro

"This work has as its objective to evaluate the effect of the incorporation of a glass powder waste obtained from discarded and Hg-cleaned fluorescent lamp into clayey ceramics used to fabricate bricks and roofing tiles. Formulations were prepared with incorporation of the waste in amounts up to 10 wt.% into the clayey body. Rectangular specimens were prepared by uniaxial mold-press at 20 MPa to fire at 850 and 1050°C. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural rupture strength. The microstructure of the fired ceramics was evaluated by optical microscopy. The results showed that the waste incorporation significantly improved the evaluated properties mainly at 1050°C.IntroductionFluorescent lamps use mercury as a main component for its operation. This metal is potentially toxic and can contaminate soils, animals and water bodies. The problem is aggravated if considerations are made with respect to the amount of lamps that are commercialized and discharged in emergent countries like Brazil [ 1].By using appropriate recycling processes applied to discharging fluorescent lamps it is possible to reuse most constituents of these lamps into new productive processes. A study has shown that one million common fluorescent lamps can generate 900,000 tubes of clean glass [2]. Moreover, this Hg-cleaned gloss may be recycled in different products.In fact, to recovery and recycle all materials that constitute the lamp instead of discharging them. This action protects the soil avoiding the formation of environmental passives [3]. It is also relevant to mention that the glass from fluorescent lamps is 100% recyclable while its permanence in the environment would correspond to very long time pollution, since its decomposition time is undetermined [4]."

Jan 1, 2011

By Ernt. W. D.

A membrane based mixed extractant process was developed for selective removal of copper from waste acidic cupric chloride etchant solutions found in printed wire board manufacturing. The process uses a mixture of Adogen 381 (tri-isooctylamine), MOC®-45 (ketoxime) and MOC® 55TD (aldoxime) in a kerosene diluent. The mixed extractants recover the copper from a hydrochloric acid medium and transfers it to a sulfuric acid medium. The process also utilizes unique wetted membranes to separate the aqueous and organic phases. The driving force for these membranes is not pressure but the difference in surface tension between the two phases. By using these membranes, complete phase separation results. There is no physical entrainment contamination as found in conventional systems. The only cross contamination is the solubility concentration of one phase in the other. This however is less than 10 mg/l.

Jan 1, 1998