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Researchers from the National Institute for Occupational Safety and Health (NIOSH) are developing a coal pillar rib rating (CPRR) technique to measure the integrity of coal ribs. The CPRR characterizes the rib composition and evaluates its impact on the inherent stability of the coal ribs. The CPRR utilizes four parameters: rib homogeneity, bedding condition, face cleat orientation with respect to entry direction, and rib height. All these parameters are measurable in the field. A rib data collecting procedure and a simple sheet to calculate the CPRR were developed.

Jan 7, 2020

Accurately estimating load distributions and ground responses around underground openings play a significant role in the safety of the operations in underground mines. Adequately designing pillars and other support measures relies highly on the accurate assessment of the loads that will be carried by them, as well as the load-bearing capacities of the supports. There are various methods that can be used to approximate mining-induced loads in stratified rock masses to be used in pillar design. The empirical methods are based on equations derived from large databases of various case studies. They are implemented in government-approved design tools and are widely used. There are also analytical and numerical techniques used for more detailed analysis of the induced loads. In this study, two different longwall mines with different panel width-to-depth ratios are analyzed using different methods. The empirical method used in the analysis is the square decay stress function that uses the abutment angle concept, implemented in pillar design software developed by the National Institute for Occupational Safety and Health (NIOSH). The first numerical method used in the analysis is a displacement-discontinuity (DD) variation of the boundaryelement method, LaModel, which utilizes the laminated overburden model (Heasley, 1998).

Jan 7, 2020

Longwall mining has existed in Utah for more than half a century. Much of this mining occurred at depths of cover that significantly exceed those encountered by most other U.S. longwall operations. Deep cover causes high ground stress, which can combine with geology to create a coal burst hazard. Nearly every longwall mine operating within the Utah’s Book Cliffs coalfield has been affected by coal bursts.

Jan 7, 2020

To gather additional field data from the western United States, researchers from the National Institute for Occupational Safety and Health (NIOSH) installed an array of field instrumentation at a longwall coal mine in Central Utah. The purpose of this field site was to monitor ground movement and changes in pressure during mining where conditions include massive, stiff overburden and relatively deep cover. To accomplish this, field instrumentation was installed in the two-entry gate road between the fifth and sixth longwall panel in the current mining district.

Jan 7, 2020

By VIVEK KUMAR HIMANSHU, M. P. Roy, P. K. Singh, A. K. Mishra, RAVI SHANKAR

Blasting with the aim to reduce oversize boulders in underground has many hurdles due to limited accessibilities and poor site conditions. Optimized drilling and blasting parameters can help to achieve this objective. The major challenges of the blast designers lie within deciding blast geometry, namely drill hole diameter, burden, and spacing. The general approaches covered worldwide to determine burden-spacing are based on various rules of thumb, which are based on previous experiences of blasts and the associated outcomes. However, many parameters influencing optimum burden-spacing to achieve desired fragment size are site specific. Sometimes drill geometry is decided based on associated blasting hazards rather than rock fragmentation. The Kuz–Ram model is a worldwide accepted rock fragmentation predictor. The parameters associated with this predictor also include burden-spacing for a blast. Back calculation of burden-spacing from the Kuz–Ram model can be used to achieve desired fragment size. This paper deals with burden-spacing determination by using an empirical approach for the underground stope ring blasting.

Jan 4, 2020

By J Taguta, B. McFadzean, P. E. Ngoepe, M. G. Mulaudzi

Computational modelling methods and isothermal titration calorimetry (ITC) were employed to investigate the interaction of a pyrite surface with thiol collectors. Modelling work was conducted in the presence and absence of water. Microcalorimetry was employed to investigate the resultant energy of interaction pyrite as a result of mineral-collector interactions. Sodium ethyl xanthate (SEX), diethyldithiocarbamate (DTC) and diethyl dithiophosphate (DTP) were investigated in this study. The results showed that the calculated surface energies and morphologies for FeS2 showed that (100) and (111) are the most stable surfaces. The morphology also indicated the appearance of the (100) and (111) surface facets and no presence of others. The calculated adsorption energies between thiol collectors and the pyrite surface were always more exothermic than the experimentally determined ones. When comparing different ligand types with the same alkyl chain length, the heat of adsorption of diethyl-DTC was greater than that of ethyl xanthate and diethyl-DTP for pyrite. Experimentally, the diethyl DTP barely adsorbed onto the pyrite surface and this may be due to a different mechanism of action. In computational calculations, water adsorption was found to reduce the reactivity of the Fe atom for the interaction with thiol collectors, and bring the adsorption energies closer to the magnitude of the experimental values. Keywords: Computational modelling, microcalorimetry, experimental and thiol collectors, adsorption energies

Jan 1, 2020

By B. Friedrich, A. Birich

Gold has been a metal of special importance for mankind for several thousand years. Its outstanding chemical resistance is an important property of this noble metal, but becomes a disadvantage when it comes to gold recovery. The established processes are based on highly aggressive and toxic reagents. Different alternative leaching reagents with a significantly lower toxicity proved to be promising alternatives in the last decades. Major research activities in this field focused on gold ores, so that leaching of secondary resources were not described sufficiently. Based on literature research and extensive experimental investigations, a reagent assessment was conducted for hydrometallurgical gold recovery from electronic waste. It was found that besides thiourea and halides, thiosulfate in particular represents an alternative of major relevance. A variety of different electronic waste (e-waste) specimens were investigated to identify suitable leaching conditions. As a result, an almost complete and selective gold recovery in less than 48 hours from different electronic waste types and components was achieved by thiosulfate leaching. Within the experiments conducted, it was found that the leaching behaviour of cyanide alternative lixiviants differ strongly from leaching of primary ores. Keywords: Gold leaching, cyanide alternative, thiosulfate, electronic waste

Jan 1, 2020

By F. Nakhaei, Z. Pourkarimi

Tailings produced from the iron ore industry present many challenges due to the high economic and environmental impacts involved with their disposal. However, the relative scarcity of high-grade iron ores has driven manufacturers to recover and recycle these valuable tailings (secondary sources). This study aimed at the purification of ultrafine tailings with high sulphur content from an iron ore concentrator via reverse flotation to produce pellet feed fines. A specially designed flotation column featured with a nano bubble generator and a conventional bubble generator were employed to assess the effects of nano bubbles on the desulfurisation performance of iron ore concentrate under different operating conditions. Results obtained from this study indicated that the sulphur content of iron concentrate could be reduced from 1.2% to 0.22% in the presence of nano bubbles. Also, the results showed that use of nano-micro bubbles increased sulphur recovery 20% more, in comparison to micro bubbles. Keywords: Column flotation, iron ore, tailings, slime, nano bubbles, desulphurisation

Jan 1, 2020

By S. M. H. Haddad, M. Saghaeian, R. Hejazi, V. Sheikhzadeha, A. H. Baladastian, A. Dehghani Ahmadabadi

Sulfide impurities in iron ore concentrates play an important role in designing pelletising and steel making plants. Therefore attempts are made to keep the sulfur content of the final concentrate produced by the plants as low as possible. Generally, in the beneficiation process of iron ore concentrate, the removal of sulfur is performed through magnetic separation systems, followed by reverse flotation. The sulfide content of the iron ore concentrates originated from two main sources, including pyrite and pyrrhotite. In this research, in order to compare the floating capability of these two types of sulfide minerals, two iron ore concentrates with different sulfide constituents, pyrite or pyrrhotite, were selected. Reverse flotation tests were done separately on these samples under similar conditions. Process parameters considered for the tests included pH (2, 4, 6, 8 and 10), collector consumption (150, 200, 250, 300 and 350 g/t) and frother consumption (40, 50, 60, 70 and 80 g/t). Potassium Amyl Xanthate (PAX) and Methyl Isobutyl Carbinol (MIBC) were the collector and frother used in the tests, respectively. For modelling and optimising process parameters, the Central Composite Design (CCD) method was applied to the test results. Empirical coded equations were obtained for responses involving weight recovery, Fe recovery, Fe grade and S grade. Finally, comparison of test results revealed that the elimination recovery of pyrite sulfides was far greater than pyrrhotite sulfides, and it was possible to remove 84% sulfur content of the pyrite sample compared to minus 30% for the pyrrhotite sample. Keywords: Reverse flotation, pyrite and pyrrhotite, sulfur removal, iron ore concentrate, beneficiation plant

Jan 1, 2020

By O. I. Rychkova, M. N. Sycheva, E. V. Poryadochnova, G. V. Sedelnikova

Deposits of copper-porphyry type occupy a leading position in the mineral resource base of the world copper industry. They are characterized by large and gigantic scales, often complex composition, their development is carried out in an open way. The raw material base of the Russian copper industry is mainly sulfide copper-Nickel and copper-pyrite ores. Exploration of copper-porphyry deposits and the creation of long-term large mining facilities on their basis is one of the most promising and priority tasks for the Russian industry. This task is especially acute for the copper enterprises of the Urals in connection with the depletion of copper - pyrite ore reserves. In recent years, Russia has carried out a large complex of studies on the composition and technology of processing of copper-porphyry ores of different subtypes. In this work the complex poor copper-molybdenum-gold ore of one of the deposits is investigated. The chemical and mineral composition of the ore containing 0.49% copper, 0.020% molybdenum, 0.39 g/t gold, 5.85 g/t silver was determined. The forms of finding metals and their distribution by size classes are established. The dependence of extraction of metals into concentrates of collective-selective flotation on the size of ore grinding, pH of the medium, reagent consumption is shown. Under optimal flotation conditions, copper concentrate with 18.6% copper content and 92.32% extraction and molybdenum concentrate with 21.5% molybdenum content and 73.4% extraction were obtained. With a high concentration of molybdenum in selective flotation products, it is possible to conclude about the expected molybdenum concentrate with a content of 45% and a recovery of 70%. The associated extraction of gold and silver into copper concentrate is 76.8 % and 73.4%. Keywords: Collective-selective flotation, copper, molybdenum, porphyry ore, grinding, pH, reagents

Jan 1, 2020

By N. V. Nemchinova, A. A. Kozlov, A. V. Epiforov

The gold dissolution in sulfuric acid media during industrial oxidative leaching test of sulfide gold-copper flotation concentrates has been achieved. The reason for this was using technological water containing thiocyanates and cyanides, which can dissolve gold under these conditions. The carbon in column (CIC) process for gold recovery from these solutions was proposed. However, significant amounts of copper and iron were adsorbed onto the carbon during CIC technology industrial tests. This resulted in a decrease of the gold content in the loaded carbon up to 0.5 kg/t. Further development of the technology was conducted by optimisation of gold and impurities stripping and implementation of carbon reactivation. It was shown, that the copper extraction from the loaded carbon during cyanide treatment was about 95%. The copper content in the stripped carbon after cyanide treatment was 1.76 kg/t. The gold recovery during high-pressure elution by caustic solution was 98%. The hydrochloric acidic treatment with thermal pre-treatment (reactivation) for removing iron and calcium from gold-free carbon was proposed. In this case, the iron and calcium extractions from carbon were 40-45 and 50-55% respectively. These tests showed that for carbon recycling the sequence operations of ‘cyanide treatment, gold elution, thermal pre-treatment, hydrochloric acidic treatment’ can be used. Keywords: Thiocyanate leaching, recovery of gold, carbon adsorption, gold elution, copper stripping, thermal reactivation of carbon, activated carbon, carbon-in-column

Jan 1, 2020

By A. V. Rasskazova

Theoretical substantiation of leaching of clustered ultra-fine gold by the electro-photo activated cyanide and chloride solutions is given in the paper; and processes of activation of leach solution by electrolysis and photo-activation are described. Comparative experiments on electro-photo activated leaching of ultra-fine gold from refractory ores by cyanide and chloride solutions were carried out. The material for research is primary ore of the Pogromnoe deposit (Russian Federation, Trans-Baikal Territory). The ore is characterised by the minimum sulfide minerals and the organic carbon content. Gold in ores of this deposit is presented as mainly ultra-fine. Gold inclusions in quartz and silica-alumina minerals (metasomatic minerals) are ultra-fine. Sulfide minerals (2.5-3%) are presented in ore generally by pyrrhotine (gold content does not exceed 10 g/t). Standard cyanide technology provides 49.5% gold recovery. Photo-electro activated air saturated NaCN provides 69.9% gold recovery. Laboratory research of chloride-hypochlorite column leaching demonstrated that the electro-photo activated method provided 78.9 % gold recovery to pregnant leach solution. Chloride-hypochlorite photo-electro activated solution can provide higher level of gold recovery with shorter process duration (10 days) in comparison with cyanide (40 days). The final decision regarding the choice of leach solution has to be done on the basis of technical and economic calculations. Keywords: Ultra-fine gold, cluster chemical reactions, active clusters, leaching, electro-photo activation of leach solution

Jan 1, 2020

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020

By X. J. Lyu, Q. Liu, M. J. Lian, X. Q. Cao, X. F. You, B. O. Erdenekhuyag, H. Y. Zang

The slag-tailings based artificial reef concrete (ARC) is made of CaO-CaSO4 activated granulated blast furnace slag (GBFS) as cementitious material and deslimed gold ore tailings as aggregate. In order to investigate the potential application of the material as ARC, the strength development, hydration characteristics and application performance were investigated under different preparation conditions. Results indicated that using seawater as the mixing water can effectively promote the hydration of slag and generate a large amount of hydration products such as ettringite, CSH gel, hydrotalcite and Friedel ’s salt in the early curing period and so render the material with good early compressive strength. Seawater curing can also accelerate the hydration reaction in the early stage of hydration. The hydration reaction of slag and the compressive strength of ARC can be effectively promoted by increasing the specific surface area of slag. The 28-day compressive strength of the slag-tailings based ARC prepared with 30-50% CaO-CaSO4 activated slag and 50-70% tailings can reach to 19.88-42.87 MPa. Also, the material has a low surface pH value, good resistance to chloride ion penetration, and sulfate corrosion. Keywords: Artificial reef concrete, granulated blast furnace slag, deslimed gold ore tailings, compressive strength, hydration characteristics

Jan 1, 2020

By A. Angelov, U. Peukerd, S. Gaydardzhieve, A. Stefanov, K. Grossman, V. Stoilov

Flotation concentrate originating from the Asarel-Medet porphyry copper mining and processing complex in Bulgaria has been subjected to regrinding using a Ro-Star mill; the effects of which on the downstream metallurgical behaviour are discussed. Particularly the effect on the liberation degree was studied through an optical microscopy and MLA-SEM automated mineralogy. On the other hand, copper selective flotation of the reground bulk concentrate was realised to evaluate the anticipated metallurgical improvement. Process parameters such as involvement of prior hydrocycloning and variation of collector dosage have been evaluated. Within a two-minute residence time inside the Ro-Star mill, an improved liberation degree of the copper bearing minerals has been observed. As a consequence, enhanced copper recovery and selectivity against pyrite was noted. It has been found that in order to guarantee efficient flotation of the resulting ultrafine particles, a modified flotation regime (i.e. changing collector suite and dosages) should be followed. Keywords: RoStar Mill, liberation, flotation recovery, ultrafine particles

Jan 1, 2020

By R. D. Alorro, B. Tadesse, E. Aghaei

Cinnabar (HgS) and native mercury (Hg) are the most common naturally occurring forms of mercury found in most gold ores subsequently released into the environment during processing. Mercury and its compounds are extremely toxic and recognised as serious health and environmental hazards. This research investigates the possibility of mercury (Hg) removal from waste solutions from gold processing using iron-aluminium (Fe-Al) bimetallic particles. The synthesis of Fe-Al bimetallic particles using zero-valent aluminium and ferric chloride as precursors were performed following the optimisation of influencing factors. The presence of both metals in the prepared bimetals was confirmed by XRD analysis. The experiments for mercury removal by bimetals were designed using the central composite design and Minitab software based on two variables including contact time and adsorbent dosage. The best result of Hg(II) removal (>90%) was achieved using 4 g/L bimetals and contact time of 75 min. However, the statistical analysis of results indicated that these parameters have only a minor contribution to the removal of Hg(II) by Fe-Al bimetals. Higher bimetal dosage and contact time resulted in a higher Fe dissolution from the Al surface which can be attributed to the presence of nitrate (# $) ions in the solution. However, adding 0.1 M NaCl to the Hg solution had a positive impact on Hg removal by improving the conductivity and electron transfer within the solution. The Fe-Al bimetallic particles are promising substances for further testing of Hg removal from gold processing waste solutions with different conditions and constituents. Keywords: Mercury removal, gold processing, Fe-Al bimetals, optimisation

Jan 1, 2020

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By C. R. Royal, B. E. Friedland

Energy & Densification Systems (EDS) has developed patented new technology crushing/milling equipment. The EDS Multishaft Mill is a compact vertical mill – utilising high-speed impacts to break down particles with large reduction ratios, low energy consumption and improved liberation. The milling action combines several processes to provide a multitude of output products to satisfy various specifications. Comminution often accounts for more than 60% of the total power consumption on a mine. Two of the key problems to be solved in comminution is to bring down the specific energy required to reduce particle sizes; and to improve liberation or improve the efficiency of the beneficiation and recovery of the required elements. The EDS Mill has shown extensive improvements in both these areas with energy efficiencies up to 75% better than conventional milling equipment and improving liberation beyond the standard beneficiation processes. Conventional comminution equipment requires massive, heavy parts to be moved or rotated, consuming a lot of energy in doing so and not inputting that energy into the breakage of particles. In the EDS Mill, ramping up the relatively small shafts to speed is all that is required. Once at speed, the momentum, together with the minimal amount of constant drive required, means that the energy can be transmitted directly and efficiently into breaking down the particles. The high-speed impacts allow for a shattering effect of the particles and this quickly generates a high ratio of fines. Furthermore, the single impact force breaks particles in a very different manner to conventional compressive force breakage. With compressive force breakage, the particle breaks from point to point. With high-speed impact force breakage, the force tends to migrate through the weakest areas of the particle, which tend to be the mineral boundaries. This, therefore, means that when the particles break, the various minerals are exposed and hence liberated. Keywords: Comminution, high-speed impact, liberation, energy efficiency, novel comminution

Jan 1, 2020

By B. S. Agbenuvor, R. Morrison, V. Jokovic, C. Antonio

Body breakage usually involves breakage of particles by compression between two surfaces or impacted against a rigid surface, with the latter of interest in this current study. This mode of breakage has been identified to be the most elementary size reduction process and the most effective breakage process in comminution devices. It has been found in the literature that the progenies produced from this form of breakage possess a residual velocity at which they move, after the breakage event. In the pursuit of efficiently utilising applied comminution energy, a laboratory-scale breakage device has been developed to deliver precise specific impact breakage using the concept of a fast-moving hammer and a slow-moving particle to effect breakage. The residual velocities of the progenies from the breakage event may be used to generate secondary breakage without further addition of energy if the particle encounters a stiff obstacle such as a steel plate at right angles to its path. To measure the extent of secondary breakage, the steel wall of the device was lined with a rubber material to suppress the second set of breakage events. The performance of the new device is analysed, based on calculated t10 values and measured residual velocities of the moving daughter particles. Testing involving anvils showed a much finer PSD and higher t10 compared to the test involving rubber lining. This finding is corroborated by the measured residual velocities of the progenies. The resulting energies calculated from the measured residual velocities of the progeny were found to be approximately 42-88% of the primary specific impact energy. This retained energy was found to be sufficient for secondary breakage. Keywords: Impact breakage, residual velocity, secondary breakage, energy utilisation

Jan 1, 2020