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By D. R. Willmer, E. J. Haas

"DISCLAIMER The findings and conclusions in this paper are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health. Reference to specific brand names does not imply endorsement by the National Institute for Occupational Safety and Health. ABSTRACT This study analyzed the publicly available health and safety policies of 26 mining companies to determine the quantity of health and safety (H&S) practices that mining companies encourage in relation to the Plan-Do-Check-Act cycle. A thematic content analysis of the policies identified elements and practices within the text. On average, companies communicated information on about 7 elements (range 1–14, standard deviation = 3.49) and discussed 15 practices (range 2–34, standard deviation = 9.13). The elements in which companies highlighted the most practices were risk management, emergency management, leadership development, and occupational health. A discussion of the policy trends shows areas that mine sites can improve upon within their Plan-Do-Check-Act cycle, in addition to encouraging the use of both leading and lagging indicators to manage health and safety performance. INTRODUCTION Mining companies and their employees are expected to identify and manage risks at their worksites to ensure the health and safety (H&S) of everyone at the site. The primary mechanism in place to control these risks is a company’s health and safety management system (HSMS) (Boyle, 2012). Broadly, an HSMS is a set of standard, interrelated, and interacting elements used to promote and achieve occupational H&S goals (ANSI/AIHA Z-10, 2012; BS OHSAS 18001, 2007). The practices conveyed within an HSMS are expected to minimize incidents, injuries, illnesses, and even save worker lives (Alsop and LeCouteur, 1999; Arocena and Núñez, 2010). In the United States, both the Occupational Safety and Health Administration (OSHA) and Mine Safety and Health Administration (MSHA) regulate and encourage aspects of an HSMS (US Federal Register, 2011, 2010). Many HSMS documents (i.e., Chemical Industries Association, 1995; Health and Safety Executive [HSE], 1995; International Labour Office [ILO], 2001) attribute the source of their basic management system to Deming’s Plan-Do-Check-Act (PDCA) model of continuous quality improvement and organize their practices within this cycle (Johnson, 2002). The PDCA cycle is a well-adopted approach in health and safety management and promotes continuous learning and adaptability (Robson et al., 2007)."

Jan 1, 2018

By M. E. Taranenko, V. A. Krivonosov, S. A. Nemykin

"In concentrating production energy-consuming power installations are wide used, the most powerful of them are the wet autogenous grinding mill operating in closed circuit with a spiral classifier. The analysis of the current state of the automation of the grinding process shows that the reserves for maximizing productivity and minimizing electricity consumption have not yet been exhausted on the existing process equipment. Usage of the achievements of the modern management theory reveals an opportunity for further optimizing of the grinding process. The purpose of the research is to develop an automated control system of complex ""the mill-classifier"" to conduct the grinding process in the most operating efficiency, ensuring the maximization of productivity and minimization of specific electricity consumption. The main idea of this work is to study the specific features of the ore grinding process and creation on this basis of automated control system complex ""mill-classifier"" which allows to find and to maintain the optimal mode of grinding based on identification of the current object parameters, observance and regulating of the object state coordinates. Research methods. We used the methods of system analysis, mathematical statistics, modern automated control theory, theory of systems identification, optimal control, modelling of dynamic processes. Developed scientific provisions: - identification algorithm of the loading sub-system management object of complex ""mill - classifier"" allowing to obtain the unbiased estimators of its parameters according to the data of normal object exploitation; - observing device, which differs from the classic version of the observer Luenberger with possibility of estimating not only the state coordinates of the control object, but also the low-frequency perturbation component; - automated system stabilizing the active power of the grinding mode on the basis of a states controller with Luenberger observer; - structure of the software and hardware that implements the developed models, algorithms, methods of control, management and optimization in the framework of the automation of grinding."

Jan 1, 2018

By R. J. Sheets

"INTRODUCTION What is the primary responsibility for geo-engineers in mining? Early in my career, I was asked this question by an experienced engineer. After explaining some various tasks, I was informed that the main responsibility was to monitor. Although this proved true for many cases, I came to understand that monitoring is merely one means to achieve the primary responsibility of a geo-engineer – ensure the safety of all personnel. The potential for groundwater to impact stability allows this responsibility to be shared with hydrogeologists as well. Inherently, we monitor to identify risks; we analyze designs and develop models to mitigate risks; and we are provided opportunities to explain to supervisors the geo-risks to personnel and mine plans that will result from particular courses of action. A couple years ago, I took an opportunity to share experiences from the first several years of my career as a geotechnical engineer with junior geo-engineering staff within my company. The intent was to share situations that were a part of my development, so they could learn and understand their responsibility to the safety of all personnel. Similarly, the purpose of this paper will be to share these thoughts with new geo-engineers in the industry in order to help prepare them for the challenges they will face. WHAT IS OUR PURPOSE? A senior hydrogeologist shared an experience that occurred in their career. The experienced hydrogeologist had spent some time with the hydrogeology staff, most of them relatively new to the mining industry, to understand how they viewed, and carried out, what they perceived as their responsibility at an active mining operation. After a couple months of observing and mentoring, the senior hydrogeologist met with everyone and posed the question above. I am sure that most junior geo-engineers would start explaining different tasks or projects that they must complete. The list would include monitor groundwater levels, track slope movement, evaluate designs, build models, oversee drilling programs, etc. These individuals did as well their supervisor. After going around the room allowing each individual to answer, the experienced hydrogeologist provided them the real answer to the question: SAFETY. If you examine the root intent of nearly every responsibility geotechnical engineers and hydrogeologists have, it is to apply our professional skills to ensure the safety of our workforce. When the objective of safety from the geotechnical and hydrogeology disciplines is achieved, inherently accomplishing the mine plan should follow suit, or it should significantly minimize the impact by gravity or groundwater. The objective of a hydrogeologist is to ensure the soil or rock around an open pit or underground mine is dewatered; this specific objective will reduce pore pressures which could lead to a possible ground failure. They ensure a working bench/UG level is dry, so operations are not dealing with adverse conditions while mining. A geotechnical engineer is expected to use all available information and engineering judgement to provide design recommendations, so that the mine will not catastrophically fail. Additionally, they will implement the monitoring systems to identify hazards in advance in the event that the design is flawed and people need to be evacuated. We all know that safety is important to everyone; however, our particular set of technical skills play a significant role in ensuring the safety of a large portion of the global mining workforce."

Jan 1, 2018

By Mike Cammack, Logan Huppert, Gustavo Azpilcueta

During the summer of 2015, Unisea Inc. sought proposals for the G1 Dock Replacement Project in Dutch Harbor, Alaska. It would be a one year project and construction was scheduled to begin in the spring of 2016. One aspect of the project was the requirement for a layer of armor stone to protect part of the dock. An estimated 30,500 tonnes (37,670 t) of armor stone were needed for the project. The source of rock was the Unisea Quarry due to its proximity to the project and the quality of the stone meeting all the required technical standards.

Jan 1, 2018

By Y. Sugiyama, K. Kitazono, T. Miura, K. Matsuo

"Impact energy absorbing system for automotive is an important technology. Open-cell porous aluminum alloys were manufactured through Powder Bed Fusion (PBF) process. Compressive properties of the porous aluminum alloy depend on the cell structure as well as the porosity. The authors manufactured two ordered cell structures, truncated octahedron and rhombic dodecahedron, and one disordered cell structure, random Voronoi structure using a 3D-CAD software. Compression tests revealed the anisotropic deformation of the porous aluminum alloy with ordered cell structure. On the other hand, the porous aluminum alloy with disordered cell structure showed relatively isotropic and uniform deformation, which is suitable for energy absorbing applications. Therefore, controlling the disordered cell structure designed by Voronoi diagram enables to develop the advanced porous aluminum alloy having various mechanical properties.INTRODUCTIONAdditive manufacturing (AM) process enables to manufacture near net-shape mechanical parts. The AM technology is typically focused on titanium alloys due to their high specific strength and biocompatibility (Attar, 2014). Recently, aluminum alloy parts can be manufactured through selective laser melting method (Leary, 2016). Metal foams or porous metals are lightweight cellular materials having closed-or open-cell structures (Banhart, 2001). Aluminum foams are focused on as an energy absorbing material for transport industries (Baumeister, 1997). The purpose of the present study is to investigate the optimal cell structure of open-cell porous aluminum alloy manufactured through AM process. Most previous researches on the AM aluminum lattice structure has been considered ordered and periodic cell structures. On the other hand, classical aluminum foams manufactured through cast or powder metallurgical processes have disordered and heterogeneous cell structures (Körner, 2000). The authors use a concept of Voronoi diagram (Moukarzel, 1993) in order to manufacture various cell structures."

Jan 1, 2018

By U. Dmitrakova, G. Sedelnikova, D. Kim, E. Savari

"The paper presents the results of research on the development of gold and silver extraction technology from refractory gold sulphide flotation concentrate of one deposits of Nord-East of Russia. The concentrate is due to the complex mineral composition. Gold and silver are finely disseminated in sulphide minerals (arsenopyrite and pyrite partially oxidized by 7-11%). These are characterized by high content of silver 219 g/t and sulphide sulfur 32%, the presence of poorly soluble silver minerals (silver sulfosalts, fahlore, finely dispersed hypergenic acanthite in iron hydroxides and jarosite, etc.), and impurity minerals capable of interacting with cyanide (pyrrhotite, marcasite, nonferrous sulphides) and causing higher than normal cyanide consumption. Pretreatment of refractory sulphide concentrate by biooxidation using a mixed association of mesophilic and moderately thermophilic bacteria at a temperature of 36-40 °C for 120 hours oxidized arsenopyrite by 97.5%, pyrite by 93.5%, unlocked refractory gold, and generally oxidized the minerals absorbing cyanide and oxygen before cyanidation. Further oxidation of these minerals-absorbents was facilitated by the aeration in calcareous medium of the solid biooxidation residues of the concentrate. Sorption cyanidation of the solid biooxidation residues with addition of lead (II) of recovered 91.2% of gold and 82.9% silver from biooxidation residue, compared with 80.1% and 46.6%, respectively, for sorption cyanidation without the preceding biooxidation step. Biooxidation of the concentrate prior to cyanidation improves the recovery of precious metals, especially silver, and significantly reduces cyanide consumption from 18.7 kg/t to 3-5 kg/t of concentrate. INTRODUCTION Biooxidation of gold sulphide concentrates using acidophilic microorganisms has been successfully applied worldwide (van Aswegen et al., 2007; Gericke et al., 2009; Sovmen et al., 2007; Sovmen et al., 2009). At least 15 full-scale plants for tank biooxidation of sulphide concentrates are presently in operation, and the construction of new ones is planned (Bulaev et al, 2015)."

Jan 1, 2018

By K. Awuah-Offei, A. U. Rehman

"Information diffusion potential of a social media user affects how quickly information about a mineral project can diffuse through that user. If management can use social media and network analysis, in community engagement program, to understand how fast and how far information will diffuse to communities and followers of particular social media users, it can selectively focus on the most influential users. This paper proposes a method to examine the information diffusion potential of social media accounts. The work uses Gephi, an open source software, to extract and analyze data from different Twitter handles to predict their information diffusion potential. The work uses case studies of real Twitter users (e.g. mining news organizations and bloggers) associated with mining to illustrate the approach. The case study results show that there are significant disparities in information diffusion potential that will demand selective attention. This research will help mines develop effective social media engagement strategies. INTRODUCTION The mineral industry provides raw material for industrial activity to support our society (Martens and Rattmann, 2001). Mines have changed conventional mining practices to sustainable ones because of the negative impacts of mining and increased public awareness (Wang et al 2016). The concept of sustainable mining is getting mature as stakeholders (e.g., governments, investors and host communities) are getting involved in mining projects (World Economic Forum, 2014). The failure of mining companies to address the demands of these stakeholders might result in failure to acquire social license to operate (Thomson and Boutilier, 2011). The social license to operate (SLO), if granted, is mutually beneficial to all stakeholders. Mines prefer being granted SLO and keeping it to avoid any kind of social unrest due to their operation (Prno, 2013; Moffat and Zhang, 2014). Mining communities can grant different levels of SLO; ranging from withholding SLO to psychologically identifying with the project (Joyce and Thomson, 2000; Thomsan and Boutilier, 2011). Most of the previous work to understand community perceptions and SLO in mining is generally qualitative (ICMM, 2012a; Thomson and Boutilier, 2011; Prno, 2013; Moffat and Zhang, 2014; IFC, 2014). In particular, there is limited work on how community perceptions change over time due to information diffusion (Boateng and Awuah-Offei, 2017). However, SLO changes with respect to time (Yates and Horvath, 2013), which can result in risks that are not easy to predict. Mine managers and engineers have a desire to understand these changes so as to mitigate these risks (Que and Awuah-Offei, 2014; Que et al., 2015)."

Jan 1, 2018

By K. Amano, K. Haga, Y. Watanabe, A. Shibayama, A. Batnasan, A. Battsengel

"Apatite is an important host mineral in igneous and metamorphic rocks for production of phosphate fertilizers and phosphoric acid, and a potential source of rare earth elements (REE) production. For dissolution of REEs, sulfuric acid is better leaching reagent to develop the economical viable process for recovering of rare earth elements from apatite ore. However, the efficiency of rare earth elements dissolution in H2SO4 is about 30 % due to the formation of calcium phosphate or calcium sulfate as precipitate. On the other hands, phosphorus is mainly produced from phosphate ore. However, when treating rare earth elements containing phosphate ore, rare earth elements were discharged. Hence, development of novel apatite ore treatment process is required for effective utilization of natural resources. In this study, apatite deposit associated with REE was treated with sulfuric acid leaching and two stage precipitation by oxalic acid (C2H2O4) and magnesium chloride (MgCl2) for recovering REE and phosphorus, individually. Results showed that it can be seen the vast majority of La (87.5%), Ce (87.3 %), Pr (86.1 %), Nd (85.2 %) and Y (90.9 %) were dissolved in 1 mol/L diluted H2SO4 solution from the apatite ore. As average leaching rate of REE, over 85% of REE were leached by the condition. In the first stage precipitation using the obtained pregnant leach solution from leaching, over 90% of REE was precipitated by oxalic acid addition after controlling pH to 1 by NH4OH solution. After pH changed to 8.5, over 90% of phosphorus was recovered as precipitate by magnesium chloride addition in second stage precipitation"

Jan 1, 2018

By Fedotov. K. V., A. Y. Senchenko, V. A. Chanturiya

"The paper describes an efficient process to treat the ore from the largest in Russia copper deposit – Udokan. The recommended process is universally applicable to Udokan ores different in composition and allows reaching high copper recoveries during production of high-grade cathode copper and sulphide concentrate with 45% copper content. There are several promising trends for the process optimization and in the case they are implemented, economics of the whole project could improve significantly. One of the most important optimization options implies reduction of specific energy consumption in the course of comminution operations. Another possible option to optimize the already selected process flowsheet is production of cathode copper from sulphide concentrate directly at a mining and metallurgical plant without sending the latter to other metallurgical works.INTRODUCTIONUdokan copper deposit with resources of more than 20 million tons of copper is the largest in Russia and one of the largest copper deposits in the world. The deposit is located in Kalar District of the Trans-Baikal Territory, 30 km away from Novaya Chara railway station of the Baikal-Amur Mainline.Scientists and engineers from various research institutions have studied Udokan copper ores for years. Along the way, some conceptual process flowsheets have been proposed and each of them has its own pros and cons. The key requirement to the processes being developed was their universal application for processing of all the ore types using a single flowsheet. Due to the hard mining and geological conditions and because of complex material composition of Udokan ores it is of great difficulty to design a process which would provide for maximum economic benefits. That is why the process optimization has been ongoing until now.According to the Russian standards, the main input document for design of a metallurgical plant is referred to as a Process Design Report that covers the following key data sections: analysis of metallurgical testing results, validation of the process, design criteria, process flow diagrams, the mass and metallurgical balances, process description, equipment list and other information necessary for the subsequent design."

Jan 1, 2018

By Harald Brekke

On 13 July 2000, the ISA adopted the Regulations on Prospecting and Exploration for Polymetallic Nodules in the Area. The first contracts for such exploration were issued by the ISA the same year. The duration of exploration contracts is 15 years, after which the contractors are expected to go into exploitation. In 2013, ISA with the LTC initiated the process for developing the regulations for exploitation, and are currently working on the first draft to put forward for the Council. In the meantime, the first seven exploration contracts have expired, and been given five years extensions in order for the contractors to get ready to apply for exploitation contracts. According to the current draft of the exploitation regulations, an application for an exploitation contract shall be accompanied by all data acquired during the exploration phase, a mining plan, a financing plan, and a set of environmental plans (i.e. an environmental impact statement, an emergency response and contingency plan, environmental management and monitoring plan, and a closure plan). All of these plans have to be based on substantial scientific and technical data and information. The mining plan requires geoscientific data regarding the mineralogy and grade of the nodules, and the physiography of the mining site as a basis for the consideration of critical aspects, inter alia for making reliable resource estimations, design the mining operations, and forecast revenues. The environmental plans require the input of a substantial set of bioscientific data and information on the exploitation technology in order to establish base-lines, and monitor and evaluate the effects of the mining operations. Under the exploration contracts, such scientific data have been acquired and reported on an annual basis to the ISA. Some testing of mining equipment and experiments on the extraction of metals have also been performed by some contractors. These scientific and technical data from the exploration phase will be the basis for the for the preparation of the studies, plans and documents required for the applications for exploitation. No time frame is specified for the preparations of an application but it must be assumed to take place before the expiration of the exploration contract.

Jan 1, 2018

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

By Wiebe Boomsma

INTRODUCTION Starting in February 2014, 19 partners from EU industry, research institutions and academia joined forces and formed the Blue Mining consortium. In the following four years, they have set out to work on the development of deep sea mining technology, looking into exploration, identification, economic assessment and vertical transport systems for the mining of seafloor massive sulphides and polymetallic nodules. In the beginning 2018 this research & development project has come to an end. The Blue Mining project was one of the first EU subsidised projects embracing the TRL system. This system describes a method of de-risking technology using a simple 9-step approach. This method requires experimental testing in laboratory and relevant environments to be able to reach the higher levels (TRL>5) This paper will discuss the progress in development of the vertical transport system, with a focus on the performed experimental work. This paper will discuss three topics: • Booster station technology • Riser dynamics • Vertical hydraulic transport process. BOOSTER STATION TECHNOLOGY Deep knowledge of transport processes is a prerequisite for a clog free vertical transport One of the key technologies in the VTS is the booster station. The centrifugal pump booster station concept is developed in Blue Mining, it consists of two centrifugal pumps and multiple valves, assembled in member-type frame. Deep sea conditions pose special requirements on all components due to the extreme pressures at large water depths. In the Blue Mining project a Deep Sea Special Motor has been developed and tested in laboratory and in the field. The motor is completely filled, lubricated and cooled using seawater due to its unique open structure, furthermore it does not require any lubricants minimizing the environmental pressure of the motor. The motor is first extensively tested in a laboratory, after these tests have been concluded successfully, the motor is shipped to Norway where it has been successfully tested for more than 100 hours at 425 meter water depth.

Jan 1, 2018

By T. Sun, J. Kou, C. Sun, D. Gong

"HPGRs (high pressure grinding rollers) have demonstrated higher energy efficiency than conventional comminution equipment due to their application of particle-bed breakage mechanism. In the past decades, a large number of studies have been conducted to understand the characteristics of particle-bed breakage, however, few of them concerned the difference between single-particle and particle-bed breakage in compression comminution. This comparison is able to demonstrate possible advantages of particle-bed against single-particle in a breakage event due to the isolation of the effect of force loading mechanism. The present study investigated progeny fragment size and energy efficiency of these two breakage methods at variable energy inputs and particle sizes. The results show that at low energy inputs of around 0.25 kWh/t, the numbers of fines resulting from the two breakage methods are very similar. However, at higher energy inputs of around 1.0 or 2.0 kWh/t, particle-bed breakage generated significantly more fines. From the perspective of newly generated surface energy, particle-bed breakage is obviously more energy efficient than single-particle breakage at energy inputs between 1.0 and 2.0 kWh/t. It was also found that HPGRs demonstrate high energy utilization rate in generating new surface energy within their typical range of specific energy input. INTRODUCTION Rock comminution is an important and energy-intensive process in mining operations. Nowadays, decreasing head grade and mineral liberation size of ore deposits greatly increase the energy cost of comminution process. HPGRs have been successfully applied in the mining industry to improve the energy performance of comminution circuits. Typically, 10 to 30% of energy saving can be achieved due to the application of HPGR (Wang et al., 2013; Casteel, 2005; Günter et al., 1996)."

Jan 1, 2018

By Sander van Leeuwen

Outline: · De Regt Marine Cables. · The link between system requirements and umbilical requirements (which system requirements have the largest impact on the umbilical design). · Design options for deep sea mining umbilicals (showing the various options for strength member constructions, power conductors and data-transmission). · Technical challenges and risks (outline on the most important technical challenges and risks involved in the construction, production and usage of deep sea umbilicals). · Umbilicals for the SWORD and Blue Nodules project.

Jan 1, 2018

By A. Y. Senchenko, Y. V. Kulikov

"The most common technique for selection of grinding equipment is the Bond method implying determination of a ball mill work index (BWi). The method is perfect for greenfield projects where a ball mill must be sized to grind an ore to 80% passing 75-100 µm. Finer grinding will require application of specific correction factors to a standard equation since initially the method was not designated for sizing of fine (minus 75 µm) grinding mills. Significant issues are related to selection of grinding equipment for treatment of originally fine materials when the standard procedure is not applicable. In 1984, Levin published his special technique titled as “A proposed test for the determination of the grindability of fine materials”, where he offered to use the standard Bond ball mill for determination of a specific grinding energy. However, this method did not meet with wide recognition. In 2017, Institute TOMS under guidance of JKMRC’s specialists performed a testwork aimed at verification of a new universal technique for determination of grindability of initially fine materials. An object was to test three aged tailings samples for the subsequent modelling of comminution circuit and evaluation of potential throughput of the existing ball mills with final grind size of ?80 passing 53 µm. In parallel with development of the universal approach, TOMS’ specialists carried out tests according to the Levin method in order to compare the data resulted from two methods. The results from lab ball mill testing on three products following the alternative test methods are presented in this paper along with the testing methodology and results analysis. Specific energy was calculated for regrinding of the materials to the required size. Difference of the examined methods and assessment of their applicability for sizing of full-scale equipment are explored."

Jan 1, 2018

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki

"Hydrogen peroxide (H2O2) is frequently used as an oxidizing agent in various applications. It has also been reported to reduce the recovery of sulfide minerals. Moreover, the previous work applied H2O2 aqueous solution in selective flotation of chalcopyrite and molybdenite. However, the oxidation method suffered in pilot scale test due to too long conditioning time. Furthermore, the excessive reagent consumption increased the reagent cost, causing the method not economically feasible. Consequently, further improvement is required to reduce the conditioning time and the reagent consumption. The oxidation performance of H2O2 can be improved by using ferrous iron as catalyst, producing a Fenton’s reagent which is more powerful oxidizer than the H2O2 itself. Therefore, the effect of Fenton’s reagent on the floatability of chalcopyrite and molybdenite was investigated in this study. The flotation test results show that selective flotation of chalcopyrite and molybdenite might be possible at low concentration of H2O2 aqueous solution by adding ferrous iron. Moreover, the conditioning time could be shortened by this improvement. To understand the phenomenon, surface characterization using atomic force microscopy (AFM) along with x-ray photoelectron spectroscopy (XPS) analysis were carried out. The AFM images show that the surface of chalcopyrite was readily covered with mountainous features which alters its hydrophobicity after the oxidation treatment. Meanwhile, the molybdenite surface remained clean and relatively hydrophobic. The XPS results indicate that the mountainous features are various oxidation products (i.e., FeOOH, Fe2(SO4)3, CuO, Cu(OH)2). Possible mechanisms of this phenomenon were proposed in this work.INTRODUCTIONConventionally, copper and molybdenum ores are separated in selective flotation circuits by using copper depressants (i.e., sodium hydrosulfide (NaHS), sodium sulfide (Na2S), and Nokes reagent (P2S5+NaOH)). However, these depressants are usually toxic or hazardous. Therefore, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, ozone, and plasma pre-treatment (Arbiter and Young 1951; Barzyk et al. 1981; Curtis 1941; Hirajima et al. 2014, 2017). Recent study by Chimonyo et al. (2016) reported the effect of H2O2 on reducing the recoveries of sulfide minerals. Moreover, Hirajima et al. (2017) demonstrated that H2O2 depressed the floatability of chalcopyrite and could deliver a selective separation on copper and molybdenum (Cu-Mo) bulk concentrate in flotation process. However, they reported that this method required a higher concentration of H2O2 and a longer treatment time (4.5 h) to get a comparable result to that of using NaHS as copper depressant. Therefore, further improvements are necessary to reduce the conditioning time and reagent consumption."

Jan 1, 2018

By James A. Finch, Xiangzhou Ding, Yue Hua Tan

"The Jameson Cell is one of the choices of flotation machine in coal, base metal processing and other specialist applications. This paper determines the effect on vacuum pressure and bubble size of two design variables, orifice size and downcomer length, and the operating variable air-to-water (AWR) ratio. The main findings are: orifice size and downcomer length impact the vacuum but have limited effect on bubble size; AWR < 1 favours high vacuum, conditions are identified where vacuum is maintained at AWR > 1, and water flowrate has slightly greater impact on bubble size than air flowrate.INTRODUCTIONFroth flotation, the most common technique for mineral separation, has been in use for over a century. The process takes advantage of the difference in wettability of mineral surfaces to achieve the separation of valuable minerals from non-valuable minerals, or gangue. Numerous flotation machines have been invented and patented over the years. The Jameson Cell, invented by Professor Graeme Jameson in the late 1980s, is one successful example. First trialed at Mount Isa Mines (Queensland, Australia), Jameson Cells have been installed at operations around the world for the recovery of fine coal (Mohanty and Honakeri, 1999; Cowburn et al., 2006; Hacifazlioglu and Toroglu, 2007; Uçurum 2009), minerals of copper (Farr 1992; Atkinson et al., 1993; Harbort et al., 1997), lead/zinc (Rohner, 1993; Munro, 2003) and gold (Bennett et al., 2012; Lauder et al., 2003), and in water treatment (Yan and Jameson, 2004), solvent extraction de-oiling (Miller and Readett, 1992; Miller et al., 1997; Harbort et al., 2003; Young et al., 2006), oil sands processing (Neiman et al., 2012), and various food industries (Brenneman, 2014). One of the largest units is the 650 cm diameter separation tank with 24 downcomers installed in an Anglo American operation (Osborne and Euston, 2015). Scale up is relatively straightforward: to increase capacity the number of downcomers is increased with corresponding increase in size of separation tank.The Jameson Cell comprises two main parts: a vertical tube (downcomer) which provides self-aspiration and intense bubble-particles contact, and a (separation) tank where particle-bubble aggregates disengage from the pulp. The intense bubble/slurry mixing in the downcomer with air holdups reaching 60% (Marchese et al., 1992) accelerates particle collection enabling the greatly reduced cell volume compared with mechanical flotation cells and columns. The disengagement of the particle-loaded bubbles from the slurry in the separation tank is usually aided by addition of washwater."

Jan 1, 2018

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018

By l. Bokányi, T. Varga

"The recycling of waste car tyres is a very important environmental task. The waste tyres usually are re-used or recycled by thermal processes like pyrolysis, gasification or incineration. The main problem associated with these processes is the sulphur content of waste tyres originated from the vulcanisation process, which pollutes the environment and the valuable products (i.e. pyrolysis oil) as well. In our research the desulphurisation of waste, mechanically prepared tyre sample was systematically investigated by the biosolubilisation with Acidithiobacillus thiooxidans, strain Karitas. Parallel, the experiments with sterile 9K nutrient medium were also carried out. It was found that the vulcanisation sulphur can be solubilised due to both the bio- and the chemical leaching, although the bioleaching is more effective. The solubilised vulcanisation sulphur then forms precipitates. The precipitates are forming in the bulk solution, as well as on the surface of rubber particles. The origin of the precipitates was investigated using XRD and scanning microscopy with micro probe. The origin of the precipitates is different: while in the process of the vulcanisation sulphur solubilisation with 9K medium the jarosite (KFe3+3(SO4)2(OH)6) forms, the course of the biosolubilisation with Acidithiobacillus ferrooxidans Karitas is accompanied by the formation of the jarosite and the halotrichite (FeAl2(SO4)4 · 22H2O) as well. The formation of the latter is the biomineralisation. The mechanisms of the bio- and chemical solubilisations are rather different as it was found and experimentally proved by several tests, and depends on the retention time of the solubilisation. Special efforts were done to elaborate the proper separation of the precipitates from rubber particles. Combination of intense dynamic stirring and recycling flotation process to remove the precipitates was applied for this purpose. The surface properties of synthetic jarosite were revealed using zeta-potential measurements at different pH and in presence of collectors. The parameters of the flotation were chosen based on the revealed surface properties of the precipitates. Finally, the sulphur recovery of the recycled rubber was achieved as low as <0.5%, sulphur content of it 0.17%, 12-times lower than that of the waste tyre sample after mechanical preparation."

Jan 1, 2018

By Xiaoxu Sun, Jianchao Yao, Jiancheng He, Shijie Lu, Hongxi Zhou

"With the trend of increasingly more mineral resources turning low-grade and refractory, more and more new ore bodies being developed worldwide are more finely grained, which drives the rapidly development and application of techniques related to tower mills (vertical spiral stirred mills). However, the lacking in fundamentals of fine grinding, as well as standard procedures for equipment selection and scale up, seriously restraint high efficient application of tower mills. Taking grinding media motion characteristic and grinding intensity as a breakthrough point, this paper studies mechanisms behind how critical parameters affect grinding efficiency of tower mill, including ratio of screw pitch and diameter, agitator rotation speed, grinding media size. Several sets of orthogonal test are conducted on the quartz ore using the grinding system of KLM-3 tower mill. All the tests are under the same character of feeding mineral and undergo the consistent sampling for at least 60min grinding time. The input power is measured by a torque measurement system and the grinding products are analyzed by the laser particle size analyzer. The test results show the influence of parameters on grinding efficiency. Among the three important parameters, the effect of grinding media diameter is the biggest, followed by the agitator tip speed, and finally the ratio of screw pitch and diameter. For the different particle size of grinding products, the best combination of grinding parameters is different, with the mineral size becoming finer, the ratio of screw pitch and diameter become smaller, the diameter of grinding media become smaller, while the agitator tip speed does not change too much. The conclusions of the study help us to improve the grinding efficiency of the tower mill, to assist in the selection and optimization of working parameters, establish new scale up method on the basis of grinding model and eventually provide theoretical basis of rational selections of structural and media physical parameters within tower mill."

Jan 1, 2018