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The observation of lower-than-predicted Fe/Cu ratios in the cementation of copper on iron in tests at elevated temperatures indicated that some other reaction was contributing to the reduction of cupric sulphate in addition to the reduction by elemental iron. Experiments showed that the copper sponge, which initially formed on the iron, subsequently reduced the cupric sulphate giving the products cuprous oxide and sulphuric acid.Tests were undertaken to determine the rate and equilibrium conditions of the reduction reaction with variations in the types of the reducing agent and solution parameters. The reaction first became apparent at temperatures above 50°C and as it ceased at pH 1·8 it was possible to induce further reaction by alkali addition.

Jan 1, 1974

By A. E. Sands

This report deals with a portion of the research and development work in the field of synthesis gas purification, carried out by the Bureau of Mines at its Morgantown, W, Va., Station in cooperation with West Virginia University. The Bureau's work in connection with gas purification has been performed with the objective of finding effective, low-cost, processes for removing impurities from synthesis gas to protect the catalyst used in the Fischer-Tropsch process for production of liquid fuels. Synthesis gas used for the production of other chemicals, such as ammonia, alcohols, and methane, requires equally rigorous purification. Although present-day practice in the manufactured-gas industry does not require such a high degree of purification, there is increasing interest in the complete removal of sulfur compounds from city gas. Although the gas-purification work at Morgantown deals with several impurities, major effort has been devoted to organic sulfur compounds in gas; this paper represents a progress report on some of the more important studies in connection with those compounds. Because this is a progress report on the Bureau's experimental work, no attempt has been made to cover the work of others on the subject; references to the literature have been restricted to those bearing directly on the work described.

Jan 1, 1950

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

It was determined by the authors that the water that remains in the filter cake after filtration in iron ore concentrators can contain several hundred times greater concentrations of calcium ions and other cations, due to surface chemical effects carrying the ions along with the water. Filter cake from two plants was analyzed. The water retained in samples of magnetite concentrate filter cake in Plant 1 contained 5088 ppm calcium and 5995 ppm magnesium, while the Plant 2 filter cake contained 231 ppm calcium and 119 ppm magnesium. These levels were dramatically elevated compared to the water that was removed from the concentrate by filtration for recycle to the plants (9 ppm calcium/15 ppm magnesium for Plant 1, and 11.9 ppm calcium/9.3 ppm magnesium in Plant 2). In addition to possible effects on agglomeration performance, the presence of these cations also affected the efficiency of filtration. In order to reduce the effects of these cations on filtration in Plant 2, carbon dioxide was injected into the slurry before it entered the filter press. This was found to increase filtration rates by up to 23.7%. Comparison of the results from the two plants shows that the concentrations of cations present in the filter cake will vary greatly from plant to plant, with correspondingly large variations in their effects on plant operations.

Jan 1, 2004

By M. Pernot

A 12 m-deep excavation has to be perfomed in the Shanghai soft clay to install an underground electric substation. This article was originally intended to study the behaviour of the wall, the excavation bottom and the surrounding ground during the excavation. Since the works are behind schedule, and the data referring to the excavations are not, therefore, available, the article is limited to a presentation of the analysis methods that we envisaged for the study of the behaviour of the excavation.

Jan 1, 2010

By Ivo Dreiseitl, Kondratenko. Anatoly

"The second prime area within the Interoceanmetal Joint Organization exploration area named H22 was delineated in 2013 with the goal to ensure sufficient nodule reserves for profitable mining operations and processing.The knowledge base for area H22 has been obtained from archive materials. The geological situation can be characterized as follows: the sea bottom is represented by tectonic blocks oriented in a sub-meridional direction. According to swath mapping, the depressions (troughs) are contoured at depths of 4500-4600 m while the tops of horsts occur at 4300-4350 m. Volcanic relief occupies 6% of the H22 area; in the eastern part a multicone volcano was detected. Its area at the base is 153 km2. The maximum height of a cone above the base is 850 m. The crystalline basement composed by tholeiitic basalts of late Oligocene age is covered by about 100 m of sediments. Semi-consolidated to consolidated calcareous nanofossil sediments of the Marquesas formation are deposited on the basement. Higher up in the profile sediments of the Clipperton formation occur. They are represented by unconsolidated siliceous (Radiolaria, Diatom) ooze. Sediments containing calcium carbonate have not been detected. Where opaline silica (or CaCO3 if any) content is below 5%, the sediments belong to zeolitic clays or red pelagic clays. Grain size composition of the seabed and the near-seabed sediments in H22 classifies them into clayey silts."

Sep 1, 2014

A general description of investigative work conducted by the Bureau of Mines at the, Missouri Valley. manganese deposits and leading to tonnage and grade estimates has been given in Report of Investigations 4375, part 1 of a three-part report of work done between July 1945 and August 1947. Basic factual information from which tonnage and grade estimates were drawn was derived through the drilling sampling of 238 large-diameter bucket-drill holes in 11 widely separated areas. Drilling areas were selected after careful reconnaissance, mapping, and consideration of earlier work done on the deposits by the Bureau of Mines, State agencies, and private organizations and individuals. Stratigraphic studies permitted extending the results compiled within the drilling; areas to outcrop and lightly covered manganiferous zones between an beyond drilling areas. The locations of drilling areas, drilling sections, and individual drill hues are shown on illustrations in part 1 f this report. The individual drill holes, aside from providing the basic information for tonnage and grade estimates, disclosed features affecting any future plan As exploitation. It in particularly significant that a large part of the visible outcrops is faulted end otherwise complicated by slides that give a false impression of the thickness, vertical location, and even the existence of manganese-bearing zones.

Jan 1, 1949

By Daniel Barkley

Underground coal mining in Illinois has a lengthy history dating back to the early 1800?s. High extraction underground mining has played a significant role in production through out this time. Modern mechanized longwall mining methods were introduced in the 1960?s and have been in continual use ever since. Regulations governing subsidence from underground coal extraction and the mitigation of resulting impacts to surface structures and surface land initiated in 1983. Despite the history of experience with subsidence, recent plans to longwall in Illinois have stirred public emotions and strong opposition. Anti and pro longwall groups formed and divided a community over the potential economic benefits new mining ventures could bring verses the potential problems associated with longwall mining in productive flat farmland. The debate culminated in a county wide referendum vote on the use of longwall mining. This paper provides an overview of the history of underground mining in Illinois, the controversy that has risen in central Illinois regarding longwall mining, and the efforts to educate the public about regulations that govern longwall subsidence.

Jan 1, 2007

By Celine Y. Zhang, Chloe J. Feng, Charles Q. Jia, Donald W. Kirk

Oil sands petroleum coke (OSPC) is a by-product of coking - a high-temperature process that converts the mined bitumen to the synthetic crude oil (SCO). For every barrel of the SCO produced, about 20 kg of OSPC are generated. Over 70 million metric tons of OSPC have been produced and stockpiled as a result of the development of oil sands industry in the past few decades. Unlike conventional petroleum coke, OSPC has uniquely high impurity contents, particularly sulphur (~ 7 wt%) and metals (e.g. vanadium at ~0.15 wt%), which has hindered its large-scale applications as a solid fuel. Vanadium is a valuable metal that is widely used as an alloy for strengthening steels. The stockpiled OSPC contains about 100,000 tons of vanadium, while the world’s production in 2013 was only 75,600 tons. At the current price of $25US/kg, the OSPC-bound vanadium represents a total value of $2.5 billion US dollars. In this work, we investigate the technical feasibility of extracting vanadium from OSPC. The work focuses on the characterization of vanadium in OSPC and the conditions for effective extraction of vanadium from the OSPC.

Jan 1, 2015

By K. S. Liddell

The Kell Process has been developed for the extraction of platinum group metals (PGMs) and base metals from sulphide flotation concentrates. The process has been successfully tested on several different sulphide flotation concentrates, including those from the UG2 chromitite horizon and the Platreef mafic/ultramafic layer. It has been shown to provide high (>95 per cent) and selective extraction efficiencies for the key valuable metals, i.e. Pt, Pd, Rh, Au, Ni, Co, and Cu. The Kell Process consists of several commercially proven unit operations. S, Ni, Co, and Cu are first selectively removed by use of a pressure oxidation step during which the dissolution of PGMs is minimized. The residue from pressure oxidation is subjected to a thermal treatment to ensure efficient PGM recovery by subsequent chlorination. All the core steps are very similar to well-proven conventional unit operations in common use, as are the subsequent metal recovery steps to provide marketable end products. Typical metallurgical responses of flotation concentrates from UG2 and Platreef to the Kell Process are provided, and key outcomes of an energy comparison study with smelting are summarized in this paper. Kell presents a potentially substantial improvement in PGM concentrate processing technology, in terms of economics via much-reduced power costs, ease of processing, and various environmental benefits. It allows for the treatment of high-chromium low-grade 'dirty' concentrates, such as secondary concentrates from the platinum industry's 'mill-float-mill-float' (MF2) flotation circuits and concentrates from retreatment of tailings. It allows greater concentrate mass pulls, has higher tolerance to gangue intergrowths in concentrates, and its use can provide substantial increases in overall PGM recovery. Its adoption would be a step change in the platinum industry, and given the commercially proven unit operations embodied in the Kell Process, at much-reduced risk compared with other more experimental technologies. Since the initial process development work, significant improvements and refinements have been introduced as a result of further compre¬hensive testing and process modelling. Pilot-scale testing and engineering study work is in progress for several selected sites.

Jan 1, 2012

Discrete Element Method - Computational Fluid Dynamics Modelling of Flow Behaviour in a Stirred Mill - Effect of Operation Conditions

Sep 13, 2010

By Brad Murray

Evaluating the performance of a shielded tunnel boring machine (TBM) can be difficult because the ground cannot be observed directly and in relation to the TBM attitude within the excavation. It is difficult to determine whether performance problems are caused by ground loading, steering issues, fine muck packing against the shield, or migration of annular grout around the shield. The Arrowhead Tunnels Project in Southern California uses strain gauges on its shielded hard rock TBMs to detect shield strains early and correlate them with tunneling conditions, thereby increasing the chances that problems will be correctly diagnosed and addressed to optimize TBM performance. The frequent automatic measurement of shield strain has also been valuable by confirming whether remedial methods used to free the machine after stoppages are effective. This paper discusses the qualitative interpretation of characteristic strain patterns on the Arrowhead Tunnels TBM shields and discusses installation details and special considerations for setting up a strain measurement system.

Jan 1, 2008

By Ralph C. Flow

In Cleveland County, North Carolina, one and one-half miles south of Kings Mountain, Foote Mineral Company operates an open pit for the production of spodumene, feldspar, mica, and commercial stone. Spodumene concentrate is sent to Footers Sunbright, Virginia plant and to other customers. Exton, Pennsylvania and New Johnsonville, Tennessee plants produce lithium compounds sold to the oil industry for multipurpose lithium-base greases, to the metal industry as welding flux, to the air conditioning market, and to the glass industry. Ceramic grade spodumene, feldspar, and mica concentrates go to other processing companies from the Kings Mountain plant. Waste amphibolite is delivered to a neighboring quarry operation.

Jan 1, 1962

By D. E. Wolfson

Twenty-two samples of West Virginia coals were carbonized at 9000 C by the Bureau of Mines-American Gas Association (BM-AGA) method, and yields of products and physical properties of cokes were determined. Eighteen samples represented the Coa1burg, No. 2 Gas, No. 2 Gas and Peerless, Powellton, Eagle, Big Eagle, Lower Eagle, Sewell, Fire Creek, and Pocahontas No.6 beds in Fayette County, and four samples represented the Sewell and Fire Creek beds in Greenbrier County. Expansion characteristics of the majority of samples were determined in the Bureau of Mines sole-heated oven. Chemical analyses were determined for all coals. The coals in Fayette County are high-volatile A, medium-volatile, and low-volatile in rank, and the Greenbrier coals are medium-volatile in rank. Most of the coals are chemically suitable for metallurgical coking. All coke strength indices are within acceptable limits for metallurgical coking coals. All the high-volatile A coals contracted and the medium-and low-volatile coals expanded in the sole-heated oven expansion test.

Jan 1, 1966

By Rapheal Trousselle

For over 5 years, Davey Bickford has been developing and testing an electronic detonator blasting system. These new-technology detonators provide more accurate timing than conventional systems that rely on the combustion speed of a pyrotechnic composition.

Jan 1, 1997

By E. P. Barret

Differences in the reducibility of iron oxide materials have been recognized for a long time. Limonites are deoxidized more readily than hematites, and unaltered magnetites are the most difficult to deoxidize. Sinters are found between hematites and magnetites and vary considerably in reducibility, depending on the sintering practice followed and on the degree of fusion of the product. The increased activity in the beneficiation of taconite recently has made available a new blast-furnace raw material, namely, iron oxide pellets made from magnetic taconite concentrate. Many of the data in this paper apply to these pellets, or glomerules, as they were called when this method of agglomerating iron ores was first considered. To clarify the terms applied to iron oxide materials in this paper, the following definitions are given. Agglomeration is the general term applied to all methods of compacting or consolidating fine iron oxide materials. Sinter is the product from a Dwight-Lloyd or Greenawalt sintering machine. Pellets are formed by balling fine, moist oxide in a rotating drum at room temperature, followed by heating in a shaft furnace to a temperature below that of incipient fusion to develop a permanent bond. Nodules are formed by heating the iron oxide material to incipient fusion in a rotary kiln. Briquets are formed in a mold under pressure, with or without the addition of a binder, and burned to develop a permanent bond.

Jan 1, 1949

By Steve Kral

Commodity price down cycles are a fact of life in the mining industry. And companies pre-pare for them as best they can. Evenso, operations are still curtailed or closed during those cycles, profits shrink, layoffs are inevitable and many companies do not survive. However, one of the few good things that occurs during down cycles is the new, innovative exploration, mining and processing technologies that come about during hard times. To survive the lean times, the mining industry turns to improved technology to decrease costs and hold the bottom line. And, because mining is a cyclical business, each down cycle brings about technology improvements that carry over into the good times.

Jan 1, 2004

By J. de Villiers

Through the application of the Rietveld method, X-ray diffraction analysis has developed into a fully quantitative method for phase analysis. The Rietveld method itself has progressed from an unstable method that required constant operator intervention to a stable and robust method suited even for routine analysis. The method, however, requires a good initial calibration and periodic checks on its precision and accuracy. Several examples from minerals processing, pyrometallurgy, and materials science show the strengths and applicability of the method. The limitations and sources of error are also discussed.

Jan 1, 2007

By Jimmy Rodríguez Las Heras

Durante la explotación de los niveles inferiores en la mina Yauliyacu, se generaron dudas sobre la ubicación de las concentraciones de esfuerzos y sus relaciones con los estallidos de roca. En este sentido, se instala un sistema microsísmico donde mediante el análisis de la microsismicidad se elaboró los estándares que permitieron reducir los incidentes por estallidos de roca presente, así como la frecuencia, magnitud y daños a las personas, y equipo e infraestructura de mina, debido a la energía liberada por los eventos microsísmicos. Por ello, el presente trabajo señala los beneficios del uso del sistema de análisis de microsismicidad como la actualización contínua de la zonificación minera de acuerdo a la concentración de esfuerzos, procediendo al reforzamiento del sostenimiento como medida de prevención.

Sep 21, 2013

By J. P. McCluskey

The effects of air quality regulations passed in the last few years have been felt in a more pervasive way by the electric utility industry than by perhaps any other industry. I'm referring especially to those regulations dealing with the control of air emissions from stationary sources, and those specifying the quality of fuel used. Particularly, I would like to describe some of the effects that these regulations have had on the Commonwealth Edison Company. To put the subject into perspective, a brief descrip¬tion of the company will be presented first. Then, a historical outline of some of the efforts at control of electric generating station emissions will be described. Following this will be an indication of the Company's response to early State and local regulations prompted by the growing pressure for stringent envi¬ronmental control. Finally, the Company's plans to achieve com¬pliance with the most recent, Federally approved, State of Illinois regulations will be summarized.

Jan 1, 1973

By P. F. Ledwaba

South Africa?s Northern Cape Province houses a variety of gemstone minerals. Diamonds remain the primary gemstone in the province, but there are also tiger?s eye, sugilite, rose quartz, jasper, amethyst, amazonite, tourmaline, and topaz deposits. This paper gives an overview of the tiger?s eye (TE) mining sector in the Northern Cape, with the objective of assessing the potential of TE to contribute to job creation and poverty alleviation in the province. Mining of TE started in 1803, but gained momentum during the 1960s. Mining is conducted on a small-scale basis, and in most cases without any legal framework. The majority of the residents are not benefiting from TE. It has been reported that an estimated R700 000 to R800 000 worth of TE is leaving the country every week through illegal trading. The potential for TE mining to contribute to socioeconomic development is hindered by illegal operations, lack of technical skills and knowledge, exploitation by dealers, lack of market information, community rivalries, and absence of value addition. A multi-stakeholder approach is needed to formalize the sector and reap the benefits. Mintek is spearheading a TE project in the Prieska area of the Northern Cape, which aims to establish a gemmological centre where TE can be beneficiated into saleable and high-value products..

Jan 1, 2014