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By C. Land, R. Hultgren

Heat contents of four Cr-Ni alloys were determined in a diphenyl ethev calorimeter. Aside from ferromagnetic effects, Kopp's law of additivity of heat capacities is approximately fol-lowed, in disagreement with earlier results of A. W. Foster. In 1934 Foster1 reported heat-capacity measurements of dilute solutions of chromium in nickel, primarily as a study of the effect of alloying on the ferromagnetic Curie temperature. He found that, apart from the Curie temperature effect, the general level of heat capacities was reduced 10 pct by the addition of 1 pct Cr; 20 pct by the addition of 2 pct Cr. His measurements of pure nickel essentially agreed with accepted values. These results indicate that small amounts of dissolved chromium cause an increase in the Debye temperature of nickel, presupposing a change of frequency of interatomic bonding vibrations which is much larger than should be expected. If Foster's results were verified, therefore, they would have important implications for bonding theory. The only other heat-capacity measurements in this system seem to be those of Taylor and Hinton,' who studied anomalies which they attributed to super-lattice formation at 25 at. pct Cr. At temperatures above the anomaly, Taylor and Hinton found heat capacities at this composition were quite normal, approximately obeying Kopp's law of additivity. EXPERIMENTAL WORK In order to verify or disprove the remarkable results of Foster, the heat contents of four dilute solid solutions of chromiunn in nickel were measured in a diphenyl ether calorimeter. This instrument, described elsewhere,, operates on the principle of the Bunsen ice calorimeter, but uses diphenyl ether as the working substance. Diphenyl ether melts at the convenient temperature of 26.S°C and supplies a more sensitive measure of heat than ice. The hot sample, in an atmosphere of argon, is dropped from a furnace at a measured temperature into a chamber which is surrounded by a mixture of solid and liquid diphenyl ether. The heat from the hot specimen melts some of the solid without chang- ing the temperature of the calorimeter. The amount of solid melted, and therefore the number of calories released by the specimen, is measured from the increase of volume of the mixture, which pushes mercury down a graduated capillary tube. The apparatus has been standardized against the known heat content of pure platinum. Heat loss during the dropping of the specimen was estimated by comparing the heat content of an empty platinum capsule with a solid platinum ball of the same radius and degree of polish of the surface. Repeated tests demonstrate the precision of measurement to be closer than *0.3 pct. Smoothed experimental results are listed in Table I. The tabulated values for pure nickel are taken from kelley, several measurements were made which agreed closely with this tabulation. For chromium, however, no similar agreement was found. The values tabulated were taken from a thorough study of chromium with the diphenyl ether calorimeter which will be published elsewhere.= Suitable plots of the data showed the expected ferromagnetic anomalies in the low-chromium alloys, while the 11 pct alloy shows no ferromagnetic anomaly, but a different, small anomaly below 900°K. This is perhaps the same anomaly found in CrNi, which was once attributed to superlattice formation,' but is probably due to some other cause, such as antifer-

Jan 1, 1960

By B. S. Xakalashe, I. J. Geldenhuys, B. Bowman, M. W. Erwee, G. A. Venter, J. Zietsman, C. Sandrock, Q. G. Reynolds

Understanding the behaviour of plasma arcs is an important part of the design and operation of direct current electric arc furnace smelting processes, which are used in the industrial production of many metallurgical commodities. In recent years numerical and computational modelling techniques have begun to illuminate the complexity of arc behaviour and how it is deeply connected to the thermodynamic and physical properties of the arc plasma. Plasma properties may be estimated from first principles using statistical mechanics methods, but this requires as input some knowledge of the composition of the gas phase that occurs over the process during smelting. In this paper the authors describe a workflow using thermochemistry software to predict the expected gas phase composition through a given process, followed by plasma property calculations using an open-source software tool that has been in development for several years. This tool, 'minplascalc' has been in development for several years and is also described in detail here. The workflow is then applied to the calculation of plasma properties of interest for a variety of historical and current pyrometallurgical processes, and the results are compared. The plasma property data are published in an open-access database for general use.

Mar 4, 2025

By William Campbell

(Cleveland Meeting, October, 1912.) [SECRETARY'S NOTE.-To avoid repetitions of foot-notes, references to authorities are made in the paper by means of figures, referring to a numbered list in the appendix.-J. S.] I. INTRODUCTION. IN the olden days the making of alloys was au art, and the secrets of the craft were jealously guarded. To-day it has become a science, though the old ideas in regard to the secrets and formula are dying hard. Modern progress may be attributed to scientific research and testing of materials, and the substitution of chemical analytical control for " cook-book " methods. We know to-day a great deal about the constitution of alloys, the reasons of the change in structure and physical properties by heat and mechanical treatment; and this new knowledge is due for the most part to the physical chemist and metallographist, who have shown us that alloys are simply solutions, and as such obey definite laws. The application of the theories of solutions and of the phase rule tells us what ought to happen when our alloys are in a state of equilibrium. The working-out of the temperature-composition diagram (thermal diagram) for numerous alloys has thrown a light on the structure and constitution which has dispelled most of the darkness in which we labored before the advent of metallography. The work began with the determination of the freezing-point curves, and here the research of Le Chatelier,1 Gautier,2 Roberts-Austen,3 and the other pioneers broke the ground. Next the physical chemists, Tammann,4 Rooseboom,5 Bancroft,6 and their colleagues, showed us the complete thermal diagram and its meaning. Then the researches of Heycock and Neville 7 on the Cu-Sn series and of Shepherd 8 on the * Associate Professor of Metallurgy, Columbia University in the City of New York.

Dec 1, 1912

By C K. Boafo, J Visser

Obuasi Mine in Ghana, with more than 100 years of mining history, developed from a surface operation into a deep >2000 m underground gold mine. The challenge is to extract value from narrow veins left after extensive mining in the wider ore zones of the mine. Since the merger of AngloGold and Ashanti Goldfields in 2004 the mine strives to achieve optimum extraction through an integrated Mineral Resource management process from geological modelling, resource evaluation to mine design and scheduling. The shear hosted gold deposit displays complex secondary shears of variable thickness and continuity. There is an ongoing process of changes taking place in the way that geological modelling and resource estimation is done. Recent developments include the use of computerised systems that support the whole resource management chain from resource modelling to reserve optimisation. The change in thought and technology now allows for targeting narrow veins previously ignored in optimisation and mine design since moving into mechanised mining. The increased knowledge and confidence in the resource models now allows for flexibility in mine design, selection of mining method and scheduling and extraction of the reserves. The focus area for change is the way the orebody is evaluated and extraction designed. Since 2005 major changes were made to the process. This paper considers the historical approach of resource management. It looks at the individual process changes and qualifying the way ahead.

Jan 1, 2008

By P Hulteberg

In this article, an integrated catalytic reactor design approach to produce PEMFC-quality hydrogen is evaluated. The design is based on a high level of heat exchanging perfonned internally, highly active noble metal catalysts and a woven wire mesh catalyst support system. It consists of an integrated steam refonner and a catalytic burner section, a water gas shift section and a preferential carbon monoxide oxidation section. The reactor design is described and experiments perfonned to evaluate the two reactors built are reported. The two reactors have a maximum output of 3 Nm and 10 Nm3 hydrogen/h respectively. In the larger unit, a total of six fuels, three gaseous (methane, natural gas and liquid propane gas) and three liquid (naphtha, ethanol and methanol), were evaluated. The larger unit was also used to investigate how variations of parameters such as steam-to-carbon ratio in the steam reforming part of the system and the relation between oxygen and carbon monoxide in the preferential carbon monoxide oxidation affect the reactor perfonnance. The smaller unit was used, after implementing automatic control, to run a system life time test for 480 h. The refonner system perfonned according to specifications on almost every aspect.

Jan 1, 2005

By Anthony D. Szpak

The purpose of this program was to demonstrate the feasibility of Illuminating various types of underground coal mining machinery as required by the Federal Coal Mine Illumination Standards Part 75.1719 to 75.1719-4 Code of Federal Regulations Title 30. Nine various machines were illuminated and the illumination systems were evaluated for a 3 month period of operation. Factors evaluated were ease of implementation, reliability, ease of maintenance, acceptance by mine workers and operators, Illumination degradation and durability.

Jan 1, 1981

By Arash Khosravifar

The seismic design of extended pile shafts for the combined effects of dynamic shaking and liquefaction-induced lateral spreading is investigated using nonlinear dynamic finite element analyses (NDA). Results of NDA parameter studies are used to illustrate how inertia and lateral spreading loads combine during shaking. The NDA results are used to evaluate equivalent static analysis (ESA) methods. Implications for design practice are discussed.

Jan 1, 2010

By Terry J. Close

A mineral resource survey of the 236-mil (611-km2) Hyalite-Porcupine-Buffalo Horn wilderness study area (RARE 11 Areas No. 1-155 G, Gallatin Divide; and H, Hyalite) between the Gallatin and Yellowstone rivers in Montana, indicates there are phosphate rock and petrified wood resources (fig. 1). The area also has some potential for oil, gas, and geothermal resources. Stone and alluvium are abundant but appear to have little potential for development because other sources are available nearer to markets.

Jan 1, 1981

By Sherif Elfass, Gary Norris

Bi-directional load testing of drilled shafts has been widely adopted as a means to evaluate their load carrying capacity. However, in order to reach failure, most of these tests are carried out on sacrificial shafts using expensive sacrificial elements such as hydraulic jacks. A proposed low-cost bi-directional testing technique is discussed. It mechanically loads the end bearing soil below a drilled shaft, against its side shear resistance. The technique was originally established as an alternative to post-grouting to reliably account for the forfeited end bearing resistance. However, since it loads the shaft in a manner similar to conventional bi-directional tests, it can be used to not only load test sacrificial shafts, but production shafts as well. Furthermore, unlike conventional bi-directional load tests, the load is applied through surface jacks. These jacks, along with other load test components, are movable and can be reused to load test all the shafts of the project thus presenting an economic benefit. The concept of this technique has received favorable feedback from a few consulted departments of transportation, and while promising, has not been field tested to date. A U.S. patent was issued for the tip loading module and the loading technique described.

Sep 8, 2021

By Mikko Loponen

Outotec has developed an operator training simulator (OTS) platformsuitable for various hydrometallurgical processes. The complete solution is run in the cloud, where virtual client instances can be managed on-demand. The aim is to build a generalizable model that produces coherent results even when operating outside of ideal parameters, allowing the operator to train in unsteady state conditions such as start-up and shutdown. Complex software products are commonly associated with significant development time and cost. Utilizing modular software architecture, only the control system and processmodel are tailored for theOTS,whereas modules such as user administration and cloud-based client machine spawning can be imported, shortening development time. A generic acidic pressure oxidation process (POX) operator training simulation consisting of feed preparation, autoclave, dual-stage flash evaporation and off-gas scrubbing is described. Process is simulated using Outotec HSC Sim 9 process simulator and controlled by Siemens Simatic PCS7 control system.

By G. Richards Gwinn

In modern warfare, mica is truly indispensable. Coordination of combatant units necessitates maintenance of intricate communications equipment, in the construction of which high-grade sheet mica is essential. Scrap, ground, and the poorer qualities of block mica, which are less essential to the military program, are not considered in this paper. Furthermore, as the paper is designed primarily to assist mica miners, mica derivatives, Such as splittings and films, also are excluded from discussion. The paper therefore relates solely to block mica of strategic quality. Understanding of t e many factor involved in marketing mica is definitely advantageous to mica, miners. The nature and detrimental effects

Jan 1, 1943

By H. E. Bartlett

Previously, the grade of ore at the shaft head was taken to be equivalent to the grade measured in the faces by means of chip sampling. The tonnage mined from the stopes is determined from survey volumetric measurements. Estimates of shaft head grade and tons include the grades and tons of waste, development ore, sweepings from old areas, and other sources, not all of which are sampled. The tonnage of ore delivered at the shaft is often estimated using skip factors. These factors are subject to manipulation and not all the skips are filled to the same level. Consequently, both the grade and tonnage of ore delivered at shaft head are subject to a measure of uncertainty. For many years, these uncertainties have led to disputes between shaft managers and metallurgists over the reconciliation between shaft tons and grade and plant tons and grade. These problems are compounded when several shafts feed a central processing plant. Shaft bonuses and a shaft?s profitability are affected by poor gold allocation methods. Without measurement of the grade and tonnage from all shafts, a poorly performing shaft could benefit at the expense of the other shafts. In order to improve the measurement of grades and tonnage at the shaft head, which is the custody transfer point between the mine and surface operations, South African mining companies have developed a methodology to measure the mass of ore from each shaft using rail weighing equipment, and the run-of-mine grades delivered from each shaft using cross-stream (go-belt) sampling. Harmony Gold Mining Company has implemented the rail weighing and go-belt sampling methods for their shafts. This paper deals with the statistical tests on the procedures and control measures that are in place to establish confidence in the gold allocations. The metal accounting system for examining the allocations follows the first principle of the AMIRA P754 Metal Accounting Code of Practice namely ?The metal accounting system must be based on accurate measurements of mass and metal content. It must be based on a full check-in check-out system?. The check-in is mass and grade of run-of-mine ore and the check-outs are the plant input grades and the recovery and residue from the plant. The balances between check-in and check-out are the subject of the statistical analyses, which have been conducted using the classical statistical tests and procedures that are generally used in all fields of endeavour. It is concluded that the gold allocation procedures that rely on go-belt sampling and rail weighing of ore from shafts has been successfully implemented, and that the system, which has been in operation at Harmony since 1993, has won general acceptance from stakeholders, with the gold allocations being perceived as being fair to all. Apart from the on-mine issues of bonuses and fair allocations, accurate metal accounting assists in the broader issues of generating accurate production figures for management. An added benefit of weighing and sampling ore at the shaft head has been that shafts now have daily moving average grades, which are used for grade control. The go-belt sample at the shaft head is the first accurate sample of production in the value chain from face sampling to gold bullion. Keywords metal accounting, go-belt sampling, run-of-mine sampling, codes of practice, AMIRA P754, train weighing, statistical analysis, gold split, allocation of gold, metal balance, grade control.

Jan 1, 2014

By M. B. Daza, B. Lattimer

"Even with modern detection and firefighting techniques, mine fires continue to be a safety concern. However, some underground mine fires can be addressed with the remote application of high expansion foam, reducing firefighter exposure to hazards. The flow of this foam can be numerically or computationally simulated in order to gain a better understanding of its behavior, but rheology parameters are needed as inputs to produce accurate simulations. For this reason, this work studies the rheology of firefighting high expansion foam using a foam generator and Poiseuille –Flow Rheometer. Rheological parameters for foams with expansion ratios between 250-1280 are represented by the consistency index (k) and the power law index (n) due to the results show a strong agreement with the Power Law model for non-Newtonian fluid viscosity. Furthermore, experimental results show that high expansion foam behaves as a shear thinning fluid with a power law index around 0.4 and viscosities in the range of s 0.1 Pa-s and 0.042 Pa-s under shear rates between 44 ??-1 and 187.3 ??-1. INTRODUCTION High expansion foams are called to foams with expansion ratio greater than 200. Expansion ratio (??) is defined as the ratio between the volume of foam produced (i.e. volume of foam solution and volume of gas) and the volume of foam solution used (NFPA 2014). Because of its high expansion ratio, one of the most important application of high expansion foams is to fill or flood large spaces such as hangars, storage facilities and underground mines for fire suppression. The foam can fill large structures using small quantities of foam solution within a short time (Sthamer 2012) (Martin 2012). Although the specific high expansion fire suppression mechanism has not been understood on a quantitative basis, a possible mechanism is fuel isolation when the foam act as a physical barrier between oxygen and the flame. Furthermore, as a consequence of this contact water is evaporated, causing cooling of fuel and surrounding air. Besides, water vapor as product of water evaporation causes a dilution of oxygen concentration available to the fire (Fleming and Sheinson 2012). High expansion foam can be applied remotely by means of conduit pipes or in situ close to the fire. In most of the underground mines scenarios, fires have to be addressed remotely to reduce miner and firefighter exposure to the hazards (Smith et al. 2005). Although high expansion foams should not be blasted and must be deposited directly on the area of application because of their low density (Harding et al. 2016) sometimes it is complicated to apply it directly to the fire due to complex access areas at underground mines. In these cases, foam has to be applied far away from the fire. Despite of this fact there is a lack of knowledge in terms of rheological behavior of high expansion foam under high shear rates (Gardiner, Dlugogorski, and Jameson 1998). Furthermore, there are a few attempts to simulate numerically the high expansion foam flow due to the ignorance of its rheological parameters and its complex behavior. (Weaire 2008)."

Jan 1, 2018

By Josef Martinsen

This paper describes two-lane dual motorway tunnels under construction in Bergen. The tunnels are part of a by-pass motorway system throuth the most congested area of the city of Bergen. The tunnels are unique due to their length, heavy traffic, longitudinal ventilation system and the use of a tunnel boring machine, or "TBM", to excavate through hard rock. The tunnels are being built by The Norwegian Public Road Administration and the TBM was delivered by the Robbins Company. The diameter of the TBM is 7.8 m and the tunnel profile is cut by conventional drill and blasting methods in the tunnel's lower half to attain a two lane motorway tunnel. This paper also describes proposed fjord crossings along the Norwegian west coast where the TBM may be used due to its great advantages in comparison to conventional drill and blasting methods.

Jan 1, 1987

By H. Foster Bain

Steel for any large structure must be imported, the Hanyang works being entirely unable to supply local demand. The United States Steel Products Co. has warehouses and small stocks at Shanghai and at normal times there are heavy importations from Europe. It is difficult to obtain any accurate index of prices, but comparison of customs valuations with Pittsburgh quotations shows angles, bars and plates to have averaged $10 gold per ton higher in China in 1914, while on galvanized and tinned plates the excess was- $38 per ton. The margin since has been greater. Previous to the war little machinery was manufactured in China. There were shipyards at Shanghai and at Hong Kong which built a small number of engines, and small foundry and repair works are found at a number of ports. Their capacity was limited and the difficulties and delays incident to transport in China so numerous that in practice every important mine has a small foundry, boiler works, and machine shop. This must be taken into account in plans for work in the country. While skilled workmen can be found it is to be noted that most of them have been trained

Jan 1, 1921

By E. J. Gleim

This report describes a trip to Europe in the interest of safety in coal mines. It reviews the Eighth International Conference of Directors of Safety in Mines Re-search, which met in Dortmund-Derne, Germany, July 5-10, 1954, to discuss results of studies made in different countries to improve health and safety conditions under-ground. It also summarizes information on subjects of special interest in the United States gained by the writer in visits to mining experiment stations in Belgium, France, and England. The efforts being made to protect life and property underground were discussed, and ideas and experiences were interchanged freely, not only during the conference but also during visits to the several countries. Helpful information was obtained on many topics of interest, but time did not permit as thorough a discussion on some of them as might be desired.

Jan 1, 1956

By V Rasouli, G Cavanough, A Mokaramian

The sampling time, the costs and its quality are the three factors that determine the best method of drilling in mineral exploration. The two principal methods of reverse circulation (RC) and diamond core drilling are often used in combination by mine operators. RC is used for drilling shallow holes and in-pit grade control, and core drilling for deeper holes to identify future resources. The RC method is faster and more flexible than coring and provides virtually uncontaminated cuttings (ranges from dust to 25 mm chips) to the surface cyclone suitable for geochemical anomalies. The diamond coring produces core samples to increase the level of geological knowledge and the 3D extension and distribution of the orebody. However, both of these methods are subjected to certain limitations and inefficiencies in reaching deeper depths and drilling complex hole geometries. Examples of such shortcomings include the inability to provide enough air pressure for RC drilling and high friction between drill pipe and the hole wall in diamond core drilling.Considering that delivering large volume of reliable samples from deep zones to the surface in shortest possible time is of paramount importance in mineral exploration, and assuming that obtaining core samples over whole overburden is not always essential, then drilling small size holes as fast as possible and delivering the small chip samples to the surface would be a good alternative with several advantages over conventional drilling methods for deep hard rocks mineral exploration. As a result, the use of coiled tube (CT) drilling technology has been proposed recently for such applications. CT is a continuous length of ductile steel or composite tube stored and transported on a large reel; and allows fast drilling by eliminating the connection time and providing continuous circulation during drilling. This enables quick access to the zone of interest to collect the cuttings or obtain core samples. CT is advantageous particularly in drilling directional boreholes and multi-laterals. In this paper, feasibility of using CT delivering reliable samples is discussed for deep mineral exploration. In addition, recent developments and practices are presented that make CT a reliable drilling technology to drill cheaper, faster and deeper and to deliver more continuous and reliable data and samples from deep formations.CITATION:Mokaramian, A, Rasouli, V and Cavanough, G, 2012. Quality sampling using coiled tubing drilling in deep mineral exploration, in Proceedings Sampling 2012 , pp 73-80 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

By P Gilroy

In recent technical investigations that were triggered from ore for rail shortfalls at Yandi, BHP Iron ore has identified a gap in resource knowledge relating to geo-metallurgical characteristics that predict materials handling performance and throughput. Within these investigations BHP has learnt that this lack of resource knowledge has translated to a lack of predictability associated with mine planning inputs which has resulted in poor compliance to plan and deviation management practices. A business value chain was developed in an attempt to identify the best possible solution to unlock this resource knowledge in the short, medium and long term planning horizons. A fast fail approach was taken with the implementation of hyperspectral blasthole analysis, which was chosen to deliver the best possible value driver for the asset. This report will detail the Yandi journey in expanding the hyperspectral and geo-metallurgical value chain, unlocking resource knowledge along the way. CITATION: Gilroy, P, 2018. Development of an empirical geo-metallurgical model that unlocks value of the mineral resources at Yandi Mine, in Proceedings Complex Orebodies Conference 2018, pp 85–87 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By Gailen T. Vandel

El presente texto describe la historia, geología, exploración, actividades de explotación como parte de la construcción de la planta de beneficio en la Bahía de San Nicolás, Marcona. Dicho proyecto contempla una ampliación del la planta de chancado y almacenamiento de la mina, así como la faja transportadora de bajada a San Nicolás y red de carreteras. Asimismo se incluye la planta eléctrica Diessel y transmisión, el muelle y zona abycente, la expansión de esta planta para el tratamiento del chancado, la planta de la peletización y la planta térmica. Con la implementación de estos elementos a la planta de Marcona, se convertirá a la región en uno de los centros industriales de mayor importancia en Sudamérica.

Jul 20, 1961

By W. T. Robson

ONE of the problems encountered in any mine is the effect of increasing pressure manifested by increasing depth. Although the depth at which excessive pressure assumes serious proportion, and the manner in which it appears in underground workings, are influenced by a variety of factors, nevertheless the difficulty is present in all mines and its gravity increases with increasing depth. In the Kirkland Lake camp, as far back as seven years ago, mining had proceeded to depths sufficient to result in the formation of pressure great enough to cause violent disruption of masses of rock. It is proposed in this paper to deal with the effect of pressure caused by mining as observed at Lake Shore Mines, and to describe some of the methods which have been adopted to counteract it. There are many contributing factors in a study of the problem, and results vary widely in individual mines and in different localities. One feature common to all, however, is that there is ground subsidence, evidenced either by a gradual settling accompanied by crushing and shearing of the ore and wall-rocks, or the disruption of the ground surrounding the periphery of an excavation may take place suddenly, attended by more or less violent shattering of the rocks. Such violent failure of a mass of rock has been designated by the term rock-burst. The history of rock-bursts extends over a great number of years. They have occurred in some form or other in practically ali places where mining operations, at all but very shallow depths, have been carried out. Since the theoretical aspects of the subject have been dealt 'with at great length by capable and experienced writers (1), the present paper will give only a brief résumé of the theories propounded by those engaged in deep mining operations in various parts of the world.

Jan 1, 1940