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By Onuralp Yücel, Süheyla Aydin, Erçin Ersundu

Turkish iron and steel sector, the base of which was established in the 1930?s, plays an important role in the industrialization and development of the country?s economy. In Türkiye this sector is the major consumer of ferroalloys. There had been a great improvement in Turkish Iron and Steel industry, especially after the 1980?sand as a result, 20.9 million tons of yearly crude steel production placed Türkiye 11th in the global steel output and 3rd in Europe. 15 % of steel produced in Türkiye is flat products, while the long products make the rest. The product composition and the general characteristics of steel production process led to an increase in ferroalloy consumption. Domestically consumed ferroalloys are especially ferromanganese, silicomanganese, and ferrosilicon. As of today, ferroalloy production capacity of Türkiye is 173,800 tons/year; 161,500 tons of which is ferrochrome with high and low carbon grades, 7,300 tons of ferrosilicochrome and the rest is ferrosilicon (5,000 tons/year). Türkiye is one of leading ferrochrome producers in the world considering the above mentioned production figures. However, this production is mainly exported since Türkiye?s stainless steel production level is modest requiring low amounts of ferrochrome. The products of iron and steel industry in Türkiye require large quantities of other ferroalloys, which make Türkiye a major importer and exporter of ferroalloys. The aim of this work is to present production, consumption, import and export quantities of: ferrochrome, ferromanganese, ferrosilicon, ferromolybdenum, ferrotungsten, ferrotitanium and ferrovanadium of Türkiye, between 1990 and 2006.

Jan 1, 2007

By A. Martin

Detailed porewater profiles of arsenic and other interstitial metabolites were used to assess the relationship between trophic status, sediment redox chemistry and arsenic mobility in a historic tailings repository. The results demonstrate that in eutrophied systems which exhibit greater sediment oxygen demand, the depth of the Fe(III) redoxcline, and hence depth of arsenic release, may lie in close proximity to the sediment-water interface. As a result, arsenic scavenging mechanisms are significantly reduced, resulting in a greater flux of arsenic to the water column. Such considerations have important implications for the management of pit lakes, tailings ponds and contaminated lakes which may consider: 1) the discharge of sewage to the water body during operations; and/or 2) post-closure fertilization as a remediation strategy.

Jan 1, 2002

Sm-Co alloy is a kind of magnetic material with high power and has been applied in modern industry widely. In this study, the wet chemical co-precipitation was developed for synthesis of the Sm-Co alloy oxide precursor. The thermodynamic analysis of the studied system was done to clarify the solution behavior theoretically based on the thermodynamic equilibrium and simultaneous equilibrium. Then, the experiments were done to address the various effects on the wet chemical process, including solution pH, reactant concentration, dispersant, reaction temperature and time, etc. It is found that by precise control of the process, the Sm-Co alloy oxide precursor was synthesized with fine crystallization and special size & size distribution.

Jan 1, 2005

By Emma Arakelova

?2?2 (98 %) vapour passed through a reactor at 25Pa where a Zn? target was placed at 273K- 373?. Experiments were carried out on a flow- type vacuum device. ?2?2 decomposition on Zn? surface accompanied by formation of a Zn-containing volatile complex which transferred to the gas phase, and Zn? deposited on a substrate at condensation. As the substrate, five sequentially located quartz cylinders were used at 293K- 423 K (?n). Decomposition of the Zn-containing complex on quartz substrates carried out as a first- order reaction. ?The complex decomposition constant (??) increased with the substrate temperature (?n=293 K, ??=7.05 sec-1;?n = 373 K, ?? = 87 sec-1;?n = 423 K, ?? =158 sec-1). ?The complex decomposition constant did not practically vary when the target temperature increased; the complex formation rate increased slightly.

Jan 1, 2006

By Paul Downing

When was the last time the documents and paperwork were cleaned out of the glove boxes, door pockets, under the seats and above the visors in your company vehicles? Insurance cards that expired three years ago and vehicle registrations from 1999 through 2003, for instance, don’t do any good and just take up space

Jan 1, 2008

By Steven E. Mischler, Jon C. Volkwein

A diesel particulate matter analyzer capable of direct, real-time measurement of engine exhaust particulate is necessary to effectively institute source control technology currently being used on diesel equipment and to ensure that the control measures are working. To investigate the potential of a differential pressure monitor to measure diesel particulate matter in undiluted exhaust, samples were collected from three different diesel engines-Kubota, Isuzu, and Deutz-running under 12 different RPM and load scenarios. These measurements were compared to elemental carbon concentrations in the sampled exhaust as determined by using the NIOSH 5040 analytical method. Elemental carbon is used as a surrogate measurement for diesel particulate matter. The results of the two data sets were then compared using a linear regression analysis. The coefficient of determination (or R2) was calculated to be 0.98, 0.94, and 0.74 for the Kubota, Deutz, and Isuzu engines, respectively. R2 values of this magnitude indicate that this method can be successful in estimating elemental carbon emissions in the engines tested. In addition, for replicate samples, the coefficient of variation ranged from 7.1% to 10.2% with an average of 8.5%. These data indicate that this method could prove useful to mechanics as they work to maintain engines and DPM control technologies.

By Sebastián H. Troncoso

Open pit mine planning is normally based on the selection of an economic envelope that has been generated by the Lerchs & Grossman algorithm, which requires individual economic valuation of each block of a geological block model. The selected envelope, usually called Final Pit, is later discretized in pushbacks and benches, which correspond finally to the fractions that the production schedule will allocate in time. This planning methodology has been widely used by the mining industry in countless projects to exploit open-pit mines, however, in many of the deposits can be found some undesirable elements such as arsenic, phosphates, ash among others that tend to reduce the value of elements of economic interest, either by disrupting the processes of concentration or as deemed impurities that affect the quality of the final product. Thus, a fair amount of blending would be required to capture the real value of the ore body. The traditional approach under estimates a block value by penalizing the block value by the amount of contaminant even when at the mine a set of blocks is amine at a time. This paper proposes a methodology for computing cut off grades over time that would maximize net present value allowing blending that should fulfill a set of metallurgical constraints. Preliminary results show significant increases in value and reserves quantity, questioning the use of fixed cut-off grades in generating a production schedule when blending applies to fulfill a set of geometallurgical constraints. Finally, the model allows the authors to show the importance of having adequate planning tools that will lead to the ability to look at the potential economic value of a mineral deposit.

Oct 1, 2009

By Morteza Gharouni Nik

Flexible Dilatometer Test (FDT) is one of the in-situ test methods for determining the deformational characteristics of rock masses. In this study, several dilatometer tests have been conducted in different geotechnical phases of site investigations by means of two types of FDTs. The purpose of this paper is comparison of the performance of these two types of dilatometers and analysis of the differences in the results of the tests.

Jan 1, 2008

By Rob Thomas

Pre-driven recovery roads are used to speed up the longwall recovery process by reducing bolt-up requirements and by improving ground conditions on the face during the removal of the powered supports. To lower the geotechnical risks associated with the use of pre-driven recovery roads, and so improve its overall acceptance in the industry as a viable alternative to more conventional, potentially difficult and costly longwall recoveries, this paper outlines (i) a geomechanical model for the use and design of pre-driven recovery roads, (ii) an updated version of the worldwide database on pre-driven recovery roads, (iii) a summary of the various methods of holing a longwall into a pre-driven recovery road and (iv) a series of relevant ground support and strata management guidelines.

Jan 1, 2008

By D. Brandt

The Dos Pobres Mine is a copper oxide heap-leach mine located near Safford, Arizona. Mine production is 180,000 tons (163,293 tonnes) per day with a stripping ratio of 2:1. During the startup phase of the mine, the required fragmentation size was easy to achieve as the ore was highly weathered and fractured near the surface. As the mine depth increased, the proper fragmentation size became harder to achieve due to less weathering and different rock types. Because copper recovery increases as crusher product size decreases, achieving the appropriate product size at the crusher is the operating priority. The Engineering Department started a project to improve fragmentation through blasting and thus increase throughput in the crushing system. It soon became clear that input from other departments was going to be required to make this a safe and economical project. Therefore the Crush and Convey and Ore Control departments worked together to evaluate all available data on blast patterns and explosive loads and tracked performance and results. Using image analysis, Drill Energy Index and databases, we have been able to improve fragmentation size and verify the results while controlling costs.

Jan 1, 2011

Innovative and Resource-Preserving Washing Processes for Primary and Secondary Raw Materials

Sep 13, 2010

By R. L. Gibson

Manpower competencies in the mining, minerals processing and energy industries in South Africa into the next century will, to a large extent, derive from the nature and quality of the teaching which pupils receive at school. This paper provides an overview of the current developments towards a new National Curriculum in South African Schools and highlights areas in which the Minerals Industry might provide input into this process.

Jan 1, 1997

By Ivan B. Cutler, Milton E. Wadsworth

Coprecipitation of anionic and cationic polyelectrolytes has been applied to flocculation of several mineral systems. Results obtained in a study of the flocculation of kaolinite and hematite suspensions of polycationic and polyanionic electrolytes are presented. Greatly increased settling rates were observed following precipitation of positive and negative polyelectrolytes on the surface of finely divided minerals in aqueous suspension. The ratios of polycationic to polyanionic electrolytes required to produce maximum sedimentation have been shown to correspond closely with the equivalence points obtained by light scattering studies of systems containing the positive and negative polyelectrolytes by themselves.

Aug 1, 1956

By Jom Gentry

Acrylamide chemical grout (C3H2NO) has been successfully used for over 50 years to control groundwater and stop infiltration. This paper will address three unique projects involving the control of groundwater with each study providing special circumstances and geological conditions: encapsulation of radioactive hazardous waste in the United States, a tailings dam for a large copper/gold mine in Argentina and 27 miles of leaking subway in Canada. The primary reasons for selecting acrylamide grout were based on the following characteristics: thinnest chemical grout on the market, a true solution grout which contains no suspended solids in the blended product, flexible gel set times, and a 362 year half-life in soil as determined by the U.S. Department of Energy.

By F. E. Diebold

The methodology for describing the geochemistry of elements in a coal seam have been developed. This has been applied to the Rosebud Coal Seam, which is an economically important member of the subbituminous coals of the Fort Union Formation in Eastern Montana. The method development has involved a detailed study of two popular techniques for determining the metal geochemistry of coal, namely, whole coal analyses and coal physical fractionation. The mathematically contrived element associations (whole coal analyses technique) and the element concentration trends in the float and sink fractions (physical fractionation technique) are considered to lead to only qualitative conclusions concerning the chemical associations of the elements in coals. Additionally, the processes taking place with the coal during low temperature ashing in an oxygen plasma are experimentally investigated and shown to be of sufficeint extent that the use of such low temperature ash for deciphering element geochemistry is questionable. The method developed in this study is a chemical fractionation that involves the sequential leaching of coal with water, 0.5 N HC1, 3 N HC1, 2 N HNO3, and 48% HF. These leach solutions are shown to selectively dissolve the predominate inorganic phases, sulfates, Ca and Mg carbonates, Fe sulfides and K alumino-silicates and quartz, respectively. These phases were identified with the use of XRD, SEM, EM and leaches (water and 0.3 N HC1) of whole coal and low temperature ash. The incorporation of the anion-exchange step in the leaching scheme was investigated and was observed to warrant further study of such intensity to be, at the time, unuseable. The use of this sequential leaching technique on several coal samples from the same seam generates element concentration trends that can be quantitatively interpreted with respect to the chemical associations of the minor and trace metals in the coal seam. The properties of the various seams of economic importance in the Fort Union Formation in Eastern Montana are compiled and presented. The subsequent conclusion is that there is not a large variation in the properties of these coal seams and that the variations within the Rosebud are within one order of magnitude. The chemical fractionation technique, investigated in this study, was applied to composite tipple samples of the Rosebud seam. Each composite sample represented 76,800 tons of coal. A minimum of 32% of the Ca and Mg are present as separate water soluble sulfates. An excess of the sulfate ion in the water extracts shows the predominating influence of the ion exchange capacity of the organic compounds in the coal. Based upon the CO content of the coal and the HC1 leachate data, 25 to 30% of the alkaline earth elements exist as separate carbonates and the remainder are associated with the organic compounds. The small fraction of the illite that dissolves in the HC1 and HNO3 leachates accounts for the K and Al. Slight dissolution of the pyrite in the HCl solvent occurs, the small amounts of Li and As do not relate to any known phase and Mn is present as a separate carbonate phase. Fe and a significant amount of the As exist in the pyrite that is dissolved in the HNO. Se is equally partitioned between the pyrite and the organic compound~. Most of the trace elements are found in the HF solutions. Li, V, and Cr were interpreted to be associated with the clay minerals (kaolinite and illite). Ni and Pb appear to be present as separate phases and 50% of the Hg is HF soluble but is not chemically related to any known inorganic phase.

Jan 1, 1983

By Jesus P. Manzano

The report of which this paper is a summary was made in 1890 for the Compania Investigadora Mexicana y Americana. Since the region examined covers 900 sq. kilom., chiefly of wooded arid rocky hills, almost without roads, and for the most part uninhabited, While the examination had to be made in two months, of which period more than 15 days were continuously rainy, I need not say that this account is not complete and thorough. I. Geography and Topography. The center of this zone, 19 kilom. SW. of San Luis Potosi, is situated in lat. 21° 24' N., and long. 2° 3' W. of Mexico City. The altitude ranges from 1866 m. (that of San Luis) to . 2816 m. (that of the Realito mountain), in the Sierra de Sail Luis. The topography is hilly—partly wooded, partly bare. The principal more level areas are the Bledos valley on the south, and portions of the haciendas of Tepetates, San Fran cisco and Santiago, on the west. The water-supply is scanty. The two streams that cross the Zone, the Santiago and Bledos rivers, carry water nearly the year through, though much reduced in the dry season. Other streams are torrents of less importance. All the waters of the valley and Sierra of Sail Luis arc absorbed or sink, not passing beyond Soledad de los Ranchos. The Continental di vide is within the Zone, some waters going west to the Pacific, others east to the Gulf of Mexico. II. Geology. Concerning the geology of this district I condense the fol lowing from the memoir, Las Minas de Guanajuato, prepared for the Minister of Fomento by Senor Pedro Lopez Monroy, mining engineer, with which I am entirely in accord. He says, ill substance:

Jan 1, 1902

By Bradford C. Wesstrom, Ricardo Parra

The Freeport McMoRan El Paso Refinery uses co-generation to produce some of its electricity and all of its steam. This paper will cover the operation of the co-generation plant natural gas turbine at a fixed RPM for blade longevity and energy output. The by-product heat from the turbine passes through boilers with additional heat from a duct burner to produce steam for the Tank House and auxiliary operations. The steam demand varies dramatically throughout the day based on unloading activities in the Tank House. The use of an automated steam control system within the El Paso Refinery will help stabilize line pressure by incrementally controlling steam consumption based on electrolyte temperature. This will minimize steam line pressure fluctuations. INTRODUCTION In the mid 1920’s the Nichols Copper Company of Laurel Hill, New York recognized the need for a modern copper refining facility in the southwest. Due to the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the logical location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Energy costs (electrical and thermal) are critically important in the viability of modern copper electrorefineries. The El Paso Refinery produces electricity and steam through its cogeneration system. The El Paso cogeneration facility is a natural gas, 15-megawatt facility containing five turbine generators and associated waste heat recovery boilers. The facility is divided into two phases. Phase I consists of two Allison 2.2-megawatt turbine generators. Phase II consists of three Solar Taurus 3.5-megawatt turbine generators. Presently three units in Phase II are operated. The Phase I units were purchased and installed in 1986 and the Phase II units in 1992 (Solar 1991). The facility operated at full capacity until 2003 when steam demand was significantly reduced due to decrease in cathode production and closure of the copper sulfate and precious metal operations. Phase I units were taken out of service and put on care and maintenance status.

Jan 1, 2019

By P. Christmann

"In June or July 2005, the European Commission will present its Thematic Strategy on the Sustainable Use of Natural Resources proposal to the Council and European Parliament, one of the seven Thematic Strategies to be developed and implemented under the 6th European Environment Action Programme in support of the European Union’s Sustainable Development Strategy defined by the European Union’s Head of State at the Göteborg European Council, in June 2001. The time scale for this Thematic Strategy is 25 years (2005-2030). This paper discusses some of the key issues related to the EU minerals and metals industry that needs to be addressed by the Strategy. These are: - the need for access to mineral reserves in the EU and abroad; - the need to strenghten the capacity of developing countries to sustainably promote and regulate the use of their mineral potential; - the need for an EU mineral resources intelligence capacity. There are additional important needs, which are not discussed in this paper, such as: - the need to foster further innovation in mining, ore beneficiation and metallurgical technologies; - the need to integrate and simplify the exisitng complex regulatory framework applicable to the EU mining industry and to effectively implement existing legislation."

Jan 1, 2005

By G. Taylor

"The Iron Ore Company Of Canada's Carol Project is located in Labrador City, Newfoundland. Labrador City is some 912 air kilometers northeast of Montreal, and 417 ratl kilometers north of Sept-Iles, Quebec.Over 2,800 employees work at the Carol Project to produce some 20.0 million tonnes of concentrate and 10.5 million tonnes of pellets annually.In 1979 our Training Department started to develop the DACUM System of training for our Concentrator Operations Department.DACUM is an individualized, self-learning, training program. It is both a curriculum plan and an evaluation instrument.To date, the DACUM System has been completed for all occupations in the concentrator and work will commence shortly to develop DACUM for our Pellet Plant and Mine Operations Departments."

Jan 1, 1982

By Kot Unrug

Mine seals are necessary in nearly every mine to isolate mined-out areas from the ventilation network. There is a large number of seals in active mines and that number continually increases as the development spreads across the reserves. The recent accident caused by the failure of seals in the Sago mine resulted in new regulations. These regulations have been set based on a principle of eliminating the risk of failure, rather than the sound engineering and understanding of the conditions that may cause seal failure during an explosion of methane in sealed areas of the mine including the probability of such occurrences. This paper discusses the following subjects related to mine seals: The potential causes of methane explosions and the dynamic effects of pressure wave propagation. Seal materials and methods of construction in view of the interaction of the seal with the host rock environment as well as requirements for gathering geotechnical data. The design of seal dimensions is based on loading conditions, therefore the probable ranges of such loading is reviewed. There is also discussion of possible methods for shielding of seals from pressure pulses following an explosion. Particular seal?s types are examined in reference to the conditions at the seals location. A novel design is presented that will be a low- cost solution for the sealing of mined out areas. Recommendations are given for further research leading to a rational engineering system for design of new seals in coal mines.

Jan 1, 2008