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By Carle R. Hayward

The growing importance of metallography has caused a corresponding interest in the improvement of apparatus for preparing specimens of metals and alloys for microscopic examination. The purpose of this paper is to describe an electric heating-furnace, a grinding- and polishing-machine, and a device for mounting specimens, which are used in the metallographical work at the Massachusetts Institute of Technology. These three pieces of apparatus were designed and made in the laboratory of the Institute, and each possesses some original features which may be of interest. Electric Heating-Furnace. The accurate control of heat necessary for metallographic work is best obtained by the electric-resistance furnace. Uufortunately, however, even the platinum-wound furnaces cleteriorate with use and ultimately burn out, while the cheaper resistance-materials are often short-lived. Since the resistance-coil must be replaced from time to time, it is of advantage to be able to make this change with as little trouble as possible, and this is an important feature in the furnace shown in Fig. 1. A is a cylindrical galvanized-iron can, with two handles, B. A porcelain tube, C, passes through the central hole in the cover of the can and rests upon the asbestos disk, D; the bottom of the tube is held in place by the asbestos ring, 3. The space, F, around the tube is filled with powdered magnesia. G is an ordinary assay-crucible, with the cover inverted so as to present a smooth top for supporting a second porcelain tube, H. The latter is wound with " Excello " resistance-tape, 0.014

Jan 1, 1912

By Teder R. I., M. M. Protodyakonov

In order to find an empirical relation between a quantity F and (m) independent variables or factors, each of which take (n) different values or levels, it is necessary to conduct nm different experiments (all possible combinations of the factors), each of which has to be repeated a few times (usually five) due to the scattering of the data. The total number of such experiments is very large, thus for example, when m = 4 and n = 5, it is equal to 5.54 = 3125; and very rarely is it possible to conduct such a number of experiments. Various possible methods of planning partial experiments are illustrated in Fig. 1. Each method shows a large combinative square consisting of five columns and five rows of middle squares, each of which, in turn, is further divided into five columns and five rows of cells. Such a partition corresponds to a plan of an experiment with four factors, each of which takes five different levels. The blackened cells indicate the combination of factors in a partial experiment. The total number of experiments is reduced on the basis of the following considerations: a) The effect of only a few levels of some factors is studied (Fig. la). Such an investigation gives no information on the effect of some factors, therefore it cannot be accepted as satisfactory; b) By reducing the number of levels of each factor; in such a case it is not possible to obtain an empirical relationship, but only whether some factors have an effect. This is evidently inadequate;

Jan 1, 1971

By A. B. Fly

Borehole mining combines the principles of hydraulic mining, slurry mucking and rotary drilling. The borehole is drilled with conventional equipment and is cased down to the top of the mining zone. The borehole mining tool is comprised of the kelly-swivel assembly, multiple drill-pipe sections, and the jet-pump barrel assembly as shown in Fig. 1. The kelly swivel is fitted with a bail to support the mining tool. The kelly drive bushing engages the rotary table to allow the rotation of the mining tool while it is being operated. The jet-pump barrel assembly is comprised of the sidewall jet nozzles, the jet-pump assembly, the suction screen, and the tricone rock bit. Clean fluid is pumped at high pressure through the kelly hose to the high-pressure swivel on the mining tool. The high-pressure pipe conducts the fluid down to the sidewall jet nozzles, the pump jet nozzle, and the tricone rock bit. The sidewall jet streams cut the formation and wash the cuttings down to the rock bit. High-pressure fluid issues from the water courses to clean the bit and to agitate the cuttings. Rotation of the mining tool causes the rock bit to grind any oversize material enough to permit its passage through the suction screen. High- pressure fluid issues from the pump jet nozzle to provide the lift needed to pump the slurry to the surface. The slurry is discharged into the settling pits where the cuttings are deposited and the clean fluid is returned to the suction of the high-pressure pump.

Jan 3, 1969

By P. J. Carroll, H. Colijn

Feeders must be considered an integral part of the over-all bin and feeder system. Improper design of either one of these parts will affect the performance of the whole system. Feeder load, material properties, feed rate, physical layout, and environment as well as first cost determine the selection of feeder type. This paper provides a new method of calculating feeder loads with some experimental data as verification. General design criteria for belt and apron feeder, rotary table and plow feeders are discussed and a special section is devoted to vibratory feeders. Feeders are used to provide a means of control for the withdrawal of bulk materials from storage units such as bins, bunkers, silos and hoppers. This control function can only be performed properly as long as the bulk materials flow by gravity to the feeder in a uniform and uninterrupted fashion. During the past few years various papers have been written and presented on feeders and their application.1-9 This paper will be confined to some specific bin-feeder design criteria such as feeder load and power requirements. Special attention is given to the basic design criteria for vibratory feeders. HOPPER AND BIN DESIGN Feeders must be considered an integral part of the over-all bin and feeder system. Improper design of either one of these parts will affect the performance of the whole system. A lot of effort has been devoted in the past decade to the development of functional design criteria for hoppers and bins.1,10 The integrated concept of bin and feeder design requires quantitative analysis of the bulk material characteristics before the design and the selection of components can be attempted. The design of a feeder system must begin with the proper dimensioning of the hopper outlet to prevent arching or ratholing. The hopper opening should be large enough to allow passage of the bulk solid at the required maximum discharge rate." A feeder can only throttle the flow. FEEDER LOAD DETERMINATION Over the past ten years, there have been various attempts to determine the exact load or pressure on feeders mounted directly under hopper openings. Many designers, however, still consider this pressure equal to the hydrostatic head of material above the opening, and because such pressure would be very

Jan 1, 1969

In Mr. Weed's interesting paper, frequent reference is made to the Cananea copper-deposits, which are said to have been so vigorously exploited that they produced 14,000,000 Ib. of copper in 1901. The ore-bodies which yielded this large quantity of metal are described as a product of contact-metamorphism, and in Mr. Weed's genetic classification of such deposits, they receive a place under the sub-heading, "Deposits impregnating and replacing beds of contact-zone."* They are considered by Mr. Weed to represent a special type under this head, and are further classified as: " l. Chalcopyrite deposits: (a) Pyrrhotite ores; (6) Magnetite ores, Cananea type." In condensing much information into a comparatively small space, the presentation of a subject may be so abbreviated as to detract from its clearness. The situation at La Cananea, considering its importance from an economic as well as scientific standpoint, may he worthy of more detailed description. As Mr. Weed rightly remarks, " structural differences are so important, and have SO marked a bearing, not alone on the theory of their genesis, hut also on the working of the deposits and a determination of their value as mines, that they merit a full discussion."† It is my present purpose: (1) to show that it is doubtful whether the copper of La Cananea is mined, except to a limited

Jan 1, 1903

By Cyril Stanley Smith

Although alloys of copper and silicon were examined several years ago,' and their excellent mechanical properties were shown, it was not until C. B. Jacobs 2 introduced manganese in small quantities to the alloys that they became of commercial importance. A few years ago The American Brass Company took over the patents and commenced to manufacture the alloy under the name "Everdur." The present study of the constitution of the ternary system was undertaken in order to reach a fuller understanding of the behavior of the alloy. Review of Previous WORK on the BinaRy Systems There have been no papers published dealing with the constitution of the ternary system, although some tests of the mechanical properties have been described," which indicate that there is a change in solubility with temperature. Copper-silicon System The copper-silicon system has been studied in detail by the author and is described in two papers published in 1928.V he portion of the diagram up to 8 per cent. silicon, as determined by this research, is reproduced in Fig. 1. The author's previous papers include a complete review of the work of other investigators and it is not necessary to deal further with this system here. Copper-manganese System The copper-manganese system has been investigated by several workers, notably Lewis,5 Wologdine,6 Sahmen7 and Schemtschuschny,

Jan 1, 1930

By W. H. Bassett

Beads of metal frequently appear at the ends of cast-copper wire bars and on the sides of wedge cakes near the top. These are richer in cuprous-oxide than the rest of the casting. A micrographical study of these exudations has been made. It is suggested that the material is forced through the surface while the copper is solidifying. If not eliminated in process of manufacture, it shows on the finished polished sheet copper in patches differing in color from the main body of the sheet. FIGURES 1 to 4 show the copper exudations, at different magnifications, as they appear on the ends of cast wire bars, and on the sides, usually near the top, of wedge cakes. Sometimes the exudations are in fine "drops;" at other times, large masses of the material are found. Microscopic examination of the copper exudation indicates that it is high in oxide and of eutectic proportions. Because of the difficulty of securing a suitable sample, the protuberances have not been analyzed chemically; but the spectroscope shows no indication that there are any more metallic impurities present than in the balance of the copper. The lowest copper plus silver content of the coppers studied for this? paper was 99.914 per cent.; the highest, 99.966 per cent.; so the oxygen content of the whole casting would be well under 0.07 per cent.

Jan 2, 1926

By P. H. Dudley

THE piping and segregation of ingots of steel is a comprehensive subject, and must be studied in reference to the different grades of soft, medium, and hard steel, rather than to discuss it in a general manner, as though applicable to all grades. Rail steel, however, will receive the most consideration in this paper, for the wheel-loads of the motive pourer and rolling stock have doubled from 1890 to 1910. Steel rails and tires which were efficient under the light loads, became less serviceable under the double wheel-loads, quadrupled tonnage, and higher speeds. Bessemer Steel. Bessemer steel of froth 0.10 to 0.15 per cent. of carbon, for splice-bars, spikes, and tie-plates, rises in setting, and is cast in bottle-mouthed molds, which must be capped to prevent an over-flow from the top. This grade of steel rises in the molds and makes a longer ingot than the volume of molten steel when first teemed. The ingots which are allowed to cool and then cut open, show, particularly in the upper part, large occluded blow-holes, and when they are Dot oxidized or do not contain foreign matter, weld more or less completely when the steel is rolled or forged above 1,100° C., and it :is in this way that the blow-holes are closed it the low-carbon steels.

Jan 4, 1913

By E. M. Wise

THE properties required of gold alloys for jewelry are not well standardized, due in part to problems peculiar to certain branches of the jewelry industry, in part to the individual preference of the fabricator and to his willingness to cope with certain difficulties in manufacture, which arise with the use of certain alloys. GENERAL REQUIREMENTS In general, the properties desired may be classed as follows: 1. Color should conform to the dictates of good taste and smart style. 2. Corrosion resistance and tarnish resistance should be good. This is to a considerable extent determined by the carat. Resistance to such corrosive agents as mercuric chloride as well as certain depilatories is unreasonable to expect and difficult to meet. 3. Strength and hardness must be adequate to maintain the delicate contours of finely modeled jewelry. 4. Wear resistance must be great enough to resist abnormal wear, such as is encountered by a wedding ring in a lifetime of wear. 5. Ductility must be sufficient to permit the fabrication of drawn shells, tubes and difficult shapes. Material having a yield point of not less than 60,000 lb. per sq. in., an ultimate strength of 100,000 lb. per sq. in., and an elongation of 40 per cent. is desirable. 6. Melting point should be between 800° and 1200° C.

Jan 1, 1928

By C. E. Jackson, E. C. Nelson, A. L. Christenson

Much information regarding the transfornlatio~lal characteristics of a steel as it cools in a known manner from the austenitic state can be obtained from dilatometric studies. This method has received more arid more attention because of its great flexibility, accuracy, and ease of interpretation. 'The method is entirely applicable to any rate of heating and cooling although the experumental procrdures for high rates of cooling have offered some difficulties. This paper presents a description of equipment employing cooling rates up to 500 °C. per secorld and the results of dilatometric observations on six commercial steels are included. French and Klopsch1 studied the cooling transformations of a serirs OF carbon steel, using the thermal arrest method. This was followed by the systematic investigatiol1 of Esser and co-workers on the effect of carhon2 and other alloying additions. in which the transforlnation temperature\ were determined by magnetic induction measurements indicated by a string galranoineter. Emphasis was placed on determining Ar' trailsformations and the critical cooling rates for these steels. The maglietic measurements wrere used in an effort to obtain more accurate data at higher cooling rates. Measurements of thermal arrest were made also to check the validity of the magnetic indications, and good correlation was found between the two, although Esser's,Ar' temperature measurements on iron-carbon alloys were about 200°F. lower than the measurements made by Fresnch and Klopsch. A notable contril~ution by Esser was the introduction gas quenching. wever and Rose4 used a moving-coil galranometcr in the study of the .Ar and Ar" of iron-carbon alloys by the thermal arrest method and obtained somewhat lover Ar" temperatures than those observed by Esser below I per cent carbon and considerably higher ahove. They concluded that the cooling rate had little influcncc on the Ar" temperatures above 0.4 per cent carbon, although Esser had observed a decrease in the -4r" temperature with increasing cooling rate with similar steels. Digges determined the .Ar" temperature4 for a scries of high-purity iron-carbon alloys, and close agreement with his results was obtained by Greninger. The thermal arrest method. together with metallographic observation used in both these studies, represents the latest investigations of this type. Any investigation by thermal analyses is dependent on the heat of reaction and the specific heat of the

Jan 1, 1945

By Arthur E. Bousu, C. T. Eddy, L. W. Eastwood

THE recrystallization and grain-growth phenomena of cold-worked metals have considerable industrial importance because of their role in the fabrication of metals. For this reason, and because of the general academic interest in the subject, these processes have received considerable attention since the time of J. E. Stead's paper1 on The Crystalline Structure of Iron and Steel. There are considerable differences of opinion regarding the theory of recrystallization and grain growth and also differences in the observation of the modus operandi of the processes themselves. The value of many of the existing quantitative data on grain growth is decreased by the failure to distinguish between the grain sizes just after complete recrystallization and those resulting from coalescence. For this reason also, the value of the diagrams of stable grain sizes, like those produced by . Bass and Glocker2 and Czochralski3, is lessened in so far as an interpretation of the facts of recrystallization is concerned. It is hoped that the data presented in this paper will help to clarify and to simplify the facts relating to recrystallization, and at the same time will show that some of the present-day conceptions are untenable. A paper on the theory of recrystallization with additional data will be completed in the near future by the writers.

Jan 1, 1935

By M. Sagheer

This paper gives a report of the laboratory work investigating the fundamental flotation characteristics of chromite and its commonly associated mineral, serpentine. Floatability curves, showing floatability of chromite at different concentrations of sodium oleate and pH, were obtained by pick-up method. One of the difficulties encountered in flotation of chromite in presence of serpentine has been attributed to dissolved metal ions. The influence of metal ions, dissolved in pulp filtrate, on floatability of pure chromite and serpentine has been studied and it has been shown that Mg, Ca and Fe ions depress chromite. A considerable amount of work applying bubble pick-up method was carried out to counteract the depressing action of metal ions. Various methods and reagents were applied in this connection. Validity of each method and reagent has been discussed. Probably due to the abundance of high-grade chrome ores, very little has been published concerning the flotation of chromite. As improvements in mineral beneficiation are realized, more attention is being directed to low-grade ores previously considered unusable. Currently, gravity concentration is the principal process applied to upgrade chrome ores, but this cannot be used for finely disseminated ore because of the substantial losses in the fines,1,2,3 To avoid these losses, flotation can be applied to material which is too fine for satisfactory gravity concent ration, and it is probable that a combination

Jan 1, 1967

By Hans Lundberg

In order to comprehend the help and information that may be expected from electrical prospecting, it is necessary to have at least a general knowledge of the methods and principles involved in preparing and interpreting results obtained in the field. Electrical prospecting is rather complicated, both in theory and practice, and in order to make a brief description clear to the practical mining man it has been necessary to idealize and generalize the problems, at the risk of having such simplification criticized by the theoretical man. This simplification must not be misinterpreted as showing a lack of theoretical knowledge. For its operation, electrical prospecting mainly depends on the fact that most metallic ores conduct an electric current much more readily than barren rocks. If an electric current flows through a block of ground within which a body of chalcopyrite is enclosed in country rock of schist, the current will find less resistance to its passage through the chalcopyrite than through the schist, even though the passage through the latter be much shorter. This is because the longer path through the chalcopyrite offers less resistance, owing to the superior electrical conductivity of the chalcopyrite (Fig. 1). The good conductor, chalcopyrite, in the poor conductor, schist, thus attracts the current and deflects the normal flow far outside the conduct-

Jan 1, 1929

By C. Ernest Birchenall, Gerd M. Rosenblatt

The pressure and molecular weight of the antimony vapor over solid solutions of tin in antimony, containing 97.4, 94.9, 93.0, and 90.7 at. pct Sb, have been measured from 445° to 545°C by the torsion-effision method. The vapor is all Sb, within experimental error. A solidus curve which differs somewhat from the accepted curve has been calculated using the measured antimony activities. Metallographic examination of additional annealed alloys substantiates the accepted solidus. The solid solutions, which show negative deviations from ideality, probably do not deviate greatly from regular solution behavior. HANSEN' considers the Sb-Sn phase diagram to be well established with the exception of the boundary of the (Sb) phase.* Although there have been no pre- Their data can be combined with data for the solid alloys to calculate the solidus curve of the (Sb) phase. This paper presents measurements of the pressure ant1 molecular weight of antimony over Sb-Sn solid solutions containing 97.4, 94.9, 93.0, and 90.7 at. pct sb. Measurements were made by simultaneous use of the volmer3 torsion and Knudsen, effusion methods. The results of these measurements have been combined with the vapor pressure of pure antimony5 to obtain the activity of antimony in the primary solid solutions. The solidus curve calculated from these data differs somewhat from the accepted curve and is rather uncertain. Metallographic examination of Sb-Sn alloys was carried out to clarify the position of the solidus of the (Sb) phase. EXPERIMENTAL The apparatus and technique have been described previously.5 The measurements were made with the same effusion cells and torsion wire used in the measurements on pure antimony. The torsion measurements were calibrated with mercury at 30" using a mercury vapor pressure of 2.96 x 10-3 mm Hg determined by concurrent, absolute, weight-loss experiments. As in the measurements on pure antimony, an extraneous vapor was observed to distill off during the first run after the cell had been loaded with A fresh sample of alloy and during the first minute or two of every run. The change in composition after a series of runs with one sample was of the order of 0.1 at. pct and thus completely negligible in the calculation of the thermodynamic properties. The alloys were prepared from pieces of Merck antimony and Matheson, Coleman, and Bell reagent-

Jan 1, 1962

By E. W. Krampert

The oil industry was very active in Wyoming in 1936, in contrast to the several quiet years preceding. Production for the year again increased about 7 per cent, following an 8 per cent increase in 1935. During the year, 85 oil wells were completed, compared to 55 in 1935. Three gas wells were completed in 1936, and three in 1935. At the end of the year 45 wells were drilling, as compared to 55 drilling at the end of 1935. Two new oil fields and one new gas field were discovered in Wyoming during the year. In the year 1936 Wyoming produced 14,475,431 bbl. of oil, a gain of 1,001,081 bbl. over the 1935 figure of 13,474,350. This increase, in the main, was due to the taking of light oil from the newly developed Sundance sand pool at Lance Creek, and from the new fields, Quealy and Medicine Bow, which contributed their first production this year. Most of the other old fields either were partly shut in in competition with the new fields, or showed a normal decline. This was especially noticeable in the black-oil fields, where production had been slowly but steadily increasing for a number of years. During 1936 black-oil production decreased approximately 100,000 bbl. as compared to 1935. The only black-oil field to show marked increase was Garland, which managed to take the market from less favorably located fields. The production of Wyoming in 1936 was 11,358,757 bbl. of light oil and 3,116,674 bbl. of black oil. Salt Creek, with a production of 6,015,000 bbl., is still the largest single oil-producing field, accounting for 42 per cent of the year's total production. Lance Creek, an old field, with newly developed production in the Sundance sand, reached second place this year for the first time in its history, with a production of 1,878,486 bbl. Lance Creek production will almost equal that of Salt Creek in 1937, if the present rate of production is maintained during the coming year. Oregon Basin, a large black-oil field, held second place in 1935, but owing to a greatly lessened demand for its production, dropped back to third place in 1936. This was in part due to greatly increased light oil available, and in part to the greater supply of black oil available at

Jan 1, 1937

By Oscar A. Glaeser

It is common knowledge that the iron orebodies of the Mesabi Range lie nearly horizontal and are of trough or blanketlike types. These orebodies are from a few feet to several hundred feet thick and vary from a few acres in extent to the size of the largest one, at Hibbing, Minn., which is over 1 mile wide and 3 miles long. They are covered with sand, boulder and clay overburden and occasionally shallow depths of ledge material, varying in total depth from about 20 to 200 ft. Large areas are not capped with overlying ledge material; the top of the ore lies directly underneath the surface material. Because of the comparatively great tonnage of ore, open-pit mining has made tremendous strides since the first open-pit ore was shipped from this range by the Merritt brothers, from the Mountain iron mine in October, 1892, and along with the great development of open-pit mining on the Mesabi Range has gone a tremendous change in the character of. equipment used. Early Stripping Operations The first stripping at the Burt mine at Hibbing, Minn., started in 1902. The engineers spent a long time in selecting the most suitable location for a small pit area, involving a stripping contract of 350,000 cu. yd. This property afterwards had several million yards of stripping and several million tons of ore removed from it, but inasmuch as it was the first open pit of the Oliver Iron Mining Co. in this district it was necessary to try several different locations for the small pit area, to uncover maximum tonnage and the best grade of ore so as to sell the idea of open-pit mining and discontinue the underground operation then going on. The writer's first open-pit work on the Mesabi Range was in 1903 as an Oliver company mining engineer on a stripping job of 1,500,000 cu. yd. at the Monroe mine, Chisholm, Minn. Here the contractor, an old-timer used to railroad methods, was, to a small extent, using teams of horses hitched to 2-yd. narrow-gage cars and hauling the stripping material from the pit area to outside of the pit limits. The dirt thus moved was loaded by hand. The same contractor was also using 60-ton and 70-ton railroad-type shovels with dippers of 21/2 and

Jan 1, 1930

By H. R. Wuthrich

The Metallgesellschaft AG decided in late 1965 to build an Electrolytic Zinc Plant at Datteln (W. Germany). Lurgi-Chemie was entrusted with the engineering and erection of the entire plant. Ground was broken in February 1967 and the operation was started on August 1st, 1968. The new Electrolytic Zinc Plant was designed to produce a minimum of 100,000 metric tons of special high grade zinc and 200,000 metric tons of sulphuric acid. Concentrates from Meggen (W. Germany) and mainly Timmins (Canada) are roasted in two turbulent layer roasters. The sulfur dioxide containing gases are converted in a "Bayer double catalysis unit" to sulfuric acid. The calcine is leached batch wise, the leach residue separated from the pregnant solution by counter-current thickeners and drum filters. For maintaining the sulfate balance a modified jarosite leach is being used. After a two step purification the neutral solution is mixed with spent electrolyte and cooled in unpacked atmospheric cooling towers. Three electrical circuits are supplying the power to the tankhouse, each rated at 30,000 amperes. With a maximum current density of 750 amperes per square meter and a stripping cycle of 24 hours, an average current efficiency of 90 percent is obtained. Cathodes are melted in one induction furnace and cast into shapes, or alloyed with aluminum and copper for die-cast metal.

Jan 1, 1970

By J. L. Gillson

Historically, rock deposits and sand deposits of titanium minerals came into production about the same time, although there may be some argument as to what is meant by production. Beach de- posits of heavy minerals in India (Figs. 1-4) and Brazil (Figs. 5) were worked for monazite about the turn of century, but as there was then no market for titanium minerals, these were thrown away. The rock rutile deposits at Roseland, Va., Fig. 6, were worked to supply rutile for titanium chemicals and for coloring ceramics long before there was a titanium pigment business. The pigment industry started about the middle twenties, both in Europe and the U. S., and almost simultaneously the rock deposits at Ponte Vedra Beach near Jacksonville, Fla., were worked for titanium content. Since those days, production from both types of deposits has continued to grow at a rapid rate; many deposits of both types have been found, and reserves have grown to very large figures. In total tonnage of reserves, there is no doubt that the rock deposits are far ahead of the sand deposits; nevertheless there is a very large tonnage of commercial sands available. It is the quality of titanium mineral in the sand and the relatively lower costs of operating sand deposits that have kept them abreast, at least in annual tonnage produced, with the rock deposits.

Jan 4, 1959

By M. G. Corson

INFORMATION regarding the use of manganese alloys has hitherto been incomplete and available only from widely scattered sources. This paper attempts a systematic description of properties .and uses of alloys other than manganese bronze, manganin and duralumin, which are probably the only non-ferrous alloys associated with manganese in the minds of most metallurgists.1 PROPERTIES OF MANGANESE Manganese can react either acid or basic; it is hard to obtain in the pure state; it has two different crystalline lattice structures, both of the cubic system, one stable above 850° C. and the other below 650° C., both coexisting in the intermediate range. Although the commercial product is hard and brittle, the pure metal seems to be ductile. In fact Zhemchuzhny, in Russia, was able to obtain ductile manganese and draw it to fine wires by the simple expedient of adding about 3 per cent. copper to the alumino-thermic product. Copper most probably brings the silicides, aluminides, nitrides and carbides present in the commercial product into a much less harmful form of distribution. One industrial use that can be foreseen for wrought manganese articles is as anodes for electrolytic processes in sulfate and nitrate solutions, particularly with high voltages. A practically insoluble skin of manganese peroxide is likely to form in such cases and an insoluble and strong anode material will be available.

Jan 1, 1927

By H. K. Livingston

THE first person to investigate intensively the vast field of surface phenomena and capillary effects was the eminent English scientist, Lord Rayleigh (1842-1919), who laid down most of the fundamentals of this subject. This work was greatly amplified by Irving Langmuir,1 who, in connection with research for the General Electric Co., spent 25 years on the study of the surface chemistry of films, finally receiving the Nobel Prize in Chemistry for 1932 in recognition of his work. At present, William Harkins,2 of the University of Chicago, is the world's foremost authority on surface-tension measurement and his independent work, when combined with that of Langmuir, resulted in the orientation con-cept of solubility and surface activity, which is now an important funda-mental in chemistry. The theory laid down by these men was first applied to practical considerations regarding petroleum reservoirs by F. E. Bartell,3 of the University of Michigan, in connection with an American Petroleum Institute research grant. The latest and most advanced application of Bartell's work is contained in an article published in 1935 by Allen Garrison,4 of Rice Institute, in which he relates Bartell's measurements to the ratio of oil to water produced by wells and shows the types of petroleum reservoirs where the effects studied by Bartell are significant. This article is intended as a minor extension of such work.

Jan 1, 1938