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By M Ljunggren, M Lundh

Dissolved air flotation (DAF) in wastewater treatment as a separation process of submillimetre biological flocs is based on the generation of bubble/floc aggregates. DAF is a complex process but has got advantages, such as allowing a high hydraulic load, compared to sedimentation. A thorough knowledge of the physics of the DAF process is, however, still lacking. This paper will present results of experimental studies on three aspects of significance to the separation process û the flow structure in the flotation tank, rise velocities of aggregates, influence of floc size on the separation efficiency. Flow structure. Measurements were performed in a pilot plant mapping and visualising the velocity field. The dispersion water (bubbles) had a decisive influence on the flow structure due to the effect of the bubbles on the bulk water density. Stratified conditions with a less dense, bubble-containing upper layer and a clear water, denser bottom layer were important for a good separation. A simple model of the stratified flow structure was elaborated making it possible to interpret the function of the aggregate rise velocities. Bubble/floc aggregates. The dynamics of single flocs, bubbles, aggregates were visualised using a borescope + CCD video camera + digital recorder + image analysis. Sequences of video frames made it possible to determine the rise velocities of the single aggregates. These velocities were found to be in the range 1 - 9 mm/s with a tendency for large flocs to have higher rise velocities. Separation versus floc size. The floc size distribution was measured in the DAF process. Data from three different DAF cases showed, that large flocs (> about 100 ¦m) were entirely separated, whereas small flocs experienced a less good separation. It was, moreover, found, that a very significant separation of flocs took place in the very upstream end of the separation zone in a pilot plant case.

Jan 1, 2005

By Lang SC

The Broken River Province, in the northern part of the Tasman Orogen, is divided into the Camel Creek and Graveyard Creek Subprovinces. In the Late Cambrian to Early Ordovician, and again in the Late Ordovician, the northern part of the Tasman Orogen was probably a convergent margin with calc-alkaline volcanism. These episodes may have been separated by a passive phase in which quartz-rich flysch and tholeiitic volcanic rocks were deposited. Subsequently, in the Silurian, the region underwent extension forming a large turbidite basin which included the Camel Creek Subprovince and the Hodgkinson Province to the north. Melange is pervasive in the Camel Creek Subprovince which was folded twice in the Devonian. The melange may be related to thrusting accompanying D1. No rocks younger than Early Devonian have been recognised whereas, in the Hodgkinson Province, deposition continued until the latest Devonian. The Graveyard Creek Subprovince formed adjacent to the Camel Creek Subprovince, probably as a pull-apart basin on stable crust. The deformation history of the Graveyard Creek Subprovince contrasts markedly with that of both the Hodgkinson Province and Camel Creek Subprovince. In the Graveyard Creek Subprovince, melange is only present in Early Ordovician rocks. No major angular unconformities have been recognised in the overlying marine to non-marine sequence, which ranges from Early Silurian to Early Carboniferous. Several hiatuses and a slight angular unconformity, all within the Devonian, may be related to the major events in the Camel Creek Subprovince. A major deformation in the Graveyard Creek Subprovince in the Early Carboniferous had only slight effects in the Camel Creek Subprovince. Movement on the Clarke River Fault was probably an important influence on sedimentation and deformation in the Broken River Province.

Jan 1, 1990

Neutralisation, normally using lime, is the most widely used method for treating high flows of acid mine drainage (AMD). Lime costs can be very high however. If carbonate sources could be used to achieve pH values above six, costs could be greatly reduced. For example, use of locally quarried limestone at Mt Lyell could potentially reduce alkali costs from about $A 3.5 to $A 1 million/year. Methods for enhancing the effectiveness of limestone and magnesite for neutralising Mt Lyell and Savage River AMD respectively have been examined through a series of investigations. Small-scale testwork found that the maximum pH economically achievable with ground limestone was about five, due to slow dissolution rates and surface armouring. The problems of surface armouring were greatly reduced by the use of crushed limestone or magnesite at high pulp densities (75 per cent solids w/w), enabling pH values >6 to be achieved in a practical time frame. The use of particle sizes in the range 6 mm and finer also reduces costs by avoiding the need for grinding, and reduces the problems of solid-liquid separation and solid recycling that arise if large additions of ground carbonate are used. Pilot scale tests were carried out using tumbling drum reactors with limestone and Mt Lyell AMD and a pulsed-bed static reactor with magnesite and Savage River AMD. pH values averaging 6.2 and 6.4 were achieved with Mt Lyell and Savage River AMD respectively. Approximately 80 per cent of feed acidity was neutralised. A preliminary engineering design and cost estimate has been completed on the pulsed-bed reactor and shows that the concept is technically feasible and, if results are confirmed, economically attractive. Further pilot testing is planned.

Jan 1, 2002

By Howard G. L

The gold treatment plant of Great Western Consolidated N.L. is at Bullfinch, Western Australia, 22 miles north of Southern Cross, which is 100 miles west of Kalgoorlie. A railway to Southern Cross connects the mine with the main Perth-Kalgoorlie line.The plant, which commenced operations on the 31st October, 1952, was, designed by Messrs. Alex: Stewart & Co. in consultation with the technical staff of Western Mining Corporation Ltd. to treat 1,000 long tons a day, made up of approximately equal parts of quarry oxidized ore and underground sulphide ore, by moderately coarse grinding (2-3 per cent plus 65 mesh Tyler) and straight cyanidation without straking. The design had to allow for future treatment of all sulphide ore at the rate of 40,000 tons per 28-day periodand to make provision for the possible later inclusion of preaeration treatment.The test work on .which design was based was done on representative development samples, the mine being divided into zones for this purpose, to check possible local variations from average treatment behaviour. Proposed mill feed mixtures were made up from time to time for complete ore dressing tests, which were conducted in the Western Mining Corporation laboratory at Kalgoorlie.The chief feature of the design was that the plant had to handle the extremes of very soft, poor settling and filtering oxidized ore and very hard, good settling and filtering sulphide ore. On one hand, crushers and mills had to be large enough to handle the sulphide ore and on the other, thickeners and filters had to be large enough to handle the oxidized ores.The design is marked by simplicity, the use of large units of equipment, and flexibility to cope with a variety of ores.

Jan 1, 1956

Acclaimed as one of the most remarkable orebodies anywhere on account of its length and richness, the Oroya Shoot occurs on the eastern side of the Kalgoorlie gold mining district close to the contact of a fine-grained with a coarse-grained greenstone, and in association with sediments. In the same stratigraphic position on the synclinal flanks of a large drag fold there are a number of other flat ore pipes, smaller, but almost as rich in tenor. Although differing in control structure they are believed to be related genetically as all show a characteristic development of a bright-green ore known locally as "green leader". Folding and bedding structures have played an important part in formation of the ore shoots.INTRODUCTIONThe Oroya Shoot is the biggest individual bonanza of Kalgoorlie's Golden Mile. It has been stoped almost continuously over a length of 4,300 ft., and about 2,000,000 oz. of gold have been won from it. Naturally pillars are not left in the best sections of such an orebody and the detailed geology of stoped out portions can only be inferred from examination of adjacent workings.No mention is made in the literature of the actual makeup of the orebody although a few structures are shown on some of the old cross sections. A diagrammatic cross section, Fig. 1, adapted from Stillwell (1929) illustrates the form of the Oroya Shoot.Gustafson (1937) drew attention to the role of folding, previously unrecognized, in Kalgoorlie geology, and indicated that the Oroya Shoot is associated with a minor drag fold on the east limb of the Brownhill Syncline, itself part of a larger left hand drag on the Central Anticline. The latter in turn appears to be part of a regional right hand fold system as shown by Campbell (1953).

Jan 1, 1959

The working of alluvial deposits has from all times been a popular form of mining, not only from the simplieity of its operations, but also, in its more primitive stages, from the possibility of carrying it on without large capital, without skilled lahour, expensive plant, long terms of preparatory work, or, in fact, any other requisite than a shovel, a dish, and a stout pair of arms. It is possibly one of the oldest industries, and probably, also, it has been one of the most profitable.In tbe Australian States the happy days of rid alluvial deposits, when gold was to be hltd for the shovelling, are now almost over. The lust for gold has caused almost every corner of the world to be ransacked, and the more easily earned wealth to he exhausted: for the most part there remain now those deposits only which are too poor to be profitably worked by means of the implements and methods of old times. But, though the deposits have become poorer, the keen inventiveness of man has devised means whereby such large quantIties can be treated at a cost so low that he can still make a profit out of them. In this article, out of the many means devised, three only will be referred to-viz., hydraulic sluicing, bucket dredging, and hydraulic dredging. All mining may be divided into three principal operations-1st, the breaking down and conveying of the ground to where it is to be treated for the recovery of the metallic values, 2nd, the treatment of the material for the recovery of those values; and, 3rd) the removal of the worthless material or tailings. In all mining the object is to effect these three processes for the least expenditure of money commensurate with the highest degree of efficiency.

Jan 1, 1907

The reduction of titanium tetrachloride to trichloride can be achieved by employing hydrogen and electric arcs. It is possible to produce melts containing up to 50% TiCk in the eutectic mixture of LiCl/KCl by striking a D.C. arc at the surface in the presence of hydrogen and TiCl. vapour. If the electrode IS made to just penetrate the surface of the salt mixture, a hot zone results from the' high resistance contact with both lower chlorides and sintered titanium may be produced. The sintered metal forms just below the melt surface while the trichloride forms at the gaslIiquid junction.The "hotspot cathode" appears to offer a solution to the problem of producing coherent deposits as the spong'e metal can 'be continuously withdrawn in a similar manner to the "calcium process".INTRODUCTIONConsiderable interest has been shown for some years in the possible development of a cheap electrolytic process for the extraction of titanium metal, since a method using simple materials and cheap electric power would materially reduce the cost of production. Even when cheap starting materials are used, however, there exist several general difficulties in the operation of plant which both limit the speed of production and increase the cost of the product. It happens that most of the techniques so far tried produce a powder as cathodic deposit, and when this is the case the following difficulties arise:1. The whole contents of the bath must be treated with solvent in order to extract the 'metal powder which may itself tend to oxidise, and thus become contaminated.2. Fine metal powders, which often contain residual entrained salts, are less easy to consolidate by arcmelting than metal sponge.

Jan 1, 1956

High-sulphidation (HS) gold, silver and/or copper deposits are generated in both the epithermal and the upper parts of the underlying porphyry environments over vertical intervals of up to 2 km. The HS deposits are generated in advanced argillic lithocaps, which are products of the absorption of acidic magmatic volatiles by voluminous groundwater systems. Mineralisation styles in HS systems reflect depth of formation as well as the interplay between structural, lithological and hydrothermal parameters. The deep parts of HS systems, at depths of >1000 m, are typified by disseminated copper¦gold mineralisation comprising digenite, chalcocite and covellite in pervasive advanced argillic as well as underlying sericitic alteration. In highly telescoped systems, suchmineralisation may overprint porphyry stocks and associatedquartz-veinlet stockworks. Intermediate levels of HS systems commonlycontain fault-controlled copper-gold mineralisation, typically as enargite in bodies of vuggy residual quartz, silicification and/or massive pyritic sulphide. The shallow parts of HS systems, at depths of The exploration focus is on four principal HS mineralisation styles: 1. copper (eg Chuquicamata, Monywa) or copper-gold (Wafi) in thedeep porphyry-hosted parts of systems preferably, in the case of thelatter, where supergene oxidation is limited and, hence, flotationmay be used for metal recovery,2. copper¦gold-bearing replacement mantos and pipes hosted bycarbonate wallrocks in the deep parts of systems (eg Bisbee),3. high-grade gold in late-stage veins or hydrothermal breccias thatoverprint the intermediate to shallow levels of systems (eg El Indio,Goldfield), and4. large, bulk-mineable gold deposits in the shallow parts of systemsthat were subjected to supergene oxidation, thereby permittingheap-leach treatment (eg Yanacocha, Pierina).To these preferred HS styles may be added the low-sulphidation veinor disseminated gold¦silver mineralisation that is commonplacealongside many HS systems (eg Victoria at Lepanto). * Originally published in the Proceedings of PACRIM æ99,published by The AusIMM.

Jan 1, 2000

By I Warren, M P. Simpson

Adularia-sericite epithermal ore deposits have well-documented alteration mineral zonation patterns with distinctive geochemical signatures. Proper use of whole-rock geochemistry can provide useful vectors for exploration and can enhance efforts to characterise and quantify the mineralogy and intensity of hydrothermal alteration.   Analyses of Au and Ag provide the most direct vectors to orebodies, and pathfinder elements such as As, Sb, Hg, Zn, Pb and Se are similarly zoned around at least some orebodies. However, the minerals that contain these elements occur almost exclusively in veins, and therefore identifying geochemical vectors related to wallrock alteration that is zoned outward from orebodies is crucial for effective exploration.   Distal alteration zones contain quartz-illite-chlorite-carbonate-pyrite, whereas samples proximal to veins contain quartz-adularia-pyrite, with lesser though variable illite-chlorite-carbonate. Therefore, adularia-sericite epithermal ore deposits show K alteration in their cores. The resulting K-metasomatism can be evaluated in several ways. Areas that have been most intensely altered are commonly characterised by highest K contents, but these results can be complicated by variations in rock type across the prospective area. Potassium mass balance results provide a robust and rigorous assessment of K-metasomatism, however, knowledge about the composition of fresh rocks and correct identification of fresh precursor compositions of altered rocks are required. Three alteration indices provide effective evaluation of K-metasomatism: 1.   the K number, which is the ratio K/(2Ca+K+Na) (molar); 2.   Barrie values [(K2O * 100) / Sr]; and 3.   the Rb/Sr ratio. In most places these provide similar vectors, although K numbers can be complicated by the appearance of hydrothermal calcite and/or albite.   Plots of K/Al vs (2 Ca + K + Na)/Al (molar) allow estimation of the intensity of K-metasomatism and its mineralogical products, thereby complementing traditional XRD and petrographic studies of alteration minerals.

Jan 1, 2005

Although the effects of sea level changes on ore concentration processes are to some extent obvious with certain deposits, e.g. beach placer deposits, they have been largely overlooked with others such as Mississippi Valley type lead-zinc deposits. It is contended that sea level variations may have more profound effects on a wide range of deposits than has previously been appreciated. These deposits include not only placer'and residual deposits but also stratiform copper deposits, Mississippi Valley type deposits, stratiform manganese deposits and Minette type iron deposits. Sea levels in paralic basins profoundly affect the influx of 'detrital sediment, and this has to be suppressed to allow for the accumulation of thick rich deposits of coal evaporites, phosphate or metalliferous sediment. Emergence can be associated with oxidized waters, erosion, and,solution of soluble rocks. Submergence can reverse the Eh trend and can lead to preservation of ores. Both realms of surficial sedimentary environments and subsurface diagenetic environments can be affected by changes in water pressure, gas pressure (pC02), Eh, pH, and temperature as sea levels fluctuate. Even relatively small sea level changes may have profound effects. For example, there is some evidence to suggest that when the level dropped below 100 metres about 10,000 years ago, the Red Sea became isolated by the sill at Bab el Mandeb in the south, and evaporated away to leave a series of shallow lakes. The Red Sea is 1 to 2 km deep. It was at times such as this that the well-known copper-zinc mineralization developed in the Red Sea trough. Changes in sea level also affect the stability field of gas hydrates which can yield large volumes of gas leading to mass movements on the sea floor (Warnke, 1986).

Jan 1, 1987

By R J. Nicholson, J M. F Clout

As part of an overall strategy to make significant new technological advances for the sustainability of the mineral processing and related process industries CSIRO Minerals has developed a new dry separation device. It represents a technology breakthrough and has the potential to radically change the way in which dry particle size classification is achieved in the minerals industry. Conventional dry separation techniques have limited applications and often suffer from low productivity, high operating costs, low separation efficiency, the need for dust control and a lack of flexibility. In the absence of efficient dry techniques, wet processing is often used. The use of wet processing either requires the introduction of water into a separation process, which causes environmental concerns through the need for water supply and tailings dams or the use of æunfriendlyÆ chemicals for dense media separations that have considerable impact on handling and disposal. Wet processing also increases operating costs due to plant instability, materials handling, thickening, filtration and product drying. The new CSIRO technology exploits a combination of natural and applied forces to achieve specific particle motions that produce size separation. In doing so, many of the traditional shortcomings of dry separation have been overcome. The CSIRO Dry Particle Size Separator is ideally suited for dry size separation applications within the size range 1 mm to 30 ¦mfor moderate moisture levels (2 per cent), have low unit throughput, produce a fixed cut size and are therefore impractical where very high unit capacity and low operating costs are required. This paper presents a review of dry separation devices together with details of the new Dry Particle Size Separator and typical results for a number of materials, including iron ore and quarry dust.

Jan 1, 2002

Although this is a symposium on "The Occurrence, Preparation and Use of Australian Black Coal", I do not think that, in these days, any of the main energy resources can be considered only in terms of country of origin or only by itself in isolation from other energy resources. Accordingly, I propose to comment on solid fuels generally in the world energy scene, and make some brief references to Australian solid fuels, and to some other matters in the latter part of this paper. In this address I am drawing heavily on the 1974 survey of energy resources published just recently by the World Energy Conference. I do this for a number of reasons. Firstly, the survey is the latest and most comprehensive publication of its kind; secondly, it is the result of several years' work by a panel of eminent people, from all the energy industries and from some 16 widely spread countries; thirdly, substantial assistance was given by the U.S. Atomic Energy Commission in its compilation; and, finally, to let all know of the existence of the book, as I believe it to be a source document for all those interested in world energy resources. The United Nations "J" series of statistical papers provide important information on the annual production and consumption of and trade in the various forms of energy. In their respective areas, these two publications are primary information sources. Our present sources of energy throughout the world are fossil fuel deposits (coal, oil, gas), nuclear materials, water, geothermal, solar and tidal - but we are at present heavily dependent upon the natural stores of non-renewable fossil energy resources. Fig. 1 shows the changing use of energy resources in the present century. A comparison between 1900 and 1973 shows clearly the shift which has taken place.

Jan 1, 1975

By L Reynolds

The portable infrared mineral analyser (PIMA) was trialled to determine the extent and intensity of any hydrothermal alteration halo associated with gold mineralisation in the Hyde-Macraes Shear Zone (HMSZ) of the Otago Schist.   Twelve diamond drillholes through the HMSZ were analysed with the PIMA at a sample spacing of 1 m. The drillholes were selected on two traverses along the line of strike and down-dip of the mineralisation in and around Panel 2 of the Frasers underground development.   The study showed that the Hangingwall shear of the HMSZ has a more distinctive infrared signature in intersections with high grades. The Hangingwall shear in these drill holes is defined by a shift in the wavelength of the Al-OH absorption feature from ~2220 nm to <2210 nm. This shift is attributed to a change in the mineralogy from phengite to muscovite. Overprinting this trend in some of the drillholes is the presence of the 2210 nm Al-OH absorption feature, ascribed to kaolinite. Kaolinite also tends to be present in numerous other regions of the schist above the Hangingwall shear associated with steeply dipping faults and foliation parallel joints. In drill holes with low grades the Hangingwall shear does not exhibit any obvious infrared signature.   At the scale of study, the PIMA does not provide evidence for an alteration halo associated with hydrothermal mineralisation above the Hangingwall shear. Possible tectonic movement may have displaced any alteration halo that once existed, away from the zone of mineralisation. For this reason, PIMA apparently cannot be used for predicting the location of the Hangingwall shear during exploration drilling. However, the study did show that the PIMA could define the Hangingwall shear when the rocks were sufficiently altered and mineralised.

Jan 1, 2007

By Juniper LA

ERM Consultants Pty Ltd was established in 1980 for the purpose of introducing a disciplined coal technology and power station planning service, to support Australia's efforts in establishing a major export steaming coal industry. At that time, major coal exploration programs were mounted on more than 50 potential export coal deposits with proven open-cut reserves to export 200 Mt/a of coal. The fact that Australia achieved an export trade of only 30 Mt/a, equivalent to the energy requirements for a population of around 5 million people, illustrates the very small achievement to date. The main reasons for this small export steaming coal growth have been: 1. Failure to convince potential overseas coal buyers of the benefits of coal-fired power generation, and the ability of proper power station design to overcome environmental problems, and achieve reliable operation and long life when burning Australian coals. 2. Failure to promote Australian power engineers to advise on the use of Australian coals, resulting in Northern Hemisphere power station experience dominating in market countries. 3. Failure of governments to draw on privately practising Australian power engineers and coal technologists in technical workshops, presentations and assistance to overseas countries, to ensure that personnel whose business it was to serve the follow-on needs of countries were readily available. The result of these failures has been that: 1. Only a fraction of prospective overseas coal-fired power projects have proceeded. 2. Australia has had no influence in the design of overseas power stations to ensure that potential customers would be confident that Australian coals could be reliably burnt in their boilers.

Jan 1, 1987

The Maddingley brown coal seam at Bacchus Marsh, where mined and bored, tends on the whole to a higher content of volatile matter than the Latrobe Valley brown coals, and this masks the presence of lignitic or earthy coal bands in the bore core analyses. Visits to the Lucifer Open Cut, at Bacchus Marsh, during 1948, revealed, however, a banded condition in the coal seam, as shown in Fig. 1. This banding showed in a face that had been exposed for a considerable period of time, permitting partial drying out and oxidation of the surface coal. The bands consist of different coal types, ,comparable with those found in the Yallournand Latrobe brown coal seams(l).The' light coloured bands in Fig. 1 consist of a buff to light-brown earthy coal of low specific gravity, that closely resembles the pollen coal, that occurs, as similar thin bands in the Yallourn and Latrobe seams. The 40 ft. of coal above the uppermost of these light coloured bands dries out on exposure to a black, closely cracked surface, composed of small dice-like fragments of a lustrous vitrain-like substance, and in every respect resembles the lignitic coal bands of the Yallourn and Latrobe seams.The coal between and below the light-coloured bands develops fewer and more widely spaced shrinkage cracks on drying out, and remains brown in colour and earthy in appearance, resembling the earthy coal of the Yallourn and Latrobe seams.Representative samples were cut of these coals, taking care to exclude surface coal, and analyses were made of them by the Metropolitan Gas Company, through the kindness of Dr. R. S. Andrews, Chief Chemist to the Company...

Jan 1, 1948

The past decade has seen a great increase in activity in deep seismic reflection profiling of the continental crust. Some 20 countries have conducted field experiments and the total length of deep seismic profiles surveyed to date is approximately 25,000 km. This total is very large compared to the quantity of such data that existed previously, but very small compared to the total length of seis- mic profiles of the shallow crust carried out for petroleum exploration, which some- times has exceeded 600,000 km on land in one year alone and 1,600,000 km/yr on land and sea. Furthermore, 25,000 km of seismic pro- filing corresponds to exploration of only a tiny fraction of the total volume of the entire continental crust. Thus at this stage of development of the subject, one must be wary of generalizations that are based on these limited data and then ex- tended in scope to include the crust everywhere. The state of the subject is such that virtually every new seismic line reveals totally unexpected seismic fea- tures, a sign that the subject is in its major discovery phase and a warning to the generalizers. Nevertheless, in addition to much new information on deep crustal structure in specific locations, some broad consequences of application of this powerful geophysical technique to a region of the earth not pre- viously explored in this manner are be- coming clear. One is that, as seismic data on the deep continental crust become more abundant and more revealing of complexi- ties, the deep crust can be far better re- lated to rocks at the surface. Conse- quently, the geological style of reason- ing is now being extended from its normal domain of the near-surface to include the deepest crust in a comprehensive story of the evolution of the continents. This change is a subtle but important one and is evident, for example, in some cross sec- tions of the North American Transect Pro- gram, which show surface geology extended in a consistent, though speculative, manner to the top of the mantle. In other words,

Jan 1, 1987

In the course of an investigation of the influence of bismuth on copper carried out some years ago, (1) the author found that phosphorus exerted a beneficial effect on bismuth-copper alloys of low bismuth and oxygen content by neutralizing the embrittling effect of the bismuth. In the intervening years, a further examination of bismuth-phosphorus-copper alloys has been canied out and the influence of other elements and combinations of elements on copper containing bismuth has been studied.The results recorded in the present paper are part of this investigation.MATERIALSAll the alloys were made from high-grade copper (KS.A. wire-bar) of the following composition: copper 99·95%, oxygen 0,040'%, iron 0·0015%, sulphur less than 0-001%, bismuth less than (j>'OOl%, other elements each less than O· 0010/<-. The bar was hot rolled and cold drawn to strip which was cut into short lengths and cleaned in nitric acid ready for melting.A piece of this 'strip was drawn to wire 0·08 in. diam., annealed at 5000 C, and measured for electrical conductivity as a check on purity. The result was 101·5% of the I.E'.C. standard.In making the alloys, phosphorus was added as 14% phosphor-copper, bismuth as 17% bismuth-copper, and the other constituents either as copper alloys or as elements of a high degree of purity.PREPARATIQN OF STRIPSThe charges were melted in plumbago crucibles (Morgan salamander brand) in an oil-fired furnace, Le;, in the manner commonly adopted in industrial practice. The copper was first melted under charcoal, well stirred with a chaned stick, and the necessary alloying elements added and stirred in with the stick. The weight of a charge varied according to requirements but generally was about 4 lb. The charges were poured into slightly tapered brass moulds heated to about 1000 C and dressed with a mixture of mineral oil and tallow. They were not only poured under charcoal through the burning mould dressing but also- through a ring of flame produced by burning kerosene on asbestos cord wrapped round the top of the mould. Experiments carried out with plain copper proved that by this means oxygen could be excluded from the stream of metal. The billets were 7·5 in. long x O·83 in. diam. x 1·3 lb. weight.The billets were cropped about 1 in. from the top, cleaned in nitric acid, and measured for density by the usual method of weighing in air and -in water. As these measurements were required only as a check on casting, technique a high degree of accuracy was not essential (accuracy = -+ 0·2%).

Jan 1, 1942

Dr Eric Bumstead is to be commended for his recent paper on gold analysis, published in the March 1984 Proceedings. It is not often that someone in industry, rather than academia, takes the time to collect and report on such a volume of data, data which is of interest to everyone involved in gold exploration and development.After reading the paper I felt, as a geochemist and as ayer, that there was another side to this whole question of analysis that few people are aware of, i.e. the problem facing a laboratory and how the laboratory can try to give the customer maximum value for money spent.Analyses for gold are carried out for different reasons, depending on the aims of the geologist or metallurgist who presents the samples. These can broadly be separated into three classes, to answer the following questions.1. "Is there any gold in this sample?"2. "Approximately how much gold is there in this sample?"3. "How much gold is there in this sample?"In every case there is a different balance between accuracy and precision, cost and avoiding chemical problems. By "chemical problems", I mean such possibilities as samples containing high levels of sulphides, gold present as tellurides, cyanide being present, contamination with mercury, and other mineralogical oddities, plus problems such as samples containing grease.There is no such thing as one assay to cover all possibilities.Samples in category I come mostly from early stages of exploration.There are often large numbers of samples, their mineralogy is not well known and hence chemical problems could exist, but the explorer wants assays at a minimum level of precision and expects minimum cost. These characteristics do not easily come together, for although the precision required is low, the accuracy required is high at low levels. A small positive result when the true answer is nil could lead to a fruitless search and a waste of money. Conversely, a nil result, when the true answer is a small but significant level of gold, could lead to the passing over of an area that may warrant further work.Because there are conflicting requirements for this type of assay, the methods chosen must be a compromise and different assayers will balance these requirements differently and come to different conclusions. The methods cover sample preparation, assay sample size and variations in assay techniques.

Jan 1, 1984

By Phipps P. J

The rate of precipitation of ferric iron as ammonium jarosite, NH4.Fe3(SO4)2(0H)6 from acidic solutions near 100¦C, was found to increase with weight of jarosite seed crystals, and with concentration of ammonium ion, but to decrease with increasing acidity. The particle size of the product crystals was larger at low sulphate concentrations and at high ammonium concentrations. Particles appeared to be agglomerates, with diameters ranging from 0.5 up to 25 um, and composed of individual crystals of diameters ranging from 2 um apparently down to 0.1 um or Lass

Jan 1, 1977

Against a background of deeper pits, the introduction of prestripping fleets and the need for closer control of operating costs (especially the waste removal component), Australian coal operations utilising draglines have in recent years become increasingly focused on:1. assessment of more efficient excavation methods; and2. application of explosive products and initiation systems which offer more flexibility than ever before.Additionally, developments in blast performance assessment techniques and equipment, and computer modelling and excavation monitoring systems have provided an improved opportunity to design a blast to achieve a desired profile suited to the excavation equipment and Sequence.

Jan 1, 1992