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The Hall-Heroult process is likely to be the dominant method of aluminium production for the remainder of the century. The characteristics of the operation of a modern smelter are described and attention drawn to their disabilities which are due chiefly to the small production capacity of individual cells.The principal components of the Hall-Heroult cell- the electrolyte, the anode and the cathodes are discussed in order to identify the problems of scale-up. The factors influencing current efficiency and energy consumption are analysed and lead to the conclusion that the greatest potential for energy saving lies in reducing the anode to cathode distance (ACD).The most promising direction for major change is in the application of a new titanium diboride-carbon composite for coating of the surface of the cathode carbon. It improves the wetting of the carbon by aluminium and should permit the use of sloping cathodes and anodes. The deep metal pad would thereby be eliminated and, in the absence of magnetic perturbations, the ACD could be substantially decreased.

Jan 1, 1987

By S Blackburn, T Veasey

The physical and mechanical properties of rock can be measured by a variety of standard tests, and studies have shown that there should be a fundamental connection between breakage in comminution and rock æstrengthÆ. The current study aims to develop the ring-loaded strength test, used as an industry standard for the characterisation of brittle ceramics, for determination of comminution behaviour from exploration borehole core samples. The test procedure is simple, reproducible and can yield 250 separate measurements from a one metre length of drill core. The effects of material grain size and fabric on the degree of scatter of results have been investigated with respect to the ring-loaded strength test. This study has also compared the ring loaded strength to the chevron bend test used to determine the Mode I fracture toughness. A wide range of rock materials have been studied and with further work it is conceivable that an operational work index could be obtained directly from exploration drill cores tested via the ring-loaded disc test.

Jan 1, 2000

Various factors influence the exploration geologist or geochemist in his choice of.an analytical method for gold and other elements which may help him find the elusive gold deposit. One of the first decisions the geologist must make is the nature of sample media to collect for his survey. Needless to say there are many media available depending on the situation. These include rocks, soils, heavy mineral concentrates (from overburden drilling and panned concentrates), humus, vegetation, water, lake bottom sediments, stream sediments, etc. The choice of the sample media will depend to a large degree on the state of development of the particular project from grassroots to mine feasibility. The nature of the geological information required will affect which media and which analytical technique should be chosen for the analysis. Valid sampling from the initial sample collection, preparation and subsampling aspects may also help to determine which analytical procedure is best. Cost and turnaround time are of prime. importance to the explorationist, as it should be, however, these aspects should not be detached from receiving accurate and reliable results.

Jan 1, 1987

By Little T. N, Bettess D

For many mining operations the challenge of equalling World Best Practices has become the key motivator for increasing mine productivities and for lowering total costs. In most instances this will only be achieved if mines optimise their total system rather than minimising specific costs within unit operations. In the past, drilling and blasting have been viewed as a cost to be minimised rather than operations which should have their impacts fully leveraged. Once a hardrock orebody is defined the activity which has the most substantial impact in determining the efficiency of a mining operation is the blasting. The output from a blast affects every downstream operation; only by understanding the extent and interactions can the mine be optimised. Substantial improvements to hardrock mining, quarrying and excavation operations are achievable. Instead of seeking the regular one to three per cent improvements based on reduction of consumables, mine operators would be well advised to go for much bigger targets of ten to 30 per cent by fully leveraging the drill and blast operations.

Jan 1, 1995

By Avraamides J, Ritchie I. M

Gold Tellurides are important sources of gold at Kalgoorlie, Western Australia, Cripple Creek, Colorado and Vatukoula, Fiji. Unlike free gold, the tellurides of gold are rather refractory and the usual treatment practice has been to oxidize the tellurides, either chemically or by roasting prior to cyanidation of the liberated free gold. There is a large measure of disagree- ment as to the actual cause of the refractory nature of gold tellurides. In order to investigate the leaching chemistry of gold telluride, a study was undertaken on the thermodynamics and kinetics of its dissolution using electrochemical methods. From this study suitable direct leaching condi- tions are suggested. In acidic chloride solutions gold telluride can be leached using iron(III) as the oxidant. At lower acid concentrations the reaction is controlled by the formation of a passivating film of H2TeO3. In alkaline solutions containing cyanide the rate of gold telluride dissolution increases with increasing pH and strength of oxidant. However, this can result in excessive consumption of cyanide in the presence of stronger oxidants.

Jan 1, 1991

By Davey P. T, Tsambourakis G

Mineralogical analysis of supergene sulphide ore recovered from areas close to the underground workings at the abandoned Mutooroo (South Australia) mine shows that the original sulphide minerals have undergone substantial alteration. The cause of this alteration is believed to be contact with the highly saline, acidic mine water. The copper is now present as a sulphide that can best be described as a copper- and iron-delicient chalcopyrite, CuxFeyS2, where in most cases x < y. The values of x and y vary from point-to-point within each grain.Leach tests under a variety of conditions show that dissolution of the copper from the supergene sulphide ore can be readily achieved, particularly when compared with the behaviour of Mt Isa chalcopyrite concentrate. For the supergene sulphide ore, an increase in the acidity and the iron(lll) concentration of the leachant re ults in an increase in the rate of copper dissolution.The results are briefly discussed in terms of the experimental in-situ leaching operation at Mutooroo, South Australia.

Jan 1, 1986

By West-Sells P, King J. A, Patel C

The Eskay Creek orebody is located in north-central British Columbia (Canada). The ore contains major gold and silver values and minor but economically significant quantities of zinc. The refractory nature of the gold necessitates a pressure oxidation pretreatment prior to cyanidation. After solid-liquid separation the oxidation solution can be treated by oxyhydrolysis for iron removal and cementation with zinc dust for noble element removal. The resulting solution, as obtained in pilot studies, contains 7 - 10 g/L Zn, 0.5 g/L Ca and 2 - 4 g/L Mg. Minor amounts of cadmium, copper and iron may also be present in the solution. Over 90 per cent recovery of zinc from Eskay Creek oxidation solutions could be obtained by four stages of zinc extraction with Cyanex 302 extractant (Cyanamid Canada Inc, Niagara Falls, Canada). Zinc was stripped from the organic with spent zinc electrolyte in two stages. A complete description of the bench scale and miniplant studies of the solvent-extraction electrowinning circuit follows. The behaviour of minor amounts of copper, cadmium and iron in the circuit is also Discussed.

Jan 1, 1993

Synthetic seismograms of reflectivity method and some field records available are studied to detect the amplitude anomalies at the interface of the gaothermal reservoir the gas and/or oil boundary, and the underground tunnel. The first arrival of PO wave on the P-SV record are weak and emergent while those of P wave only rotated with respect to an incident angle are clear. This can, be explained by means of the energy loss of P-SV wave conversion. The primary reflections of P waves about depth fade away as compared to SH waves which do not perform any conversion, although they hold high attenuation in the fully saturated fluid layers. Reflection of comparable strength is present at the P-wave and S-wave... boundaries, but gas-saturated zones correlating with P wave bright spots do not show equivalent attenuation anomalies. Thus the comparative technique of P-SV wave and SI i wave records is very useful to indicate the strong amplitude anomalies at the boundaries of sealing targets.

Jan 1, 1990

As an Inspector of Mines in Queensland, my main responsibilities include the enforcement of the Mining Act 1968 - 1986, the Mines Regulation Act 1964 - 1989 and the Metalliferous Mining regulations 1989 to promote the safe and responsible exploitation of the States' mineral wealth.An important adjunct to this task is the offering of an advisory service to the mining industry. However, in the pursuit of my duties to this regard, I have sadly observed in some cases, numerous wrong doings and negative activities by miners which have led to their ultimate demise, not to mention that of others. Despite what I consider corrective advice, I have witnessed, again in some cases, disregard and blind pursuit for the wrong end.This then is a novel approach to get the message home in the form of a light hearted cartoon presentation relating the saga of an average Aussie battler entering the mining game unprepared, making the wrong decisions due to his own ignorance and the cleverness of others, leading finally to his and possibly others' downfall.

Jan 1, 1990

By C Gormley, G Lane, J Kwak, A Hopkins

Complex processing plants present a myriad of safety issues to the design engineer. The extent to which the design engineer manages to lay the foundations for a safe plant ultimately sets the stage for life long safety performance. Industry traditionally measures engineering safety performance by indicators such as Lost Time Injuries, Restricted Work Case Injuries, Overall Incident Frequency Rates, etc. While these measures are useful indicators of performance for the construction, commissioning and operations phase of a project, they do not necessarily drive the most appropriate behaviours for Safe Plant Design. Achieving an inherently safe design requires a diligent focus on low frequency, high consequence events. First and foremost the engineering team needs to have a design culture and methodology which leads to a plant which is as close as possible to being inherently safe. Such a culture might come from an organisation that has æmindfulnessÆ about safety, and which is nurturing a culture where warning signs are recognised and addressed. This paper explores the development of mindfulness and warning signs in design.

Jan 1, 2004

I wish that in addition to being a Pro- fessional Engineer I was also a communications expert. My principal task this morning, and yours after this meeting, is to convince a wide variety of individuals that steel industry slags are a high quality material that can be used for many purposes; and that their use can significantly alleviate some of the problems facing engineers, public officials, and the general public in our countries. By actual in- place performance over a long period of time steel industry blast furnace slags have proven that they are as good as the best natural aggregates, and better than some, for any type of construction or purpose for which natural aggregates are used. Steel furnace slags have many unique favorable characteristics and prop- erties when compared to other types of aggre- gate even though they cannot be used for all types of construction. We have the facts, all we have to do is present them to the right people in the proper manner.

Jan 1, 1979

By Stubbs B

In conjunction with Charles Copeman, we have arranged the presentation of a paper by Charles with a support paper by myself presenting alternatives to currentaccepted legal concepts involving the ownership of minerals by the Crown and the absence of ownership in any minerals or entitlement to benefit therefrom by the owner of the land on or under which the minerals occur.2. The current situation has its historical route in the concept of gold and silver being royal metals and belonging wherever situated in the Kingdom to the King and it is submitted it can be'seen as being archaic in nature perhaps even feudal and perhaps worthy in this day and age of reconsideration.Our purpose in these papers is to present an alternative view supported by argument challenging the present system and hopefully, creating room for comment and interchange amongst those involved in the industry. My solutions are not Charles Copeman's solutions and vice-versa. However, we do share a common belief that the present system may not be the best system.

Jan 1, 1990

By Lewis IE

Copper-lead dross is a by-product of the refining of lead bullion produced by the Imper- ial Smelting Process. This dross contains some 27 percent copper, 50 percent lead, four percent zinc and one percent sulphur. An ammonium carb- onate leach at atmospheric temperature and pressure removed the copper from the dross while the lead zinc and precious metals remained in the leach residue for return to the smelter. The leach solution containing the copper was then purified by liquid-liquid ion exchange using LIX64N in a kerosene diluent. ("LIX" is the registered trade mark of a range of hydroxy oximes marketed by General Mills Inc.) The pilot plant had a capacity of 0.7 kg/h of CuSO4,5H20 and was operated for some fifty days on a two shift basis. Copper sulphate of excellent purity was produced, and the results obtained indicated that a copper recovery of ninety percent from the dross could be expected from a commercial installation.

Jan 1, 1975

By A Kyllo a, D R. Swinbourne

Electric arc furnace (EAF) dusts contain significant quantities of zinc, found almost entirely as either zinc oxide or zinc ferrite. The dust has been classified as a hazardous waste due to the relative high lead, cadmium and hexavalent chromium contents. It is important that environmentally acceptable processes be developed to treat this waste. One possible process involves reacting the zinc compounds in the dust with metallic iron, thus avoiding zinc vapour reoxidation by CO2 as occurs in carbon reduction processes. It consists of two stages where the first is the reduction of iron oxides to iron and the second the reduction of zinc oxide to zinc vapour by the iron. In this work the effects of operating variables such as temperature, CO/CO2 ratio and pressure on the recovery of zinc from an industrial EAF dust obtained from the Smorgon Steel Mill were investigated. Zinc recoveries in the second stage were found to approach 100 per cent at 1000oC after about four hours in nitrogen but within 40 minutes if a low vacuum was used.

Jan 1, 2000

By S M. C Verryn

The amount of raw material used in the production of cement can be reduced by partially supplementing it by pozzolanic waste material without changing its properties negatively. This paper discusses results of an investigation using slag from the Pt industry, from the production of steel using Midrex processes as well as fly ashes from different coal power plants in South Africa. These are blended in a 20 per cent slag or fly ash to 80 per cent cement ratio. The properties of the mixtures depend on the phase composition, chemistry, grain size and the sources of the materials. The results are promising, but show variable behaviour depending on slag and cement composition. Compressive strength tests as well have heat flow curves showing the hydration behaviour, indicating that 20 per cent addition of slag or fly ash to ordinary Portland cement is viable. There is a large potential to use slag in cement mixtures and this study can be used to develop cements that will positively influence CO2 emissions and help to reduce large slag and fly ash stockpiles.

Jan 1, 2008

By Somasundaran P

Controlled modification of mineral/liquid interfacial properties by adsorption is critical for mineral processing operations such as flotation, filtration, dispersion and flocculation. Ionic/nonionic surfactant mixtures usually show enhanced surface activity and salt tolerance over ionic surfactants, and this is especially beneficial for flotation of salt type minerals in which case dissolved multivalent cations in high concentrations usually cause loss of anionic surfactants by precipitation. Adsorption of nonionic/anionic surfactant mixtures on kaolinite has been studied with sodium dodecylsulfate as the anionic surfactant and octaethyleneglycol mono-n-dodecylether as the nonionic surfactant. Synergistic interaction between these surfactants was found to cause adsorption of the nonionic surfactant with its hydrophilic chains protruding into the bulk, leading to substantial changes in flotability and dispersion characteristics of kaolinite. Similarly, hydrophobicity changes are observed also' for silica particles upon adsorption of nonionic ethoxylated alcohols owing to possible changes in the orientation of the adsorbed surfactant species at the interface. Also, based on the results obtained with surfactant adsorption, a hydrophobically modified polymer was used successfully to disperse graphite particles in aqueous solution.

Jan 1, 1993

By Reimer TH

The model described in this paper has been developed for and in close collaboration with the Bong Mining Company Ltd, Liberia/West Africa. When working an irregular deposit a de- tailed short term production schedule becomes necessary in order to ensure an equal and homo- genous concentrator feed. If the irregularity of the ore body exceeds a certain degree, blen- ding facilities have to be provided between the mine and the concentrator, but even then sche- duling of the mine production is inevitable to meet the given requirements of the blending bed and to keep these conditions steady for at least some of the successive periods. To assist the planning department in set- ting up optimal production schedules a computer model has been developed using a linear pro- gramming approach. The deposit is divided into equally shaped blocks containing defined quali- ties and quantities of ore and/or waste; from which one has to select those quantities of ore which will meet the requirements of the blen- ding bed. The objective function of the model

Jan 1, 1977

By Moelle KHR

The successful operation of a longwall face depends significantly on the efficient actions by support systems and on the ability to form a supported beam for a limited time span.The mechanical action of the supports can set up complex stresses in the immediate roofstrata.The cyclic application of supporting loads to the immediate roofstrata of a longwall face creates a special type of fabric disintegration in the rocks -affected. The mode of application and the distribution of the supporting forces is thus severely modified in a number of cases.The occurrence of true fatigue damage in brittle sandstones has been identified by studying the subcritical crack growth and microcrack development in the fracture-tip region. Several mechanical effects peculiar to the cyclic fatigue process have been identified. These effects had not previously been widely recognized. Damage in brittle rocks subjected to cyclic loads is shown to be distinctly different from any other damage processes under either monotonic or sustained (creep) loading conditions. The face support systems will frequently support rockmasses with mechanical properties not identified in conventional monotonic or sustained load tests.

Jan 1, 1991

The Joint' Venture Method is a procedure for assessing the value of exploration properties, particularly those for which resources have yet to be delineated. It aims to convert the terms of an actual or synthetic joint venture into the equivalence of an arms- lengths cash transaction between a willing seller and a willing buyer. This paper sets out one approach to achieving that conversion. It discusses both simple and complex cases and gives some examples from both public and private documents. It also includes some case studies in which the Joint Venture Method of valuation can be compared with values derived for the same project using other methodologies including actual cash deals. The Method has failings in both mathematics and logic. However because it does reflect or simulate an arms-length deal which takes into account past exploration effort and expenditure and an assessment of prospectivity at a particular point in time, it is felt that it can provide a reasonable approximation of trade value or asset value of a prospect, particularly if used in conjunction with other methods.

Jan 1, 1994

Discounted cash flow (DCF) methods are well suited and recommended as a primary valuation method for mineral assets for which there are at least indicated resources and some form of feasibility study containing engineering, production and capital and operating cost data. DCF methods are also applicable as a secondary or check valuation method for exploration properties for which no technical study has been prepared. For projects where little or no engineering, production and/or cost data is available, the process of formulating a project concept by specialists who do not possess experience and expertise in the relevant technical faculties is totally rejected as a basis for applying DCF techniques as a primary valuation method. Such an approach runs counter to The Australasian Institute of Mining and Metallurgy (AusIMM) requirement to apply relevant expertise to specific aspects of mineral valuation. Technical and commercial inputs to mineral valuation should be reviewed by specialists who have specific expertise in the relevant disciplines, and should be tempered by the quantity and quality of technical evaluation which has been undertaken and the development status of the asset.

Jan 1, 1994