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By Adrian Dance

Barrick Gold Corporation?s wholly owned subsidiary, Barrick (Granny Smith) Pty. Ltd. operates the Granny Smith operation in Western Australia and has been operating a SAG/ball mill (SABC) circuit for a number of years processing a blend of secondary crushed, open pit and underground material. With closure of the open pit in 2008, Granny Smith was considering different options to process underground only material at a lower throughput. Using the existing equipment available on site, a number of circuits were evaluated by Metso Process Technology & Innovation (PTI) through modelling and simulation. A single stage SAG mill circuit was selected based on power requirements and operating efficiency. In April 2008, Granny Smith started operating their SAG mill in single stage, processing primary crushed feed and using their existing pebble crusher for scats. Smaller cyclones were used to control the final grind size. PTI surveyed the new single stage circuit in July 2008 under normal and high rock load conditions to show the effect on final grind size. Granny Smith continued to operate this circuit until the end of 2009, when alternate feed sources resulted in a return to the complete SABC circuit at a higher tonnage once again. The variable speed, single stage SAG mill proved itself to be very efficient and flexible option to process the hard underground Wallaby Deeps material. This paper will review circuit performance following the conversion to single stage in comparison with the full SABC circuit.

Jan 1, 2012

By Lawrence Nordell

A Conjugate Anvil-Hammer Mill (CAHM) has the potential to replace conventional crushers and SAG mills, with their respective conveyors and stockpiles, in a SABC circuit. It may improve comminution circuit efficiency by 100%. CAHM compresses rock in a more efficient way, similar to 19th century stamp mills, which follows the fundamental research of Schönert (1990 & 1996). CAHM efficiency is being proven through the use of ROCKY (2011) Discrete Element Method (DEM). ROCKY features allow it to simulate realistic comminution. CAHM is customizable with many geometries that are rock-property specific. ROCKY?s wear modeling compliments the structural integrity of the design.

Jan 1, 2012

By L. Xia, B. Hart, G. Gingras, M. Furlotte

Plant and laboratory test work was performed in order to optimize a copper/zinc flotation separation circuit at Matagami concentrator, Canada. The testing identified a significant difference between the laboratory testing and the plant flotation, particularly for the sphalerite recovery in the rougher copper concentrate. Tests indicate that sphalerite recovery of the flotation concentrate in the laboratory testing was significantly higher than in the plant. The ToF-SIMS surface analysis identifies surface species responsible for the discrepancy in Zn recovery. It shows that sphalerite flotation is in response to the collector attachment and a significant enrichment of Cu on the surface of sphalerite grains. A comparative surface chemical analysis was performed on both sphalerite and chalcopyrite grains from the plant flotation and laboratory testing in order to identify surface species variability between the two testing. Two significant observations were revealed. First, there is considerably more hydrophilic iron oxyhydroxide on sphalerite surface from the plant flotation sample relative to those from the lab testing. The secondary coating likely completely or partially passivates sphalerite surfaces, reducing Cu enrichment and hence sphalerite floatability. Secondly, comparing the surface chemistry on sphalerite and chalcopyrite, the hydrophilic iron oxyhydroxide species have preference for the sphalerite grains relative to chalcopyrite. Despite numerous studies on the effect of galvanic coupling during grinding, there is limited documented evidence on the effect of the milling environment on the flotation and plant operations. This observation suggests that interaction between sulphide minerals and grinding media have a significant influence on subsequent flotation. This paper discusses the results of a detailed surface chemical evaluation of sphalerite grains from both the plant and laboratory testing in the context of grinding environments and pulp chemistry.

Jan 1, 2016

By M. Goto, F. Kubota

"In this study, we show the successful separation of rare earth metals, which are indispensable elements for the high-tech industry, from a solution containing a metal mixture by using a liquid-liquid extraction and liquid membrane based on ionic liquids. We employed newly synthesized N, Ndioctyldiglycol amic acid (DODGAA) as an extractant for rare earth metals. The DODGAA exhibited a high affinity for rare earth metals such as Y, Nd, Eu and Dy and the extraction efficiency was greatly enhanced in ionic liquids (ILs). Furthermore, stripping of the metals was readily achieved by using an acid solution. INTRODUCTIONRare-earth metals have important applications in cutting-edge technologies employed in the electronics, information technology, and automobile industries. As Japan does not have many natural metal resources, maintaining a steady supply of imported rare-earth metals is important. The total amount of rareearth metals imported into Japan was 19,000 tons/year in 1996, and this amount increased to 40,000 tons/year over the following decade (Kramer 2010). Japan is now one of the world’s major importers of rare-earth metals (Kramer 2010). However, more than 90% of the rare-earth metals imported into Japan come from China, the world’s leading supplier of rare-earth metal resources, due to their low costs. This situation made us realize the importance of a second resource of rare-earth metals: “urban mines” or discarded electronic waste. Rare-earth metals are generally separated from their natural ores by solvent extraction. However, since urban mines have different metals and the concentrations of rare-earth metals are usually low, highly efficient separation and recovery methods are required for rare-earth metals.Recently, ionic liquids (ILs), which are molten salts at room temperature, have attracted considerable attention since they are novel, environmentally friendly solvents (Kubota & Goto, 2006; Han & Armstrong, 2007). The use of ILs in liquid-liquid extraction of rare-earth metals has been reported (Kubota et al., 2012). In some cases, the IL-based systems showed better extraction ability and selectivity than those showed by the conventional organic solvent extraction systems(Nakashima et al., 2003, 2005; Hirayama et al., 2008; Fang et al., 2012). Therefore, more efficient solvent extraction processes by using ILs can be developed. In this study, we investigated solvent extraction processes in which ILs are employed and discuss the possibility of using ILs in the separation and recovery of rare-earth metals from electronic waste."

Jan 1, 2012

By D. Emadi

The ASTM B108 Mould and a Modified Mould were used to cast test bars under a variety of conditions: mould and pouring temperatures, mould coating and tilt. Mechanical properties were determined in the as-cast and heat-treated conditions. The ASTM Mould is less sensitive to casting variables. Enlarging the gating system and adding additional gates to the ASTM mould can improve properties in the tilt position. The reproducibility of properties in as-cast and T6 heat treated bars was investigated.

Jan 1, 2004

By Arun Verma

Thermal energy storage offers a means of effecting significant costs savings and conservation of premium fuels. Na2SO4 has been found to be a good material for storing thermal energy in the medium-temperature range, mainly because of its dimorphic nature and high heat of transition. Basic data and development of the salt to a practically usable block are discussed.

Jan 1, 1978

By Rodnei Graça, Jorge Silva Bettencourt, Lena Virgínia Soares Monteiro, Baruch Spiro, Tolentino Flávio De Oliveira

Abstract - The Vazante Mine is located in the Vazante District, the largest zinc district in Brazil. The Vazante deposit consists dominantly of an unusual willemitic ore. Small sulfide bodies are tectonically imbricated with the willemitic ore, within the Vazante shear zone. Structural styles of deformation and petrographic and isotopic evidence indicate that willemitic mineralization and deformation occurred synchronously during the Neo-Proterozoic. Various generations of hydrothermal veins and hydraulic breccias may pre-date, accompany and overprint the mineralization. Ore-formation temperatures are deduced from stable isotope geothermometry and mineral chemistry of both sulfide bodies and willemitic ore. Temperatures during the main stage of mineralization range from 206°C to 294°C (willemitic ore) and 317°C (sulfides), and reflect the prevailing metamorphic conditions within the shear zone. The fluid from which the gangue minerals of the sulfide bodies precipitated (at 250°C) had an oxygen isotopic average value of ?18O = +19.4‰. This value appears to reflect the interaction of metamorphic fluid with the carbonate rocks of the Vazante formation. At 250°C, the fluid in equilibrium with the vein mineral phases and willemitic ore assemblage exhibits a uniform oxygen isotopic composition, with an average value of ?18O = +11.5‰. The positive linear covariance of ?18O and ?13C ratios of the carbonates is most likely due to the mixing of metamorphic and meteoric fluids. The ?34S values of sulfides indicate a direct crustal origin for the sulfur. It is suggested that the sulfur is largely derived from pre-existing sulfide bodies and has been transported by metamorphic fluids. The willemitic ore may have originated from the precipitation of metal in sulfur- poor fluids under oxidized conditions, within the Vazante shear zone.

Jan 1, 1999

By M. Drozd, M. Somppi, Z. F. Yamak

"Activated carbon is used to recover gold in solution from various gold circuit designs including carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes; however, the characteristics and durability of the activated carbon can vary. Handling this medium poses challenges when fine carbon losses occur in the CIP, CIC, and CIL circuit discharge. Additionally, adsorbed gold on carbon fines can be lost to the discharge. The studies in this paper aim to standardize laboratory methods for testing activated carbon qualities specific to the gold industry. The investigation focused on size distribution, platelet content, wet attrition resistance, gold kinetics, and gold loading. The results demonstrate that a 96 h attrition test and a gold loading test form a basis for ranking carbon samples based on expected economic performance of the plant. ¦ KEYWORDS Activated carbon, Carbon attrition, Carbon ball-pan hardness, Carbon evaluation, Carbon fines loss, Carbon turnover RÉSUMÉ Le charbon actif sert à récupérer l’or en solution dans diverses conceptions de circuits de broyage d’or, notamment les procédés de charbon en pulpe (CIP, de l’anglais carbon-in-pulp), de charbon en colonnes (CIC, de l’anglais carbon-in-column) et de lixiviation au carbone, ou charbon au lixiviat (CIL, de l’anglais carbon-in-leach). Toutefois, les caractéristiques et la durabilité du charbon actif varient. La manipulation de ce milieu pose des problèmes dès lors que se produisent des pertes de carbone à grain fin dans la décharge des circuits CIP, CIC et CIL. Par ailleurs, l’or adsorbé sur les fines de charbon peut se perdre durant la décharge. Les études réalisées dans le cadre de cet article visent à normaliser les méthodes de laboratoire pour tester les qualités du charbon actif spécifiques au secteur de l’exploitation aurifère. L’étude portait sur la composition granulométrique, la teneur des plaquettes, la résistance au frottement humide, la cinétique de l’or et l’adsorption de l’or, à savoir la capacité du charbon actif à adsorber l’or sur une période spécifique. Les résultats ont montré qu’un test de frottement de 96 heures et un test d’adsorption de l’or constituaient le fondement d’un classement des échantillons de carbone du point de vue économique en vue de trouver l’échantillon générant le meilleur rendement des usines. ¦ MOTS CLÉS charbon actif, dureté de la batée des billes de carbone, évaluation du carbone, perte de fines de charbon, renouvellement du carbone, résistance au carbone INTRODUCTION The use of activated carbon for gold extraction is among the most common processes in modern gold-milling plants. Although gold losses are inevitable in the milling process, operators often focus on reducing gold loss to tailings. One focus area that is important in gold recovery is optimizing the use of activated carbon and examining potential changes to realize improved economics for carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes. Granular activated carbon (Figure 1) is widely used for gold extraction from slurries containing gold-cyanide complexes. This activated carbon—produced from charred coconut shells—is well suited because of its adsorption kinetics, gold-loading capacity, attrition resistance, and ability to be reactivated. The extraction process using activated carbon technology involves adsorbing gold from an aqueous leachate; the gold is dissolved using a cyanide salt and consequently a dicyanoaurate(I) ion (Au(CN)2–) is formed, as noted in equation 1."

Jan 1, 2019

By E. R. Weltevreden, C. Klauber, C. Vernon

"In this paper a review of the current status in recycling technologies for cathode ray tubes is given for both the glass and phosphors. Particular emphasis is placed on the opportunities for the recovery of the rare earth elements (REE) from the phosphor coatings. This is placed in the market context of alternative virgin sources and some of the advantages and disadvantages for REE waste recovery. Future opportunities are explored and also some experimental detail on a low cost leach system is presented. INTRODUCTIONThe disposal of cathode ray tube (CRT) based colour televisions has accelerated world-wide with the development of high definition flat screen panels. The total number of colour CRT televisions that have been sold in the United States in the mid-20th century is estimated to have been over 2 billion (U.S. Environmental Protection Agency, 2007), with high current rates of disposal. It is estimated that of the 20 million televisions annually discarded, 78% are send to landfill (Nnorom, Osibanjo & Ogwuegbu, 2011). However, this easily accessible item of electronics cannot only be turned into a valuable resource using the right recovery procedures, it can also prevent the substantial environmental contamination arising from improper disposal. In this review we focus on previous and current work performed on the recycling of CRT based televisions. Due to the increasing demand for rare earth metals, the main focus will be on the possibilities and challenges of recycling the fluorescent phosphor powders on the CRT’s panel glass.CATHODE RAY TUBE’S GLASS RECYCLINGConventional cathode ray tubes consist of three main parts, the panel, the funnel and the neck (Figure 1). To produce the different colours on the screen, the inside of the panel is coated with a matrix of hundreds of thousands of small phosphor dots. Each dot is one of three types of coloured phosphors, emitting either red, green or blue light. These emit light when excited by a beam of electrons generated by electron guns located in the neck of the CRT. These beams pass through holes in the shadow mask and excite the phosphor coating on the inside of the panel, to give light of variable RGB composition, see Figure 1."

Jan 1, 2012

By E. C. W. Perryman

Materials research and development has played an important role in the commercial success of the CANDU- PHW nuclear reactor and in the production of heavy water. Both capital investment and energy conservation demand very high component reliability in such systems. The interactions among reliability, plant performance and economics will be discussed in relation to materials research and development. Likely materials requirements for the nuclear industry over the next twenty five years will also be discussed.

Jan 1, 1977

By T. Orser

In 2010 Newmont made the decision to purchase a 42 foot (ft) Semi-Autogenous Grinding (SAG) mill from Metso and a 28 Mega-Watt (MW) Gearless Mill Drive (GMD) from ABB for the Conga Project in Peru. The test and study work showed that a single line 42 ft SAG mill circuit gave the most favorable project economics in comparison to an equivalently powered single line 40 ft SAG mill circuit. This paper does not address the process design or the project economics, but instead focuses on the key aspects of the SAG mill design, GMD design and the associated component manufacturing. This paper also addresses, where applicable, the potential reliability differences between the initially proposed 40 ft SAG mill and the finally accepted 42 ft SAG mill.

Jan 1, 2012

By W. N. Hamilton

As a result of a test-drilling program conducted by the Research Council of Alberta in 1968, a gypsum deposit averaging 30 feet in thickness, with a chemical purity of 84 per cent gypsum, has been proven to underlie the Clearwater River valley for a distance of 18 miles at depths ranging from near-surface to 300 feet. This and other subsurface deposits in the vicinity of Fort McMurray, Alberta are the product of local hydration of anhydrite beds believed to be the water-insoluble remains of the leached Prairie Evaporite formation of Middle Devonian age, the thick salt section of which is preserved down dip. The effects of salt solution are seen in the disturbed bedding and the intermixture of greyish green shale with gypsum in the core, the shale content being responsible for the rather low chemical purity of the deposit. A similar gypsum deposit, but probably of higher purity, is postulated to occur beneath the Athabasca River valley about 60 miles north of Fort McMurray.

Jan 1, 1969

By M. R. Hegge

The Jabiluka One and Two uranium deposits occur in Lower Proterozoic metasediments of the Cahill Formation, which is part of the Pine Creek Geosyncline in the East Alligator River area, Nothern Territory. The Jabiluka One deposit coincides with a "window" through unconformably overlying Middle Proterozoic sandstone of the Kombolgie Formation; Jabiluka Two is completely covered by that sandstone. The observed part of the Cahill Formation exhibits four horizons which are favourable hosts for uranium mineralization. These have been folded into an east-southeast-striking, gently plunging, open asymmetric syncline-anticline structure. The host rocks are mainly chlorite and/or graphite schists and their brecciated equivalents which have undergone initial regional prograde metamorphism to the amphibolite facies, then retrograde metamorphism to the greenschist facies. Mineralization consists of pitchblende, mainly filling open spaces and to a lesser extent in disseminated form. Chlorite, pyrite and quartz are commonly associated with the uranium mineralization. A portion of the Jabiluka Two deposit contains economic concentrations of gold. Structural preparation with low-pressure conditions at these sites appears to be the most significant ore control. Genetic hypotheses favour initial deposition in Lower Proterozoic sediments, followed by remobilization during later orogenic events. The deposits bear a marked similarity to some pitchblende deposits in central Canada.

Jan 1, 1977

By K. Purazrang, P. Musavi Garavi, P. Sh. Naseri, P. Abachi

The fracture behavior of high strength Al7050 alloy was investigated at room and elevated temperatures using small size, V-notched tear (called Kahn specimen) and compact tension, CT, specimens, respectively.To study the elastic-plastic behavior of the alloy, the tensile test was also performed on the sub-sized cylindrical tension test specimen. The microstructure of the alloy was examined using optical- and scanning electron- microscopy. The rupture mechanisms and crack path were also studied by examination of specimens' fracture surfaces using SEM. The microstructure examination revealed equiaxed grains and some elongated grains in rolling direction, with the areas of partial re-crystallized grains where coarse intermetallic particles are mostly found.In general, fracture surfaces were indicative of dimpled ductile type. Considering the fractographs of tensile specimens, the void growth mechanism is also dominant in fracture of these specimens. Nevertheless, in some regions, smooth areas can be observed due to the friction during rupture process. The results of mechanical tests at RT made the evaluation of tear strength to 0.2 % tensile yield strength ratio, as a measure of notch toughness, available. According to elevated temperature, 150°C, test results and plots of log da/dt vs. log KI , the crack propagation behavior over discrete ranges of crack growth rates could be assumed linear and then be obeyed as a power law equation in the form of da/dt = A (KI)n .

Jan 1, 2015

By Martin Grenon

This paper presents two case studies where fracture set orientation was quantified using three methods: a simple fracture pole grouping, a Fisher distribution and a Kent distribution. The three fracture orientation representations were then used as inputs for kinematic slope stability analysis. Differences showed up in the probability of sliding for all instability modes considered.

Aug 1, 2013

By C. Mawdsley

The Tata Steel mill at Skinningrove in the North East of England produces top hat sections for mineshaft guides in sizes 102 and 150 mm. The top hat section is the technically preferred shaft guide choice for modern deep mine shafts. This paper explores the relative service performance of top hat and square hollow section guides in service. Comparative corrosion performance is reviewed and the paper describes work commissioned by Tata Steel (as Corus) undertaken by Aker Kvaerner Engineering to evaluate relative winding speeds, relative loads and fatigue life in service. The experience of supply to UK Potash mining is discussed and the future view of high capacity hoisting and larger section size market need and availability is assessed.

Aug 1, 2013

By Michel Jébrak, Claude Bellehumeur

Abstract - Regional and orientation geochemical stream sediment surveys were carried out by the Quebec Department of Energy and Resources in southwestern Quebec, over a part of the Mont­ Laurier Terrane of the Grenville Province. The area contains some small stratiform zinc deposits. The response of Zn mineralization to geochemical surveys is weak; the known mineralization is not defined by anomalous samples and consistent patterns. This study uses a technique that increases the geochemical signature of Zn mineralization in filtering out geochemical background components related to lithologies and surficial conditions. The background variations were modelled using principal component analysis, and the filtering technique consists of the partial reconstruction of the data matrix from results of principal component analysis . The filtering procedure considerably enhances the Zn anomalies located in the catchment basins of Zn deposits, and defines some new anomalies in proximity to the marbles of the Mont-Laurier Terrane, the principal metallotect of Zn mineralization.

Jan 1, 1993

ABSTRACT It is critical that historical processes and concomitant exposures to specific nickel substances be understood because some diseases linked to inhalation of certain nickel-containing substances have a long latency between first exposure and disease onset, and because nickel substances vary significantly in their toxicological properties. A discussion of the smelting history and related processes at Vale Canada’s (Inco’s) Copper Cliff, Ontario, smelter is integral to the understanding of these processes. The post-1950 processing history, equipment, propensity for aerosol formation, operational procedures, and ventilation controls used by Vale Canada in roasting, smelting, converting, and copper-nickel separation is discussed.

Jan 1, 2013

By J. E. Gebhardt, D. McBride, M. Cross

Heap leach processes can encounter diverse flow conditions, such as infiltration into dry ore material, drainage, perched water tables and heterogeneous materials, leading to large variations in permeability and the creation of preferential flow pathways. Climate and meteorological conditions, such as precipitation, evaporation, and temperature, can also have a significant effect on the hydrodynamics of the heap. Nonuniform and adverse flow behavior within the heap contributes to reducing the leaching efficiency of the heap leading to lower metal recoveries. The variability of flow within the heap can result in solute transport problems, which limit the leach reaction kinetics. Therefore, understanding the flow and transport phenomena within the heap is critical in its design and optimization. A comprehensive heap leach model, developed within a computational fluid dynamics (CFD) framework, employs robust algorithms to solve diverse variably saturated flow conditions. The model allows for a wide array of complex thermo-fluid physics to be represented and captures suites of very complex reactions that are closely coupled with thermal conditions and key microbial populations. Employing a three-dimensional heterogeneous ‘test’ heap, a number of flow conditions are investigated and the sensitivity of metal recovery is discussed.

Jan 1, 2014

By G. B. Harris, C. W. White

A study to investigate the recovery of base metals, notably copper, nickel, cobalt, zinc and manganese from iron-free concentrated chloride solutions using ion exchange was undertaken. In such solutions, apart from nickel and, to a lesser extent manganese, these metals are present predominantly as complex anions, and therefore conventional separation techniques based on cationic resins are not applicable. The results demonstrated that zinc, copper and cobalt can all be separately recovered leaving nickel and manganese behind. Specifically, zinc is a major nuisance element in nickel and cobalt processing, and the testwork showed that it can be preferentially removed prior to copper and cobalt. Selective resins for both copper and cobalt were identified, and it was demonstrated that the strength of the chloride background matrix has a significant effect on the efficiency of separation. An additional major advantage in such systems is that stripping can mostly be effected with water. Finally, some observations are made on the hurdles that must be overcome when attempting to introduce and commercialise new technologies.

Jan 1, 2015