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By R W. Hutchinson

Cupreous pyrite deposits in Cyprus have many geologic similarities to Canadian massive sulphide copper-zinc ores as well as certain significant differences. A comparison of the Cyprus and Canadian deposits indicates a complex genetic history for the latter and suggests that their origin should be re-examined. The Cyprus ores occur in subaqueous extrusive rocks near and at the top of a Cretaceous volcanic pile or igneous complex. The rocks have not been deformed, nor have they been deeply buried or deeply eroded. Apparently the ores formed near or at surface in the top of the volcanic pile by a volcanic-exhalative process and from an ore-fluid of volcanic derivation. The Canadian deposits are of comparable composition and have similar geologic set-tings, but occur in the most ancient Precambrian rocks. Their enclosing Keewatin greenstones have, in most places, been deformed, regionally metamorphosed and invaded by granitic intrusions. Comparison suggests that the Canadian ores also formed initially near surface in ancient Keewatin volcanic complexes by a syngenetic, volcanic-exhalative process. Subsequently, during orogenesis, they were deformed, remobilized under conditions of elevated pressure-temperature and re-emplaced as epigenetic bodies into

Jan 1, 1965

By G. B. Hudson

Previous papers (1, 2) pertaining to the treatment of uranium-bearing ores were concerned with the flotation of the radioactive minerals. In this investigation, the application of flotation to the removal of acid-consuming minerals from uranium ores was considered. Two pitchblende-bearing ores, which, because of the presence if dolomite were abnormally high acid consumers, were studied. In both in-stances commercial reagents of widely varying fatty acid composition proved satisfactory as flotation col-lectors, particularly at a pH of 10.5, for the carbonate minerals. From an economic viewpoint, however, Neo-Fat 42-12 was favoured. A mixture of sodium tripolyphosphate and citric acid was an effective depressant for the pitchblende in the ores. The tailings remaining after the removal of the dolomite by flotation contained, in one case, 88.5 per cent of the uranium in the original sample, and, in the other, 93.8 per cent. Analyses conducted on these tailings and on the original ores showed that

Jan 1, 1963

By R. R. Bassermann

THE property of Howey Gold Mines, Limited is situated at Red Lake, Ontario, one hundred and seventy-five miles east of Winnipeg and eighty miles north of the Canadian National Railway line. The mine has been a continuous producer since April, 1930, and at present is hoisting 1,350 tons of ore per day. The shaft consists of three compartments (see Figure 1, sketch B). Hoisting is done by two skips in balance, one of which is interchangeable with a cage. Sinking had been carried out at three different periods. From the surface to the 550-foot level, the sets had been spaced at seven-foot intervals, from the 550-to the 1,060-foot level at six feet, and from the 1,060-to the 1,500-foot level at five feet. During the five years of operation, the shaft had become so badly worn, due to spill from the tipples and, to a certain extent, from the loading pockets, that re-timbering was considered necessary. It should be explained that no crushing is done underground because of the ad verse effect this would have on the efficiency of the sorting. The grizzly rail clearance above the ore pockets is fourteen inches and consequently the ore hoisted is extremely coarse. More than average spill from the loading pockets and tipples under such conditions is inevitable, and it is debatable whether underground crushing with consequent increased sorting costs would not be justified. The cost of complete re-timbering according to standard practice would have been prohibitive both directly and indirectly: A lengthy shut-down of the shaft, with the consequent disorganization of the staff and workmen, could not be considered. Accordingly, it became necessary to devise some method of repair that could be carried to completion in a very limited period of time. The shaft timber for the first 250 feet was not in need of repair. From the 250-foot to the 1,060-foot level the wall plates, posts, and blocking were in good condition. These had been protected by a one-inch plank lining put in at various periods during the past three years without interfering with hoisting operations. The end plates and dividers, however, could not be protected in this manner because of the lack of skip clearance. It was decided that, if the dividers in this section could be replaced, the shaft would be as satisfactory as if completely re-timbered. Several factors had to be taken into consideration in deciding on a suit-able method of repair. In the first place, the tipple plates had to be re-designed. To complete the job in a reasonable time, not only had work to be done on the tipple, but simultaneously from several points in the shaft itself. Since all power cables, pipe lines, etc., were in the manway compartment of the shaft, this compartment had to be left undisturbed.

Jan 1, 1935

By M. B. Kime

"Discrete-element method (DEM) modelling is a powerful tool for studying particulate systems within the mineral processing industry. DEM simulations were conducted to investigate the power draw, load behaviour, and impact energy profile of an experimental ball mill under different milling conditions. The variables considered were mill rotational speed (percent critical speed), ball size, and lifter face angle. The simulation results indicated that the grinding efficiency would be enhanced by using 80% critical speed, 30 mm ball diameter, and 45° lifter face angle. These findings can be useful in guiding actual ball milling tests involving an ore sample.RÉSUMÉ La modélisation par méthode des éléments distincts (MED) est un outil puissant qui permet d’étudier les systèmes particulaires au sein de l’industrie de traitement des minerais. Des simulations par MED ont été menées de façon à étudier le profil de la consommation énergétique, du comportement de la charge et de l’énergie de rupture d’un broyeur à boulets expérimental dans diverses conditions de broyage. Parmi les variables prises en compte figuraient la vitesse de rotation du broyeur (vitesse critique en pourcentage), la taille des boulets et l’angle de coupe de la cornière élévatrice. D’après les résultats de la simulation, on pourrait améliorer l’efficacité de broyage en utilisant une vitesse critique de 80 %, un diamètre de boulet de 30 mm et un angle de coupe de 45 ° de la cornière élévatrice. Ces résultats peuvent se révéler utiles pour les essais concrets de broyage à boulets impliquant un échantillon de minerai.INTRODUCTIONComminution is a very energy intensive process. It consumes approximately 5% of the electricity produced worldwide and more than 50% of the total energy used in mineral processing plants (Pokrajcic, 2010). Among all the comminution stages, ball milling is one of the most energy intensive processes. In ball mills, rotational movement provides the rise of the load and the media that are projected and impact on the mill shell at lower angular displacement, resulting in particle breakage. Ball mills are able to reduce particle size over a relatively wide range of particle sizes. This explains their wide applicability in research laboratories and the mineral processing industry."

Jan 1, 2017

By L. B. Tsymbulov, L. Sh. Tsemekhman, A. N. Golov

Gipronickel Institute, JS is developing a process of continuous converting of Nicontaining copper matte and concentrates resulting in the production of blister copper and fluid NiO-containing slag in a two-zone Vaniukov furnace. The process under development is an alternative for the existing technology of blister copper production in converters, the latter being characterized with insufficient sulphur utilization, low direct copper recovery and the production of inconvenient for further processing solid slag on the basis of NiO and NiFe20 4- The results of pilot testing on processing of copper concentrate obtained from high-grade matte (HGM) separation in the two-zone Vaniukov furnace with the hearth area of 11.4 m2 are presented.

Jan 1, 2007

By Tim Watson

Andacollo Hypogene Project ?Overview Project description: Sulphide copper concentrator Throughput:55,000 tpd Location: Approximately 50 km from La Serena Elevation: Approximately 1,000 m ASL Start feasibility study: July 2005 Start of construction: May 2007 Construction completion: December 2009 Final cost(1,2,3):435 Million US $ (1) Excludes third party costs, 220 kV power line (2) Cost is based on a Chilean Peso to US Dollar foreign exchange rate of 535 to 1 (3) Does not include US$40.3 million for the Elqui River Pipeline Project or US$8.0 million for the stock pile cover

May 1, 2010

By A. D. Dalvi

Economics, Resources, Environment and Technology are the major driving forces in the base metals industry. However, these factors are intertwined and together will propel the industry in the future. The demand for metals has grown with economic expansion, between 2 to 4 % p.a. The current growth cycle has been driven by economic expansion in China where the demand for base metals has risen from - 7 % of the world demand in the 90's to - 25 % of world demand today, and rising. Base metals are commodities and their demand and price are cyclical. Historically metal prices have declined in constant dollars, forcing the industry to reduce costs, increase productivity and increase the scale of operation for economies of scale. Due to resource depletion and capacity expansion the industry is driven to expand its reserve and resource base. However, in the case of sulphide deposits of copper and nickel it appears to be a losing battle. For nickel the laterites represent a vast source at this time. Their development requires development of new technologies to make these resources economic. Emission reduction is being increasingly mandated in most jurisdictions with all governments enacting progressively more stringent regulations. The industry has been responding with technological innovation. With the Kyoto protocol there is a push to reduce energy intensity in metal production. Technological innovation is driven by all the other factors and is leading to novel ways of doing exploration, mining and processing, that would maximize resource delineation and utilization, reduce costs, increase productivity, reduce energy consumption, maximize asset utilization and reduce environmental affects. Development of alternative technologies such as Pressure Acid Leach of laterite for nickel, bio-leaching, heap leaching, SX-EW etc are being adopted to achieve the aims of the industry.

Jan 1, 2005

By P. C. Thurston, T. Setterfield, D. H. Watkinson

"The Maybrun copper deposit IS In a succession of pillowed basaltic flows in the Wabigoon sub-province, northwestern Ontario. The rocks have primary flow morphologies and remarkably well-preserved crystallization textures, including quench-textured plagioclase, in spite of metamorphism to the amphibolite facies. The sulphide assemblage chalcopyrite-pyrrhotite-cubanite with minor sphalerite and pyrite is primarily in interpillow spaces and is stratabound. Basaltic rocks immediately enclosing the copper sulphide minerals have an enrichment in Fe, Mg and K and depletion in Ca and Na relative to surrounding flows. The Maybrun deposit is interpreted to have formed contemporaneously with volcanism and alteration, and was subsequently metamorphosed with the enclosing basalts.IntroductionThe association o f significant base metal accumulations with mafic submarine flows in the Archean is as yet poorly documented. Such deposits, where noted, have typically been small, and are therefore commonly over looked. The Maybrun Mine, a 2.6 x 106-tonne copper deposit in pillowed basalt, has many similarities with large, well-documented volcanogenic deposits. Given the interpretation of the Maybrun Mine to be volcanogenic in origin, there is n o reason why similar processes could not produce large deposit s. This is an important realization in an area where Archean submarine mafic rock s are very common, but frequently are examined only superficially. As gold commonly occurs in deposits such as Maybrun, even modest-sized deposits may be economic. The basalts at Maybrun are remarkable for amphibolite-facies rocks because of their extremely well-preserved delicate volcanic textures, including quench textures.The Maybrun Mine is one kilometre south of Atikwa Lake, in the Wabigoon sub-province of the Superior structural province, 75 km southeast of Kenora, northwestern Ontario, at longitude 93°35'W, latitude 49°25'N (Davies, 1973). Archean metavolcanic and metasedimentary rocks and intrusions underlie the area. Goodwin (1970) concluded that the mafic and minor felsic metavolcanic rocks, as well as the overlying metasedimentary rock s, were an eastward extension of the lower cycle of the Keewatin type section for the Lake of the Woods area. He estimated that the stratigraphic thickness of Keewatin rock s in this area is about 6900 m, of which 87% is basalt. The flows contain numerous interlayered sills, predominantly of basaltic composition; they have been extensively folded, faulted, metamorphosed to amphibolite facies and intruded by numerous felsic bodies, most importantly the Atikwa Batholith."

Jan 1, 1983

By T. Schepp, T. Friedrich

"The natural stage of deep mines operation is a closure of unnecessary shafts. It is extremely important to ensure a proper shaft closure to avoid stability loss and the associated damage to surface facilities in the future. For the still active shafts, it can be done by a dedicated shaft closure design, but even then, depending on the shaft closure method, it may be necessary to perform regular shaft inspections. The paper presents a short overview of shaft closure methods and available tools and devices developed in the last time for such shaft inspections. INTRODUCTION The natural stage of deep mines operation, commonly occurring after depletion of the reserves of mined materials, is a closure of unnecessary shafts. All over the world, the number of liquidated shafts grows continuously and the problem of shafts disposal is especially critical for deep shafts. The typical depth of 600 m of currently liquidated shafts in Poland may already be seen as a challenging task. The greater is the challenge of shaft closure in Germany where the last active coal mines for shafts with a depth of up to 1,300 m have been recently closed. It is therefore extremely important to ensure a proper shaft closure to avoid stability loss and the associated damage to surface facilities in the future. For the still active shafts, it can be done by a dedicated shaft closure design, but even then, depending on the shaft closure method, it may be necessary to perform regular shaft inspections. In many cases, it is more important to inspect old, abandoned shafts, where the wall stability or even liner type are not fully known. SHAFT CLOSURE METHODS Abandoning a shaft is a complicated task, as shafts, being the link between the surface and an underground network of workings, disturb hydrogeological and gaseous conditions in the rock mass (Sztelak, 1991). Closure procedures at older mine sites have been carried out in accordance with earlier legislative requirements. For very old shafts (+100 years), it means in many cases only a sealing of the shaft entrances by means of timber or concrete slabs. In the 20th century, the shafts were also closed by means of filling with grainy materials, but even then the retrospective activities at abandoned mine sites were extremely limited and in most cases no further monitoring measures were performed. The possible consequence of an improper shaft closure and lack of monitoring is presented in Figure 1."

Jan 1, 2019

By E. Engelbrecht

"A pressure non-oxidative leach is employed at Anglo American Platinum Base Metal Refiners to extract nickel from a slow cooled matte. The design base requires two 80 m3 autoclaves in parallel to achieve a nickel extraction of 60% at the nameplate capacity of 32.4 ktpa nickel plated. Isothermal modelling of mineralogical and chemical concentration profiles, through a reactive mass balance, permitted rate constant parameter estimation and selection of the most probable reaction pathway. The model was validated with plant data up to a capacity of 26 ktpa Ni plated and suggested by extrapolation that nameplate capacity may be viable through one 80 m3 autoclave.INTRODUCTION Anglo American Platinum Base Metal Refiners is situated on the outskirts of Rustenburg in the North-West province of South-Africa. The refinery produces nickel cathode, copper cathode, cobalt sulphate powder, covellite rich copper pressure leach residue and bulk sodium sulphate through an integrated circuit that refines slow cooled converter matte. The converter matte is milled, non-magnetics are separated as solid nickel copper matte (NCM), and the magnetics are leached yielding a pressure vessel liquor (PVL). The remaining solid platinum group metals (PGM) concentrate after leaching is sent for downstream processing in the Precious Metals Refinery (Hofirek & Kerfoot, 1992). The work presented here is applicable to the base metals refinery which receives the two base metals feed stocks NCM and PVL. In 2009 the capacity of the refinery was upgraded from 21 ktpa nickel cathode plated to 32.4 ktpa. This paper deals with evaluating the capacity of the pressurised non-oxidative nickel leach (NOX) process which accounts for at least 28% of the nickel leached from NCM by design. The NOX design base requires two 80 m3 autoclaves divided into four compartments operated in parallel at 155°C and 600kPa(g). Elevated temperature is required to speed up the leach kinetics of particularly nickel and iron which are trapped in slow leaching mineralogical phases namely millerite and bornite, (Dinham, 2006). The stated equivalent capacity for the NOX configuration was 32.9 ktpa nickel plated at first pass nickel and iron leach efficiencies of 60% and above 80% respectively and is a key step for the selective removal of iron (Bryson, Hofirek, Collins, Stiksma, & Bereaowsky, 2008)."

Jan 1, 2017

By W. C. Whittaker

"This paper gives a brief resume of the changes in the market picture for Western coal since 1948. It then analyzes present markets and recent developments in Western Canada, the western United States and Japan, and forecasts future markets in these areas to 1975.INTRODUCTIONCOAL HAS BEEN MUCH IN THE NEWS OF LATE, both in the United States and in Canada. In the United States, this is because of the booming condition of the industry and because of the purchase of control of a number of America's largest coal producers by the integrated oil and metal producing companies seeking additional fossil fuel reserves and diversification. In this regard, it is interesting to note that ownership of America's largest strip coal producer was recently acquired by one of the world's largest copper mining companies. In Canada, the conclusion of several large-scale, long-term contracts for the sale of coal to the Japan Steel Group and the projected use of Canadian coal in steel mills in the western United States has focused much attention on the coal industry."

Jan 1, 1968

By Iwueze Anaekperechi Rose

The International Labor Organization has declared mandatory adequate provision of safe workplace and safety for all workers in all occupations including the mining sector. Early scientists like Agricola (1559) who studied the health of Miners, found that there are peculiar health problems associated to their work and working environment. This unsafe working condition was one of the major factors that resulted to the Industrial revolution in England and eventually led to the establishment of regulations and laws guiding operations in all workplaces and workers in England and all over the world. Recent studies by Heinrich suggested chains of events of safety issues in the mining sector. Occupational injuries, accidents and ill health have huge social and economic implications on workers, their families and communities. Top mining top issues are respiratory diseases, noise, explosives, ventilation, fire, and explosion. However, one of the principal mechanisms for achieving Occupational Health and Safety (OHS) goals and mapping the future is government regulations of employers. In Nigeria, the situation is not different; mining operations are equally hazardous and have far reaching implications. In 1995 the Ministry for Solid Minerals was established to focus on the development of other categories of mineral products ranging from gold, coal, uranium, and tantalum deposited across the country. Prior to this an Act of Parliament Act Cap 121 of 1946, was in place to regulate amongst other contents mining safety. This was subsequently reviewed following the incidence of Lead poisoning resulting from small scale miners processing gold ore highly contaminated with lead in Zamfara state (northern Nigeria). Hundreds of children died as a result of exposure to lead poisoning, it was clear that the regulations were not sufficient (details to be discussed). However, advances have been achieved in mining engineering since then. A review team was constituted to provide a more stringent law to regulate mining operations in Nigeria. The strategies for mapping the future of OHS in mining engineering will employ amongst others setting and adopting ISO/ILO standards and enforcement; providing technical assistance; and establishing sustainable developmental structures as surveillance and compensation. The management systems approach was also developed as a result of cases of accidents. The accepted international standards guidelines and requirements will be proposed. Furthermore in mapping the future for Mining Engineering, it is suggested that most countries have their own management strategies and legislation to improve safety of workers through greater consistency and efficiency of OHS programs. Some American researchers came up with the Safety Engineering Model. The Australian Mining Council of mineral and petroleum resources after the Catastrophic Maura Disaster developed the National Mine and Safety Framework. In Canada, after the Hillcrest mine disaster in 1914, Allan shaft coal mine catastrophe in 1918, Westray mine explosion in 1992 and other disasters, Occupational Health and Safety Act R.R.O 1990 was sufficiently developed to provide adequate safety conditions and standards. In Nigeria after the disastrous Zamfara lead poisoning, which claimed the lives of hundreds of children due to exposure and lack of appropriate safety measures, stringent measures were developed by the federal ministry of Justice to address and regulate mining process in Nigeria.

Aug 1, 2013

By Jacque Trottier, Marcel Vallée, Gratien Gélinas

"Mineral exploration in Canada traditionally has gone from boom to bust in cyclical pat-terns following market and discovery cycles, but other endemic factors related to exploration financing and performance have contributed to the amplitude and recurrence of these fluctuations. In view of these problems, junior exploration is reviewed here in a marketing perspective, looking at the 4 Ps: Product, Price, Placement and Promotion.In the 1980s, MEDA incentives gave the shares of junior and mining companies significant price and promotion advantages, and contributed to excessive exploration funding. Many were thus led to minimize the basic values needed for continued investor interest: appropriate levels of product quality, sustained share value and customer satisfaction. Basic changes are needed to improve the marketing of junior mineral exploration in the future, with or without improved fiscal incentives. To be successful, the required improvements must come from the technical participants, but the financial partners also need to be involved.Exploration in Canada must be marketed with vigour, both in Canada and internationally. Exploration, mine development and mine production are essential to our economy. They are environmentally acceptable and they are welcome in Quebec and in most Canadian provinces and territories. Canadian exploration and mining are entrepreneurial industries that must take better advantage of their strengths and achievements and remove the shortcomings that hinder them: nobody can do it for them!"

Jan 1, 1996

By Z. Ren, M. Tomlinson, E. Asselin

"Organic carbon blinding is a common, yet often partial, solution to the reduction of preg-robbing. A quantitative method to assess the extent of adsorption of a given blinding agent is presented herein. The adsorption of several blinding reagents on various carbon samples is quantified using electrochemical impedance spectroscopy (EIS). EIS results showed that kerosene is more strongly adsorbed on carbon than sodium lauryl sulphate (SLS), while SLS can hinder the charge transfer process of the oxygen reduction reaction on the carbon surface more effectively. The effectiveness of SLS is pronounced when its concentration is higher than 100 ppm. Raman spectra are presented for selected carbon samples: as the area ratio of the disordered peak to the graphitic peak increases, blinding agent adsorption increases.INTRODUCTION The presence of naturally occurring constituents in gold ores may adversely affect the extraction of gold in cyanide leaching since the gold cyanide complex, Au(CN)2–, can be adsorbed by these constituents (M. Adams & Fleming, 1989; Afenya, 1991; Miller, Wan, & Díaz, 2005). Such ores are known as “preg-robbing”. Preg-robbing behavior may arise from natural carbonaceous materials in the ore (M. Adams & Burger, 1998). In the past decades, a number of pre-treating methods have been developed for refractory carbonaceous ores (Arriagada & Osseo-Asare, 1984; Beer, 1994; Dunne et al., 2007; Jiang, Liu, Xiao, & Yang, 2012; Kohr, 1997; Kulpa & Brierley, 1993; Menne, 1992; Menne & Revy, 1994; Moyes & Houllis, 2010; Petrie, Craw, & Ryan, 2005; Simmons, 1996). The method known as blinding is one of the most effective and economical pre-treatment methods (M. D. Adams & Burger, 1998; Albert, 1923; Darrow, 1924; McQuiston & Shoemaker, 1975; Van den Berg, 2000). Blinding, also referred to as blanking or passivation, uses a chemical reagent to passivate the preg-robbing carbon by selective absorption or wetting (Bas, Altinkaya, Yazici, & Deveci, 2012; Brierley & Kulpa Jr, 1993; Dunne et al., 2012; Van den Berg, 2000; Yang, Qian, Song, & Dong, 2013; Yen, Amankwah, & Choi, 2008; Zhou, Jiang, & Choi, 2014). Organic reagents, which selectively adsorb on the surfaces of activated carbon and “smother” the surface, have been used for blinding carbonaceous matter in gold ores prior to cyanidation. Two comprehensive studies by Abotsi and Osseo-Asare and Adams and Burger have been published on this topic (Abotsi & Osseo-Asare, 1986; M. D. Adams & Burger, 1998)."

Jan 1, 2017

The Autogenous milling of ores holds an increasing attraction as the focus moves towards reducing energy usage, both direct and embodied in grinding media. However, most of the early AG mills were converted to SAG for improved stability and increased throughput. This imposes a huge penalty in steel grinding media consumption. The LKAB iron ore operations in Sweden process highgrade magnetite through fully-autogenous milling lines to a final product P80 of about 45µm. The outcomes of P9O AMIRA research surveys, covering a wide range of mill fillings and throughputs and with different feed blends, are presented. Insights are provided on operational strategies, opportunities, the influence of feed size control and balancing the blend of competent gangue and softer magnetite. Areas of importance in the successful operation and control of energy-efficient autogenous circuits are highlighted.

Jan 1, 2012

By W. Beres

Many non-commercial operators are currently faced with the need to operate fleets of legacy gas turbine engines. How long such engines can be kept in service safely, without replacing a significant portion of their aging structural components, has become a growing concern to engine life-cycle managers, due to uncertainties in the remaining lives of critical components of these engines. This paper describes the application of the damage tolerance methodology to predict safe inspection intervals (SII) for critical components of gas turbine engines, using components of a turboprop engine for a transport aircraft as examples. High temperature components of this engine are made of advanced aerospace alloys. The methods of predicting three-dimensional fatigue crack growth at the critical location of turbine discs and spacers using both commercial and in-house developed algorithms are presented. Sensitivity analyses are performed to determine the effect of variations in material parameters on the predicted safe inspection intervals. In addition, spin rig tests performed for both turbine discs and spacers are described. Finally, crack growth rates predicted by numerical analyses are compared to those obtained from spin rig testing and the damage tolerance of the turbine components is assessed.

Jan 1, 2015

By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By V. A. Leão, A. M. Silva, S. M. Bertolino, B. C. S. Ferreira, D. Guimarães

Although not considered a high risk pollutant as compared to toxic metals and acidity, environmental agencies worldwide are proposing regulations to control sulphate in effluents and drainages by setting a threshold value varying between 250 mg/L and 500 mg/L. The aim of this study was thus to compare four different techniques for removing sulphate ions from mining/metallurgy effluents. The first alternative studied was sulphate removal by precipitation as ettringite. Treating a synthetic solution containing 1650 mg/L sulphate at 22±1 ºC resulted in removals close to 85% during continuous precipitation. Sulphate sorption was also investigated using three different ion exchange resins as well as limestone. Fixed bed experiments produced sulphate loadings of up to 70 mg SO4 2-/L resin, at pH 2.0. In neutral wastewaters, limestone is also a potential adsorbent producing a maximum particle loading of 19 mg/g. Sulphate sorption on limestone seems to be an alternative to treating mine waters with sulphate concentrations below the 1200-2000 mg/L range, where lime precipitation is not effective. Subsequently, sulphate removal by sulphate reducing bacteria was also investigated and it was observed that reactor’s hydrodynamic conditions and the choice of substrate are important factors for the process. The different technical aspects of each technology are addressed.

Jan 1, 2014

By Bertrand Quiniou, Pierre Amadieu

Ion exchange technologies and processes are proven and established technologies widely used in numerous industries including hydrometallurgy for metal separation and recovery from metal bearing solutions. They have evolved through innovation which includes the development of countercurrent multistage (or multivessel) ion-exchange contactor systems with the benefit, for industrial operations, of greatly reduced footprints and ion-exchange media inventories, as compared to more traditional fixed bed contactor systems. Information on procedures for design and sizing of countercurrent multistage ion-exchange contactor systems is not readily available since it is most often proprietary know-how. The purpose of the present work is to develop a simple and innovative approach for the sizing and modeling of industrial countercurrent multistage ion-exchange contactor systems. The suggested approach builds upon published results and upon the following observation: in an industrial setting, knowledge of how component concentration or load on a contactor output streams vary with time t within a cycle duration (0 < t < T) is generally of little interest, only knowledge of time average of such concentration or load over a cycle duration T is sought for. The presented approach will be tested against current or past performances of industrial countercurrent multistage contactors of Orano Mining operations such as SNK‑3M moving packed bed contactors in Kazakhstan and NIMCIX fluidized bed contactors in Namibia.

Jan 1, 2020

By E. Barsky

"Theoretical notions of mass transfer processes in cascade separation of bulk materials have not been adequately developed as yet (Barsky M.D. 1980). In this paper we have derived linear difference equation of the second order for a cascade with initial feeding top any stage proceeding from mass exchange regularities. The solution of these equations has allowed us to determine quantitative dependences of the material distribution over the cascade stages, which serve the basis of the method of predictive estimate of the process results. We have also examined the model of the material distribution coefficient formation at individual cascade stages.We have checked the adequacy of this model to experimental data. It is noteworthy that the obtained theoretical results are phenomenological, i.e. they can be applied to the processes of separation of different physical nature, e.g. of isotopes, liquid media, gases, etc.INTRODUCTIONRecently, the processes of cascade separation of bulk materials have found broad application in various industries. They ensure a high separation efficiency and high-quality composition of final products. Although specialized literature gives serious attention to cascade processes [1], their theory is not sufficiently developed yet. To achieve optimal organization of this process, we examine mass transfer in a cascade gravitational classifier with stages of identical design."

Jan 1, 2016