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By J. P. Harrison, N. Bozorgzadeh, M. Dolowy-Busch

"It is common in rock engineering practice to characterize the triaxial strength of intact rock by using only data samples of small size. Practical guidelines such as ASTM support such sample sizes. In this paper, we investigate the reliability of the Hoek-Brown strength criterion estimated from such samples. For this purpose, we use an unusually large published set of triaxial strength data to randomly select a large number of data samples of small size to simulate the situation that frequently encounters in practice. The samples are generated with different arrangements with regards to the confining pressure. We fit the Hoek-Brown criterion to each of these samples, obtain estimates of strength parameters and compare them to those obtained from the complete data set. Our analysis suggests that estimates based on small samples are not reliable and can lead to both over- and under-estimation of strength.Additionally, we use these small samples to investigate the statistical methods for obtaining design values of strength as suggested by limit state design standards such as Eurocode 7. We show that, if used in conjunction with small samples, these methods do not guarantee a safe estimate of strength and in many cases lead to highly over-conservative estimates.We present a potential solution to this problem by augmenting the small data sets with Bayesian informative priors to give much more reliable estimates of strength. We conclude with suggestions for the development of informative prior distributions."

Jan 1, 2015

By L. C. So, S. Faucher, S. Mostaghel, A. Triwahyuono, D. Sauter, S. -Y. Oh, S. K. Lee, K. Aswin

"Molten hauling and water granulation are the commonly used slag treatment methods in the production of nickel. Water is present in these processes either to accelerate cooling of the dumped slag or in the granulation itself which creates an inherent safety risk of explosions. Even good design and operation are not sufficient to prevent explosions or injuries from occurring. Several dry methods to treat slags have been intensely studied. However, most of these technologies have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple Dry Atomization process, which eliminates water and allows for heat recovery. As part of the development towards other sectors, laboratory-scale and pilot-scale trials have been completed in a number of base metals and PGM facilities. Recently, Dry Atomization of a nickel laterite slag was successfully demonstrated at the laboratory-scale. The current paper introduces the technology and reports the test results obtained from atomization of the nickel slag.INTRODUCTION The processing of nickel laterites produces vast amounts of slag with over 90% of the feed to the furnace reporting as slag. Slag handing is therefore of critical importance to a laterite smelter. Traditionally there are two ways in which the slag is handled (1) Molten hauling, dumping, cooling and quarrying (2) Water granulation, dewatering, stockpiling. There are inherent disadvantages of both methods that will be outlined in this paper. An alternate route of Dry Atomization provides distinct advantages over the two conventional routes that are of particular interest to the nickel producer such as elimination of molten hauling, dumping and quarrying, elimination of water and improved safety. There is also the potential to convert the slag, which is typically regarded as a waste product, into a value added product and the continuous nature of slag tapping makes it amenable to heat recovery. Hatch has recently conducted laboratory-scale test work on laterite slag to demonstrate its viability for Dry Atomization. Results of this work are presented."

Jan 1, 2017

By E. Ghali

"Corrosion of support system components (e.g., bolts, mesh, plates) is a safety and economic concern in underground mines. This paper reports the results of a five-year study wherein corrosion coupons were installed at select locations in participating mines, recovered at regular intervals, analyzed for signs of corrosion, and tested to quantify loss in capacity. Complementary tests were conducted on recovered mesh and friction bolt specimens. The data provide insights into contributing factors for support systems corrosion, which aid in the selection of appropriate support strategies and reliable assessment of the useful life and need for rehabilitation of a support system.RÉSUMÉ La corrosion des composantes des systèmes de soutien (p. ex. boulons, grillages et plaques) est une préoccupation économique et de sécurité dans les mines souterraines. Cet article présente les résultats d’une étude de cinq ans pendant laquelle des coupons de corrosion ont été installés à des endroits spécifiques dans les mines participantes; ces coupons ont été retirés à des intervalles réguliers, analysés pour des signes de corrosion et mis à l’épreuve pour quantifier la perte de capacité. Des essais complémentaires ont été effectués sur les grillages récupérés et sur les échantillons de boulons d’ancrage. Les données aident à comprendre les facteurs qui contribuent à la corrosion des systèmes de soutien, ce qui est utile dans le choix de stratégies appropriées de soutien et pour une évaluation fiable de la durée de vie utile et du besoin de remise en état d’un système de soutien."

Jan 1, 2015

By G. Girard, A. Larouche, J. Colbert, G. Doyer

"The Direct Chill (DC) casting process uses water to extract heat from molten aluminium and helps to control the solidification process. Many factors such as the water flowrate, water distribution around the mould and water impingement angle have significant impacts on the solidification process. It has been noted that the chemistry variation of the cooling water is also an important factor that has a major impact on the presence of defects on the ingot. A significant change in the water quality can produce defects on the ingots such as cracks, bleedouts, or runouts. Understanding the impact of water quality variation on ingots is therefore essential to ensure good ingot production and reduce defects. This paper aims at describing a new approach to follow the variations of process water quality over time. It is an original and innovative method, which is still under progress. A water quality and stability index (WQSI) is under development to evaluate changes in the water composition based on water physico-chemical parameters. The index is calculated by comparing each of the actual parameters with historical values previously modeled by a statistical law. It is a dimensionless number having an adjustable weight factor for each parameter. The positive or negative contribution of each parameter, with respect to the water cooling capacity, is taken into account to calculate the WQSI. The current selection of parameters is based on knowledge from the literature as well as on empirical experience. When the developed tool will be mature, it could be used to track water variations upon time and anticipate problems, enabling proactive actions to ensure good ingot production.INTRODUCTIONFor many years, the impact of water chemistry on heat transfer, during DC casting, has been of great interest in the aluminum industry. Several papers have been published to demonstrate the correlation between water chemistry and heat transfer (Yu, 1985), (Gildemeister, 2014). Although numerous studies do present the effects of water parameters (i. e. hardness, conductivity, oil, and grease…) on cooling capacity under controlled experimental conditions, they do not reflect the strong interactions between the parameters and variations present in a casting center. Wells and Cockcroft also demonstrated that laboratory based studies are not fully representative of real heat transfer in an industrial casthouse, there are too many factors involved (Wells, Li, & Cockcroft, 2001). In this context, it becomes very difficult to obtain a quantifiable relationship between the capacity of water to cool the ingot and ultimately the performance of the cast."

Jan 1, 2016

By J. Stiksma, J. Dennett, R. Kalanchey, J. Ji, M. Collins, T. Chan, R. Berezowsky

A pilot plant campaign has been conducted by Sherritt Technologies in support of Eldorado Gold Corporation’s evaluation of pressure oxidation technology for the treatment of refractory gold concentrates from the Certej deposit in Romania. Four separate concentrates, containing 3.5 to 5.4 g/t Au, 13.0 to 14.5% S2- and 12.0 to 32.5 g/t Ag, were tested in the eight-day campaign. The major gold-bearing mineral was pyrite. Preliminary batch tests indicated that gold extraction from the oxidized concentrates in subsequent cyanide leaching was adversely affected by the presence of organic carbon in the pressure oxidation feed when chloride in solution was at an elevated level. As such, the process conditions that were tested during the pilot plant operation were selected to either counteract the negative impact of the organic carbon, or to deactivate it during pressure oxidation. Both process routes proved feasible, yielding gold extraction of 95 to 98% in cyanide leaching of the oxidized concentrates. Silver extraction was typically in the range of 80 to 90%, provided that the oxidized concentrates were also processed in a lime boil step prior to cyanide leaching.

Jan 1, 2014

By H. Kim

"IntroductionThe Hat Creek coal field contains low-grade coal deposits which are the thickest in the world. The diamond drilling and geophysical surveys conducted by B.C. Hydro over the last six years have indicated in excess of 2 billion tonnes of sub-bituminous to lignitic coal. The coal field is in the Interior Plateau Dry Belt, about 240 km northeast of Vancouver, and contains two explored, nearsurface coal deposits amenable to surface mining (Fig. I). The No. I deposit contains approximately 740 million tonnes of coal at 17.71 MJ / kg, or 7,600 Btu/lb, at 34.82% ash and 24% moisture. The No. 2 deposit to the south contains appreciably more coal resources at somewhat lower grade, but it has not been explored so extensively because of its higher stripping ratio. Therefore most of the exploration activities to date have been directed toward the development of the No. I deposit. The No . I coal deposit has been selected as the source of fuel for a proposed thermal powerplant to be built about 5 km east of the deposit. The purpose of this paper is to summarize the data obtained from the diamond drilling and the geophysical logging in the No. I deposit between 1974 and 1979. An attempt is made to explain the depositional environment of the Hat Creek coal measures. Because the understanding of the depositional environment in.a particular basin is essentially an evaluation of all the geologic properties of the area, the available geological information in the No. I deposit has been compiled on the basis of consistent criteria. This includes data on the lithology of the coal measures, thickness and areal distribution of the elastic sediments, and on the changes in the megascopic stratigraphic profile based on geophysical correlation. The palynopetrographic relationship and detailed sedimentological aspects are not examined in this paper. Such studies should provide important information relating the causal vegetal and chemical responses of the coals to -environmental changes. Extensive deposition of surficial materials during de-glaciation left most of the area of the Upper Hat Creek Valley devoid of bedrock exposures. Structural and stratigraphic features are hidden beneath glacial deposits and/or post-Eocene volcanics. As a result, the geological interpretation of the Hat Creek coal basin has been based primarily on drilling and geophysical data. Because of this, any explanation of the depositional environment details is tentative until the deposits are stripped for development."

Jan 1, 1985

By F. R. Nogas

"Because of the elements of uncertainty and instabilitp associated with single-enterprise communities, there is increasing interest in the alternatives to developing additional new communities of this nature. Gulf Minerals Canada Limited has chosen a unique alternative means to accommodate employees at a new uranium mine/mill complex at Rabbit Lake in Northern Saskatchewan. Gulf has adopted a fly-in program which moves their staff from a 450-mile radius, in and out of the on-site facilities, on a 7-day rotation."

Jan 1, 1976

By B. R. Hart, S. S. Dimov, J. Fournier

Carbonaceous matter (c-matter) in sulphide ores can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob, gold from a cyanide leach solution. This paper describes a standardized procedure for characterization of c-matter in an ore sample providing detailed information on its composition, maturity and preg-robbing capacity. The procedure utilizes the following complementary analytical techniques in conjunction with several chemical tests and assays: SEM/EDX Raman spectroscopy and TOF-SIMS. Results of the test can be used as a predictive tool to estimate the impact the c-matter will have on the gold recovery process. A comparison between predicted preg-robbing behaviour and cyanidation test results are presented.

Jan 1, 2011

By James L. Parks, David M. Kjos

"Significant increases in mill liner life and plant availability can be achieved by following guidelines that have evolved from over twenty years of practical experience with autogenous grinding (A0) and semi-autogenous grinding (SA0) mills. A0 and SA0 mill liner functions, performance criteria, designs, wear-resistant materials and maintenance procedures are reviewed. Operating practices that can lead to accelerated wear and breakage are discussed.IntroductionEfforts to improve the performance of liners for autogenous grinding (AG) and semi-autogenous grinding (SAG) mills began as soon as the modern, large-diameter versions of these comminution machines were first intalled in commercial plants twenty years ago . While concentrators with conventional circuits were typically running at 95010 or better mill availability, many of the new autogenous and semi-autogenous circuits were struggling to achieve 80% availability. Liner maintenance, which involves not only material and labour costs but also loss of production, was quickly identified as one of the major reasons for downtime.Today, liner designs and materials have evolved to the point where virtually maintenance-free liner life of two to three years is possible in autogenous mills and one year in the more severe operating conditions encountered in semi-autogenous mills. Of concern, however, is that hard-won lessons from the past sometimes seem to be forgotten or ignored during the design of new mills and the operation of existing mills. As liner suppliers, we are often confronted with performance problems that could have been avoided by applying well-publicized guidelines for liner design and materials selection.This paper provides an overview of AG and SAG mill liner functions, criteria for evaluating performance, designs, wear-resistant materials and maintenance procedures. Also, operating conditions that can lead to accelerated wear and liner breakage are discussed in detail."

Jan 1, 1990

By Tom Setterfield

Conclusions ?Canada is a prospective place to explore for IOCG deposits ?Time distribution of IOCG mineralization in Canada mimics that in the rest of the world ?Canada may have been the first country to start mining IOCG deposits ?Production from newly discovered IOCG deposits in Canada may start soon

May 1, 2006

By E. Henderson, L. K. Daneshmend

Drawpoint control is critical in determining the cutoff point for load-haul-dump mucking operations to minimize dilution. It is also necessary to ensure even mucking distribution and to prevent possible hang-up of material within a stope. A prototype production monitoring and reporting system has been developed for load-haul-dump operations in under-ground mines. The system generates accurate and timely information regarding mucked tonnages and drawpoint and ore/waste pass utilization. The monitoring system integrates a PLC-based load weighing system with a radio frequency identification (RFID) system for locating the vehicle. The system records the identification and time of entry and exit of each draw-point and ore/waste pass visited during a shift, as well as the weight of each bucket load. A trial of the system was conducted at the CAN-MET Experimental Mine near Val d’Or, Quebec. The monitoring and reporting system functioned as designed, with the exception that the maximum read range of the RFID tags under dynamic conditions was found to be a limitation. RFID systems with greater range capabilities have been identified for a second generation system. The system is the first of its type in North America to demonstrate that RFID tagscan be successfully applied to locate trackless underground equipment. Because of their ability to locate equipment and personnel within underground mines, RFID systems should be considered a key technology for future mine information and process control systems.

Jan 1, 1996

By L. Yaun

In underground coal mining operations, gas content in a coal seam is used to assess the risk of coal and gas outbursts. To estimate the gas content, a number of systems have been developed, however issues remain about the rapidness and accuracy of these systems. To address these issues, a new and improved system has been developed that includes a sampling-while-drilling unit for coal sampling, a coal canister, an underground-based portable measurement unit, a surface-based measurement apparatus, and gas content calculation software. The system has been successfully applied in underground coal mines at Huainan, China. This new, rapid and accurate system, its main components and field trials are described in this paper.

Aug 1, 2013

By Z. Huda

The effect of various percentages of cold-working and recrystallization on the microstructure and hardness of commercially-pure aluminum plate, has been studied. The 'A critical deformation for the aluminum, has been determined. Experimentation involved cold rolling and recrystallization processes followed by quantitative metallographic practice and the hardness measurements. The raw material chosen was a plate of commercial aluminum which was cold rolled to different percentage of cold-work and then recrystallized by heat treatment at 150°C. The critical deformation percentage of aluminum was computed to be around 30% of cold-worked.

Jan 1, 2007

By H. M. Woodrooffe

IT IS WELL KNOWN that chrysotile asbestos from various occurrences exhibits varied physical properties and certain differences in chemical corn position, both of which conditions may have an important bearing on the industrial utilization of the fibre. The usefulness of a harsh fibre in the manufacture of asbestos cement products and of low-iron fibre for certain electrical uses are examples. It is also .possible to obtain a fibre with a texture too harsh and brittle to be of economic value. Much research into the structure of the mineral and to a lesser degree observations relating the water of combination to certain physical properties have ?been reported. This paper is an attempt to show that the pyrolysis of ?chrysotile takes place in three stages and that the conditions of pyrolysis are peculiar to the fibre and may afford some clue to the variations in physical properties of asbestos fibres which affect their utilization.

Jan 1, 1956

By Karl J. C. Harries

"1.1. WHAT ARE AGREEMENTS AND HOW ARE THEY FORMED?In order to have an agreement, at common law, there must be an offer, acceptance of that offer, and consideration passing between the parties. In addition, the material terms (i.e. the basics or substance) of the agreement must be discernible, preferably by means of documentation. Although these concepts may appear simple and straightforward, the law relating to them is voluminous and complex. Some brief comments are worthwhile.• Offer/acceptance: Both offer and acceptance should be in writing, but they need not be. The actions, conversations, and/or correspondence of the parties may constitute either or both of them. Notwithstanding, the local law or practice of a jurisdiction will impose some specific requirements for certain types of agreements. If these requirements are not met, the agreement may be unenforceable. For example, Ontario’s Mining Act requires transfers of unpatented mining claims to be evidenced in writing and recorded.1• Consideration: Consideration is usually thought of as being money, but it can be virtually anything, even “the premises” (i.e. the mutual covenants or promises contained in the agreement itself). In addition, if one party, relying upon the offer of another, does something to his detriment, then the doing of the act can be considered to be an acceptance of the offer and, under the legal concept of “detrimental reliance”, can also be consideration. Whether or not detrimental reliance exists will depend upon the circumstances of each case.2• Material terms: The requirement that the material terms of an agreement must be discernible does not mean that all of the terms of an agreement must be documented or even have been considered, just the basic or material ones. In addition, it will be up to a judge to decide what is material – not necessarily the parties. In order to establish the material terms, a Court may look at all relevant documentation and may hear oral evidence. It will resist “writing the agreement”"

Jan 1, 2003

By Hökmark. H., M. Lönnqvist

"The Swedish Nuclear Fuel and Waste Management Company are planning to construct a permanent storage facility for high-level nuclear waste at about 500 m depth in fractured crystalline rock. One potential concern for the long-term performance of the repository relates to large fracture shear displacements, since these may damage intersected waste containers. Although details in fracture surface geometries are known to influence slip magnitudes and distributions, fractures are commonly approximated as planar features with lab-scale properties due to lack of relevant field-scale data and to limitations in available modelling tools. The purpose of the work described in this paper is to explore the possibilities to use the distinct element code 3DEC to generate and analyze models with isolated, non-planar fractures and, based on the results of such models, get perspectives on the influence of basic disturbances such as ridges, steps and waves. Given the model set-up, fracture segments with orientations deviating from the critical one will contribute to stabilize the fracture. As a result, all analyzed non-planar fractures slip less than the critically oriented planar fracture. We demonstrate that the angle of deviation is the most influential parameter determining the slip magnitude for comparable surface geometries. Similarly inclined steps and ridges have almost equal slip reductions despite differences in surface area restricting the movement. Although it may be possible to translate the influence of such irregularities to an effective coefficient of friction that could be used as input to models with idealized planar fractures, additional analyses with randomly shaped and distributed asperities, different fracture sizes and with alternative stress loads, need to be carried out to devise a defensible strategy for this type of parameter variation. INTRODUCTIONThe Swedish Nuclear Fuel and Waste Management Company’s (SKB) concept for deep geological storage of high-level nuclear waste is the KBS-3 method according to which the waste will be encapsulated in copper canisters and deposited, surrounded by compacted bentonite clay, in vertical deposition holes at about 500 m depth in fractured crystalline rock (SKB 2011). A site has been selected in the Forsmark area, which is located some 120 km north of the Swedish capital Stockholm. One potential concern for the long-term performance of the repository that has been identified by SKB (SKB 2011) is related to large shear displacements along repository host rock fractures induced by a nearby earthquake, since these may cause mechanical damage to intersected waste containers. Due to lack of relevant data at the appropriate field scale and to limitations in available modelling tools, fractures are commonly approximated as planar features with lab-scale properties. The standard numerical tool, 3DEC (Itasca 2013), used in SKB’s rock mechanics analyses, for example, generates planar fractures by default. Results from dynamic 3DEC earthquake-models (Fälth et al. 2010) currently provide input to layout decisions, i.e., the diameter of the smallest planar fractures that must be avoided when deciding on waste container positions at different distances from potential earthquake faults. It is, however, well known that fracture surfaces are rough or undulating on a wide range of scales (e.g., Candela et al. 2012) and that such deviations from planarity influence the mechanical behaviour of the fractures (e.g., Dieterich and Smith 2009, Marshall and Morris 2012, Ritz and Pollard 2012). It will probably never be a realistic option to attempt to represent the geometrical complexity of a population of fractures of different size, shape and surface structure in any large-scale rock mechanical analysis relevant for the performance assessments of the nuclear waste repository. It may however be possible to find approximate ways to represent different styles and degrees of non-planarity by assigning mod"

Jan 1, 2015

By Nessetech Consulting, L. A. Cisternas, E. D. Galvez, S. H. Kuan, L. H. Saw

"In Malaysia, there were two rare earths processing plants namely Asian Rare Earth (ARE) and the Malaysian Rare Earth Corporation Plant (MAREC) in Perak, which were operated until 1992 and were subsequently closed due to problems pertaining to disposal of large amount of radioactive waste. Recently, Lynas Advanced Materials Plant (LAMP) has become one of the largest rare earths processing plant in the world producing rare earth elements (REE) in Gebeng, Pahang. The primary raw material is lanthanide concentrate (LC) which is imported from Mount Weld mine in Australia and shipped to Malaysia. LC is produced from lanthanide ore after mining and mineral processing. The ore has a lower impact than Bayan Obo, Mountain Pass and adsorbed clay deposits, given the small footprint of the mine itself and the remoteness of the location. The type of ore being mined (rare earth phosphates: carbonatite, monazite) may have higher thorium content than bastnasite ore from the Chinese or American mines but still far below radiation concerns. This paper was written to review the processing flowsheet at the Lynas Advanced Materials Plant (LAMP), the environmental impact associated with the processing of the said ores and the sustainability of the operation.INTRODUCTIONRare earth minerals are one of a set of 17 minerals or chemical elements which consists of yttrium and scandium, as well as the 15 lanthanide elements (lanthanum, cerium, praseodymium, neodymium, promethium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium). Despite their importance, rare earth minerals rarely exist in economically viable concentrations and they are usually difficult to extract. Rare-earth minerals create strong magnets when added to magnetic elements such as iron, and are useful for the production of electronics systems as well as electric cars. They are also used extensively in automotive catalytic converters, fluid cracking catalysts in petroleum refining, wind turbines, phosphors in colour televisions and flat panel screens, displays for mobile phones and laptops, rechargeable batteries, and various medical devices. The elements are typically split into two subgroups: the cerium sub-group of ‘‘Light’’ rare earth elements (LREEs) which includes La to Eu and the yttrium sub-group of ‘‘Heavy’’ rare earth elements (HREEs) which include the remaining lanthanide elements, Gd to Lu, including yttrium (Gupta and Krishnamurthy, 1992; Jordens et al., 2013; Trifonov, 1963). Scandium, however, when it is classified as a rare earth element, is not included in either the LREE or HREE classifications (Gupta and Krishnamurthy, 1992; Jordens et al, 2013). Half of the world’s 110 million tons of reserves exist in China while other sizable deposits are found in Russia, United States, Brazil, India, Australia, Canada, and Greenland. The countries known to be actively mining REE are China, Russia, India, Brazil and Malaysia (Hao et al., 2015). Among these countries, China has the largest REE production, accounting for more than 93% of global supply (Yap, 2015). The critical metal report (Moss et al. 2011) listed 14 economically vital raw materials that are prone to supply disruption and concluded that supply disruption would threaten the goal for cleaner transport and sustainable energy since rare earth metals are used in products using green technology, such as hybrid/electric vehicles, carbon capture systems, wind power generation, low-energy lighting, and energy efficient flat-screen displays."

Jan 1, 2016

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By Y. Guglielmi, C. Gout, P. Henry, P. Dick, C. Nussbaum

For a decade, observations and experiments conducted in underground environments worldwide (mines, underground research laboratories - URL) made it possible to bridge the scale gap between laboratory scale and large scale faults. Indeed, underground rock laboratories allow developing decameter scale relatively well constrained experiments at the smallest distance from the hypocenters. URL’s experiments allowed developing new monitoring technologies coupling pressure-strain-seismic measurements and reproducing complete earthquakes sequences analogous to natural ones. They also allowed exploring past movements of faults and sometimes also paleofluids in three dimensions and characterizing different fault architectures and hydromechanical properties in unaltered conditions. This is particularly important in the study of faults affecting clay formations which could not be observed at the Earth’s surface because of the high alteration. Here we show how examples from the Mont Terri (Switzerland) and Tournemire (France) The URLs may help in (i) defining the concepts of fault architecture in shales, (ii) estimating fault hydromechanical properties from field decameter scale experiments. Some key results are that faults which are critically stressed or at the rupture limit can reactivate for stresses variations within the range of those produced by shallow underground excavations, and that slight micrometer-to-millimeter scale reactivations may lead to large factor-of-10-to-1000 permeability increases. Such promising results show that URL’s experiments may bring new insights on some key processes that control the relations between fault stability and permeability evolutions in very permeable layers.

Jan 1, 2015

By Long Han, Beijing General Research Institute of Mining and Metallurgy, Yu Xie, Yunhai Zhang, Yangge Zhu, University of Science and Technology Beijing, Yanbo Shang, Xingrong Zhang

"The first-principles method was employed to study the adsorption of hydroxyl calcium (CaOH+) and hydroxyl (OH-) on hematite and quartz surfaces. The calculation results suggested that OH- preferred to interact with the active Fe sites on the hematite surface, whereas OH- adsorbed on the quartz surface by weak hydrogen bond. Though CaOH+ could easily adsorb on the hematite and quartz surfaces by the formation of Ca-O bond, the covalence formed on the quartz surface was apparently stronger than that on the hematite surface, meaning a stronger and more stable adsorption. CaOH+ adsorbed on quartz surface was mainly through the interaction of O-2p and Ca-3d states, and this interaction on hematite surface was weaker.INTRODUCTIONIron Increase and Silicon Reduction Technology (Yu & Duan, 2002) of hematite is mainly through the reverse flotation (silica is floated away from the iron concentrate). There are two ways to achieve this (Houot, 1983). One is to collect quartz by cationic collector directly; the other is to activate quartz by lime and then collect it by anionic collector. There are two main different views with respect to the mechanism of quartz activation: mono-hydroxyl compound theory (Fuerstenau, Rice & Somasundaran, 1965; Fuerstenau & Palmer, 1976) and surface hydroxyl precipitation theory (Hu & Wang, 1988; Wang & Hu, 1990). The former indicated the formation of the mono-hydroxyl complex is one of the two criteria of quartz flotation. The later theory, on the other hand, suggested that surface precipitation is the adsorption of active species of metallic ion on quartz surface. However, most of those researches are based on the solution chemistry of flotation and little is done at the microscopic level.In this paper, by the help of first-principles calculations, the adsorption models, bonding conditions, Mulliken charge populations and adsorption energies of hydroxyl and calcium hydroxyl ions (OH- and CaOH+) on hematite (001) and quartz (100) surfaces were investigated to find out the lime activation of quartz at atomic level, which is significant for the researches of quartz activation theoretically and practically."

Jan 1, 2016