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By E. W. Shaw

The past year (1950) has been a big one for the oil industry in Canada, with new records being set in almost every phase of exploration and development activity. New highs were reached in acreage holdings, in geophysical activity, in wildcat drilling, and in field development and production. The only item that did not show a substantial increase over recent years was the amount of reserves added by new discoveries. This was not due to a decrease in the number of new discoveries, however, hut rather to the fact that most of the discoveries were made during the later months in the year and could not be fully evaluated by the year end. The foregoing remarks pertain mainly to activity in Western Canada. In Eastern Canada, operations continued on a modest scale. with exploration drilling down slightly from the previous year but with development drilling and production at about the same level. Returning to Western Canada, it is observed that the general exploration play was one of expansion and intensification. The issuing of new petroleum and natural gas regulations by the province of British Columbia precipitated a moderate entry of companies into the northeastern part of the Province.

Jan 1, 1951

By M. Marchese

It is no secret that scarcity of fresh water is an issue that at a global level in the years to come will have a major impact on the business landscape. A number of projects, beyond the mining sector, could remain on paper only due to this. At the same time, this situation is seeing the rise of new business opportunities, such as development of technologies for more efficient usage of water, water recycling, and desalinization of sea water. Despite that most of Chilean mining facilities are located in the driest area of the world, business has developed strongly and actively for more than a century. However, the negative effect on the water reservoirs and the environment is, lately, resulting in the reduction of the authorized water rights. Holding Water Rights for any given volume does not guarantee that the resource will be available when needed. A recent report from the United Nations on global climate change indicates that global warming can be directly related to changes in the natural and human environment. Chile would not be an exception. The reduction in snow levels in the high Andes and reduced rainfall during the so called "Bolivian winter", have directly affected the replenishing of the underground water reservoirs in the lower parts of the valleys, where most of the extraction of the resource takes place. Mining facilities shall be designed to reduce potential environmental effects, using proven technologies, and considering the best practices available. These measures shall constitute a complete structural framework for the environmental impact assessment (EIA) of the Project. The measures to prevent and mitigate the impacts on the water resources shall be considered during the design stage of a mining project. Current and future mining projects in Chile are conscious that the increasing pressure on the limited water resources is becoming unsustainable, and are already facing the water scarcity and social pressure by implementing sea water desalination plants, including long pressurized pipelines to the mine sites (e.g. Escondida, Candelaria, El Morro, Regalito). This paper presents, in summary, an analysis of the present and potential future scenarios.

Jan 1, 2007

By P. R. Jones

"The paper describes the CDN$400 million expansion at Hudson Bay Mining and Smelting Co., Limited’s operations. The company has continuously produced copper and zinc at the Flin Flon metallurgical plant since 1930. The paper details the company’s operational turnaround since 1995 and “The 777 Project” which includes two new mines, expansion and modification of the concentrators, expansion of the zinc pressure leach plant, a new zinc electrolytic cellhouse and modifications to the copper smelter gas handling system to reduce ground level gas emissions. IntroductionHudson Bay Mining and Smelting Co., Limited (HBMS) was incorporated in 1927 to mine and process the world-class Flin Flon copper and zinc orebody. Ore concentration and metallurgical facilities were constructed in Flin Flon. The metallurgical complex capability is currently 89 000 tonnes of copper metal and 98 000 tonnes of zinc metal from both HBMS and purchased concentrates.Flin Flon, with a population of 7000, is in Manitoba and partly in the province of Saskatchewan. The location is isolated with Winnipeg 800 km to the south and Saskatoon 500 km southwest.Today, three underground mines feed the Flin Flon concentrator, one feeds the Ruttan concentrator at Leaf Rapids, 200 km to the north of Flin Flon, and Chisel North mine feeds the Snow Lake concentrator (Fig. 1).The Flin Flon volcanic massive sulphide proximal and distal orebodies are within the Flin Flon greenstone belt which stretches from the west of Flin Flon to the east of Snow Lake, a distance of 250 km. The belt is approximately 100 km wide before disappearing below the paleozoic cover to the south."

Jan 1, 2001

By A. K. Verma

This paper provides a brief overview of evolution of deformations, stresses, and pore pressures due to different excavation stages during construction of an URL. Excavation of a rockmass develops a damage zone of finite width around the excavated zone which is associated with changes in permeability and which affects the fluid flow mechanism. In this study, a coupled hydromechanical (HM) analysis has been conducted for a water saturated porous rock mass which has been created by sequential excavation and backfill of vertical disposal pit of an URL. For this purpose, an Atomic Energy of Canada Limited?s in-floor concept for a deep geologic repository suitable for Indian conditions has been used. Changes in rock deformations, stresses, strains and mechanically induced pore pressure in an undrained condition, during excavation, as well as those caused by mechanically induced rock deformations after backfill of the disposal pit, have been modeled. A three-dimensional finite difference tool FLAC3D has been used for the analysis.

Jun 1, 2012

By Claude A. Jr. Seger

Introduction This paper presents in detailed form the results of settling tests that were published in a few preliminary notes in the April 1949 issue of the Bulletin (p. 166). Carborel is the trade name for sodium carboxymethyl-cellulose and aluminium carboxymethyl-cellulose produced by the reaction of monochloroacetic acid on the alkali cellulose to form an ether. The water-soluble sodium carboxymethyl-cellulose has been known in Europe for several years as sodium cellulose glycolate and has been marketed under several trade names. These cellulose ethers, however, are relatively new in North America, where the name carboxymethyl-cellulose is often abbreviated to C.M.C., or they are referred to as cellulose gum. The particular grade of Carboxel used in the settling tests in the mill of Chesterville Mines, Limited, is the high-viscosity sodium carboxymethyl- cellulose known as Carboxel H.V. It is a white, fluffy powder and is hygroscopic, although not deliquescent. Carboxel solutions in water are colourless, odourless, and resistant to beat and light. They are stable to alkalies, but are precipitated by acids when the pH is reduced below 4.0, and also by solutions of soluble lead, iron, copper, aluminium, and chromium salts. Solutions of Carboxel exhibit the properties of hydrophilic colloids.

Jan 1, 1949

By Sarah Bélair, Denis Beltrami, Valérie Weigel

"Mabounié is a polymetallic deposit in Gabon containing niobium (1.2%), tantalum (0.03%), rare earth elements (REE) (1.4%) and uranium (0.03%) that are mostly carried by Pyrochlore minerals. Classical route for niobium recovery is a pyrometallurgical process that consists in pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF.ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore. After solubilisation of the valuable elements, niobium / tantalum are precipitated as a concentrate (12% w/w Nb and 0.3% w/w Ta) while REE (2.7 g L-1) and uranium (90 mg L-1) remain in solution. Nearly 90% of REE are recovered from the solution by conventional REE double salt precipitation [NaREE(SO4)2.xH2O) method but some REE still remain in solution as this method does not allow to quantitatively recover medium (Sm, Eu, Gd, Tb, Dy) and heavy (Ho, Er, Tm, Yb, Lu, Y) rare earth elements. From the different process routes studied (solvent extraction, precipitation, ionic exchange etc.), an innovative method has been developed and patented to recover REE residual concentration in solution. This is based on an aluminum removal step followed by precipitation of REE as REE phosphate concentrate (REEPO4) by phosphate addition into solution. The phosphate concentrate is then purified according to the conventional monazite treatment, i.e. caustic conversion and REE solubilisation in acidic media."

Jan 1, 2016

By Vard H. Johnson

"In contrast with the well-publicized Pittsburgh coal, and the Everglades of Florida, most coal-forming swamps of Cretaceous time in western North America occupied relatively limited areas. They formed in areas of irregular subsidence, bounded by the changing levee systems of meandering streams. Coke quality is determined by the physical and chemical behaviour of the vitrain during thermal decomposition. Vitrain is at least in part a colloidal substance, originally containing large proportions of water; its formation and survival depend on maintaining a shallow cover of stagnant water up to the time of burial. Heat from swamp fires or subaerial dyhydration could destroy it or impair its quality. Observed patterns suggest that the metamorphism is almost entirely thermal, and that there is little relation to tectonic stresses, or loading. These coals had probably achieved essentially their present rank prior to deformation. Evidence of frictional heating along the thrust planes is minimal or absent. Normally, coal beds are aquifers. Oxygen carried into the subsurface becomes available and reacts with the vitrain to destroy its natural thermoplastic properties. The tolerance of oxygen without loss of thermoplasticity is inversely related to the volatile content. Significant lateral variations of coal thickness are common and sometimes occur in short distances. In deformed areas these thickness changes are more commonly due to differential tectonic stress rather than to original thicknesses of coal. Locally, coal is known to have flowed into cavities, or fractures. These principals are discussed in relation to coal deposits of western Alberta and eastern British Columbia."

Jan 1, 1972

By A. F. Sirianni

The Peace River iron ore deposit represents the sole source of raw material for an integrated steel industry in Alberta. The ore has proved refractory to beneficiation by a number of techniques. A selective oil-phase agglomeration technique is described. Medium-grade concentrates, analyzing 48-53% Fe and 10-14% SiO2 were obtained with recoveries of about 75% of the total iron. These results appear to represent the optimum possible for this ore body.

Jan 1, 1977

By Y. Wang

In this study, homogeneous (unseeded) precipitation of nesquehonite (MgCO3.3H20) by the reaction of MgC12 with (NH4)2CO3 in supersaturated solutions at 30 °C was investigated. Factors which influence the precipitation of MgCO3.3H20, such as initial concentration, temperature, stirring speed, titration speed, equilibration time, have been studied. SEM images show that the initial concentration and titration speed have significant effect on nesquehonite's crystal morphology and particle size. In addition, stirring speed and equilibration time also have some influence on its properties. With the optimization of operating conditions, the crystals can grow up to a length of about 40µm and a width of 5µm, indicating good filtration properties. High purity nesquehonite obtained in this study was calcined to produce highly pure MgO at 800 °C as shown by XRD results. The novel process may be used to separate Mg and Li from high Mg/Li ratio brines in Qinghai, China.

Jan 1, 2007

By A. Zrimsek, G. Vingas, R. Wolke

IN 1952, prompted by the great demand of the Canadian drilling and foundry industries for sodium bentonite, the Geological Department of Magnet Cove Barium Corporation, Limited began an extensive search for bentonite deposits throughout western Canada. Their efforts were rewarded in 1958, when substantial deposits of high quality material were found approximately 100 miles southeast of Edmonton, Alberta. The bentonite material, a part of the Edmonton formation in the Upper Cretaceous, is located approximately nine miles south of the town of Rosalind. The land where the bentonite lies has in places .been eroded by stream and glacial action to form a wide gully, convenient for strip mining methods (see Figure 1). The bentonite bed is almost flat-lying, dipping to the southwest at approximately 12 feet per mile. The main bed is 8 to. 10 feet thick and is covered with 15 to 25 feet of overburden. Before stripping, the area is drilled and sampled to evaluate the quantity and quality of the bentonite.

Jan 1, 1962

By M. Rudolph, T. Leißner, TU Bergakademie Freiberg, C. Mämpel, R. Möckel, M. Embrechts, T. Leistner

Tin-mining activities have taken place in the region of the German Erzgebirge (Ore Mountains) for over hundreds of years up until 1991. For long times, gravity separation processes used to be the dominating beneficiation approach in those mining districts to recover cassiterite, the main tin-bearing mineral. For fine (< 100 µm) and very fine (< 20 µm) particles these approaches might not represent effective techniques, significant valuable materials could not be recovered and reported to tailings, where it was subsequently disposed. Thus, there are substantial amounts of cassiterite still present in these tailings disposals, most of it as very fine particles with already high degrees of liberation. That fact brings these tailings disposals into focus for potential reprocessing using beneficiation approaches, which are more sensitive to fine and very fine particles. In this paper we present results concerning the laboratory-scale treatment of material from exemplary heaps of the former Altenberg and Ehrenfriedersdorf mining sites using various flotation methods (including conventional froth flotation and oil-assisted flotation). Different size ranges of the material were previously prepared in order to investigate their response to the different techniques. For the study, special emphasis is put on agglomeration flotation, an oil-assisted flotation method. Therefore, an aliphatic oil phase of alkane basis is used to either selectively aggregate or collect the cassiterite particles. Recovery and flotation performance results are presented with respect to different process parameters: various collectors (including sulphosuccinamates and phosphonic acids) and depressants (including sodium fluorosilicate and oxalic acid) regime, oil dosage, agitation time and pulp density during oil/pulp agitation. Furthermore, the oil/particle aggregation behavior is analyzed via particle image analysis and, additionally, collector adsorption characteristics are investigated by contact angle measurements and zeta potential analysis. The data obtained is correlated with the testwork results achieved in order to interpret the flotation response of very fine cassiterite particles.

Jan 1, 2016

THE Michipicoten area, one of numerous iron-bearing "Archean" segments in the Shield, contains two main types of iron formation, a normal Keewatin-type, consisting of interbanded chert, siliceous magnetite and jasper, and, gradational to this, a carbonate-sulphide type which contains large de-posits of siderite and pyrite. The carbonate-sulphide type of iron formation bears a direct and intimate relationship to the volcanic development of the area; it there-by affords some insight into genetic problems of Archeanron formation in general. The purpose of this pa-per is to summarize the geological setting of Michipicoten iron formations and to briefly review genetic aspects of recent work in the area. GENERAL GEOLOGY in largely by assorted volcanics and sediments of the Michipicoten series and younger, regional granite masses. (Fig. 1). The Michipicoten series comprises a thick assemblage of mixed flows and pyroclastics together with elastic sediments and banded iron formations. The volcanics belong to the Andesite-Rhyolite Association, and characters-

Jan 1, 1961

By Takayuki Takasugi, Naoya Masahashi, Yasuyuki Kaneno, Satoshi Semboshi, Yusuke Kadoi

Cu–Ti alloy wires doped with and without a small amount of Ni were fabricated by over-aging and using intense drawing procedures. For both the Cu–Ti alloys with and without Ni doping, the over- aged microstructure was occupied fully with a coarse lamella of Cu solid solution and β-Cu4Ti plates precipitated discontinuously by grain boundary reactions. The full-lamellar microstructure was developed much more rapidly by aging in multi steps at 873 K to 723 K rather than by isothermal aging at 723 K. Ni doping in Cu-Ti alloy was also effective to accelerate the formation of the lamellar microstructure. When drawing the over-aged alloy with inferior hardness but superior electrical conductivity, the strength increased steadily and eventually exceeded that for the wires drawn from the peak-aged alloy. In addition, the electrical conductivity of the wires drawn from the over-aged alloy was always much greater than that from the peak-aged alloy. Eventually, the procedure of over-aging, followed by intense drawing, could enhance both the strength and electrical conductivity of Cu-Ti alloys, whichever they contain a small amount of Ni or not, rather than the conventional peak-aging and drawing process. INTRODUCTION Cu-based alloy wires, which have an excellent combination of strength and electrical conductivity, have attracted extensive attention for highly mechanically stressed electrical devices, such as conductive lead wires and wires in suspension springs. Cu-Be alloys are widely used for such electrical components owing to their combination of strength and electrical conductivity among industrial Cu-based alloys. However, since beryllium is potentially toxic and also a rare element, substitute materials for Cu-Be alloys have been searched for several decades. Age-hardenable Cu–Ti based alloys have been proposed as candidates because their mechanical and physical properties are comparable to those of Cu-Be alloys; however, their electrical conductivity is inferior (Datta & Soffa, 1976; Soffa & Laughlin, 2004). In order to satisfy the requirement of downsizing and streamlining electrical devices, further improvement of the mechanical and electrical properties of Cu–Ti alloy wires is needed. Age-hardenable Cu–Ti alloys, which contain approximately 3 to 6 at.% Ti, are typically prepared using a solid solution treatment above 1100 K and then aging at a moderate temperature of 700 K to 800 K. It has been revealed that the microstructural events during aging progress as follows (Soffa & Laughlin, 2004): (1) compositional modulation of the parent supersaturated Cu solid solution in an initial aging stage (Laughlin & Cahn, 1975), (2) continuous nucleation and growth of fine needle-shaped precipitates of metastable β’-Cu4Ti with a tetragonal structure in a peak-aged stage, and (3) discontinuous precipitation of cellular components laminating the plates of a terminal Cu solid solution and stable β-Cu4Ti with an orthorhombic structure at the grain boundaries in an over-aging stage. It has been also accepted that the highest number density of dispersed fine β’-Cu4Ti needles should contribute to maximal strengthening. On the other hand, decease of the strength in the over-aging stage occurs due to the replacement of the fine β’- Cu4Ti needles with cellular components containing coarse β-Cu4Ti plates, while the electrical conductivity is significantly enhanced due to the depletion of solute Ti in the Cu matrix. This suggests that a combination of strength and electrical conductivity for age-hardenable Cu-Ti alloys is in a trade-off relationship, and that innovative improvement of both properties might be limited to tuning the aging conditions.

Jan 1, 2019

By M. Yavuz

As a branch of Operations Research, decision making is a widely used application in both science and social sciences. There are many different methods developed to solve decision making problems in the literature. In this study, Fuzzy Analytic Hierarchy Process (AHP) method is performed for the selection of reclamation project selection in an open pit mine and the optimal solution of the problem is investigated. Different reclamation project alternatives are prepared for an open pit mine, which continues to its production activities in magnesite sector in Turkey. The data obtained from Magnesite Cooperation is used in the application of the method. A decision-making process is prepared as considering the project alternatives for the purpose of selecting the most suitable reclamation project. The entire criteria that affect the decision-making process are identified and transformed into a hierarchical structure. The problem is solved by using Fuzzy AHP method developed according to this structure. It is found that Fuzzy AHP is a method that may help decision-makers in solving different decision-making problems in mining.

Aug 1, 2013

By C. H. B. Leitch

"The Bralorne-Pioneer deposit produced more gold than any other deposit in British Columbia over its 70 years of operation (130 kg or 4 million oz of Au, from 7 million tonnes of 18 glt ore). Mineralization is related to a suite of late Cretaceous albitite dykes of 85 to 90 Ma age. It thus occurred long after and is genetically unrelated to the Early Permian (275 Ma) Bralorne diorite and soda granite.The major veins strike about 110 degrees and dip north at 70 degrees, with slickensides plunging 45 degrees east that indicate last movement was reverse. Major ore shoots in the veins occupy somewhat less than 20% of the vein and plunge steeply west, roughly perpendicular to the slickensides. The structures that contain the veins probably formed at around 95 to 90 Ma during a strike-slip episode with easterly directed maximum compression.Disseminated pyrite, pyrrhotite, and minor chalcopyrite occur within envelopes up to several metres from the veins. Arsenopyrite is confined to vein selvages. Local sphalerite and galena appear to correlate with gold-rich portions of the veins. Traces of tetrahedrite and stibnite have been observed but tellurides have not. Gold is found principally as thin smeared flakes of the native metal in the black sulphidic septae of the strongly ribboned veins. Hydrothermal alteration envelopes around the veins grade outwards from intensely foliated quartz - ankerite - sercite (±fuchsite) to less sheared calcite - chlorite - albite to unsheared epidote -calcite.Open-space vein filling textures found in the deep (mesothermal) environment at Bralorne can be explained by a fault- valve model. High-angle reverse faults may have acted as fluid-pressure activated valves on geopressured reservoirs, causing large cyclic fluctuations in fluid pressure that promoted mineral deposition in an episodic fashion . The faults that were mineralized were reactivated sub-vertical former strike slip faults, oriented at a high angle to the northeast-directed stress in a compressive regime."

Jan 1, 1990

By E. J. Wade

The general location, climatic conditions and access of the Tasu mine are covered briefly, with comments on the Jack of conventional transportation and communication facilities. The Haïda story of Tasu and early at-tempts at production are presented, together with a discussion of the government legislation which throttled exploration and production in the late fifties. General and specific details of local geology, mineralogy and current ore reserves are also covered.

Jan 1, 1968

By D. Michaud, C. Bazin, S. Lévesque, L. Pérez-Barnuevo, H. Longuepée

In recent years, with the emergence of Geometallurgy, a great effort has been made to characterize ore resources as early and accurately as possible, to allow better design and a more efficient operation of mineral processing circuits. In this context, core logging plays an important role, since drill cores provide the first insight into the ore characteristics. However, to satisfy geometallurgical requirements, traditional core logging does not suffice. New tools and methodologies need to be developed for the automation of core logging and the acquisition of mineralogical data better related to mineral processing performances. In this paper, a methodology for the geometallurgical characterization of drill cores is proposed, based on the drill core textural patterns. Textural pattern is defined here as the macroscopic spatial arrangement of minerals. The Mont-Wright iron ore deposit (Quebec, Canada) is used as a case study. The first part of this work aimed at analyzing the potential link between the iron ores textural patterns observed in drill cores and their response to ore processing, namely comminution and concentration. Preliminary results show similar performances in terms of energy consumption and heavy liquid separation for samples showing the same textural pattern. In the second part, this work seeks to develop a methodology for the automated identification of drill core textural patterns by the application of digital image analysis and discriminant function analysis. The results obtained show that this methodology is able to discriminate between the textural patterns identified at Mont-Wright with a good rate of success. Therefore, this work lays the foundation for the development of a new drill core characterization tool, which would allow for the early prediction of the iron ore behaviour during mineral processing through the identification of drill core textural patterns.

Jan 1, 2016

By Young Hyun Paik, Hyung Sup Choi, Yeun Sik Kim

The basic studies on the surface properties and flotation characteristics of ilmenite were made by electrophoretic, adsorption, contact-angle and floatability measurements. The isoelectric point of ilmenite is found to be at pH 5.6. By combining the results of electrokinetic studies and adsorption measurements, a clearer picture of the ilmenite-solution interface was observed. These findings were correlated with the floatability of ilmenite obtained by Hallimond tube tests. The general flotation characteristics of ilmenite are compared with those obtained for magnetite and rutile. It is indicated that the above three minerals, namely, ilmenite, magnetite and rutile, have very similar surface properties and flotation characteristics. Therefore, it is difficult to make an effective separation of these minerals by flotation. However, it is found that sodium orthophosphate acts as a selective depressant for magnetite in anionic flotation. Therefore, close pH control of the pulp in the presence of the phosphate ion enhances the possibility for a successful separation of these minerals.

Jan 1, 1967

By Chunfeng Zhao, Chong Bao, Cheng Zhao, Jiashen Tian, Matsuda Hiroshi

"Based on digital image correlation (DIC) method and self-developed code, the global strain field changing and failure properties of rock-like materials with pre-existing double flaws are experimentally studied under uniaxial compression. By theoretical analysis with linear elastic fracture mechanics (LEFM), the strain approach proves to be practicable to investigate cracking process. Thus, two types of process zone are defined to discuss the specimen’s coalescence evolution at different loading stages. Crack initiation, propagation, and coalescence is a process of zone development and nucleation. DIC strain field results are studied on a meso-level using a strain approach. In the shear coalescence mode, the SPZ (shear process zone) in a bridge area coalesces with each other, while the TPZ (tensile process zone) grows independently. In general, the paper tries to establish the link between microscopic mechanical mechanisms and macroscopic mechanical responses in flawed rock. Further research should be done to study the cracking process and its effect on rock strength in detail by the DIC method.INTRODUCTIONNatural rock contains discontinuities including pores, fractures, inclusions or other defects. The existence of these discontinuities in the rock can decrease the strength and stiffness of the rock and they are a source of initiation of new discontinuities which may in turn propagate and link with other cracks and further decrease the strength and the stiffness of the rock (Sagong & Bobet, 2002). Lots of theoretical, experimental and numerical researches have been done in studying crack initiation, propagation and coalescence in rocks (Hoek & Bieniawski, 1965; Kranz, 1983; Reyes & Einstein, 1991; Park & Bobet, 2009; Gonçalves & Einstein, 2013). But when it comes to multiple pre-flaws, the issue that how the preexisting flaws affect each other becomes complicated and uncertain. The stress field around the tips of flaw can either enhance the impact of single flaw or weaken it. According to the observations have been done before, it is found that the way and function in which these cracks propagate and coalescence depends on the geometric arrangements (Bobet, 1997; Bobet & Einstein, 1998; Wong & Chau, 2001)."

Jan 1, 2015

By B. A. Strathdee

An arsenical ore containing both pyrite and arsenopyrite was heated to a temperature at which decomposition and distillation took place. The condensate consisted of metallic arsenic and arsenic disulphide, although the analysis of the ore showed that volatile arsenic and sulphur were present in proportion to produce a condensate of arsenic trisulphide and sulphur. Distillation tests on the mineral arsenopyrite also produced a condensate of metallic arsenic and arsenic disulphide. This arsenic sulphide gave a distinct x-ray diffraction pattern which was not listed in the A.S.T.M. data file. This same sulphide can be produced by heating a mixture of arsenic and sulphur in vacuo. Its chemical analysis corresponds to As2S2. The dissociation pressures of arsenopyrite and the vapour pressures of arsenic disulphide and arsenic metal were measured, using a quartz "spoon" gauge. The dissociation pressures of arsenopyrite were compared with the published data for the dissociation pressures of pyrite to account

Jan 1, 1961