Search Documents

By R. Minto, W. G. Davenport

The slag removed from the reverberatory furnaces of copper smelters contains significant copper values. A serious financial loss is involved, as further recovery operations are not normally carried out. This paper describes the factors affecting physical transport of matte into slag by gas bubbles, and the subsequent entrapment and flotation of matte drops. Three distinct patterns of transport behaviour have been identified from studies of a number of liquid/liquid systems, including liquid metal and liquid matte systems. A theoretical approach is proposed to explain these behaviour patterns, and to predict transport and entrapment behaviour in matte/slag systems. The concepts of "Film Coefficient" (ø) and "Flotation Coefficient" (?) are introduced. The effects of smelting process variables on the physical loss of copper matte in slag are also discussed.

Jan 1, 1972

By A. Ockewitz, A. Trondl, D. -Z. Sun

"Numerical simulation of extrusion processes offers an efficient method for tool design and optimization of geometries and properties of extruded parts. However, until now there are few systematic investigations about influences of material model and different parameters e.g. for friction and thermal processes on calculated local and global responses. Since extrusion processes are essentially influenced by friction between billet and extrusion tools, new friction tests were performed in this work to develop a reliable friction model. Compression and torsion tests were performed at different temperatures and velocities to calibrate the material model for extrusion simulations. Extrusion processes for circular rods and U-profiles were conducted at TU Berlin with backward and forward extrusion for different extrusion ratios, billet temperatures, product velocities and cooling conditions. This work focuses on numerical simulations of the extrusion tests with the FE code HyperXtrude. Based on the calculated distributions of local strain, strain rate and temperature the recrystallized volume fraction and grain sizes were calculated with empirical models and compared with the experimental results from optical micrographs and EBSD scans. The calculated total and friction forces and temperatures were compared with the experimental results and the deviations between experiment and simulation were analyzed.INTRODUCTION Extruded aluminum components are widely used in vehicle constructions due to light weight and manufacturing consideration. Local mechanical properties in the components are inhomogeneous as a consequence of the spatial distribution of microstructure which is influenced by numerous factors like material composition, temperature, tool design, friction, extrusion ratio and speed during the extrusion process. For the optimization of the extrusion process with regard to all these factors numerical simulation can be an essential tool. Based on results of finite element simulations of the extrusion process the microstructure in the extruded components can be predicted and then the resulting mechanical properties can be numerically determined instead of by costly trial and error methods. The aim of the work presented in this paper is the development of a numerical method for the simulation of extrusion processes with modeling of microstructure."

Jan 1, 2018

By André Bérubé

Since the disappearance of Les Forges du Saint-Maurice at the end of the last century, many historians have taken an interest in the lengthy past of this enterprise. They considered the political, socio-economic, administrative and anecdotal aspects of the industry, but barely dealt with the elements of technology. The purpose of this article is to try to fill this gap (1). Les Forges du Saint-Maurice was an integrated industrial concern, specializing in the production of semi-finished wrought iron and finished cast iron that operated almost without interruption between 1734 and 1883. Les Forges first came into being in 1729, when Montreal merchant Franc;ois Poulin de Francheville submitted to the King of France a request for the right to exploit the bog iron ore deposits on his seigneury of Saint-Maurice. This request, agreed to in 1730, was one of a long series of attempts, previously unsuccessful, to establish a local iron industry in the colony. Several such proposals were held up by a lack of capital from promoters or a too rigid application of the mercantilist policy by the metropolis. In 1730, however, the French minister Maurepas favoured a more liberal policy which would encourage private enterprise. The benefits of an iron industry to the naval construction industry was a factor that caught the attention of administrators. The choice of the site for Les Forges was based on the following factors: - the abundance of surface deposits of bog iron ore in the Saint-Maurice region; - the presence of a vast supply of hardwood and conifers needed in large quantities by this industry; - the proximity of sandstone and limestone deposits, md1spensable materials for the construction and operation of the blast furnace; - the presence of a water stream, with sufficient flow to provide the hydraulic power needed for the operation of the machinery.

Jan 1, 1999

By L. H. Bergmann

THE blasting practices described are fairly representative of those employed in the coal mines of Eastern Canada. As such, they may be of interest to Western Canadian coal mine operators. The treatment of the subject is general, no attempt being made to discuss blasting operations at any particular coal mine in detail. All the mines dealt with are mining bituminous coal and are classified under the Coal Mines Regulation Act of the Province of Nova Scotia as 'closed light' mines. As such, they are required to use only 'permitted' explosives and to apply them in a 'permitted' manner, except where authority is given by the Mines Department to do otherwise.

Jan 1, 1945

"Industry Guide 7 contains the Securities and Exchange Commission’s basic mining disclosure policy. It provides guidance for Registrants on various matters including the definition and disclosure of proven and probable reserves and the definitions of exploration, development and production stages. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures. As NI 43-101 is law in Canada, the SEC allows mineral resources and mineral reserves prepared under CIM Definition Standards for issuers that are reporting in Canada but are also registered with the SEC. The SEC places conditions on the disclosure of these estimates. US shareholders are cautioned that the requirements under NI 43-101 and the CIM Definition Standards differ significantly from those of Industry Guide 7.Note: this Guide contains the Commission's basic mining disclosure policy. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures pursuant to the rules of Regulation S-K. Questions regarding the application of these definitions and rules to specific situations should be asked of the Commission's mining engineers or geologists at either the Office of Engineering, Division of Corporation Finance, 202-272-3252, or the Branch of Geology, Central Regional Office, 303-844-1000.(a) Definitions. The following definitions apply to registrants engaged or to be engaged in significant mining operations:(1) Reserve. That part of a mineral deposit which could be economically and legally extracted or produced at the time of the reserve determination.Note: Reserves are customarily stated in terms of DoreD when dealing with metalliferous minerals; when other materials such as coal, oil shale, tar, sands, limestone, etc. are involved, an appropriate term such as Drecoverable coalD may be substituted.(2) Proven (Measured) Reserves. Reserves for which (a) quantity is computed from dimensions revealed in outcrops, trenches, workings or drill holes, grade and/or quality are computed from the results of detailed sampling and (b) the sites for inspection, sampling and measurement are spaced so closely and the geologic character is so well defined that size, shape, depth and mineral content of reserves are well- established.(3) Probable (Indicated) Reserves. Reserves for which quantity and grade and/or quality are computed from information similar to that used for proven (measured) reserves, but the sites for inspection, sampling, and measurement are farther apart or are otherwise less adequately spaced. The degree of assurance, although lower than that for proven (measured) reserves, is high enough to assume continuity between points of observation.(4)(i) Exploration StageDincludes all issuers engaged in the search for mineral deposit (reserves) which are not in either the development or production stage."

Jan 1, 2003

By Peter A. Amelunxen, Richard LaDouceur, Courtney A. Young

"Many of the rare earth elements, the lanthanide series on the periodic table, are on the U.S. Department of Defense Strategic and Critical Materials list. In this regard, the U.S. Army Research Laboratory (ARL) has funded several projects at Montana Tech focusing on rare earth element recovery from natural resources. Current froth flotation operations utilize octyl hydroxamate for rare earth mineral extraction, however recovery is not ideal and flotation performance can be improved. Salicylhydroxamic acid (C7H7NO3) was identified as a novel collector due to similarities with n-octyl hydroxamate, notably the amine head group. Salicylhydroxamic acid is primarily used in the medical industry but due to the amine head group is ideally suited as a collector for rare earth mineral flotation.Parametric studies were performed for the flotation of rare earth minerals by modifying a wide range of variables. Mechanical variables of a 6L bench scale flotation cell, such as air inlet flow, rotor speed, and milling time for liberation were modified to elucidate energy input parameters for the desired minerals. Chemical parameters such as collector concentration and pH were varied to understand solution chemistry considerations of the salicylhydroxamic-rare earth mineral system. The study obtained a statistically significant experimental model for the flotation of rare earth minerals. A two stage compartmental model was also utilized for the determination of the first order flotation rate constants for each mineral. Optimized recovery of rare earth minerals was found to occur at near neutral pH ranges using salicylhydroxamic acid with maximum recoveries approaching ideal industrial standards although rare earth mineral grades were still not sufficient.INTRODUCTIONRare earth elements (REEs) are found in minerals that contain several REE which makes costeffective separation of the rare earths difficult. Significant scientific challenges have hindered mineral separation. The molecular similarity of rare earth elements results in minerals containing several REEs, such as bastnaesite [(Ce, La) CO3F]. This prevents efficient separation during concentration steps, for instance flotation, and has a direct impact on successive metallurgical processes. Consequently, concentration during flotation is of rare earth minerals (REM) as opposed to REE."

Jan 1, 2016

By W. G. McBride

THE present demand for men with engineering training exceeds anything in the history of the profession. Recent estimates indicate that mechanization of war has reached such a stage that at least twelve horsepower is required now for every one horsepower needed to run the machines of the first Great War. The scale of operations exceeds anything in the past, while more territory and people are involved than ever before. Many of our allies have inadequate or no facilities for producing the thousand and one articles absolutely necessary to the conduct of modern warfare. Lack of preparedness has made it necessary to produce at an unparalleled rate to gain parity with the enemy, while our losses have been so heavy that replacement, in itself, presents a task which might well stagger less courageous peoples. This means that not only is there an unprecedented demand for engineers to produce the machines, munitions, and supplies of war, but there is a correspondingly large need for men with engineering skill in the uniformed forces to operate and maintain the vast numbers of ships, 'planes, tanks, trucks, radios, and a myriad of other devices to carry on the varied activities of war. This abnormal demand came upon us after almost ten years of stagnation in the engineering industries. During this time many trained engineers drifted into other callings, while the lack of jobs for graduates caused a falling off in the number of men training for this profession. Consequently, the supply of well trained engineers was below normal when the madman of Germany precipitated us into the present turmoil. Added to all this, we in Canada are still suffering from governmental inefficiency in the utilization of the available supply of engineers. In the armed forces, engineers have been assigned to office and other work where their engineering training is not only wasted but for which men with more suitable training could be found. Mining engineers are debarred from service as aeronautical engineers, and students in mining engineering are denied the bursaries provided for aiding students in engineering. Mining and metallurgical engineers are both barred from the Ordnance department of the army. This arises from a misunderstanding in relation to engineering training. In Canadian engineering schools, all engineers are given a sound training in the branches of human knowledge which are fundamental to engineering: mathematics, physics, and chemistry. The basic difference between the several categories of engineers lies in the fact that training in the application of this fundamental knowledge to the solution of engineering problems is given in different subjects.

Jan 1, 1942

By M. Pawlik, E. Arinaitwe, V. Ferrera

A series of flocculation tests were performed on dilute quartz suspensions with the use of five polyacrylamide-based flocculants of similar molecular weights but of different degrees of anionicity. The tests were performed as a function of ionic strength and pH. The macromolecular conformation of flocculants in solution was assessed through intrinsic viscosity measurements under the same physicochemical conditions as those of the flocculation tests. It was generally found that the flocculating efficiency of the polyacrylamides correlated with their ability to coil or stretch in solution. Polyacrylamides with the degrees of anionicity on the order of 10-18% showed the highest flocculating efficiency in terms of the settling rates of the flocculated solids and the residual turbidity of the resulting supernatant. At the same time, these most effective flocculants were also found to exhibit the greatest tendency to coil and stretch in solution. This result suggests that the flocculating power of a flocculant is determined not only by its ability to adsorb onto (and bridge) fine particles but also on its ability to conform to the size of the resulting floes.

Jan 1, 2009

By R. von Gal

Hazelett Strip-Casting Corporation has been producing the Hazelett® twin-belt casting machines for copper casting since the mid-1960s. The first commercial casters were developed for copper alloy strip and anode plate. In 1968, development work was started to adapt the twin-belt caster for copper bar casting to be rolled in-line into wire rod. Since then, 36 casters have been sold as part of the CONTIROD® system for the production of a substantial portion of the world's copper rod supply. A unique feature of the twin-belt caster is the mold's ability to comply with the size and shape of the cast bar as it shrinks during solidification. Maintaining contact between the mold and the bar provides a high rate of heat transfer as well as other benefits, including the prevention of surface imperfections caused by remelting in the mold. This paper will give an overview of the continuous evolution of the twin-belt caster technology with an emphasis on recent developments in compliant mold technology for copper casting.

Jan 1, 2007

By M. Boussuge

Ceramics and refractories have many common constituents and consecutively exhibit several analogous properties. For example, concerning the thermomechanical properties this paper will focus on, the type of creep that can be observed in both materials is often the same (kinematic hardening). Changes in microstructure (phase transformation, dehydration, sintering, crystallisation,...), induced by heating and/or cooling, can also drastically modify the mechanical behaviour of ceramics and refractories. But the coarse granulates, the porosity and the impurities contained in industrial refractories may lead to specific responses of this material to thermal and/or mechanical loadings. In particular, some differences can be observed with technical ceramics in the main type of damage observed in service : diffuse damage in refractories (microcracking) and localised damage in ceramics (macrocracking). In this paper, the possibilities of transferring a part of knowledge from ceramics to refractories will be discussed, in the field of thermomechanical properties : experimental characterization techniques, mechanical behaviour models. Finally, some problems caused by scale effects and by the integration of thermomechanical properties of refractories in the numerical simulation of industrial structures will be evoked.

Jan 1, 2004

The quality of refractory bricks and castables could be determined by direct measurements of their material properties such as elastic properties, porosity, density, etc. using conventional static or non-destructive testing (NDT) dynamic techniques. Quality monitoring of refractory linings is much more challenging and complicated. The static methods require undesirable drilling and sample extractions from the furnace structure. A more desirable alternative is the use of NDT techniques for material quality estimation. The Acousto Ultrasonic-Echo (AU-E) technique is a new stress wave propagation approach for monitoring the quality of refractory linings in operating furnaces. In this paper, the conceptual methodology for the AU-E technique is described, the capabilities and limitations are expanded, and the results from two case studies are discussed.

Jan 1, 2005

By Frank Lemy

This paper presents an application of digital face mapping in an underground mine. Based on photographs it was possible to construct discontinuity maps, which were used to characterise the rock mass. The results were compared favourably with values obtained through scanline and area sampling mapping for the same site. The case is made for digital mapping as a safe, fast, and efficient way to characterise rock mass structure for engineering purposes.

May 1, 2001

By J. Mullins

Coal was first banked by the Dominion Coal Company, Limited, in 1898, near No. 2 Colliery, the same site as is presently used for that purpose. Though today there are banks at Glace Bay, Sydney, and Sydney Mines, these notes, except when otherwise desirable, will be confined to describing the practice as developed at the No. 2 Banking Station, Glace Bay, as being typical of methods obtaining at all sites. Storing The manner in which the coal was piled is illustrated diagrammatically in the accompanying sketch. A train of coal was brought on the main trestle, which extended the full length of the banking ground at a height of 22 to 39 feet above the natural surface, and dumped into bins which were integral with the trestle work. Chutes from these bins permitted the coal to be fed into 3-ton cars, which were horse drawn laterally on narrow gauge tracks laid about 10 ft. centres, to a maximum distance of 400ft. from the trestle. These cars were end-dump and as the pile extended laterally the narrow gauge tracks were lengthened by shorter or longer filling pieces, so that their ends were always kept at the brow of the bank. Much coal, however, had to be dumped directly on the tracks and hand trimmed to fill the valleys, and level off, between the tracks.

Jan 1, 1931

By C. Cristonffanini, S. Nazari

"In the past, simulation was considered to be an offline tool disconnected from plant operation. Advancements in the computation power combined with utilizing physics and chemistry sciences have allowed us to significantly improve the modeling and simulation technology for mining and mineral processing. This paper investigates the benefits of first principle models and simulation by connecting them to real time operation. Process data are connected to high fidelity models executed in parallel to the operation. In recent literature, this concept is known as Digital Twins. The Digital Twin is used for various purposes such as optimization, virtual instrumentation and condition monitoring. Using IDEAS™ simulation software we are able to construct a digital twin for different equipment inside a mineral processing plant. Two case studies for building a digital twin for the primary hydrocyclone feed pump and thickener underflow are presented. Using the pump’s model, a digital twin is developed and is installed in a gold extraction plant that is able to infer the slurry density in real time. Additionally, it is used for detecting sanding in the pipes and impeller condition monitoring.INTRODUCTION Since the eighties, thanks to advances in computation technologies, computer based simulation of processes using first principle models has become a well-known engineering tool for various industries. As our understanding of processes has increased, their representative models have become more realistic and more sophisticated. Due to this increase of accuracy, use of simulation is becoming more fundamental in process industries. The main goals to use accurate simulation is to decrease the engineering and construction cost, optimize the process design and improve the operation performance by decreasing operation cost and increasing efficiency. The term Digital Twin was first introduced in 2010 by NASA (Shafto et al., 2012) in aerospace industry. Subsequently, the concept quickly spread through other industries. As of today, no standard organization has provided an official and unique definition of Digital Twin for process industries. However, there are three important aspects that are common throughout various descriptions. When simulation is core functionality of the process (1) along the entire life cycle of the plant (2) with direct linkage to operation (3), it is called that process has a Digital Twin. According to Gartner, the concept of Digital Twin has elected as fourth most important disruptive technology for the year 2018 (https://www.gartner.com/, 2017)."

Jan 1, 2019

By J. J. Benitez

MIBC (methyl-isobuthyl carbinol) was previously shown to enhance significantly sylvite flotation when used at the stage of preparation of amine dispersions. In this paper Atomic Force Microscopy (AFM) is used to study the effect of MIBC on deposition of octadecylamine (ODA) on the surface of mica. The AFM images indicate that amino terminated, and therefore hydrophilic, deposits of ODA are observed on the mica surface in the ODA dispersions free of MIBC. In the presence of MIBC a methyl terminated (hydrophobic) monolayer is obtained on the mica surface. The transition between the monolayer and bilayer phases is due to the presence of MIBC. Experiments carried out in distilled water reproduced the results obtained from the brine. Working in pure water instead of brine simplifies the preparation conditions and the analysis by AFM.

Jan 1, 2006

By Y. Wang

In this paper, the tribological and electrochemical corrosion properties of Al2O3/polymer nanocomposite coatings were studied using a micro-hardness test, a single-pass scratch test, an abrasive-wear test, and finally an electrochemical technique such as potentiodynamic polarization measurement, The coatings containing Al2O3 nanoparticles showed improvement in scratch and abrasive resistance compared with polymer coatings; this improvement is attributed to the dispersion hardening of Al2O3 nanoparticles in polymer coatings, Corrosion test results showed that the embedded Al2O3 nanoparticles in the polymer matrix do not sacrifice the corrosion resistance of the polymer itself.

Jan 1, 2005

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

By E. A. Haack, L. A. Warren

Microbial biofilms are essentially biologically driven, geochemically reactive interfaces between solid surfaces and aqueous solution. Field investigation of acid rock drainage (ARD) associated biofilms at the Onaping nickel mine (Onaping, ON, Falconbridge Ltd.) characterizing: (1) micro-geochemical gradients (pH and 02) (2) metal fractionation amongst biofilm solid components, and (3) microbial communities; over both seasonal and diel timescales, indicates biofilms are highly metal reactive. Results show that biofilms accumulate metals seasonally within two microbially controlled solid fractions: amorphous hydrous manganese oxide (HMO) biominerals and the organic biofilm matrix. The biofilm geochemical microenvironment, driven largely by microbial activity, dynamically impacts biofilm metal behaviour over diel timescales. These results indicate that microbes can play significant roles in bulk system reactive metal transport. On-going investigation seeks to characterize the microbial players and the microbial-geochemical linkages involved in Mn oxyhydroxide formation and subsequent metal sequestration, with the goal of engineering this microbial activity as a bioremediative approach. This approach will have utility beyond specific application to the Falconbridge Onaping site to ARD mine environments in general, as the likely microbes involved in these processes are typically common across ARD systems.

Jan 1, 2004

By B. Grinbaum

The solvent extraction of Cu from acidic leach solutions is carried out using oxime extractants. The mechanism can be described as liquid ion exchange, where a labile H+ in the oxime replaces Cu++ ion from the pregnant leach solution. The process is reversible and, at high acidity, the copper is stripped back to the aqueous phase. As the extraction proceeds, the acidity of the aqueous phase increases and the equilibrium may shift against the extraction reaction. This phenomenon may become significant in leach solutions with high copper concentration, where large amounts of acid are transferred from the solvent into the aqueous phase. An efficient way to increase the recovery of copper consists of splitting the extraction into two circuits, and either neutralizing with lime or extracting the excess acid of the intermediate raffinate. In the second case, the acid can extracted using a solvent, which can be stripped with a base, e.g., NaOH or ammonia. A third option is direct neutralization with soluble basic salt, e.g., Na2CO3, within a single extraction battery. The choice of the preferred process depends on the specific process demands and on the relative availability and price of the raw materials and by-products price.

Jan 1, 2007