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By Boyd Guthrie

Methods of distilling topped crude oils and distillates under vacuum, accompanied by good fractionation, have taken a place of major importance in the refining industry. In the refining of petroleum products it is generally desirable to produce a distillate of good quality, and this objective is attained by fractionation of a high degree. The laboratory and commercial practice have proved that by varying the amount of fractionation the quality of the distillate can be changed, and refiners are cognizant of the advantages of good fractionation. Distillation under high vacuum, however, is a relatively new practice in petroleum refining, and only during the last few years has there been an indication that this method may become a general practice in the industry. Vacuum distillation offers many advantages over older methods of distilling petroleum products. Vacuum combined with steam distillation, for example, is replacing straight-steam distillation because the quality of the products of vacuum and steam distillation surpasses that of those produced by straight-steam distillation. Although the injection of varying amounts of steam in a vacuum unit is common practice, the amount of steam used is becoming loss as the vacuum within the unit is increased. This report describes the construction of a visible-action laboratory batch still and fractionating column and gives certain data pertaining to the operation of the apparatus under vacuum for the production of lubricating distillates. The apparatus was designed and built to produce lubricating distillates under as nearly ideal conditions as possible, in order that a subsequent study of the characteristics of the distillates could be made. For example, a study could be made of the distillates obtained up to the point of cracking of the charge if a topped crude were charged to the still; if the still was used as a rerun unit for lubricating distillates a study of nearly the entire charge could be made. Only topped crude has been charged to the still so far, and therefore this paper is limited to the results obtained from the distillation of such a charge. The results so far obtained indicate that such an apparatus is valuable in a study of different crude petroleums as sources of lubricating distillates.

Jan 1, 1932

By P. R. Miles, J. K. H. Ma, J. Y. C. Ma, L. Bowman

"The bisbenzylisoquinoline alkaloids are compounds which can be isolated from plants and which exhibit a broad range of pharmacological activities. Perhaps the best known alkaloid of this group is tetrandrine (TT), a compound isolated from the root of a traditional Chinese medicinal herb, Stephania tetrandra. It has been tested for its effects on the cardiovascular system, tumors, and the lungs. For example, tetrandrine has been shown to act as a calcium entry blocker in cardiac sarcolemmal vesicles (King et a/., 1988) and has been used in China as a treatment for angina and hypertension. Its possible effects as a tumor-inhibitory substance have also been investigated (Kupchan and Atland, 1973). In addition, there are several lines of evidence to suggest that it is a possible therapeutic agent for the treatment of silicosis. Yu et a/. (1983) have shown that TT inhibits the development of experimental silicosis in rats when it is administered orally after intratracheal instillation of quartz. Other studies have shown that the alkaloid inhibits the synthesis of collagen by fibroblasts and the formation of silicotic nodules in rats exposed to silica (Huang et al., 1981; Liu et al., 1983). In fact, tetrandrine has been used clinically in China as an antifibrotic agent and has been shown to improve both the appearance of chest radiographs and the measurements of diffusing capacity in patients with silicosis (Li et al., 1981).Since tetrandrine may have a potential use as a therapeutic agent for fibrotic lung diseases, its effects on various pulmonary cells and tissues should be studied. Alveolar type II cells are located in the alveolar regions of the lungs and are important because they are responsible for the synthesis and secretion of pulmonary surfactant (Dobbs et al., 1982; King, 1984), regeneration of the alveolar epithelium after lung injury (Kauffman et al., 1974), and metabolism of foreign compounds (Bend et al., 1985). Furthermore, in silicosis, for which TT has been suggested as a treatment, there are increased amounts of pulmonary surfactant produced (Dethloff et al., 1986a,b) as a result of increased rates of surfactant synthesis by type II cells (Dethloff et a/., 1989; Miller et al., 1988). Because type II cells play a critical role in maintaining normal lung function and because type II cells are affected in silicosis, for which 'TT has been used as a treatment, we studied the effects of tetrandrine on energy metabolism in these cells in vitro. Energy metabolism was chosen because it is a basic cellular function which is neces-sary for other cellular processes to occur. Since type II cells depend on mitochondrial metabolism for energy production (Fisher et al., 1980), we examined the effects of tetrandrine on cellular and mitochondrial ATP production and oxygen consumption. Additional experiments were performed in an effort to determine if intracellular calcium levels may be involved in the TT-induced effects. A preliminary report of those results has appeared previously (Ma et al., 1991)."

Nov 1, 1995

By Robert E. Barieau

In the design of plants to separate helium from natural gas , it is necessary to estimate the enthalpies of the various streams at various positions in the process . This Bureau of Mines report surveys the various methods that have been used to determine enthalpies and gives information on the organizations with such capabilities . The minimum information required for developing an enthalpy diagram is presented , and the relative merits of the various methods are discussed . It is concluded that methods that require no mass flow rate or energy measurements are to be preferred .

Jan 1, 1965

By W. H. Blackburn

This paper describing the milling practice at the Tybo concentrator is one of a series of similar papers being prepared by the United States Bureau of Mines on milling methods and costs at the various mills in the United States. ACKNOWLEDGMENT A large part of this paper way prepared by H. M. Lewers, mill superintendent of the Tybo plant of the Treadwell Yukon Co., Ltd.

Jan 1, 1931

By Henry E. Blake

Defluorination studies on refractory fluoride - bearing compounds and minerals , particularly on partly defluorinated residues from high - temperature pyrohydrolysis , required a dependable and reasonably accurate analyticalcontrol method for the analysis of fluorine . The difficulty in liberating fluorine from the fluorides of metallic elements such as aluminum, zirconium , and rare earths by steam- distillation can be largely overcome if the distillation is made from a sulfuric - phosphoric acid solution of a sodium carbonate fusion of the sample material and if the distillation temperature is maintained at about 155 ° C. The data presented in this paper show that liberation of fluorine by this method is more complete and proceeds more rapidly than by usual distillations from perchloric or sulfuric acid alone or a mixture of phosphoric and perchloric acids . Fluorine in amounts ranging up to about 140 mg can be recovered by collecting only about 300 ml of distillate . Determination of fluoride in the distillate is made by the usual thorium nitrate titration .

Jan 1, 1963

By R. C. Annear

This report describes open, sublevel, and shrinkage stoping at the Greenwood mine, operated by Inland Steel-Co. The iron ore mine is in Marquette County, Mich., about 6 miles southwest of Ishpeming (fig. 1). The Greenwood is one of three active underground hard-ore mines on the Marquette range, the others being the Cliffs-Shaft and the Champion mines. The operation reflects an achievement in exploiting small, difficult-to-mine hard-ore bodies lying beneath a 200-foot overburden of glacial drift, which is partly water bearing. This report can indicate only briefly the efforts of personnel in overcoming adverse conditions in mining more than 2 million tons of ore, 80 percent of which was in lump form, for open-hearth production of steel. Significant data presented include descriptions of the principal mining methods employed, sublevel and shrinkage stoping; percent aged mining costs for the entire year 1957, covering both direct mining costs and general expenses; and performance records in units of labor, power, and supplies.

Jan 1, 1960

By F. R. Lee

This publication lists permissible equipment approved by the Bureau of Mines during 1967 and 1968 (calendar years), except breathing apparatus and explosives. The purpose of this publication is to inform the public about approved equipment for use in underground mines.

Jan 1, 1970

By David H. Yee

Because of environmental concerns, the Bureau of Mines investigated an anhydrous chlorination process for the recovery of copper from chalcopyrite, Pelletized concentrate was reacted continuously with chlorine in a vertical shaft reactor at 550° to 750° C to extract copper-iron chlorides and elemental sulfur. The resulting molten metal chlorides drained from the reactor and collected in a receiver while sulfur distilled from the top and condensed in a separate unit. The tests were conducted in a 10-cm-diam reactor constructed of glass and in l5-cm-diam reactors constructed from various refractory materials. A high-alumina ramming mix exhibited the best resistance to molten metal chlorides and elemental sulfur in chlorine atmospheres. A reactor made with this high-alumina refractory was operated for 55 hr under actual chlorinating conditions without suffering any deterioration. Tests results show that more than 96 pct of the chalcopyrite was converted to copper-iron chlorides and elemental sulfur. Good separation of the metal chloride and sulfur products was achieved. After filtration, elemental sulfur of greater than 99 pct purity was obtained.

Jan 1, 1977

By J. E. Tiffany, Gaigler. Z. C.

"PREFACEIn presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 16 and 21 outlining the conditions in use under which, and only under which, the explosive or blasting device is permissible.In view of a recent publication recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 16 and condition 2 on page 21. An explosive or a blasting device enumerated in the permissible lists of this Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.PERMISSIBLE EXPLOSIVES TESTED UNDER SCHEDULE 17CAn active list of permissible explosives was published in December 1937 as part of Bureau of Mines Report of Investigations 3361, under the title ""Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1937.n This list included 196 brand names.Changes in the list that have been authorized to June 30, 1938, placed 7 additional brands of permissible explosives on the active permissible list as a result of tests, changes in brand names, or transfer from the inactive list. Twelve permissible explosives were transferred from the active to the inactive list. The present list contains 191 brand names. The brand names of the permissible explosives placed on the active list are as follows:"

Oct 1, 1938

By S. A. N. Sheya

The U.S. Bureau of Mines performed batch equilibrium contact experiments to examine the ability of activated coconut-shell carbon to adsorb various metal cyanide complexes. Tests were also conducted to determine the effect these cyanide complex impurities might have on the adsorption of gold by the activated carbon. Metal cyanide species included in the investigation were antimony, arsenic, cadmium, calcium, cobalt, gold, iron, mercury, nickel, silver, thallium, and zinc. Tests were made over a pH range of 6.4 to 12.5. The carbon exhibited a preference for gold adsorption over other metals present in solution. In the absence of gold, the metal cyanide complexes were adsorbed; adsorption generally decreased with increasing pH. However, calcium and thallium adsorptions increased with increasing pH, while arsenic and iron were not adsorbed at any pH.

Jan 1, 1989

By A. J. Kraemer

[The Bureau of Minas for a number of years has been studying the properties of crude petroleum from producing fields in the United States and Western Hemisphere and has published a series of reports on these fields, including oil fields of Texas.5]

Jan 1, 1927

By P. Nicholls

[This paper sets forth the burning characteristics of coke used as a domestic fuel as shown by work of the U. S. Bureau of Mines and others. Coke is a truly smokeless solid fuel and is held in high regard for this quality. Ways are being found for making commercial coke from a wider range of cools than heretofore, and tale use of coke for domestic heating is increasing. ACKNOWLEDGMENTS The experimental work reported in this paper was conducted at the Pittsburgh Experiment Station of the U. S. Bureau of Mines cinder the authority of O. P. Hood, chief mechanical engineer; M. L. Orr, assistant feels engineer, and W. M. Brewer, junior fuels engineer, assisted by Charles Schramm cooperated in making the tests.]

Jan 1, 1929

By G. W. Elger

The Bureau of Mines conducted laboratory and larger scale studies on samples of domestic perovskite and ilmenite ore concentrates to devise a procedure for recovering TiC from these ores. From the concentrates, mixtures of titanium and calcium carbides were produced. The carbides were then ground and reacted with water. This reaction decomposed the CaC2 to acetylene and hydrated lime and simultaneously liberated the TiC. Using a combination of elutriation and gravity-separation techniques to separate the hydrated lime, approximately 93 pct of the titanium was subsequently recovered as purified carbide containing 54 to 70 pct titanium with CaO content as low as 0,6 pct. This combination of techniques can be used to separate more than 90 pct of the CaO from the TiC. Therefore, this carbiding procedure is a viable method for treating titaniferous materials, including perovskite, that contain more than 20 pct CaO. Tests made in a static-bed reactor showed that for the reaction of TiC with elemental chlorine to produce titanium tetrachloride (TiCI4), a temperature of at least 940° F is desirable to achieve a suitable extraction of titanium in a laboratory chlorination reactor. In fluidized-bed tests at 840° F, 98 pct of the titanium contained in TiC was extracted.

Jan 1, 1980

By W. C. Phalan

"Prewar Conditions:Metallic magnesium may be considered a war metal, but a war metal with a future, so far as the industry in the United States is concerned. Its production in the United States prior to 1915, on a commercial scale, was negligible, but imports prior to that year may be taken as a gaze of the demand for the metal. Unfortunately, magnesium was not listed separately by the Department of Commerce prior to the war, among the importations, but was included with other metals, as follows: ""Barium, calcium, magnesium, sodium, and potassium, and alloys of which said metals are the component materials of chief value."" However, the imports of metals enumerated other than magnesium were probably small, so that the importations under the above caption may be considered chiefly metallic magnesium in one form or another and, therefore, is an approximate gage of the demand for the metal in the United States. These imports were as follows:These figures are so close that they give a good idea of the figures for the respective calendar years.Of this prewar use, it has been estimated that about 85 per cent was used annually and in approximately equal quantities in the production of (1) flash-light powder, (2) fire works, (3) aluminum casting work, and (4) nickel and nickel-copper alleys, such as monel metal, etc. The re¬maining 15 per cent was employed for general uses, such as deoxiding brass and other copper alloys in foundry work, and to a small extent in laboratory and research work."

May 1, 1920

By Frank A. Peters

This Bureau of Mines report is the second of a series of process evaluations planned to determine the relative processing costs of producing metallurgical-grade alumina from low-grade aluminous materials. Included in these evaluations are recommendations for additional research and development to improve the processes and to lower their costs. The design for each process is based on published work. The processes considered in this report are designed to extract alumina as aluminum chloride from calcined clay with 20 percent hydrochloric acid and to remove the silica residue by filtration. Iron is removed by one of the following processes: Isopropyl ether extraction, in which iron chloride is extracted before decomposing the aluminum chloride; gas precipitation, in which the aluminum chloride is precipitated with hydrogen chloride while leaving the iron chloride in solution; gas precipitation-isopropyl ether extraction, in which the aluminum chloride from precipitation is extracted with isopropyl ether, if necessary; caustic purification, in which a crude alumina is produced and then purified by a modified Bayer operation; or sinter purification, in which a crude alumina is produced and then purified by a lime-soda sinter operation. For plants producing 1,000 tons of alumina a day the estimated operating costs per ton of alumina are: [Isopropyl ether extraction process $ 65.09 Gas precipitation process 89.04 Gas precipitation-isopropyl ether extraction process 119.65 Caustic purification process 73.79 Sinter purification process 80.47] The estimated fixed capital costs per annual ton for these plants on a Marshall and Stevens chemical equipment basis of 240.0 are: [Isopropyl ether extraction process $229.03 Gas precipitation process 287.16 Gas precipitation-isopropyl ether extraction process 356.59 Caustic purification process 266.48 Sinter purification process 279.13]

Jan 1, 1962

By David J. Kusler

This report describes a rapid, reliable, and relatively simple method developed by the Bureau of Mines Pyrometallurgy Laboratory at Bruceton, Pa., for determining lime (calcium oxide) and magnesia (magnesium oxide) in various materials containing these constituents in greater than trace amounts. Optionally, titania (titanium dioxide) may be determined for the same sample. The accuracy of the method, suitable for most purposes, is shown by comparing the Bureau results with those obtained by accepted procedures. The method has been applied satisfactorily to the routine analysis of blast-furnace slags, for which purpose it was primarily developed, and to other calcareous compositions. In the Pyrometallurgy Laboratory it has replaced the standard methods previously used to determine lime and magnesia, and has been in general use by that laboratory for the past several years. The analysis time, generally under 3 hours, is considerably less than required by standard methods.

Jan 1, 1960

By Jerry A. Wichser

A series of linear programmed instruction modules was developed in the general subject areas of Blasting Technology & Explosives Safety & Electrical Training. The linear programs (modules) were developed in the form of tape-slide plus workbook materials, while the branching format evolved from the LTS teaching machine system from MIT, through several other teaching machines and micro-computers, finally settling on Radio Shack TRS-80 microcomputers, Models I & III. Initial validation figures indicate that essentially the same result, are attained from both methods (based on pre and post test scores), with the most noticeable difference being an approximately 25% savings in study time with the branching modules. In December 1980, the development of modules on High-Voltage Training, Trolley Wireman Training, and Compressed Gas Safety was added to the overall tasks of the contract.

Jan 1, 1984

By William E. Bruce

The Bureau of Mines performed drill calibration tests on two industrial percussive drills of 2-5/8- and 3-1/2-inch piston diameters to determine operating characteristics for their use in conjunction with penetration rate data in developing drillability equations and furthering the knowledge of percussive drills. The use of a linear velocity transducer for measuring piston velocities and application of its instrumentation are described. Data presented include relationships between maximum piston velocity and feed air pressure other results confirm the theory or data of previous investigators, and some comparisons are made with the performance prediction formulas of other investigators.

Jan 1, 1969

By James J. Jessop, Richard E. Thill, Michael J. Friedel

As part of an investigation aimed at improving the health and safety and competitiveness of the mining industry, the U.S. Bureau of Mines evaluated the application of common offset radar profiling, using a 250-MHz ground-penetrating radar (GPR) system, for the detection of fractures in igneous rock. A series of radar reflection surveys were conducted to detect and delineate the extent of fracturing at various granodiorite and gabbro quarries and outcrops located in Minnesota. The application of radar profiling for detecting joints, sheeting fractures, shear zones, and depth to water table was demonstrated to be feasible with minimal processing. Radar reflection interpretations were verified by visual inspection of the rock mass and field mapping of local structure. The radar reflection section provides a simple, rapid, and cost-effective means for mapping of shallow (less than 10 m) small-scale fractures (greater than 0.25 cm) in igneous rock masses (characteristic of velocities between 0.061 m/ns for gabbro and 0.125 m/ns for granodiorite). Depth or distance estimates to fractures are within 10 pct of the actual, and time-shift compensation is necessary only when topographic irregularities exceed 30 cm.

Jan 1, 1992

A revolutionary development in blasting materials has occurred in recent years. Ammonium nitrate, sensitized by the addition of a small percentage of No. (class) 2 diesel fuel or other suitable petroleum product, has been adopted as a low-cost, efficient blasting agent2 in a wide variety of mining, quarrying, and heavy construction operations. Moreover, the ready availability of the component supplies throughout the Nation, together with the ease of formulating them into effective blasting agents, has made it possible for the blaster himself to prepare the mixes at the site of use. Recently, most established explosives manufacturers have begun supplying premixed AN-FO (ammonium nitrate-fuel oil) or a comparable product to various mining operations. However, many individuals and small business establishments are marketing premixed products prepared in facilities that are often poorly constructed and poorly located. Although these blasting agents have partly or wholly displaced explosives such as dynamites in many applications, there are some blasting operations in which the fuel-sensitized ammonium nitrate agents do not appear to be well adapted. As long as the hazards they present are clearly understood and respected, ammonium nitrate-based blasting agents have important safety characteristics when prepared under competent factory control or field-mixed under equivalent close control. This publication attempts to summarize the knowledge of those hazards and to incorporate practical ways to cope with them.

Jan 1, 1963