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By Maria I. De Rosa

The major fire and fire injury findings for all coal mining categories for 1990-1999 are reported in tables 37-38. Table 39 and figure 13 show the number of fires. fire injuries, risk rates, employees' working hours, and coal production (under- ground and surface coal mines only) by time period for all coal mining categories. Table 40 shows major findings (for under- ground coal mines only) for 1978-1992. For all coal mining categories, 458 fires occurred during 1990- 1999; 157 of those fires caused 164 injuries and 2 fatalities (Ewhr = 2,070 x l0%r, Irr = 0.016: C'P (for underground and surface coal mimes only) - 10,363 x l0\t, Frr = 0.044, LWD = 14,753). Twenty-nine fires and 17 injuries involved contractors. Sixty-six fires required firefighting interventions by mine rescue teams (25 times in underground mines) and fire brigades and fire departments (at least 41 times at surface coal operations). In all, 51 fires destroyed or heavily damaged equipment (including 16 pieces of mobile equipment) because of failure of other firefighting methods, late fire detection, undetected fires, or fire size. A total of 114 fires were detected late, and 42 fires were undetected. The greatest number of fires and fire injuries occurred at surface coal mines; the highest risk rate values were also calculated for this category. For all coal operations, the ignition sources that caused the greatest number of fires were flame cutting/welding spark/slag/flames (1 03 fires or 23% with 69 injuries), hydraulic fluid/fuel sprayed onto equipment hot surfaces (98 fires or 2 1 % with 29 injuries), spontaneous combustion/hot coal (62 fires or 14%), electrical short/arcing (49 fires or 11% with 18 injuries), and conveyor belt friction (3 1 fires or 7% with 6 injuries).

Jan 1, 2004

By R. L. Schmidt

Research conducted over the past 20 years in France, Great Britain, and the United States on the use of the large-hole burn cut has established cer¬tain advantages for this system. Advantages include longer pull and more complete fragmentation from blast rounds. However, research is needed to establish a set of parameters for optimum performance. As part of the Bureau of Mines Advancing Mining Technology for Marginal Resources program, the Twin Cities Mining Research Center, Twin Cities, Minn., acquired a horizontal rotary drill capable of boring holes up to 24 in. in diameter. This was used for a series of underground experiments at White Pine mine, White Pine, Mich., during 1973. Exceptional results were obtained with a 12-1/4-in void hole that yielded up to 18 ft of pull in a 10- by 20-ft drift, Fragmentation was excellent, and the compactness of the muck pile facilitated loading.

Jan 1, 1975

By Lloyd A. Morley, Robert Stefanko

This report has presented a literature review of explosion proof¬ing of coal mine electrical equipment. The international "state-of¬the-art" is an extremely difficult definition to quantify but, from the preceding paragraphs, it is evident the international community be¬lieves that it is represented by the International Electrotechnical Commission's Publications. Five questions were set forth during the beginning of this report. Each will be evaluated in light of the preceding discussion. 1. Can Schedule 2G specifications on explosion-proof containers be substantiated? Literature was found in the three main problem areas, surface temperature, mechanical strength, and explosion transmission, to determine this. Surface temperature requirements are adequate except for equipment that can normally overload, and the required intern¬al pressure does afford some margin of safety. However, in terms of safety, gap dimensions are about ten times smaller than that needed. 2. Is it possible to replace the Schedule's design requirements with performance specifications? Two primary areas were determined as mechanical strength and explosion transmission. As was mentioned, for present flange and gap standards, the 150 psig requirement is adequate. Furthermore, it is the authors' opinion that the level cannot be re¬duced if the present gap requirements are retained. The Schedule now requires that 16 tests be run, but the literature suggests that only from three to six examinations are necessary. Then by using the abso¬lute maximum pressure from these measurements or 150 psig, whichever is

Jan 1, 1974

By Larry J. Nicks

The Bureau of Mines is investigating the catalytic activity of rare-earth compounds to develop a catalyst for the cathode reaction of a hydrogen-oxygen fuel cell. This report presents the results of studies of the catalytic activities of lanthanide oxides for the oxidation of hydrogen at 150° to 250° C. Preliminary activity tests were made with approximately stoichiometric mixtures of hydrogen and oxygen diluted with helium. A series of tests was also run under oxygen-rich conditions in which specific rate constants and activation energies were determined. Variations in rate constants up to 2,000 times were observed for the various lanthanide oxides. The three most active catalysts were oxides of Ce, Pr, and Eu, having specific activities of 6.93 X 10-7, 4.88 X 10-7, and 4.06 X 10-7 moles H2.sec-1.m-2, respectively, at 200° C.

Jan 1, 1973

By F. P. Haver

A procedure is described for recovering both lead and sulfur from galena flotation concentrate, comprising the following steps: (1) Aqueous oxidation of the concentrate, using ferric sulfate to convert lead sulfide to sulfate and to give elemental sulfur; (2) regeneration of the ferric sulfate by electrolysis in a diaphragm cell; (3) treatment of the leach residue with ammonium carbonate solution to change the lead to an acid-soluble form and to produce ammonium sulfate as a byproduct; (4) solution of the lead carbonate in hydro-fluosilicic acid followed by electrolysis to recover the lead as metal and regenerate the acid; and (5) extraction of the elemental sulfur from the final residue with an organic solvent. About 90 percent of the lead can be recovered by the above method as 99.9-percent-pure metal, together with two-thirds of the sulfur--half in the elemental form and half as ammonium sulfate.

Jan 1, 1970

By Laurance L. Oden

The Bureau of Mines studied three processes for preparing NaAl(OH)2C03) the intermediate compound which is calcined to produce alkalized alumina: (1) Mixing of Na2 C03 and of A12 (S04)3 solutions, (2) digestion of aluminum hydroxide in solutions of Na2C03 and NaHC03 at 90° C, and (3) addition of CO2 at 25° C to caustic solutions of aluminum to precipitate aluminum hydroxide followed by digestion at 90° C. The first process had the highest raw material consumption and washing requirements, and successful application of process 2 depended upon the availability of active aluminum hydroxide. Process 3 was the most effective, considering both process technology and raw material requirements. Procedures were also investigated for washing, filtering, drying, and calcining precipitates. Analytical methods included X-ray diffraction, atomic absorption spectroscopy, differential thermal analysis, and thermogravimetric analysis.

Jan 1, 1969

This chapter defines light as a type of energy, and tells how different features of light are measured. It 1s important to understand the units of light measurement because they are used throughout the rest of the book. But more Important, this will help you to understand the "regs" and how to get the best out of the lighting you have available! By the time you complete this chapter, you should know what candle-power, foot-candle, and foot-lambert refer to, and you will also be able to tell why the helmet that the new miner wears appears orange to human eyes. Light that you "see" is really radiant energy that hits the retina of the eye. Radiant energy moves out from a light source much like a series of bullets from a number of machine guns being fired at the same time in all directions.

Jan 1, 1976

By Verne S. Mutton, William A. Slivensky, Eric S. Weiss, Kenneth L. Cashdollar, Deepak R. Kohli

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory, cooperated with Tecrete Industries Pty. Ltd. and BHP Australia Coal in a research program to evaluate the strength characteristics and air leakage of four seal and two stopping designs for use in underground coal mines. A fundamental safety research area for NIOSH is to eliminate the occurrence of coal mine explosions or to mitigate their effects. One approach to achieve this goal is to develop new and innovative seal designs that provide increased explosion isolation protection for the mining personnel against ignitions that originate from within the gob or. other worked-out areas of the mine Full-scale seals and stoppings were constructed in the Experimental Mine at Lake Lynn Laboratory near Fairchance, Fayette County, PA. They were ail--leakage tested, then subjected to a series of explosions with average pressure pulses ranging from 25 to 500 kPa (3.5 to 72 psi). Instrumentation measured seal displacement and acceleration as a function of time, providing data to assist in the development of numerical models 1'01- future seal design. All three seals designed with Meshblock wire forlnwo~-k ant1 a lnonolithic shotcrete core withstood the first explosion test, which generated an avcr-age rnaximu~n pressure of - 140 kPa (-20 psi) while maintaining acceptable air leakage rates. These seals I-anged from 175 to 325 mm thick. They included a 2.7-m-high by 325-mm-thick seal that was tesled 27 hr after completion against this - 140-kPa explosion pressure, a special requirement of the test program. This seal survived explosions with pressure pulses up to 300 kPa (43 psi). The 2.3-m-high by 325-mm-thick Meshblock seal survived three explosion tests with overpressures up to 455 kPa (66 psi) and satisfied the air leakage criteria. A I ,200-mm-thick plug seal was constructed of two Gunmesh formwork walls in-filled with shotcrete and a 3,450-kPa (500-psi) strength Aquablend core. This plug seal survived three explosions with pressure pulses ranging 11-om 150 lo 430 kPa (-22 to 62.5 psi) with no measurable postexplosion air leakage. Two Gunmesh stoppings with thicknesses 01' 40 and 75 inln withstood explosion overpressures of 23 and 115 kPa, respectively. Anchoring all seal and stopping designs into the roof, ribs, and floor with steel "rootbolts" provided very effective boundary constraint that is critical to the performanceofstructures subject to explosion overpressures.

Jan 8, 1999

By W. H. Ode, F. H. Gibson, W. A. Selvig

The great expansion of production of aluminum for war purposes has aroused some concern regarding the available supply of carbon suitable for making carbon electrodes required in the electrolytic aluminum process. Approximately three-quarters of a pound of carbon electrode is consumed for each pound of aluminum produced. 5 Because of its small amount of impurities and its suitable physical characteristics, calcined petroleum coke is the standard material used by the aluminum industry for making electrodes As it may be necessary to use some substitute materials, the possibility of using coke made from coal has been considered. Besides this possible use, information concerning the source of low-ash coals is of general interest. Specifications of the aluminum industry for calcined petroleum coke suitable for the manufacture of electrodes are very stringent in regard to allowable impurities. In one such specification the maximum allowable ash is 1.0 percent; the maximum allowable content of iron (as Fe) is 0.06 percent and that of silicon (as Si) is 0.08 percent; the maximum for cal- cium (as Ca) and for sodium (as Na) is 0.12 percent for each, but the two combined may not exceed 0.12 percent; maximum allowable sulfur is 2.0 per- cent. The presence of barium, nickel, chromium, manganese, cobalt, or vanadium is objectionable, and only extremely small amounts are allowed. In regard to physical properties, the coke is required to be so thoroughly calcined that it has a real density of at least 2.02.

Nov 1, 1943

By Nicholas Kyriazi

It is of interest to know how to obtain as high an absorption efficiency as possible from a CO2-absorption canister used in closed-circuit breathing apparatus. In this study the Bureau of Mines found that varying the bed depth and the cross-sectional area of a canister changes its absorption characteristics. In tests using four ,1 rectangular, variable-depth canisters with different cross-sectional areas, the Bureau found that, given a constant weight of the chemical absorbent, LiOH, and a constant COa input, the canisters with a greater cross-sectional area reached C02 levels of 0.5 volume-percent in the effluent gas sooner than did the canisters with a greater bed depth. However, resistance to flow through the canister increases with bed depth, and a trade-off is inevitable. It was anticipated that the efficiency of a canister would increase with increasing intergranular air space approaching the tidal volume of the breathing waveform and then level off at some point under 100 percent. This postulation was partially substantiated. Cylindrical and radial canisters were also tested and compared. It appears that shape is not as important a factor in absorption efficiency as bed depth, since neither canister differed significantly from the rectangular canisters with regard to absorption efficiency values.

Jan 1, 1980

By Kenneth E. Hjelmstad

The U.S. Bureau of Mines (USBM) has developed an electromagnetic (EM) fire warning alarm sys-tem for underground mines. The system generates a magnetic field for through-the-earth signal trans-mission to microreceivers carried by individual miners. EM fields can induce electric currents in metallic conductors; if an EM transmitting antenna and an electric blasting cap array are too close, the field could induce a current in the blasting array and cause an unintentional initiation of the electric detonators. The USBM conducted tests that define the safe and unsafe regions for using electric detonators near the transmitting antenna of the warning alarm system. The minimum safe distance between a transmitting antenna and a blasting array is the distance where the induced electrical current in the blasting array is 50 mA, which is the safe current level specified in Federal mine safety regulations. Tests indicate that at transmitting power levels of 100-and 1,000-W, separation distances of 9 and 21 m, respectively, were required. These distances are small compared with the dimensions of a mine. Thus, the tests indicate that, with proper placement of the transmitting antenna, the warning system can be used safely in the proximity of blasting arrays.

Jan 1, 2010

By M. C. Irani

The Bureau of Mines has designed and put into operation a fail-safe control system for use in underground coal mines equipped with methane drainage pipelines. This control system can detect certain unsafe conditions and respond by automatically shutting off the flow of methane from the degasification borehole to the drainage pipeline. Methane flow is shut off when the methane content in the return airways reaches a predetermined level (typically 1.5 pct), when the methane drainage pipeline is ruptured by roof fall, or when there is an electric power failure. The fail-safe control system was designed using commercially available components and a methane analyzer system previously developed by the Bureau. The fail-safe system consists of a unit that combines a shutoff valve and pneumatic valve actuator, and electronic and mechanical equipment designed to detect hazards and effect shutdown. The fail-safe control system was designed to meet regulatory requirements issued by the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, and State regulatory bodies for the safe operation of underground methane pipelines used for mine degasification. MSHA has inspected and tested this system and permitted its use in two mines. The Bureau installed the fail-safe system in two working coal mines, where successful performance has been demonstrated.

Jan 1, 1979

By P. W. Jeran, S. J. Pepperney, M. C. Irani, F. F. Kopsch

The Bureau of Mines has designed and put into operation a fail-safe control system for use in underground coal mines equipped with methane drainage pipelines. This control system can detect certain unsafe conditions and respond by automatically shutting off the flow of methane from the degasification borehole to the drainage pipeline. Methane flow is shut off when the methane content in the return airways reaches a predetermined level (typically 1.5 pct), when the methane drainage pipeline is ruptured by roof fall, or when there is an electric power failure. The fail-safe control system was designed using commercially available components and a methane analyzer system previously developed by the Bureau. The fail-safe system consists of a unit that combines a shutoff valve and pneumatic valve actuator, and electronic and mechanical equipment designed to detect hazards and effect shutdown. The fail-safe control system was designed to meet regulatory requirements issued by the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, and State regulatory bodies for the safe operation of underground methane pipelines used for mine degasification. MSHA has inspected and tested this system and permitted its use in two mines. The Bureau installed the fail-safe system in two working coal mines, where successful performance has been demonstrated.

Jan 1, 1980

By F. W. Benn

The Bureau of Mines investigated flotation methods for recovering fluorite and byproducts from two samples of the Fish Creek deposit in Eureka County, NV. The preferred method for tre.ating a fluorite-beryllium sample included (1) fluorite rougher and cleaner flotation, (2) desliming at 20 um, (3) muscovite flotation, (4) silicate flotation, (5) sodium hypochlorite wash of silicate concentrate, and (6) beryllium rougher and cleaner flotation from the silicate concen-trate. Laboratory results showed that over 94 pct of the fluorite was recovered in a recleaner concentrate containing 98 pct CaF2, Beryllium flotation produced concentrates containing in excess of 5 pct BeO with recoveries over 70 pet. The preferred method used for a fluorite-mica sample consisted of (1) fluorite rougher and cleaner flotation, (2) desliming at 20 um, and (3) mica flotation using an anionic-cationic collector system. Laboratory results showed that 84 pct of the fluorite was recovered in a recleaner concentrate containing 96 pct CaF2, Mica flotation produced a concentrate containing 95 pct mica at 85-pct recovery.

Jan 1, 1986

By K. J. Liles

To encourage the development and conservation of the Nation's ceramic raw materials, the Bureau of Mines, U.S. Department of the Interior, under an agreement with the Georgia Department of Natural Resources, evaluated samples from a clay resource located in Clay County, Ga., for use as a raw material for lightweight aggregate. The physical properties of clay samples, taken from 5-foot increments of drill cores from 11 holes, were determined. Raw materials were plasticized and extruded to produce 1/2-inch by 1-inch pieces and fired in a rotary kiln to produce lightweight aggregate samples. The resulting expanded material had excellent loose pour weights ranging from 30 to 37 lb/cu ft. The expanded test materials were crushed, sized, and used as aggregate to form concrete cylinders. The unit weight and compressive strength of the cylinders averaged 106 lb/cu ft and 3,350 lb/sq in, respectively; these values meet American Society for Testing and Materials specifications for structural concrete. The clay from the drill cores was also used to make test bars that were evaluated for building brick.

Jan 1, 1980

By D. Z. Hobbs

Because an economic method for preparing pure boron has not been developed, a program was started by the Bureau of Mines to evaluate existing techniques or to develop new methods for preparing the pure element. This report describes investigations directed toward the development of techniques for the preparation of pure boron by fused-salt electrolysis. Only two of the several fused-salt baths tested were satisfactory for the preparation of boron. These baths contained (1) potassium fluoride, lithium fluoride, potassium fluoborate and boron trioxide; and (2) potassium fluoride, potassium chloride, and boron trioxide. Of these two mixtures, the latter was more satisfactory. Elemental boron of from 90- to 95-percent purity and, in isolated cases, as high as 98-percent purity, was prepared from these two types of fused-salt baths. There appeared to be no distinct differences either in the yields or the purity of boron prepared at current densities ranging from 795 to 1,000 amperes per square foot. Current efficiencies were as high as 85 percent.

Jan 1, 1961

Develop a portable emissions measurement apparatus to sample and measure tailpipe concentrations of diesel particulate matter (DPM), carbon monoxide (CO), carbon dioxide (CO2), nitric oxide (NO), and nitrogen dioxide (NO2) under steady-state engine load and speed conditions during a 1-minute test.

Jan 1, 1994

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of the Ohio coalfield. Washability analyses were made on 39 coalbed samples collected from a 14-county area. None of the samples were of metallurgical quality as received. Nine of the samples could be sufficiently upgraded to produce metallurgical-grade products, and the remaining 30 samples could not be upgraded to this quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, 10 of the samples were of medium sulfur content as received and one could be upgraded to a low sulfur content. Of the 29 samples having a high sulfur content as received, 18 could be upgraded to a medium sulfur content. The original sulfur content of the other 11 samples having a high sulfur content as received can be appreciably reduced by removal of the sink 1.58 specific gravity material; however, these coals would be classified as high sulfur coals both before and after removal of the sink 1.58 specific gravity material.

Jan 1, 1972

By Steven J. Page

The increasing concern for dust control in metal and nonmetal mining prompted the Bureau of Mines to investigate the comparative effectiveness of three wet dust control techniques for face drilling. Previous attempts to achieve effective dust control on face drills with dry collectors have not met with success, the largest problem being sustained effective dust capture at the face. Results show that (1) foam-through-the-drill can provide 95-pct average total dust reduction in gypsum; (2) water mist-through-the-drill can provide approximately 91-pct average total dust reduction and 93-pet average respirable dust reduction in salt; (3) external boom-mounted water sprays can provide approximately 50-pet average dust reduction for both total and respirable dust in salt. The investigation showed that (1) foam and water in small quantities are very effective dust control techniques for face drills when applied through the drill steel at the point of dust generation, and (2) boom-mounted water sprays are only minimally effective for dust control on face drills.

Jan 1, 1981

By G. A. Brady

Seven samples of Pennsylvania anthracite from the Bottom Ross bed were analyzed and tested to obtain data on cleaning characteristics, proximate and ultimate analyses, specific gravity, grindability, heating value, and ash softening temperature. Ash content of the samples varied irregularly from 9.0 to 34.4 percent, the range being narrowed to an upper limit of 14.8 percent ash by removing impurities dense enough to sink in a medium with a specific gravity of 1.90. Ash content of the sink material with specific gravity greater than 1.90 ranged from 56.4 to 80.4 percent; corresponding specific gravities were 2.095 to 2.534. Volatile matter contents were indicated to be higher for the ash-forming minerals than for the pure coal substance in the various specific gravity fractions of a given sample. Specific gravities of anthracites with compa¬rable ash contents but from different locations in the bed varied as much as 0.06. The grindability index increased significantly with increasing ash con¬tent of specific gravity fractions from all the samples.

Jan 1, 1968