Search Documents

VERSLAG- REPORT No. 1365 STUDIES OF INCIPIENT FUSION IN THE SYSTEM CHROMITE- MgO- Al2O3-SiO2-C 5th January, 1972 Investigator: N. A. Barcza SYNOPSIS A fundamental study was made of twelve chromite ores by use of a thermobalance under atmospheric and reducing conditions. It was found that their thermal behaviour under atmospheric conditions can be related to the mineralogical composition of the chromite spinel and the gangue. The overall mechanism of reduction with solid carbon over the temperature range of 1 200 to 1 500°C was shown to be diffusion of carbon through the reaction product. The effects of additions of fluxes and variations in particle size on the kinetics and mechanism of reduction were determined. It was shown that carbon monoxide does not reduce chromite ore up to temperatures of 1 550 °C, and it can therefore be eliminated as the diffusing reducing species. However, the reaction product of reduction, namely a mixed carbide of iron and chromium, was shown to be an effective reducing agent for chromitc ore, while also facilitating the transport of carbon. VERSLAG - REPORT No. 1380 AN ELECTROCHEMICAL MODEL FOR THE LEACHING OF URANIUM DIOXIDE 10th January, 1972 Investigators: C. R. S. Needes, M. J. Nicol SYNOPSIS A correlation between the rate of leaching of UO2 and the electrochemical properties of the oxidant concerned has been derived. This correlation is found to be borne out by experimental results. Certain effects observed in UO2 leaching and hitherto unexplained have been clarified in terms of an electrochemical mechanism. Experiments have shown that the mixed potential of a UO2 electrode gives a measure of the rate of dissolution of UO2. Its significance to commercial practice is discussed. CONCLUSIONS (I) The dissolution of UO2 in the presence of a number of oxidants can be explained in terms of an electrochemical mechanism. (2) The mixed potential of the UO2 electrode is a measure of the rate of UO2 leaching. This principle could be used in the control of industrial leaching operations. (3) A simple treatment has provided a mathematical basis for a fundamental correlation between the rate of U02 dissolution and the chemical properties of the oxidants concerned. This relation has been found to agree well with experimental results. (4) A number of phenomena occurring during the leaching of UO2, hitherto not explained in a satisfactory manner, have now been clarified in terms of an electrochemical mechanism.

1. Book review . Australasian coal mining practice, edited by C.H. Martin. Reviewer: R.B. MacGilIivray This book is an extremely comprehensive coverage of coal-mining practice in Australasia, the countries covered being Australia, New Zealand,and Papua New Guinea. 2. From The Institute of Metals The folowing are available from The Institute of Metals, 1 Carlton House Terace, London SWl Y 5DB. Physical and elastic characterisation, edited by M. McLean. 1989. 228 pp. £25.00. High nitrogen steels, edited by J. Foct and A. Hendry. 1989. 461 pp. £49.50. Proceedings of the First International Calcium Treatment Symposium. 1988. 116 pp. £15. New cored-wire injection techniques, particularly as Design for recyc/ability, by Michael E. Henstock. 1988. 150 pp. £15. Solidification processing. 1988. 549 pp. £45. Marine engineering with copper-nickel. 1988. 103 pp. £18. Characterisation of High Temperature Materials. 3. New journal FMJ International Publications Lid have announced a new quarterly publication, Aluminium Today. 4. Other new publications Algorithms in real algebraic geometry, edited by Denis S. Arnon and Bruno Buchberger. London, Academic Press, 1988. 274 pp. £15.95. Proceedings, Foundry and Heat Treatment 88. R150 per set of 5 volumes, or R40 per volume.

Jan 1, 1989

By C. Yu, N. Topliffe, H. Song, W. Yu

The water separation pump is a highly effective alternative for medium pressure (1.6?6.4 MPa) slurry pumping requirements and has been widely used in industry since it was invented in the 1980s. The water separation pump is powered by a single or multi-stage clean water centrifugal pump. The water separation pump combines the advantage of high flow centrifugal pumps with the high pressure capability of reciprocating pumps. The clean water pressure is exchanged to slurry kinetic energy through the separating chamber, the principle component of the water diaphragm pump. Currently in its the third generation, the separation chamber uses a ball and flexible water seat that provides a true separation mechanism and can completely isolate the two fluids with near zero water loss.

Jan 1, 2007

By J. Bai, C. Zang, W. Yuan, L. Zhuang

"This study evaluates the efficiency of using mechanochemical reduction to assist the extraction of zinc from zinc ferrites by alkaline leaching. The transition of zinc ferrite into a metastable state after mechanochemical reduction with metallic iron contributes to the ready dissolution of zinc from the activated zinc ferrites in alkaline solution. Zinc ferrites were mechanochemically reduced under conditions of Fe:ZnFe2O4 mole ratio of 2:1, using 5 mm diameter stainless steel balls as the activation medium at a mass ratio of balls to raw materials of 25:1. Subsequent leaching in 6 mol/L NaOH solution at 90°C resulted in more than 70% Zn extraction. These results may be used to further develop a hydrometallurgical process for recovering zinc from zinc ferrites in alkaline solution.IntroductionZinc is an important nonferrous metal required for various applications in batteries, solder, dielectric materials, and piezoelectric materials. High-grade, easily concentrated ores are becoming scarcer: to meet world demands for zinc, it is necessary to develop economical and environmentally safe metallurgical technologies that use secondary materials such as leach residues of roasted zinc concentrates and electric arc furnace dusts. The zinc in the majority of these wastes occurs in the form of zinc ferrite (franklinite, ZnFe2O4), which is very stable and insoluble in most acidic and alkaline solutions (Langova and Matysek, 2009; Youcai and Stanforth, 2000).Several pyrometallurgical and hydrometallurgical processes (Jankovi et al., 2014; Langova and Matysek, 2010; Morcali et al., 2012; Shawabkeh, 2010) have been proposed for the treatment of zinc ferrites. Pyrometallurgical methods are costly owing to high energy consumption and their emissions of toxic gases are considered an environmental problem; hydrometallurgical methods are preferred for process economy and environmental reasons (Copur et al., 2004)."

Jan 1, 2016

By L. H. W. Walker

As part of an overall design of a computer based mining managerial system, the geological and mineral estates management disciplines find themselves centrally placed in terms of producing fundamental data both before and during the mining operation. Computerisation of all aspects of these fields of endeavour has come to be seen as essential for complete integration with other mining orientated disciplines. Release 1 .l. of the Anglo American system of mineral estates management has been tested and is in the process of being implemented at several Anglo American Gold Division mines.

Jan 1, 1987

By M. J. Southwood

SYNOPSIS Experiments carried out under atmospheric pressure and temperature (25°C) and sterile conditions show that the dissolution rate of nickel and copper from a pyrrhotite-pentlandite-chalcopyrite ore in a lixiviant of sulphuric acid is greatly enhanced in the presence of pyrite. At a pH value of 1,8 and in the presence of pyrite of equal mass to that of the ore, the recoveries of nickel and copper improved dramatically (21 and 80 per cent respectively). At a pH value of 4,0 the recovery of nickel was enhanced, but the chalcopyrite was refractory. A galvanic mechanism is probable, but cannot be proved from these experiments. The economic implications of the results are discussed.

Jan 1, 1985

1. Books on management The following are available from Knowledge Resources, P.O. Box 3954, Randburg 2125. . Competitive advantage of nations, by Professor Michael Porter from Harvard Business School. This book highlights the importance of industries in contributing towards national competitiveness. It is being regarded as one of the 10 best business books published during 1990. . The borderless world, by Kenichi Ohmae, Managing Director of McKinsey in Japan. This deals with business in the new interlinked economy. . Megatrends 2000, by John Naisbitt and Patricia Aburdene. This book outlines the mega/macro trends that will

Jan 1, 1991

By Y. Zhen, N. Topliffe, G. Shou

The typical service life for a long distance slurry pipeline is15 to 25 years. Determination of wear rate for a pipeline could have a high economic impact on the pipeline project. Wear is a combination of chemical corrosion and mechanical abrasion. The contribution of each factor has to be determined project by project. Normally, chemical corrosion dominates the pipe wear in fine slurry pipelines. These pipelines have been designed with a velocity between 1.5 m/s and 2.5 m/s. Solids are suspended with high homogeneity across the pipeline section. Bottom wear is not much greater than the top wear and not sensitive to velocity. The wear pattern in the pipeline transporting medium coarse solids, such as milled ore and tailings, is different. Wear concentrates on the bottom of pipeline and the outer bends, and is more sensitive to flow velocity. Wear distribution along the pipelines is similar.

Jan 1, 2007

By J. M. Eriksen, T. Rosenqvist, H. Elstad, S. Seim, A. Hildal

The titanium industry demands high titanium feedstock for their processes. As rutile resources are limited, ilmenite has become the most important titanium source. Ilmenite smelting is an important part of upgrading ilmenite to high titanium feedstock. In the year 2005, upgrading of ilmenite by smelting, producing a slag with 80-90% Ti02, accounted for approximately 40% of the feedstock to the Ti02 pigment industry. In ilmenite smelting molten iron is produced together with a slag, which in addition to titanium oxide contains iron oxide as well as various impurity oxides of manganese, magnesium, silicon, aluminium, etc. Titanium is present mainly as Ti02 but partly also as Ti203. It is known that the concentration of Ti203 increases with decreasing concentration of FeO, but this dependency is affected by the nature of the impurity oxides. Sigurdson and Moore1 showed that slags high in CaO and MgO had a lower concentration of Ti203 than slags high in Si02 for the same amount of FeO. Pistorius2 showed in 2002 that if the impurity oxides MnO and MgO are counted, on a molar basis, as FeO, and Cr203, V203 and part of the A1203*), as Ti203, industrial slags will have a composition close to that of the M305 phase, where M denotes the elements Ti, Fe, Mn, etc, and which has the pseudobrookite structure. However, for equilibrium with liquid metallic iron he computed, by means of a computer program FACT, that the slag equilibrium composition is represented by a curved line in the ternary phase diagram FeTi03-TiO2-Ti2O3, but with a significantly higher concentration of trivalent titanium than actually observed in the industrial slags, and he discussed various mechanisms by which the slag during solidification could change its composition to a lower Ti203 content, but the possibility that the computed compositions might be wrong was not mentioned. Trane113 found in her research on titaniferous silicate slags a lower Ti3+/ Ti4+ ratio than that which is computed by the FACT program. The purpose of the present investigation was to study the equilibrium composition of Fe-Ti-O slag in equilibrium with liquid metallic iron, as well as the effects of impurities such as Si02, CaO and MgO on the slag composition. Industrial slags from TINFOS Titan and Iron KS (TTI) will also be discussed and their compositions will be plotted in the ternary phase diagram. These are slags produced from Tellnes ilmenite, quite high in magnesium and iron. Experimental In the past, equilibrium studies of the Fe-Ti-O slag system were difficult when it came to producing the slag. It was difficult to find a suitable crucible for the meltings. The highly corrosive slag would attack all known refractories, and the metal would attack metallic crucibles such as those made of platinum and molybdenum. In the present investigations the slag-metal combination was prepared in a high-frequency induction furnace with a vertically segmented water-cooled copper crucible. The crucible is shown in Figures 1 a and 1b. It was designed by the Australian Nuclear Science and Technology Organisation (ANSTO) with power from a 75 kVA high-frequency generator (750 kHz) supplied by Farfield Electronics Pty, Ltd, Australia. This enabled the slag-metal combination to be melted with turbulent stirring and is expected to be isothermal. The entire temperature gradient

Jan 1, 2007

By P. J. D. Lloyd

The Witwatersrand reefs contain gold, uranium, and pyrite in the following average concentrations: 0,001 per cent, 0,02 per cent, and 1,7 per cent respectively. The paper discusses the flotation of pyrite to produce a s,ulphide concentrate, reviews work done on the production of gold concentrates, discusses attempts to produce maximum concentrates, and closes with a review of processes for the simultaneous flotation of these three species. It is concluded that high recoveries of all three species can be achieved only if a rougher concentrate of perhaps 20 per cent of the feed (by mass) IS produced, and it is suggested that reverse leaching (leaching before cyanidation) of this concentrate, followed by a cleaning flotation step for the recovery of the pyrite, would be more efficient than the routes employed at present.

Jan 1, 1981

By B. M. Wainstein

An extension of lognormal theory and its application to risk analysis models for new mining ventures by B. M. WAINSTEIN*, B.Sc., M.B.A. (Witwatersrand) (Visitor) The lognormal distribution, which remains the most popular distribution model for ore values, is investigated. The T-distribution, an integral part of this theory, is dependent on the sample size, n, and the unknown population parameter, o2, which cannot be integrated out. Hence, o2constitutes a nuisance parameter. In this study, the robustness of the T-distribution to changes in o2 is examined. It is found that the T-distribution is robust for 0,1 <= o2 >= 2,5, a domain covering most practical applications of the lognormal theory. By the use of o2 = 0,7, multiplier factors, which facilitate the computation of the confidence limits, are derived for a comprehensive set of confidence levels.

Jan 4, 1975

This report describes the investigational work on the development of a fire-assay method capable of concentrating, in a button of nickel sulphide, all six of the platinum-group metals present in samples of ores, concentrates, and mattes. In the method adopted, the sample is fused with a mixture of sodium carbonate, sodium tetraborate, nickel carbonate, and sulphur. The nickel sulphide formed during fusion collects the noble metals and carries them to the bottom of the crucible. The nickel sulphide button is dissolved, and the noble metals are isolated and determined. The coefficients of variation range between 1,0 and 4,9 per cent for the various platinum-group metals when they are present in concentrations between 0,3 and 75 p.p.m.

Oct 15, 1971

By C. Norden

The purpose of this article is to show how a representative overall equipment effectiveness (OEE) measurement can be calculated for an underground coal mining bord and pillar batch process. The calculation method, the typical losses (which include planned and unplanned availability losses, coal quality losses, and process rate losses) and the underlying logic are presented and discussed. It is argued that the current traditional underground bord and pillar mining process can currently provide a maximum theoretical OEE of only 49 per cent, while a realistic benchmark target should be in the order of 37 per cent, which relates to an average of 2400 t per shift or 1.2 Mt/a. In addition, it is argued that the current bord and pillar process is the current bottleneck to further improvement past the 2400 t per shift benchmark, and that fundamental process changes will be required to eliminate this bottleneck.

Jan 1, 2012

By J. H. van Dalen, P. J. Brandt, F. W. Wessels

A maximum of ten process streams (Merrill barren solutions) can be monitored sequentially with this on-line analyser, and gold concentrations as Iow as 0,005 mg/I can be determined. The design is a further development of the Tell-tale analyser constructed by the Corner House Laboratories during the period 1965-69. The barren solution is preconcentrated automatically by solvent extraction, the solvent being a solution of I per cent Aliquat 336 in di-isobutyl ketone. An aqueous-to-solvent ratio of 40: I is maintained. The extracted gold in the organic phase is determined by flame atomic absorption, each analysis taking approximately II minutes. The long-term reproducibility of the absorbance readings over a 24-hour period of repetitive sampling of four simulated process streams varied from 6,9 to 4,1 per cent relative standard deviation for gold concentrations of 0,0 I to 0,05 mg/I.

Jan 1, 1980

By K. E. Mantell

1. TRACKLESS MINING AT OAMITES by K. E. MANTELL Oamites Mine, brought into production in late 1971, is located 50 km south of Windhoek, South West Africa, on the northern boundary of and just outside the Rehoboth Gebied. Oamites was known as a possible mining proposition at the turn of the century when Hanseatische Minen Gesellschaft was adit mining on the adjacent farm Kamzwas. Rand Mines Limited carried out a small amount of prospecting in the early 1960s, Falconbridge Explorations Limited later taking over the prospect. Approximately 4600 m of diamond drilling was carried out between 1965 and 1967.

MASSMIN 92 edited by H.W. Glen. Johannesburg, The South African Institute of Mining and Metallurgy, 1992. xiii, 485pp. ill. 30 cm. (SAIMM Symposium Series S12). Includes bibliographies. ISBN 1-874832-18-8. R342 (MemberR285; Student Member R218,88. Available in Australia from the AMF Bookshop, 63 Conyngham Street, Glenside, SA 5065 at $A171.00 (approx). This volume is the twelfth in a series of symposia published by The South African Institute of Mining and Metallurgy since 1962. This particular meeting addressed the subject of the underground mining of massive ore bodies.

Jan 1, 1994

METRICATION In order to bring South Africa into line with metric countries the world over and in view of the indisputable advantages of using the comma as a decimal sign, the Metrication Advisory Board has decided to recommend that the comma be used consistently as decimal sign as from April 1, 1971. Numbers consisting of more than three figures are separated by spaces into groups of three to the left and right of the comma, and not by commas, e.g... 2 734 671,512 73 A quantity such as 12,41 kg is read as "twelve comma four one kilograms" and 31,34 km as "thirty-one comma three four kilometres." A motor-car previously described as a 3.8 litre model now becomes a 3,8 litre model. THE BRITISH COUNCIL AWARDS 1972-1973 The British Council invites applications from permanent residents of all races in the Republic of South Africa and South West Africa, for the following awards:- SCHOLARSHIPS Scholarships are available to such residents who hold University degrees or comparable professional qualifications. The scholarships are tenable for post-graduate study at Universities and other educational establishments in Britain for the academic year of approximately ten months beginning 1st October 1972. All arrangements will be made by the British Council and the scholarships will include tuition fees, a maintenance allowance, approved travel in Britain, return fares to Britain, a books grant and a clothing grant. The closing date for applications is 31st July, 1971. BURSARIES Bursaries are available to such permanent residents who hold University degrees or who, being already established in their professions or trades, hold other qualifications. The bursaries are tenable at British educational in-institutions or other suitable establishments in Britain for a course of training, study or research lasting not less than two months or more than six. The British Council will arrange full programmes and professional contacts, and the bursaries will include a maintenance grant, a books grant, authorised course fees and certain other expenses. The British Council may, at its discretion, bear the cost of single or return fares to Britain. The closing date for application is 31st July, 1971. TRAVEL GRANTS Travel grants each of £300 are available in respect of journeys to Britain undertaken between 1st April, 1972, and 31st March, 1973, and are provided to facilitate visits to British Universities by persons holding staff appointments or graduate research posts at South African Universities. Visits must normally be of at least six months duration though grants are occasionally made for visits lasting for one complete term. Grant holders will make their own arrangements with the universities which they wish to visit and will be responsible for finding their own accommodation. The British Council&apos;s assistance is limited to the contribution towards cost of fares. The closing date for applications is 31st October, 1971. For further particulars and the relevant application forms please write stating the type of award you wish to apply to: THE CULTURAL ATTACHE BRITISH EMBASSY PRETORIA

The following contributions were received to the paper entitled &apos;Safety in South African mines: An analysis of accident statistics&apos;, by H.S. Eisner and J.P. Leger, which appeared in the J. S. Afr. Inst. Min. Metal., vol. 88, no. 1, Jan. 1988, pp. 1-7. Contribution by H. WAGNER* The paper by Dr H.S. Eisner and Mr J.P. Leger is critical of the safety situation on South African mines and portrays the industry as having little concern for the health and safety of its workers. Moreover, the casual reader gains the impression of deliberate misinformation by the industry to the public concerning safety maters. Furthermore, certain socio-economic reasons are advanced for the apparent differences between the fatality and injury rates reported for coal mines in South Africa and those for the United Kingdom. Contribution by S.A. WATTS. Authors Eisner and Leger are to be commended on their paper, which highlights, according to their interpretation, various shortcomings of both the Chamber of Mines accident statistics and those published by the Department of Mineral and Energy Affairs. Authors&apos; Reply We gratefully acknowledge Dr Wagner&apos;s contribution to the discussion on our paper. For convenience, we shal use his sequence of comments in our reply. Before doing so, however, it may be useful to explain how our paper came to be written. After the explosion at Hlobane Colliery in 1983, one of us (HSE), in February 1984, was retained by the lawyers acting for some of the dependants of the victims to advise on technical maters relating to the explosion. Contribution by Ms S.A. Wats Some of the points made by Ms Wats have already been answered in our comments on Dr Wagner&apos;s contribution. We are fully aware that the number of accidents leading to absences of less than 4 days would be much greater than shown in our bar chart, and are grateful to Ms Wats for drawing attention to the specific exceptions that can make a 1-3 day accident compensable and that are clearly responsible for the relatively low count in that category of the chart.

Jan 1, 1988

By K. -I. Higuchi, M. Mizutani, K. Haga, A. Shibayama, A. Batnasan

In recent years, the quality of iron ores has decreased due to the increase in the content of impurities, namely quartz, aluminum, phosphorus, and sulfur. It indicates that the removal of impurities from iron ore is an extremely challenging task. In particular, the high amount of phosphorus in iron ore could be a problem for energy consumption and CO2 emission in the steelmaking process. To reduce the impact of phosphorus, mainly two approaches: the utilisation of low-phosphorus iron ore, or dephosphorisation of high-phosphorus iron ore using mineral processing technology, have been suggested. In this paper, the removal of phosphorus from a low-grade high-phosphorus iron ore containing 0.1 mass% P and 57.5% Fe by alkaline roasting and wet grinding is discussed. The iron ore consists mainly of hematite, goethite, and quartz. Effects of sodium hydroxide concentration used as an alkaline source, roasting temperature, grinding time, and particle size on the dephosphorisation of highphosphorus iron ore were investigated. The dephosphorisation efficiency, iron loss, and mineralogical components of low-grade high-phosphorus iron ore under various experimental conditions were characterised by using XRD, SEM-EDS, and particle size distribution analysis. Results showed that the phosphorus content was lowered from 0.1 mass% to 0.034 mass%, while the iron grade reached 59.8 mass% from 57.5 mass% by alkaline roasting with 0.05 w/w NaOH at 300 °C for 2 h, followed by wet grinding in an attritor with water for 30 seconds at room temperature. Under the experimental conditions, the dephosphorisation rate was about 54.7%, and the solution obtained by wet grinding contained 22.7 mg/L of phosphorus and 21.5 mg/L of iron. The recovery rate of iron by this process reached 99.9%. Keywords: Iron ore, phosphorus, dephosphoriszation, alkaline roasting, wet grinding

Jan 1, 2020

By N. X. Feng, S. G. Zhou, X. L. Wu, J. P. Peng, Y. Z. Di

"Szaibelyite–suanite type ore is rich in magnesium oxide and boron oxide. We propose a new method to extract both metallic magnesium and valuable residues rich in boron by reduction using metallic aluminium.Thermodynamic analysis of the reactions between aluminum and MgO, Mg2B2O5, and Mg3B2O6 was carried out. The effects of CaF2 addition, temperature, mass of Al, and pellet formation pressure on the extraction of magnesium were also investigated experimentally.The results indicate that the magnesium oxide phase can be displaced from 2MgO-B2O3 and 3MgO·B2O3 by CaO in the reduction system. The reduction ratio of magnesium oxide was 38% without calcium fluoride addition, increasing to 94% with 5.1% calcium fluoride. The reduction ratio increased with increasing temperature and mass of Al. To obtain a higher reduction ratio, the reduction pellet should be formed under a reasonable pressure.IntroductionBoron and its compounds are widely used in textiles, borosilicate glass, metallurgy, fertilizers, and nuclear shielding. Boron resources are mainly found in Turkey, the USA, Russia, and China. In Liaoning, China, there are abundant szaibelyite–suanite type ores that are rich in magnesium oxide and boron oxide. Szaibelyite and suanite ores are used to produce borax by a carbon dioxide– soda process. Annually, 2 Mt of waste materials containing 3–20% B2O3 and 2–25% MgO are produced during the process. It is necessary to make use of these waste materials containing high concentrations of boron oxide and magnesium oxide to avoid environmental problems as well as for economic reasons (Ozdemir and K1pcak, 2007)"

Jan 1, 2016