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By C. A. Young, J. L. Bowden

"Cyclic voltammetry experiments were conducted on copper and chalcopyrite (CuFeS2) in the absence and presence of ethyl xanthate, and compared to mass-balanced EH–pH diagrams. The results for copper duplicate those found in the literature and confirm xanthate chemisorption. However, the, results indicate that chalcopyrite oxidizes to chalcocite (Cu2S) and only afterwards is chemisorption observed due to small currents appearing with xanthate. This phenomenon suggests that the mineral's hydrophobicity is induced by more than dixanthogen and copper xanthate. Hydrophobicity was found to be pH-dependent over a range of alkaline conditions (pH 7–11) at narrow potentials (0 to –200 mV). An EH–pH diagram for chalcopyrite with xanthate is presented to illustrate the conditions under which chalcopyrite would be hydrophobic and thereby more thoroughly explain the results in the literature. IntroductionSulphide minerals are generally concentrated from ores by froth flotation, a physiochemical process that induces separation based on differences in hydrophobicity. In this process, a gas is bubbled into a slurry and the minerals that are hydrophobic (water-repelling) adhere to the bubbles and float to the surface while the hydrophilic (water-loving) minerals remain in the slurry. With sulphide minerals, the hydrophobicity is generally established in two ways. The first is by the addition of a collector, which is a heteropolar molecule with a reactive inorganic head group and an inert organic tail. Typically, the head group bonds with the sulphide mineral surface by adsorbtion either chemically (chemisorption) or physically (physisorption) or by complexing with atoms that solubilize somewhat at the surface (surface precipitation). These interactions leave the organic tail protruding from the mineral surface, thereby inducing hydrophobicity. The second method is by oxidation of the mineral surface to form a layer that is metal-deficient/sulphide-rich or comprised of elemental sulphur. Because the layer mimics naturally hydrophobic sulphur, this enables ‘collectorless’ flotation. Furthermore, this oxidation phenomenon adds an electrochemical dimension to the understanding of sulphide mineral flotation."

Jan 1, 2016

By M. F. Handley

This paper covers in situ stresses in the Earth?s crust prior to any man-made disturbances, such as mining. It introduces the Southern African Stress Database, which contains primitive stress measurements obtained from locations spread all over southern Africa. The measured stress data shows large variability without any visible trends, except a relationship with increasing depth. The stress database is reviewed briefly, establishing means to measure the variability or dispersion in the measurements, and showing that the dispersion is not as much a result of experimental error as it is a feature of primitive stress. The paper demonstrates from the beginning that the state of stress in rock is highly variable, but that there are well-defined maximum and minimum limits to all the stress components in rock. Formal error analysis is introduced to check the consistency of the database and to separate out a database of consistent stress measurements for use in a primitive stress model. The aim is to provide a picture of primitive crustal stress based on objective stress measurements together with interpretations of how the primitive stress can be affected by the five main influences; namely, depth, rock mass properties, tectonism, isostacy, and erosion. Four elementary models for primitive stress are introduced and compared with the measured data. It is quite clear that none of the elementary models is sufficient to describe the data. In the absence of a better model, this paper suggests a generic model based on the Hoek-Brown failure criterion and the consistent stress database, since it incorporates the variability in the stress tensor that is likely to be encountered underground all over southern Africa. Rock engineers should take every opportunity to obtain local primitive stress data at every mining operation and civil engineering project, and to adjust the proposed model accordingly Keywords primitive stress, Southern African Stress Database, error analysis, generic primitive stress model.

Jun 1, 2013

By D. J. Hallbom

A new graphical method termed the ?Design Curve Diagram? (DCD) has been developed to analyse non-Newtonian pipe flow data by relating the plastic Karman number to the plastic Reynolds number. Since the plastic Karman number is directly proportional to the pressure loss gradient and the plastic Reynolds number is directly proportional to the velocity, the DCD is essentially a non-dimensional pipe flow curve. This makes the DCD conceptually easier than the commonly used Hedström-Moody diagram. While, the DCD was developed for the analysis of yield plastic fluids (e.g., Bingham plastics), it is equally applicable to Newtonian fluids.

Jan 1, 2007

By H. D. Mtegha

The Southern African Development Community (SADC) aims to harmonize mineral policies and regulatory regimes in the minerals sector. This paper provides a review of the progress made towards harmonization of mineral regimes in the region. It singles out only the mining fiscal environment, as this is normally one of the key issues of interest to potential investors as well as the host state. Indications are that the region is slowly progressing towards a more harmonized approach, and there is evidence that the ?race to the bottom? has been prevented, which is the basis for an integrated mineral sector that the region aspires to.

Jan 1, 2011

By E. H. R. Schümann, H. Wagner

SYNOPSIS The paper gives a detailed overview of the history of subsidence engineering on South African collieries. Surface displacements resulting from total-seam extraction are discussed, and the important role of local geology is highlighted. It is shown that the differences in subsidence behaviour between South African and European collieries can be attributed to the presence of competent strata in the overburden of South African coal seams. Criteria are given for the prediction of the most important subsidence parameters, and a new model for the simulation of surface subsidence above total-extraction panels is introduced. The final section of the paper deals with the damage to surface structures caused by total-seam extraction. A brief summary of the most important undermining experiments on South African collieries is given, and it is concluded that local experiences of damage compare with those in Europe.

Jan 1, 1991

The optimization of sample spacing In South African gold mines by J. M. RENDU*, Eng. Se.D., M.S. (Min.) U.S.A. (Graduate Member) A first attempt is made at optimization of sample spacing in South African gold mines. The De Wijs model, which is shown to give a good representation of the geostatistical properties of gold values, is used to analyse the influence of the distance between samples along a stope face on the error of estimation of the stope value. The influence of other factors such as the face advance before resampling, the sample density, and the stope size, is also considered. Practical conclusions are drawn concerning the optimum sampling policy to be followed in various situations, and it is shown that sampling on a regular grid does not necessarily give the best results.

Jan 4, 1976

By M. U. Ozbay

The stability of pillars is analysed on the assumption that pillars shed load in a stable manner if the slope the strata load-deformation relation is steeper than that of pillars in the post-peak regime. Concepts of local stiffness, mine structural stiffness, and critical stiffness are discussed. Procedures are described for the determination of strata stiffness for various pillar layouts by use of the available boundary-element computer programs. The postpeak stiffness of pillars is assessed from the available data relating to the post-peak load-deformation relationship and width-to-height ratio. Stability analyses are carried out by the contrasting of strata stiffness with post-peak pillar stiffness. It is shown that the strata stiffness becomes unacceptably small for a stable yield-pillar layout when the span exceeds about 5 times the depth. The strata stiffness is found to increase, thereby increasing the stability, as the span-to-depth ratio, number of pillars, and percentage extraction are decreased. It is also found that the stability in a yield pillar becomes difficult to achieve when al the pillars in a layout are in the descending part their post-peak load-deformation curve

Jan 1, 1989

By O. L. Papendorf

For purposes of simplification, a case is presented for an engineer to discount cash flows in real rather than in current terms when giving evidence in a court of law. The difference between the two methods is highlighted, and a recommendation is made in the case where differential rates apply.

Jan 1, 1981

By R. H. O?Connor, B. N. Soutar

The paper reviews the introduction 01mechanical shaft drilling into the sinking 01shafts in the Gold Fields Group. A comparison is made between the operating costs 01the drilling rig and those of conventional hand-held machines, and it is concluded that, despite certain disadvantages, mechanical drilling is preferable.

Jan 1, 1988

By H. W. Read

Sustained growth in demand for platinum group metals has resulted in an unfettered increase in new projects undertaken by the platinum producers. These projects are outsourced to various degrees. The argument of this paper is that both the client?s project manager and the consultant?s project manager are essential elements in the successful execution of a project. Their roles are not only different but also complementary, and are defined in the paper. Data gained from considerable experience in the South African corporate mining environment underpins the opinions expressed in the paper. Furthermore, an extensive literary search was undertaken to determine trends in related industries outside the South African context. Throughout the argument it is emphasized that project philosophy emanates from a systems view and must be treated as an overarching whole. The elements of project management become meaningless unless they are connected to one another and integrated into a cohesive unit. Advancing the knowledge field of project management is of critical importance to mining investors. There is no doubt that a key determinant of the sustainability of mining business is closely related to the efficiency of all-inclusive project management. From pre-investment and feasibility studies, implementation and execution, to ramping-up to full production, scientific project management has a critical role to play. Guidelines for the pursuance of this ideal are proposed. The introduction contextualizes the subject matter in an overview of the evolution of mine management in South Africa and abroad. Then, brief insight is given into the philosophy of project management. This exposition is confined to the predispositions, presuppositions and defining characteristics of project management. The core of the paper looks at the roles of the client?s project manager in relation to the consultant?s project manager. This section is underpinned by practical experience gained by the author on numerous mining projects. A view is taken of the future of project management in the mining industry. The conclusion summarizes the argument and aligns project management trends in the mining industry.

Jan 1, 2004

A dual rate kinetic model consisting of differential equations is used to describe the kinetics of the adsorption of gold cyanide on activated carbon. The partial differential equation describing the material balance in the liquid phase is written for the special case of a fixed bed system. It is shown that an isotherm for the case of a closed system is required to yield accurate simulations of the equilibrium in a column of activated carbon. Whereas the equilibrium loading of gold cyanide is influenced by the free access of oxygen to the system, the traditional open batch stirred tank experiments, which are used to estimate parameters for the calculation of breakthrough curves for organic solutes, cannot be used here. The program solves this model at incremental heights in the column at a specific future point in time. Runge-Kutta and backwards- difference methods are used in the numerical solution. A Von Neumann method is used to show that the solution is stable. Kinetic parameters can be estimated either from batch experiments or from short column runs. In the latter method the column should not be long enough to contain the concentration wavefront for the system of interest. Results obtained from bench scale continuous column experiments were used to verify the computer model. Pure gold solutions as well as real leach liquor were used in both short column and countercurrent moving bed experiments.

Jan 1, 1987

By P. K. Van Manen

Anglo Platinum?s Polokwane Smelter is situated outside Polokwane, in the Limpopo Province in South Africa. A single 168 MVA six-in-line rectangular furnace smelts dry concentrates containing platinum group metals (PGMs). Furnace energy consumption since commissioning is presented, showing that energy efficiency improves as capacity utilization increases. An energy balance for the furnace is outlined, indicating the measured or calculated energy losses from the hearth and side-wall cooling, the copper coolers, the upper furnace walls and roof, and the energy losses in off-gas, matte, and slag. From the energy balance, the potential to improve energy efficiency by controlling the slag temperature, the slag level, and the off-gas volume is derived. Furthermore, the impact on the energy balance of different concentrate types is discussed, as well as the potential impact of replacing all upper waffle coolers by plate cooler panels.

Jan 1, 2009

By O. I. Rychkova, M. N. Sycheva, E. V. Poryadochnova, G. V. Sedelnikova

Deposits of copper-porphyry type occupy a leading position in the mineral resource base of the world copper industry. They are characterized by large and gigantic scales, often complex composition, their development is carried out in an open way. The raw material base of the Russian copper industry is mainly sulfide copper-Nickel and copper-pyrite ores. Exploration of copper-porphyry deposits and the creation of long-term large mining facilities on their basis is one of the most promising and priority tasks for the Russian industry. This task is especially acute for the copper enterprises of the Urals in connection with the depletion of copper - pyrite ore reserves. In recent years, Russia has carried out a large complex of studies on the composition and technology of processing of copper-porphyry ores of different subtypes. In this work the complex poor copper-molybdenum-gold ore of one of the deposits is investigated. The chemical and mineral composition of the ore containing 0.49% copper, 0.020% molybdenum, 0.39 g/t gold, 5.85 g/t silver was determined. The forms of finding metals and their distribution by size classes are established. The dependence of extraction of metals into concentrates of collective-selective flotation on the size of ore grinding, pH of the medium, reagent consumption is shown. Under optimal flotation conditions, copper concentrate with 18.6% copper content and 92.32% extraction and molybdenum concentrate with 21.5% molybdenum content and 73.4% extraction were obtained. With a high concentration of molybdenum in selective flotation products, it is possible to conclude about the expected molybdenum concentrate with a content of 45% and a recovery of 70%. The associated extraction of gold and silver into copper concentrate is 76.8 % and 73.4%. Keywords: Collective-selective flotation, copper, molybdenum, porphyry ore, grinding, pH, reagents

Jan 1, 2020

By L. A. Cisternas, A. Lopez-Valdivieso, Y. L. Botero, L. Cortes

In the processing of sulfidic ores, pyrite is usually depressed and ends up in the tailings. However, pyrite is the most common species responsible for acid mine drainage (AMD) due to its spontaneous oxidation. This AMD affects the tailing chemical stability by dissolving some toxic or heavy metals species such as As, Cd, Co, Pb, and Zn, which can migrate into the surrounding ecosystems. Therefore, the strategies to reduce pyrite’s environmental impacts are a crucial point to produce more chemically stable tailings. Consequently, numerous studies have been made to find procedures that could inhibit or restrain AMD. This work aims to develop a procedure for designing conceptual flotation circuits that can produce tailings with low content of pyrite and to assess this type of circuit with traditional flotation circuits. The method consists of applying optimal flotation design where three products are considered: metal concentrate, pyrite concentrate, and tailing with low content of pyrite. Two approaches are considered; in the first, a flotation circuit is designed to generate a concentrate rich in all sulfide minerals and to obtain a tail with low pyrite content. Then, a second flotation circuit is designed for the selective separation of the bulk into metal concentrate and pyrite concentrate. This is called fractional separation design. In the second approach, a flotation circuit design is realised that generate the three products simultaneously. This is called integrated separation design. Both fractional separation design and integrated separation design are assessed in this paper. This methodology is focused on cleaner production (waste prevention and resource minimisation) rather than end-of-pipe technology (treat existing waste). The methodology was applied to a copper sulfide ore from a local company in the Antofagasta region (Chile). This ore contains chalcocite, covellite, iron oxides, and pyrite. Keywords: Flotation, tailing, pyrite, cleaner production

Jan 1, 2020

By A. J. Duncan, Bath M. D., E. R. Rudolph

Some factors influencing gold recovery by gravity concentration by M. D. BATH,. M.A.Se. (Met.) British Columbia (Visitor) A. J. DUNCAN,. B.Sc. (Hons.) Rhodes, M.S.A.C.I. (Visitor) E. R. RUDOLPH,* M.Se. (Eng.) Rand (Member) Recent studies have shown that the overall extraction of gold from Witwatersrand ores is increased as the proportion of gold reporting to the amalgamation circuit is increased. Testwork has therefore been carried out with a view to improving recovery by gravity concentration. In this paper, the history of gold recovery by gravity concentration is reviewed, and methods and machines at present in use are briefly described. The results of plant and laboratory tests are presented, and the limitation of existing concentrators is discussed. A pilot plant is being built for the testing of improvements to the existing concentrators and of several new devices, particularly the Reichert-cone concentrator.

By G. D. Schena

The issue of evaluating the economic impact of large mineral projects in developing countries was studied by the use of econometric models. The evaluating system is demonstrated by its application to an example from Namibia. Three-dimensional graphics are used to illustrate the procedures leading to an assessment of the economic effects of the mineral development. The analysis allows the assessment of the overall economic consequences of mineral developments where there is a need to incorporate in the evaluation issues that are broader in scope than the pure financial objectives. Sets of technical coefficients are exploited for the development of input-output models of the productive structure of an economy. The models are refined to incorporate country-specific behaviours. The increased flexibility of the enhanced semi-input-output model permits a more confident investigation of the economy wide effects associated with a new project in the mineral sector of a developing country. Synthetic measures of profitability at market and shadow prices are introduced, and the cost/benefit ratio is used to rank mineral projects according to their economic profitability. The cost is the capital mobilized for the development of the project and for increasing the productive capacity of the related satellite industries. The benefits are identified with the economy-wide increase in value added induced by the project. 80th costs and benefits are initially valued at market prices. Their ratio is likely to be an index of economic profitability superior to measures that concentrate exclusively on the benefit side of projects. To allow for market distortions, the concept of shadow prices is introduced, and accordingly project-related costs and benefits are re-evaluated. A new cost/benefit ratio at shadow prices is recalculated, which is more meaningful to the policy-maker than decision-making based on socio-economic issues.

Jan 1, 1993

In many practical situations, calculation of the point semivariogram is not necessary. Such a case is analysed in this chapter. The purpose of this analysis is to give a better understanding of the meaning of the mathematical formulae developed in the previous chapters. A similar problem will be studied in Chapter 11, using the point semivariogram.

Jan 1, 1978

By A. Kijko, C. W. Funk

Methods for the analysis of seismic hazards in mines are reviewed as illustrations of the techniques that are being used in some South African mines. The classical parameters that describe a hazard are the seismic activity rate, ?, the Gutenberg-Richter value, b, and, occasionally, the maximum regional magnitude, mmax The activity rate is calculated readily owing to the inherent simplicity of its definition. The evaluation method presented for the Gutenberg-Richter b value takes into account the presence of mmax Three statistical procedures are described for the assessment of mmax which the maximum observed magnitude, Xmax a crucial role. Often, the configuration of mine seismic networks is changed, or the networks are improved, which inevitably gives rise to changes in the completeness of the seismic catalogues. The routine analysis of seismic hazards must account for these time dependent changes. A method for the evaluation of hazards is reviewed that accommodates varying levels of quality in the catalogues. Finally, the concept of the volume of ground motion (VGM) is presented. This is a technique that allows for most aspects of seismic hazards in mines. The advantage of the VGM is that a hazard can be described by one physically significant value: the volume of rock (cumulated over a time period) in which the ground motion exceeds some critical particle velocity. Data from the gold mining region in South Africa known as the Far West Rand is used in a demonstration of the discussed methods of hazard analysis.

Jan 1, 1994

By H. M. Wells

The investment decision under uncertainty by H. M. WELLS, Pr. Eng., M.Se. (Fellow) The future outcome of a proposed investment is uncertain at the time the decision must be made to accept it or reject it. This uncertainty can be expressed in the form of a probability distribution. An attempt is made to rationalize the investment decision under these circumstances, especially when the range of possible outcomes extends into both the acceptable and unacceptable domains. A rigorous definition of risk is proposed, and a criterion of risk aversion is developed that forms the boundary between acceptable risk and unacceptable risk (called the loss limitation line). It is shown that this decision criterion can also serve as a quantitative yardstick in the evaluation of various possibilities for 'tailoring' the proposal to mlke it more compatible with the particular financial circumstances of the company concerned.

Jan 4, 1976

By C. Pamukcu

In this paper, which is aimed to serve as a review article, first of all a breakdown of the earth?s total water reserves is given. The usage areas of water in the mining industry are mentioned and these uses are briefly outlined, together with the main pollution potential of each. According to this, most of the water (almost 80% of it) is utilized in processing. Later on, probable damages that the mining would give to groundwater as a result of acid mine drainage, heavy metal pollution, euthrophication and deoxygenation is described. Finally, the measures and controls that should be taken against water contamination in mines are presented.

Jan 1, 2008