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By M. Pawlik

Canadian sylvinites contain over 90% of KCl and NaCl and a few percent of water-insoluble minerals. Cationic flotation is used to produce KCl concentrates. Since water-insoluble minerals appear in the pulp as slimes, and since long-chain primary amines are utilized as a collector, desliming is essential. The potash industry utilizes different desliming methods. This may involve selective flocculation of the slimes with polyacrylamide and removal of the flocculated product by flotation, or mechanical desliming with the use of classifying cyclones. Whichever method is applied, desliming is never complete; the flotation feed after desliming still contains about one percent of the slimes which heavily affect collector consumption and flotation selectivity. Therefore, the remaining slimes have to be rendered inactive by “blinding” them with polymers such as carboxymethyl cellulose or guar gum. The commercial blinders used by the potash industry include natural and synthetic polysaccharides. The most common is the use of carboxymethyl cellulose (CMC) and guar gum (GG). These are quite different polymers, while CMC is anionic, GG is non-ionic; while the applied CMCs are of relatively low molecular weight (about 300,000) GGs have much higher molecular weight. Guar gums are also heavily used as the depressants of naturally floatable gangue in the processing of platinum-bearing ores, and according to Harris et al. (1999) quite a large variety of modified guar gums are available in South Africa for this application. Cheng et al. (2002) claim that natural guar gum’s molecular weight is 1.935 • 106. Robinson et al. (1982) found that the molecular weights of five grades of commercial guar gums ranged from 4.4 • 105 to 16.5 • 105. The highest molecular weight sample is then very close to the natural guar gum studied by Cheng et al. (2002). According to the manufacturer, the Rantec KP4000 guar gum which is used by the Canadian potash industry has a molecular weight of about 1.5 x 106. Since both KCl and NaCl are soluble in water, the flotation process is carried out in saturated brine. At 20 oC, 1450 kg of NaCl-KCl-H2O saturated solution contains about 0.300 kg of NaCl, 0.150 kg of KCl, and 1 kg of water (Gaska et al., 1965). Thus, in the saturated NaCl-KCl brine there are about 5.1 kmole of NaCl and 2 kmole KCl per 55.5 kmole of water. This gives 3.9 molecules of water per each ion assuming complete dissociation of NaCl and KCl. Thus, it is obvious that all water molecules in the saturated brine must be bound in the hydration shells around the hydrated ions. The surface tension of the NaCl-KCl saturated brine was recently measured to be 85 mN/m (Laskowski et al., 2003).

Jan 1, 2004

By Donald A. Dahlstrom, Wai-Ping Kam

The mineral industry and individual processing plants are large consumers of energy. While energy conservation has received some attention in the present Federal Administration National Energy Strategy proposal it is obvious that the mineral industry should also continue to emphasize energy consumption reduction for important economic savings alone. As indicated by other studies, comminution is the largest single consumer of energy in the mineral processing plant (1.3% of total electrical energy consumption in the U.S.A.).1 Fine grinding is the largest portion of this amazing statistic. While substantial energy savings have been demonstrated by new machine developments and improved control methods, undoubtedly there are additional areas in comminution where substantial progress can be made. Some time ago, the U.S. Department of Energy published a report on "Comminution and Energy Consumption" by a committee composed of experts in the field of comminution from industry and academia. They identified the following potential for energy savings by specific areas? Classification device design 9-13% Comminution device design 3-16% Control 9% Grinding additive 3-6% Materials 3% It is apparent that the classification device had the first or second highest savings potential. Obviously, serious research consideration must be given to this technology area. A series of three papers have previously been written on the subject of two stage classification research work for ball mill operation by the authors. Accordingly, a brief review will be made. Previous Research Results on Two Stage Classification The hydrocyclone was selected as the type of classification equipment for this study as it represents by far the majority of the devices used in ball milling. While four different hydrocyclone circuits have been proposed by others,3 only two were considered in this work as illustrated in Figure 1. Flowsheet A is truly counter-current in nature in that the product from the ball milling circuit is taken from the first stage overflow

Jan 1, 1992

By R. H. Grau

This Bureau of Mines report describes methane liberation trends from all U.S. coal mines liberating over 100 Mcfd (100,000 cfd) (2.8 Mm3/d). Detailed are results from the latest Bureau survey performed in 1985 and shown are mine and company name, location, coalbed and methane liberation quantity. The report shows that in 1985, there were 180 mines producing more than 100 Mcfd (2.8 Mm3/d) and the total quantity of methane liberated by these mines was 303,900 Mcfd (8,605 Mm3/d). This data is compared with previous studies performed in 1971 , 1973, 1975, and 1980. From 1971 to 1985, there was a 10% decrease in the number of mines liberating at least 100 Mcfd (2.8 Mm3/d) but there was a dramatic 34% increase of liberations from these mines. The increase seems to be caused by new mines being developed in deeper, gassier coalbeds, particularly in Alabama. Likewise, in comparing the ten highest liberating mines in 1975, 1980, and 1985, an increase in methane liberations each year was experienced. The report classifies mines by three levels of liberations: greater than 100 Mcfd but less than 500 Mcfd (2.8 to 14 Mm3/d); 500 Mcfd to 1 ,000 Mcfd (1 4 to 28 Mm3/d); and greater than 1,000 Mcfd (>28 Mm3/d). It was found that 87% of liberations were from mines producing over 1,000 Mcfd but these accounted for only 38% of all the mines in the study.

Jan 1, 1987

By Floyd C. Bossard

A method of hand-calculating the air-cooling requirements of a conceptualized underground mining operation is presented for the reader's orientation. Separate air heat load calculations were conducted for adiabatic compression, electromechanical equipment, wallrock, broken rock, groundwater, and blasting operations. The air heat sources were calculated for four mining levels under conditions representative of a typical planned mining operation at depth. The total heat gain on each level will approximate the level air-cooling requirements. The results of these hand calculations can be further modified by the use of mine ventilation computer software that refine the heat-source calculations, predict underground ambient air temperatures, and establish the air-cooling requirements of a mine. INTRODUCTION The principal mining method employed is a modified vertical crater retreat (VCR) blasthole operation. Typical scopes range from 20 to 40 feet wide, 75 to 100 feet long, and 100 feet in height. Six and one-half inch blastholes are drilled with an "in the hole" hammer drill. Eight-foot high horizontal rounds are blasted down. Mucking of ore from the undercut to orepass is done with LHD equipment operated from a remote control station. Backfill includes hydraulically placed tailings with cement, and waste rock when available. Stope access is from ramp sub-levels on 50-foot vertical intervals. Crosscuts are ramped down to the first stope cut 25 feet below the sub-level elevation. Then the crosscuts are raised by taking down the back when each stope cut is completed, until an elevation 25 feet above the sub-level is reached. The crosscuts are filled with tailings, and/or waste rock. See Figure 1. Typically, a two-pronged approach to defining the air-cooling requirements is conducted. First, the principal sources that make up the air heat load are individually hand-calculated. Second, projections of mine heat load are calculated by utilizing computer modeling techniques. This paper discusses the first method (hand calculations) of determining the individual components of heat flow into the mine. CALCULATED AIR HEAT LOADS Adiabatic Compression The plans for the mine include delivery of 300,000 cfm of air to ventilate the lower level operation. This is equivalent to approximately 200 cfm/ton of rock produced (300,000 cfm/1500 tpd of ore and waste). As air flows down a shaft, with no heat interchange between the shaft and air and no evaporation of moisture taking place, the air is heated in the same way as if it were compressed in a compressor. Dry air increases in temperature about 5.4°F per 1000 feet. One BTU is added to each pound of air for every 778 feet of decrease in elevation, or is subtracted for the same elevation increase. For dry air, the dry-bulb temperature change is 1/(0.24 x 778) = 0.00535°F/ft., or 1°F/187 ft. elevation. Auto-compression may be masked by the presence of other heating or cooling sources, such as shaft wallrock, groundwater, air and water lines, electrical facilities, etc. The major factors influencing the temperature of the air delivered underground by a shaft are (1) the night time cool air temperature's effect on the rock or lining of the shaft, (2) temperature gradient of ground rock related to depth, and (3) evaporation of moisture within the shaft which increases the latent temperature and decreases the sensible temperature. [Calculation For Adiabatic Heat of Compression] a. Assumptions: 1. Three hundred thousand cfm of fresh air at 3000 level has increased in temperature during the summertime to the point where it has little available cooling power. Air-cooling will be required on 3000 Level and below. 2. Elevation of 3000 Level is approximately +1000 ft. above sea level.

Jan 1, 1993

By W. M. Ma, Daniel W. H. Su, K. Centofanti, Yi Luo, W. L. Zhong, Syd S. Peng

3.1 INTRODUCTION The final subsidence basin discussed so far is that developed long after mining has stopped. In a supercritical final subsidence basin, the central portion subsides uniformly. Thus any structures located there are not subjected to any final permanent surface deformation. But this statement is only true for the final subsidence basin. When the face is moving, the structures are subjected to dynamic deformations associated with the dynamic subsidence basin. For instance the house in front of a moving face (location 1 in Fig. 3.1) is subjected to the maximum tensile strain and the maximum positive curvahue. When it falls behind the face in location 2, it is subjected to the maximum compressive strain and the maximum negative curvature. When the house is far behind the face in location 3, it returns to its original condition with only uniform subsidence. However, the magnitude of the dynamic deformations may be sufficiently large to damage a structure in locations 1 and 2 before it reaches location 3. Therefore it is very important to study the characteristics of the dynamic subsidence basin. Under normal conditions, when the face has advanced for a distance approximately one-sixth to one-third of the seam depth from the setup entry, depending on the seam depth and the physical properties of the overburden strata, the movement of the over- burden strata reaches the surface, whereupon the surface also be- gins to deform. Thereafter, the surface point where the movement initiates is always located at a fixed distance ahead of the face. The angle between the vertical line at the faceline and the line connecting the movement initiation point on the surface and the face- line is the angle of advance influence, w. The angle of advance influence can be used to determine the distance, [ 1], which is the influence zone ahead of the face. w is approximately 20O to 35 O for the northern Appalachian coalfield (Peng and Geng, 1984). The movement of each surface point is a relatively complicated process both in time and in space, because the relative position between the faceline and each surface point varies continuously, so that the direction and rate of movement for each surface point differ. In the following sections, the movements of each surface point on the major cross section are illustrated. 3.2 DYNAMIC SURFACE MOVEMENTS Dynamic surface movements include dynamic subsidence and displacement. The movement of each point on the subsidence basin is different as the face advances from 1 to 6 (Fig. 3.2). Surface points A and B, being far in front of the moving face, subside and displace toward the face (i.e., from A to A' and from B to B'). Point C, which is quite near but in front of the moving face, subsides continuously but displaces initially toward the face and then turns to pure subsidence ending up at C'. Point D, which is behind the face above the gob, subsides continuously, but displaces initially toward the face when it is in front of the face and reverses to follow the moving face when it is behind the face, with the amount of displacement toward the face being larger than that following the face. As a result the net displacement is toward the center of the gob (i.e., from point D to D'). The same statement is true for point E. For point F, the net displacement is zero, i.e it appears to have dropped down vertically to F'. For points G to I, the net displacements are in the direction of face advance except the magnitudes are increasing in sequential order. Point 1, has reached the final dynamic position of 1'. In other words, the face has passed sufficiently away such that it does not affect the movement at point I. All other points (A to H) are still within the face influenced area. 3.3 DEVELOPMENT OF DYNAMIC SUBSIDENCE PROFILES When the face has moved for a distance of h/6-h/3 from the setup entry, surface subsidence reaches the surface. At this time the surface subsidence basin is very mild (S, in Fig. 3.3), and it is symmetrical about the center. As the face continues to advance, the maximum subsidence continues to increase, and its location moves with, but falls farther behind the face. When the face has advanced a sufficient distance, e.g., (0.9-2.2)h, away from the setup entry, the maximum subsidence reaches the maximum possible value (curve S,). At this time, the dynamic subsidence profile is fully developed. Thereafter both sides of the dynamic subsidence profile become stabilized. The subsidence profile on the face side moves with the advancing face in an orderly manner (curves S, and S,). When the face stops, the face side of the profile continues to subside and becomes stabilized (curves;) sometime after. Curve S; is the final subsidence profile (see Fig. 2.22). 3.4 DEVELOPMENT OF DYNAMIC DISPLACEMENT AND SLOPE PROFILES The dynamic displacement profile moves with the advancing face (Fig. 3.4), but changes according to some specific rules. When the face has advanced to A, the surface begins to move and its dynamic displacement profile has two maximum values (curve Ua): one positive near the setup entry moving toward the face advancing direction and the other negative on the face side also moving toward the face advancing direction. As the face continues to advance, the positive maximum displacement on the setup entry side increases and moves toward the face continuously. The same statement is true for the negative maximum displacement on the face side. When the opening increases to the critical size, both the maximum positive and negative displacements reach the peak values and remain constant thereafter. Notice that when the opening becomes critical in size, the point of zero displacement no longer moves with the advancing face. Rather it spreads into an area of zero displacement (curve Ue) and expands as the face advances. When the face stops, the displacement on the face side continues until it becomes stabilized (curve Úe). Curve Úe is the final displacement profile. The ratio of maximum dynamic to final displacement ranges from 60 to 75%. The dynamic slope profile follows the same patterns of change. The ratio of maximum dynamic to maximum final slope ranges from 50 to 80%. The maximum slope decreases with in- creasing rate of face advance (Peng and Geng, 1984). It must be pointed out that except for those near both sides of the profiles, each point on the displacement and slope profiles is subjected to a cycle of positive and negative displacements and slopes depending on its relative position with respect to the face.

Jan 1, 1992

By John Drew Ridge

Recent work by Haas has made available information on densities and vapor pressures of solutions of differing salinities at temperatures up to 330°C. From these data it is possible to predict the behavior of volcanic exhalations of various degrees of salinity as they approach the sea floor. Particular attention is devoted to solutions of 5.0 weight per cent NaCl and 20 weight per cent NaCl, two fluids that approximate quite closely the salinities of what Roedder termed: (1) normal hydrothermal fluids and (2) fluids typical of stratiform deposits of low-temperature conditions of origin. It is apparent that solutions above 220-230°C. cannot reach a sea floor on which the depth of water is 600 feet or less in the liquid state but will boil at some appreciable depth beneath the sea floor. Such boiling would result in the precipitation of all constituents of the ore fluids of significantly lower vapor pressure than water. The principal such constituent would be salt, and no sulfide deposits, the major constituent of which is salt are known. It follows, therefore, that ore fluids probably never get close to the sea floor of shallow seas at temperatures high enough to permit boiling. Ore fluids significantly above 230°C. can reach the sea floor in the fluid state only if the depth of the sea in the area. in question is well above 600 feet, for example, solutions at temperatures of ±300°C. reach the sea floor in the liquid state only if the depth of sea water is slightly over 3000 feet. Ore fluids reaching the sea floor at such depths may be the parents of such fluids as the Red and Salton Sea brines. On the basis of these data, the Cyprus and Kuroko deposits are discussed.

Jan 1, 1973

By J. A. King, D. R. Weir, P. C. Robinson

The complex mineralogy of the Porgera resource has a pronounced effect on process selection for the recovery of refractory gold and silver. Intimate association of gold with pyrite necessitates a high degree of sulphur preoxidation to achieve acceptable levels of gold recovery. Acid pressure oxidation has been demonstrated to be the only commercially proven process capable of achieving the required level of pyrite oxidation. Gangue mineralization dictates preconcentration of the sulphides to limit the acid consuming capacity and carbon dioxide generation during oxidation. However, the relationship between concentrate sulphur grade and gold recovery to concentrate ultimately governs the optimum degree of sulphide preconcentration. Minipiloting of the preconcentration and oxidation stages of the Porgera flowsheet are described. The influence of these processes on subsequent recovery of precious metals together with the technical and economic necessity of concentrate pretreatment prior to oxidation are discussed.

Jan 1, 1987

By James T. Finley

Profit, product quality, speed of operations, reliability, operator confidence, safety and environmental improvements have all been enhanced as a result of the recently completed maintenance, renovation and construction program at Crown Central Petroleum Corporation?s (Crown?s) coke calcining unit at its Pasadena, Texas refinery. (Figure 1) BACKGROUND The calcining unit was built in 1969 - 1970 and has been operated continuously. Approximately 400 to 500 TPD of high quality metallurgical grade coke is manufactured, stored, and shipped to consumers. About 1/2 of the feed stock to the calciner is manufactured in Crown's coking unit and the remainder is received, via barges, from various sources. The green coke is off loaded from the barges with a conventional grab crane that discharges into a small travelling hopper over a conveyor belt that feeds a radial stacker, which forms a stockpile on the ground. The green coke, from the coking unit at the refinery, is moved to the calcining unit with front end loaders. Reclaiming from the stockpiles is also done with front end loaders. The coke is primarily handled by covered conveyor belts. The finished product is stored in steel silos and can be shipped via railroad cars, but the majority of it is shipped out in ocean going bulk carriers. Maintenance work in the calcining unit is performed by Crown's refinery maintenance department on an as needed, on call basis.

Jan 1, 1983

By D. Altizer, E. Thompson, K. F. Unrug

Because of frequent sudden changes in the geologic composition of strata, the extrapolation of rock properties obtained from core samples to the surrounding areas can cause problems. To address this issue, a method of rapid strength testing in situ using a borehole penetrometer is being developed. This method, as opposed to conventional laboratory testing, does not require rock samples to be retrieved and handled/machined before testing. Rock strengths are determined di¬rectly on the drill-hole wall. The latest development is a borehole penetrometer that requires only a 38.1-mm- (1.5-in.-) diam hole. The small diameter of the penetrometer body allows for the drilling of test holes with production mine equipment such as a roof bolter. The new penetrometer allows for the possibility of a broad application in coal mines, as well as in hard rock mines and tunneling. The principles of the apparatus are described and are illustrated with examples of its applications.

Jan 1, 2002

By J. E. Hoffman, S. P. Sandoval, T. J. Keefe, K. P. V. Lei, O&apos

The U.S. Bureau of Mines investigated the use of the Fe2+/Fe3+-SO2 (FFS) anode reaction in the copper leaching-solvent extraction-electrowinning circuit. The investigation revealed that six process variables, including anode type, Fe 21 concentration, current density, electrolyte temperature, degree of agitation, and manifold injection point were found to influence cell voltage and cell current efficiency. A 47% voltage reduction (0.8 versus 1.5 V) compared to conventional electrowinning with activated lead (ALE) anodes was achieved at a current density of 258 A/m2 (24 A/ft2) with an industrial electrolyte. Current efficiency was maintained above 90%, and S02 above the cell measured less than 1 ppm when activated carbon was used to assist the reduction of Fe" by S02 in the copper electrolyte. Solvent extraction tests showed that Alamine 336 is a stronger H2SO4 extractant than is needed to extract the excess acid produced by the FFS anode reaction.

Jan 1, 1993

By Y. H. Cheng, H. EI-shall, S. Gupta, N. A. Abdel-Khalek

A 14.6 cm (5.75 in.) diameter by 1.83 m (6 ft) tall laboratory-size column is used in flotation of Florida phosphates of different feed sizes. In this paper, the effects of different parameters on the flotation efficiency of coarse particles (belt feed, -1.4 + 0.5 mm, i.e., 14 x 35 mesh) under negative bias are discussed. Parameters included collector dosage, frother type and dosage, and conditioning water, which contained a residual concentration of collector. Flotation tests were performed using statistical designs. The results strongly suggest that flotation performance is dependent on the used combination of reagents. Interactions between frothers and the collector and, consequently, the flotation efficiency were found to be dependent on frother type and presence or absence of conditioning water. Under the negative bias, an excellent recovery of more than 98% of phosphate was achieved in concentrates of high grade (above 31% P205) from such feed of coarse particles.

Jan 1, 1999

By Michael J. Sapko, Robert A. Cortese

A flame powered trigger device has been developed to explosively activate suppression barriers to quench gas and coal dust explosions. The important feature of the device is a silicon solar panel, which collects 0.3 p to 1.1 D wavelength radiation from the developing explosion, and generates electrical energy to initiate a detonator, which in turn causes the rapid explosive release of an extinguishing agent into the advancing flame front. Solar panels that are rated to produce 20 w of electrical power when exposed to the sun light are producing about 200 w when exposed to full-scale dust explosion propagating in the U.S. Bureau of Mines' Lake Lynn Experimental Mine. The solar panel is electrically isolated from the detonator by a pressure sensitive switch until the arrival of the precursor pressure pulse, which always precedes a deflagration. This combination of pressure arming and flame powered photo generator prevents false barrier activation and requires no external power supply.

Jan 1, 1991

By R. N. Chakravorty, R. J. Kolada

Explosions of methane in coal silos and coal ships is an ever present hazard. Recent investigations have shown beyond question that considerable accumulations of methane do occur in coal storage silos and numerous recent explosions in coal transport shipping strongly indicates that the same conditions also exist in ship storage holds. Investigations have shown that the main concentrations of methane occur within the actual coal pile. Within this region normal silo and ship ventilation systems are ineffective. The main 1ine of defence is therefore to exclude potential sources of ignition or to place the coal in an inert atmosphere, or both. This paper presents the results of a methane survey of all operating silos in Western Canada. These results demonstrate that a serious and widespread hazard of explosion exists. This paper also discusses various methods by which this hazard may be reduced including methods of venti1ation, inertization, microbiological control and early warning systems.

Jan 1, 1987

By W. C. Morgan

Recently passed federal strip mining legislation officially emphasizes that the increased coal production required by this country through surface mining is going to be obtained only with stricter environmental standards. Dozing overburden down the hillside in Appalachian contour mining or leaving drag1ine spoils in area mining is now taboo and it is now or will soon be necessary to return the disturbed land to as good or better condition than before mining. These new restrictions will create a need for new and better ways to do the job. This paper describes one approach for utilizing scrapers and dozers to strip all of the overburden and to replace that overburden in an environmentally satisfactory fashion. The objective was to do this at a lower cost than that possible with the traditional dragline system using dozers and scrapers for reclamation and topsoil handling. In area stripping, the dragline has been able to move overburden at an extremely low cost. Operating costs of 8-13¢/bcy are typical in many operations where rehandling is not required. However, the cost of leveling the spoil piles and rehandling topsoil add considerably to the low basic cost of drag1ine stripping.

Jan 1, 1977

By D. J. Frey

While costs of most commodities and services have increased markedly over the past 25 years, the cost of electricity has steadily declined. One of the reasons for this price decline is the improved efficiencies of generating plants which is shown in Fig. 1. 1,2 Another reason for this is the decline in coal production costs. Efficiencies for the best plant increased from about 32 percent in 1540 to about 40 percent in 1962 and then decreased slightly to 38 percent in 1965. The increase in efficiency for all plants (US average) has been even more notable, progressing from less than 15 percent in 1940 to about 32 percent in 1965. The chief reason for the improved efficiency is the change in operating steam temperatures. These increased about 12 F per year until 1200 F was reached in 1962. At this high temperature excessive corrosion of super-heater and reheater tubes was experienced and steam temperatures were dropped back to 1050 F and even 1000 F in some cases. To successfully compete against other energy sources for generating electricity, this corrosion problem must be solved so that operation at higher temperatures and thus, increased efficiencies will be possible.

Jan 1, 1967

By R. H. Seraphim

The name is derived from an Egyptian myth, "A beautiful lone bird which lived in the Arabian desert for 500 or 600 years and then consumed itself in fire, rising renewed from the ashes to start another long life." HISTORY This account of the first history is gleaned from old reports and documents which are listed in the Bibliography and from discussions with old-timers of the district. Prospectors were active in the vicinity of Greenwood in 189 1, and in that year staked the Mother Lode, Crown Silver, and Sunset. Henry White staked the Knob Hill claim in Phoenix on Jul. 15, 1891, and by the end of the year, other prospectors had staked most of the claims covering the valuable ore bodies in the camp. Much surface work done in the early years indicated that the values in copper, gold, and silver were low. Large capital investments were required to develop the ore bodies and build smelters. The discovery that the ore was practically self-fluxing greatly enhanced the value of the deposits. A map of the area showing the geology is given in Fig. 1. The bedded Brooklyn conglomerate is shown in Fig. 2.

Jan 1, 1991

By J. P. Morgan

The Vesta Preparation Plant of the Jones & Laughlin Steel Corporation is located on the Monongahela River, eight miles south of Brownsville, Pennsylvania. This plant is capable of cleaning 2400 NT/hr of a mixture of Pittsburgh seam high volatile coals from the Vesta and Shannopin mines to produce a metallurgical coal of 6.75% ash and a steam coal containing 14% ash. Heavy media vessels are utilized to upgrade the coarse coal while launders and tables. handle the -1/4" fraction of the raw coal feed. Cleaned -coal goes to boot classifiers where the +48 mesh material settles and is removed by bucket elevators. This 1/4 x 48 mesh material is then sent to centrifugal driers for dewatering. As designed, the minus 48 mesh fraction overflows the boot as a 7 to 8% solids slurry and is recovered by cyclones and a thickener and dewatered by filtration. The-products of the heavy media circuit, the launder-table-boot-drier circuit and the cyclone-thickener-filter circuit are combined to constitute the shipped metallurgical coal. This Vesta-Shannopin mix is combined at J&L's Pittsburgh and Aliquippa Works with purchased low and medium volatile coals for the production of metallurgical coke.

Jan 1, 1962

By W. Dresler

Since 1900, smelters have produced in Canada over 10 million tonnes of iron silicate waste slag containing significant quantities of nickel, cobalt and copper. The slag is reduced with aluminum and calcium oxide additions to produce a copper, nickel, and cobalt enriched alloy and an obsidian slag. It was found that the obsidian slag contained very low copper, nickel, and cobalt contents, indeed below 0.06% of each the base metals. These metals have been collected in a type of ferroalloy with up to 1.6% Cu, 2.1% Ni, and 0.7% Co. These alloys can be recycled according to standard procedures in base metal smelters. Surprisingly, the obsidian slag was found to display good cementitious and pozzolanic properties, which is a requirement for cement production. The strength producing properties of the obsidian slag are considered to be exceptional at the 28 day standard test age. In most cases, the obsidian concrete is characterized by significantly greater strengths than control concrete tests and concrete containing fly ash or blast furnace slag. Compressive strength data at 365 days for the obsidian concrete is impressive.

Jan 1, 2003

By C. A. Fleming, K. W. Sarbutt, P. K. MacPhail

The SART process has been developed for Teck to treat bar­ren solution from the cyanidation/CIP process that has been developed for the Lobo-Marte project in Chile. The objective of the process is to recover cyanide in a form that is suitable for recycling to the leaching part of the process. The Marte and Lobo ore bodies require a dosage rate of about 2 kg/t NaCN, of which only 0.5 kg/t is truly consumed (as thiocyanate, cyanate and ferrocyanide species). The remaining -1.5 kg/t is present as cop­per cyanide (-1 kg/t) and free cyanide (-0.5 kg/t), and is poten­tially recoverable and recyclable. SART is an acronym that describes the unit operations in this cyanide recovery process; namely, .. Sulphidization .. Acidification .. Recycling of precipitate " Thickening of precipitate The basic chemistry has been applied previously, and has also been the subject of two patents (American Cyanamid Company, 1965, Potter et al., 1986). The process involves the conversion of all free and WAD cyanide in solution to hydrocyanic acid by acidification of the tailings solution to pH :s,4, and the conversion of all copper in solution to cuprous sulphide (synthetic chal­cocite) by the addition of a sulphide salt:

Jan 1, 1998

By Yu. A. Polozov, V. A. Lagunov, O. Yu. Lushinkova, Yu. I. Svirskiy, Eh. Ya. Kipko, Roy A. Williams

Hydrodynamic investigations in exploratory boreholes and grouting holes are conducted for the purpose of obtain¬ing information about the hydraulic properties of the hydrostratigraphic section to be intersected by the proposed underground workings. The information obtained from the investigations provides the basis for calculating the hydrau¬lic coefficients of fractured permeable rock, the dimensions of the anticipated grout isolation curtain(s) around the un¬derground workings, the number and location of grouting holes, the injection pressure modes, and also the volume(s) of grout that will be required (Anon., 1976, 1978). The following data on each aquifer are obtained from the investigations conducted in monitoring and grouting bore¬holes and the analysis of the results: 1) the top of each hydrostratigraphic unit, 2) the thickness of each unit, 3) the ground water fluid potential distribution in each unit, 4) the coefficient of permeability, 5) the piezoconductivity, 6) the fracture porosity, 7) the geometry of the fractures in the rock, 8) the elasticity-compressibility coefficient of the fractured rock, 9) the chemical composition of the ground water, 10) the direction of flow of the ground water, and 11) the expected inflow rate of water into the shaft, drift or tunnel. STG uses its DAU-3M type flowmeter to conduct in¬vestigations of directions of flow in vertical, inclined and horizontal drillholes. The DAU-6 instrument is used to de¬termine the direction of flow of ground water in each frac¬ture or fractured aquifer. Various singular and double DAU type packers are used for pumping and for injection studies (tests) and for flowmeter investigations. Normally the instruments enumerated above permit in¬vestigations to be conducted in each separate aquifer with¬out reinforcing the holes with casings. On the basis of these investigative data, both the hydraulic properties of unfractured rock and the hydraulic properties of the fractured rock are estimated. Dual porosity rocks require special attention because they tend to segregate the grout. 3.1 FLOWMETER INVESTIGATIONS IN BOREHOLES The STG flowmetric methodology is based on the mea¬surement of the ground water flow rate through the borehole by hydrostratigraphic interval after the disturbance of the hydrostatic equilibrium in the "hole-aquifer system" (after pumping or injecting). The relationship of the head changes to the discharge into or from a particular hydrostratigraphic unit obtained during the tests serve as the basis for calcu¬lating the hydraulic properties. Flowmetric investigations facilitate the determination of the number of aquifers, their depths, their thickness, the hydraulic properties of the fractured rock and the magnitude and direction of the flow of ground water. 3.1.1 FLOWMETER HARDWARE STG conducts flowmetric investigations in boreholes using its DAU-3M-108, DAU-3M-73, DAU-3M-57 and DAU-3M-44 instruments.' They have respective external diameters of 108, 73, 57 and 44 mm. The type of flowmeter selected for use depends on the borehole geometry and the technological scheme for carrying out the investigations. Boreholes with a drilling diameter of 76-93 mm are inves¬tigated with the DAU-3M-73 flowmeter; boreholes drilled by bits with a diameter of 112 mm and more are investi¬gated using the DAU-3M-108 flowmeter. The DAU-3M¬108 and DAU-3M-57 instruments are used for flowmetric investigations with a packer. 3.1.1.1 The Downhole Sensor The sensor design of the DAU-3M-73 hole flowmeter is shown in Fig. 2. The design of the DAU-3M-108 instru¬ment is similar to the design of the DAU-3M-73 instrument. The frame of the flowmeter sensor shown in Fig. 2 consists of a casing, an upper and lower centering mount and two rings to which the guiding rods are attached. The upper rods are built into the connector bushing; the lower rods are built into the coupling sleeve. The borehole cable is attached using a half-coupling, a packing ring and a constriction nut. Thus, the frame of the flowmeter sensor is made so that the free passage of water to the impeller is facilitated along with the necessary rigidity. The primary moving component of the flowmeter is the double-bladed impeller, which rotates on cobalt-tungsten pivots and agate thrust bearings. Special extended air cham¬bers protect the supports of the impeller from the action of the borehole fluid which may contain fibrous and abrasive particles. The air located in the chambers shields the sup¬ports from direct contact with the borehole fluid when the sensor operates in a borehole. The hollow casing of the impeller serves the function of a lower cap. The upper cap is attached to the casing using a threaded connector; it is affixed also with a lock-nut. An adjusting screw with a

Jan 1, 1993