Search Documents

By Morris Loshinsky, George Ziegler

The New York City Transit System is celebrating its Diamond Jubilee this year. In 1904, 9.3 route miles of New York's first subway was placed in operation in lower Manhattan. Since that date the system has grown to 230 route miles and 458 stations (See Exhibit #1). The age of the system immediately provides a clue to the nature of our construction activity. While we must always plan for the future and expand the system in the direction of the future needs in New York, a substantial amount of time and money must be channeled towards the modernization and maintenance of the existing system which provides vital transportation for 3-1/2 million passengers a day. This paper however will be directed to our New Route's Construction and, specifically, to three rock tunnel and cut and cover sections presently under construction. Currently, New York is engaged in the construction of about 9 New Route miles of structure. Briefly, the 3 Sections we will discuss are as follows: Route 131-A Section 5A is a 4 track structure in Manhattan and includes the new Lexington Avenue Station. This 1240 foot long section is located between Park Avenue and 3rd Avenue and is a combined cut and cover and rock tunnel section under 63rd Street. Route 131-A Section 5B is an intricate 2423 foot long 4 track rock tunnel section extending from 3rd Avenue to the FDR Drive under 63rd Street in Manhattan.

Jan 1, 1979

By R. G. Swanton

The Bureau of Mines is investigating the leaching of phosphate values from Florida phosphatic clay wastes using sulfuric acid (H2SO4) as the leaching agent and methanol as the solvent. Acid-alcohol leaching studies were done using pure crystalline apatite to investigate potential causes for low extractions. It was found that a barrier layer formed on the surface of the apatite. Initial discovery of the barrier layer was made by analyzing pure apatite samples before and after leaching using an optical microscope. Subsequent Fourier Transform Infrared (FT-IR) analyses proved the coating was calcium sulfate hemihydrate (CaSO4-1/2H2O) and that unreacted apatite existed beneath the coating. Scanning electron microscope (SEM) photographs depict the CaSO4-1/2H2O morphology as long slender crystals adhering to the apatite surface. It was also shown that grinding the leached tailings and leaching again in the H2SO4-methanol system resulted in additional phosphate extraction.

Jan 1, 1991

By L. A. Clark

Although vein-, syenite-, and pegmatite-type deposits are known in Saskatchewan, recent intense exploration stems from discovery of several exceptionally high grade uranium and uranium-nickel deposits locallized near the basal unconformity of the 1.3-1.4 b.y. Athabasca Sandstone Formation. Graphitic basement rocks and post-Athabasca faulting or brecciation coincident with the unconformity are important in locallizing uranium deposits which form as tabular, shoe lace-like bodies with grades averaging over two percent and containing up to 50,000 tonnes U308. Some deposits have similar nickel contents. A few published sandstone analyses average 0.8 ppm uranium while basement granitoid and meta-sedimentary rocks vary from 0.5 to 20 ppm. In the proposed genetic model, traces of uranium are leached from these rocks by oxidized formation waters sweeping through the sandstone and along faults. Solutions are reduced and uranium is precipitated as basement graphitic meta-pelites are encountered along brecciated fault zones.

Jan 1, 1979

By Kenneth J. Leib, Laurie Wirt, M. Alisa Mast

Chemical-constituent loads were determined for an alpine stream in southwestern Colorado that is affected by natural acid drainage from weathering of hydrothermally-altered rock and from acidic metal-rich discharge from abandoned mines. Base-flow loads were compared to storm-related loads using a tracer-dilution approach. A rainstom occurred during the tracer injection, providing the opportunity to measure metal loads before, during, and after storm runoff. Chemical-constituent loads during the storm increased by 1 to 2 orders of magnitude relative to base-flow conditions. The increase in loads was related to two distinct periods; (1) a flush of higher concentrations that occurred soon after rainfall began, and (2) the peak of storm runoff. The initial flush-having no measurable change in discharge--contained the highest loads of trace metals and dissolved iron. The chemical character of peak runoff was distinctly different, as evidenced by the highest loads of total and dissolved major elements and total iron.

Jan 1, 2000

By R. Hogg, T. F. Dumm

A simple shape description scheme has been developed which has the specific aim of distinguishing between angular and more rounded particles. The procedure involves fitting a general polygon (usually about 20 sided) to the particle profile. Geometric shape descriptors have been defined based on variations in the angles between adjacent sides and their radial displacement from the particle centroid. A two-parameter shape description, incorporating an angular variabli1ity and an elongation index, has been shown to be clearly consistent with visual observations. A single-parameter angularity index has been shown to be very sensitive to small differences in particle roundness and seems to provide a better description of angularity than other approaches such as signature and fractal analyses. The scheme has been applied to three sets of fine quartz particles produced by different grinding procedures. The results indicate that the technique is capable of distinguishing between angular and re1atively rounded particles and can quantify their specific shape features.

Jan 1, 1991

The sixth annual conference of the Mineral Economics and Management Society (MEMS) was held Feb. 27 through March 1 in Boulder, CO. This year's event was attended by more than 100 academic, industrial, government and other professionals interested in mineral economics and materials management. With about 250 members worldwide, this not-for-profit society seeks to promote scientific and economic analysis of current relevant issues. This year's program was sponsored by Alcan, Bateman Engineering, Cyprus Amax Minerals, J.P Morgan, Knight Piesold LLC and Newmont Gold. The conference's technical program consisted of six sessions. These included "Financial tools for a changing world," "Access to minerals," "Comparing North and South America," "Environmental issues in today's world" and "Transporting minerals." The program was concluded with a panel discussion titled "National minerals policies in Asia." In addition, a student papers session was held, in which students were given the opportunity to compete for a $1,000 award. The following is a brief review of the technical pro¬gram.

Jan 1, 1997

By G. M. Wilemon, Swanton. R. G.

The Bureau of Mines is investigating the leaching of phosphate values from Florida phosphatic clay wastes using sulfuric acid (H2SO4) as the leaching agent and methanol as the solvent. Acid-alcohol leaching studies were done using research-grade apatite to investigate potential causes of flow extractions. It was found that a barrier layer formed on the surface of the apatite. Initial discovery of the barrier layer was made by analyzing pure apatite samples before and after leaching using an optical microscope. Subsequent Fourier Transform Infrared (FT-IR) analyses proved the coating was calcium sulfate hemihydrate (CaSO4•1/2H2O) and that unreacted apatite existed beneath the coating. Scanning electron microscope (SEM) photographs depict the CaSO4• 1 /2H20 morphology as long slender crystals adhering to the apatite surface. It was also shown that grinding the leached tailings and leaching again in the H2SO4-methanol system resulted in additional phosphate extraction.

Jan 1, 1992

By J. R. Weber, R. D. Haddenham, J. H. Bailey

Introduction The Vernal Phosphate Operation is located in northeastern Utah, about 18 km (11 miles) north of Vernal, about 280 km (175 miles) east of Salt Lake City, UT. The plant began initial operations in 1961 under the name of the San Francisco Chemical Co. In 1981, Chevron purchased the operation from Stauffer Chemical Co. In 1982, plant capacity was doubled to about 72.6 kt/a (800,000 stpy) of phosphate concentrate. From 1984 to May 1986, another expansion increased the capacity to 1.2 Mt/a (1.3 million stpy) of concentrate. It also incorporated a number of equipment and process changes designed to increase the overall plant phosphate recovery. A 150-km (94-mile) slurry pipeline, the world's longest phosphate pipeline, was also constructed from the Vernal plant to a new Chevron Chemical and Fertilizer plant near Rock Springs, WY. Over the past five years, plant expansions and the pipeline construction have been accomplished without missing a single concentrate shipment.

Jan 1, 1987

By R. Bhaskar, H. Xie

Fractal theory was horn in the mid-1970s. Since then, its application has been spreading day by day, from mathematics and geology to areas such as geophysics, physics and material sciences. In this paper, fractal models are developed to characterize particle size distribution and surface area. Theoretical formulas are derived for the computation of fractal dimensions D (size) and D[s] (surface area). The models developed are applied using experimental data of particle size distribution and surface area obtained from the Microtrac Particle Size Analyzer for dust processed by several size reduction devices. The theoretical models and the experimental data are found in good agreement. The fractal dimensions obtained are D = 1.350 to 1.770 and D[s] = 2.058 to 2.584 for fine coal dust particles (< 15 µm) produced by various size reduction mechanisms. The physical meaning of these fractal dimensions is also related to the dust generation processes.

Jan 1, 1994

By Michael R. Smith

Barrick Goldstrike Mines Inc.’s Betze open pit is located at the north end of the Carlin Trend, in Eureka County, NV. Ten open pit gold mines exist on the trend, which strikes northwesterly, through the north end of Eureka County and into Elko County (Fig. 1). The final pit will be about 2440 m long x 1550 m wide (8000 x 5100 ft), elongate in a west-northwesterly direction and about 425 m (1400 ft) deep. The pit straddles the Barrick-Newmont Gold Co. property boundary. History The first hole at the Goldstrike Mine was drilled in 1962. Between 1963 and 1964, 17 shallow holes were drilled with little encouragement, in view of the price of gold at $1.12/g ($35/oz). From 1962 to 1975, several different companies explored the Goldstrike property. In 1975, Pancana Industries acquired the property. In 1976, Pancana’s exploration efforts found sufficient gold mineralization to initiate heap leach production. In 1977, Pancana formed a joint

Jan 1, 1994

By J. Alvarez, S. H. Castro

The feasibility of chalcopyrite-pyrite separation in the flotation of a chalcopyritic copper ore, at reduced surface tensions regulated by methanol, was investigated. It was found that with methanol dosages from 0.5% to 1.5% v/ v, the chalcopyrite might be effectively separated from the pyrite, without use of other flotation reagents and pH regulators. However, under this simple condition, the chalcopyrite recovery was only around 50%, recommending the use of other reagents to reinforce the collector action. Low dosages of different collectors were tested, including SF-323 (Shell Float), S-6588 and S-7251 (Cytec), and S-701 (Molycop). Very promising results were obtained with low dosages of the collector S-701 and 1% v/v of methanol in the pulp, which evaluated against a reference test, gave similar copper recovery, higher Mo recovery and higher depression of pyrite. Consequently, this is an alternative process which does not require the use of lime to depress pyrite.

Jan 1, 1995

By John O. Marsden

Process selection is the systematic development of the optun.m metal extraction route for a particular feed matenal and has two main objectives: (1) to optimize project economics, principally a function of gold recovery, throughput rate and processing costs, and to develop a process that satisfies all of the proct requirements including, for example, political and environmental considerations.

Jan 1, 1992

By Gale F. Hoffnagle

INTRODUCTION On November 15, 1990, President Bush signed the Clean Air Act Amendments of 1990. These Amendments cover many aspects of air pollution control. The provisions which seek to control emissions of "air toxics" may, however, be the most far-reaching and will potentially have the greatest effect on American industry. The Administration has estimated that by the year 2005 industry will be spending $6.7 billion per year on air toxics control. Meanwhile, the Business Round Table has estimated that the price will be far higher, up to $62 billion per year, depending on how EPA and the States implement the program. BASIC REQUIREMENTS Any "major" source of emissions of 189 air toxics will be required to install "MACT." The translation of this statement requires some definitions: •MAJOR SOURCE - A facility (a contiguous property under single ownership and control) which has actual emissions of 10 tons or more per year of any single one of the air toxics or 25 tons per year of any combination of air toxics. •AIR TOXICS - Congress has provided a list of the 189 chemicals on this list. Those that may be important to the mining industry are shown on Table 1. This list can be changed by petition or by EPA. •MACT - Maximum Achievable Control Technology is to be defined by EPA for each industrial source category. EPA says there are about 400 categories. The Act defines MACT as: "the average emission limit achieved by the best performing 12% of the existing sources ... for categories with 30 sources or more" or, "the average emission limitation achieved by the best performing 5 sources in the category." TABLE 1 SELECTED AIR TOXICS FROM CLEAN AIR ACT LIST IMPORTANT TO MINING INDUSTRY Antimony Compounds Arsenic compounds (inorganic including arsenic)&apos; Beryllium Compounds&apos; Cadmium Compounds Chromium Compounds Colbalt Compounds Cyanide Compounds (dissociation compounds) Lead Compounds&apos; Manganese Compounds Mercury Compounds&apos; Fine Mineral Fibers Nickel Compounds Radionuclides (including radon)1 Selenium Compounds 1Previously listed under NESHAP 2The Administration may not list elemental lead as a hazardous air pollutant.

Jan 1, 1991

By L. G. Austin

Introduction My first contact with industrial milling was during the time I worked in the electricity generating industry in the United Kingdom. In visits to power stations to investigate either deposits in the boiler furnaces or polluting deposits settling around the stacks. I had to check the performance of the vertical coal pulverizers, since poor pulverization aggravated both problems. Naturally, then, when I came to the USA in 1957 to take a PhD in fuel technology at Penn State, I was put to work to review the science of coal pulverization. After this reviewing, I was completely confused. On one hand, there was a well-developed understanding of stress-strain equations, and a rap- idly developing knowledge of how stressed, brittle solids fractured, based on the Griffith crack theory. On the other hand, reading in the grinding literature gave me: • Kick&apos;s Law, which was clearly not correct in the light of modern fracture theory; • Rittinger&apos;s Law, which was also clearly not correct; • Bond&apos;s Third Law of Comminution, which was claimed to have something to do with the Griffith crack theory, but where the connection between the two was made by intuitive pseudo- scientific reasoning I could not accept; • the choice of mill motor power for the most common type of coal mill, the Raymond pulverizer, was calculated from the fan power required to move air through the mill. Although I could accept the empirical connection between the two, it made no sense from the point of view of fracture energy. Even today, most books or review chapters on size reduction start from these laws. incorrect statements abound in the literature, such as “the Hardgrove Index is based on Rittinger&apos;s Law," which it is not, "The Bond theory states that work input is proportional to new crack tip length produced in particle breakage," which is not true, etc. My own test work showed that these "laws" did not fit the data for grinding of coal. At about this time, Epstein (1 948) and Broadbent and Callcott (1 956), following the original work by R.L. Brown (1941) at the British Coal Utilization Research Association, proposed describing breakage as a series of fracture stages. I took their concepts and developed the basic differential equation for a batch grinding process continuous in time, analogous to a batch chemical reactor. Robin Gardner then joined the project and did his PhD on treating batch grinding in the same way as a batch chemical reactor. He found that the basic equation had already been partially derived by Sedlatschek and Bass (1 953) in Germany. We confirmed experimentally the validity of the equations for describing batch grinding (1 962) and formulated the equation describing steady-state continuous grinding in a fully-mixed mill. At about the time this work was published, Gaudin and Meloy (1962) and Filippov (1961) independently published essentially the same equations, but without experimental proof of the validity of the concepts. I will give a brief overview of what these beginnings had led to in the design of mills for size and power, and show some of the results of this more detailed understanding of grinding processes. Concepts of Fracture Mills such as tumbling ball, rod, pebble and autogenous mills and vertical mills such as the Raymond, and E-type apply compressive stress to lumps or particles relatively slowly. Compressive stress applied to a particle of an elastic brittle solid imparts overall strain energy to the solid and produces local regions of tensile stress, (Fig. 1) (Berenbaum and Brodie, 1959). Irwin (1949) showed from solution of the stress-strain solutions that a small hole in a region of tensile stress reduces stress concentration at the hole, that is, the tensile stress at the tip of a crack or flaw in a solid is much higher than the general tensile stress in the region. The longer the crack, the higher the stress concentration. Griffith (1920) hypothesized that when the regional tensile stress is large enough, then the chemical bonds at a preexisting crack tip are stretched to breaking point, as illustrated in Fig. 2. When the bonds break, the crack becomes longer, the tensile stress concentration increases, the situation is unstable and a crack opens up (propagates) a surface of tensile stress, creating its own tensile stress at the leading edge. Stored strain energy is converted to the kinetic energy of the moving stress field, which is analogous to sound propagation through the solid, so the crack tip accelerates to velocities approaching those of sound. The moving crack will pass through regions that were previously under regional compressive stress. The equations for "ideal" and "Griffith" strengths are where a is the intermolecular distance, y is Young&apos;s modulus, g is the energy

Jan 1, 1998

By E. A. Laurila

During last years many different types of X-ray fluorescence analysers have appeared in the market most of these instruments being designed for laboratory use. The instruments applied ins continuous processes are usually modifications of these laboratory types. The application of these instruments to the analysis of heavier elements seems to be quite satisfactory. By lighter elements difficulties are caused by the strong absorption of the characteristic fluorescence radiation, which sometimes makes the use of vacuum or helium chambers necessary. In the following an instrument of another type will be described. It has been developed exclusively for the analysis of titanium in ilmenite concentrate, where the content of Ti02 varies between 43 - 46%. Preliminary measurements have shown that in this interval absolute change of 1% in the Ti02 concentration causes a relative change of about 2% in the intensity. Because: the accuracy of 0.5 % Ti02 is sufficient, 1% relative accuracy should be, attained in intensity measurement. The problem is not very easy to solve due to the fact that Ti K radiation is rather soft and the requirement&apos;s for accuracy are rather high. Being applied to the analysis during a continuous process may statistically fluctuating variables in connection of sampling and disturbances of many kind set special requirements for the instrument design.

Jan 1, 1960

By A. G. Oppegaard

Most iron ores treated by the R-N direct reduction process yield metallic iron products considerably lower in titanium, manganese, and chromium oxides and alkaline metal sulfates/sulfides than were contained in the original ores. These metallic iron products are suitable as feed stock for the open hearth and electric steel-making furnaces. The elements which are rejected in part are acceptable in the product since the product is designed to by-pass the blast furnace. R-N reduction conditions (PCO+H2-1 atmosphere, 1830° to 2150° F.) are adjusted for each ore. The iron ore which is reduced to 90 to 95 percent metallic iron is then subjected to the conventional beneficiation techniques. Under these conditions, 55 to 80 percent of titanium oxides, 75 to 95 percent of manganese oxides, 60 to 90 percent of chromium oxides and up to 97 percent of alkaline metal sulfates contained in the ore are rejected with the gangue to the non- magnetic tailings. The metallic iron products illustrated in this work contained 89 to 96 percent total iron, one to five percent TiO2, 0.2 to one percent MnO, 0.3 to 1.6 percent Cr2O3 and/or up to one percent alkaline metal sulfide. Usually only one of these components was present. Recoveries ranged from 80 to 96 percent of the iron in ore.

Jan 1, 1958

By Charles F. Stack

The A. P. Green Refractories Co. operates clay mines in ten states. Eight of these states have reclamation laws with which we have to comply and indications are that the U. S. Congress will pass a federal surface mining reclamation act in the near future. These regulations, in addition to the value of land in most areas, dictate that mining and reclamation be considered as a single operation. In many instances the land may be more valuable after properly planned mining and reclamation than before. Refractory clay, commonly called "fire clay" is defined as a siliceous clay rich in hydrous aluminum silicates, capable of withstanding high temperatures. It is deficient in iron, calcium, and alkalies and approaches kaolin on composition. Refractory clay is much more limited in occurrence and usage than common clay or shale. During 1971, common clays and shales were mined in 47 states with a total production of 45 million tons. Fire clay production was reported in 22 states with a total production of only slightly over 3 million tons.(1) Many of these producing areas are extremely limited in extent and production. Several are contained within a one or two county area. This reflects the unique geological conditions required for the formation or development of fire clay. The major fire clay producing areas in the United States are shown in Figure 1.

Jan 1, 1974

By M. Karmis

According to international projections and future energy scenarios, coal will continue to be a prominent fuel for the next 25 years. In fact, in many regions around the world, coal is expected to dominate the electricity sector until the year 2030. At the same time, with instability and volatility of oil prices, coal is also positioned as an alternative feed stock for conversion into liquid fuels. Energy economists maintain that coal liquefaction is viable at crude oil prices of $35 or more per barrel. Depending on technology and coal composition, 1 ton of coal can produce 1 to 4 barrels of oil. Increased coal production and the expanded utilization of coal also raise environmental concerns regarding greenhouse gases and the problem of handling CO2. Carbon sequestration research, currently conducted in many parts of the world, has demonstrated considerable potential for C-storage in unminable coal seams. Such geologic storage, when possible, can also be integrated into an enhanced coal bed methane recovery process Can coal fuel power plants and industrial facilities, provide diesel and other liquids and, at the same, also be used as a medium for permanently storing CO2? This presentation will provide a global perspective on these questions and stress on the need to reconsider, or even redefine, coal as the fuel for the future.

Jan 1, 2006

By A. L. Mular

Steady-state material balances calculated from data measured at various locations around process units are useful for many purposes, such as metallurgical accounting, on-line control, and the development of mathematical models. Often it is possible to calculate material balances by several independent procedures when excess measurement information, i.e., redundant data, is available. Clearly, if the data were collected without measurement errors, a theoretical condition never found in practice, all material balances calculated from redundant data would be in agreement. The real situation is that error exists in practical measurements, so that the results of material balances determined from available optional procedures differ. Consequently, best fit computational procedures to improve the material balances by taking measurement errors into account have been formulated. Such procedures can be used also to judge whether measurements are grossly in error due to either faulty observations or defective data sensing devices. A variety of mathematical techniques are available which serve to adjust raw data. The adjusted data permit mass balancing that does not depend on the computational method. To illustrate the need for an adjustment procedure, Table 1 shows a raw data set acquired around the Brenda Mines Ltd. No. 4 grinding circuit shown schematically in Fig. 1. At least seven optional ways to calculate a circulating load ratio may be employed. These are shown in Table 2 where, depending upon the calculation [ ]

Jan 1, 1979

By Kenneth R. Ware

I INTRODUCTION The Washington Metropolitan Area Transit Authorities (WMATA) rapid transit system (METRO), currently under construction, will have a total length of 98 miles. Forty-eight of these miles are underground and require either open cut excavations or tunnels. Despite stringent construction controls, it is inevitable that some ground settlement will occur adjacent to the deep open cut earth excavations and large diameter earth tunnels. It is therefore essential to underpin nearby important structures to prevent excessive differential settlements and Fig. 1 presents the METRO criteria for this underpinning. This paper describes the underpinning methods currently used on METRO and evaluates the effectiveness of each method. II DESCRIPTION OF SUBSURFACE STRATA The foundation materials in the Washington, D.C. area are extremely variable. Fig. 2 presents an idealized profile showing typical subsurface strata. The engineering properties of each stratum have been determined by extensive exploration and testing programs. Fill: Washington, D.C. fills consist of every variety of soil and rubble. They are not important to this study because no underpinning is founded on fill material. Terrace Deposits: Formed in outwash plains during the glacier period, these deposits are composed of random layers of either sand 1 The writings and opinions expressed herein are solely those of the author and do not necessarily reflect those of WMATA.

Jan 1, 1974