Search Documents

By Richard A. Brown

The direct precipitation of uranium with hydrogen peroxide has been known since 1877. Commercial use of the process began in the 1960's. During 1967 the Bureau of Mines assisted the Climax Uranium Co., Grand Junction, Colorado in the development of a uranyl peroxide precipitation process to control a molybdenum impurity problem (1). Atlas Minerals, Moab, Utah has used hydrogen peroxide to control vanadium and sodium levels in their uranium concentrates since 1969 (2). Recently, the use of hydrogen peroxide by the uranium industry has grown, particularly since the increased demand for uranium has led to the processing of low grade ores. Impurities present in low grade ores can be concentrated with the uranium during milling and will substantially complicate the refining of uranium yellowcake concentrates. Consequently, commercial nuclear fuel processors have imposed stringent specifications and penalties to control these impurities. The ability to produce a pure uranium yellowcake can eliminate penalty or reprocessing costs. Hydrogen peroxide precipitation of uranium is specific and quantitative, producing a very high purity product.

Jan 1, 1980

By M. Yekeler

The critical surface tension of wetting values (Ye) of realgar (AsS), talc [Mg3si401o (OH) 2]' stibnite (Sb2S3), and sulfur (S) were determined by flotation in the absence of conventional flotation collectors as 38.7, 38.0, 35.5, and 30.0 dyne/cm, respectively. The surface tensions of flotation media were arranged by methanol. Separation of binary mixtures of these minerals was performed exploiting their Ye differences-which form the basis of the "ganuna flotation process". One step flotation test showed that sulfur floats preferentially from its mixtures with realgar and stibnite at recoveries of 73.6 and 70.7 % and grades of 81.7 and 91.2 %, respectively. The separation of stibnite from realgar gave a recovery of 4.1 % and a grade of 41.2 % for stibnite, indicate that a minimal Ye difference of 3.6±0.2 dyne/cm is essential for such separation when conventional flotation reagents are not used. This paper presents data and describes the approach employed in these separations.

Jan 1, 1994

By Mark S. Dunsbier, Steven J. Schatzel

Large roof outbursts began occurring in November 1986 at Domtar's Sifto Salt Mine in Goderich, Ontario, Canada, working the bedded Salina A-2 Salt unit. The outbursts, measuring about 13-20 m in diameter, released high concentrations of methane from cavities that extended into carbonate roof units. Spontaneous ignitions of methane gas during an outburst seriously burned a mine technician. The Canadian Ministry of Labour contacted the U.S. Bureau of Mines for technical assistance to aid in mine managements1 efforts in alleviating the problem. Initial gas content determinations of salt samples from the outbursts by acoustic test methodology revealed no methane enrichment. In- mine core drilling and subsequent methane content testing indicates the main source of methane in overlying roof units. Drilling the roof units demonstrated the potential of draining methane from areas showing signs of impending outbursting and alleviating the danger. Three mechanisms are considered the most likely means by which methane was introduced to the mine environment. These are (1) hydrocarbon gases released from brines, (2) gas transport along horizontal bedding planes or gas accumulations in bedding separations, and (3) mining-induced fracturing. The abundance of higher hydrocarbons in gas yielded by non-evaporite rock samples from the Goderich mine may be indicative of a former association with liquid petroleum.

Jan 1, 1989

By Legett Garrett

Texas Utilities Generating Company (TUGCo) surface mines lignite for use as a boiler fuel at mine mouth generation stations. Currently, the annual lignite production requirement of approximately 28 million tons necessitates mining across approximately 1,600 surface acres each year. The mining operations, located in Freestone, Panola, Titus, and Hopkins counties, Texas, have drastically disturbed some 13,000 surface acres to depths of up to 110 feet since initial startup in 1971. The TUGCo mining philosophy, a commitment made prior to initiation of mining operations and prior to any mining regulations, includes a return of mined-out land to private ownership in the most useful state possible. In the areas of TUGCo operations, the local economies are based upon agricultural production. Historic land use surveys have typically shown a trend from row crop production to pastureland for cattle production. During the 1960?s, the percentage of acreage devoted to row crop production approached zero with respect to the total acreage devoted to agriculture. TUGCo reclamation operations have therefore emphasized restoration of land to a state that is favorable to cattle production

Jan 1, 1982

By C. P. Lazzara, R. W. Pro, A. C. Smith

The U.S. Bureau of Mines conducted a study to evaluate the effectiveness of automatic water sprinkler systems in the extinguishment of incipient conveyor belt fires under ventilated conditions. Large-scale experiments were conducted using a double strand conveyor belt configuration. Standard response, pendent-type sprinklers, with activation temperatures of 100°C, were installed above and between the two strands of belting, in accordance with Federal standards for sprinkler system installations in belt drive areas. Experiments at airflows of 1.1 and 4.6 m/s showed that the sprinklers activated later, the peak heat release rate was larger, and more betting was consumed at the higher airflow. In experiments with 74°C, fast response, directional sprinklers, the sprinklers activated at the same heat release rate for both high and low airflows, but the peak heat release rate and amount of bett consumed was slightly higher at the lower airflow. Experiments were also conducted with 100 °C, standard pendent sprinklers installed above the top belt, in accordance with the National Fire Protection Association (NFPA) Standard 123 for sprinkler system installations in conveyor belt drive areas in underground coal mines. In these experiments, the heat release rate and amount of betting consumed was larger at the higher airflow.

Jan 1, 1995

By Frank E. Kottlowski

Widespread high-calcium (HC) limestones in New Mexico and adjoining areas, are low in magnesium, but some units include shale interbeds that would be deleterious for usage in sulfur removal. In southwest New Mexico, southeast Arizona, and adjoining parts of Mexico, limestones in the thick Mississippian Escabrosa, Pennsylvanian-Permian Horquilla, and Cretaceous U-Bar units are HC as are strata in the Mississippian Lake Valley, Pennsylvanian formations, Permian Hueco, and parts of the Permian Capitan Limestone of south-central and southeast New Mexico and west Texas. In north-central and central New Mexico, many limestones in the Pennsylvanian Madera Formation are HC as are some of the Cenozoic travertines. In northwest New Mexico, where the present-day mine-mouth coal- fired power plants occur, there are no HC limestones, but to the north in southwest Colorado some beds of the Mississippian Leadville Limestone and Pennsylvanian Hermosa Formations are HC. HC limestones considered contain at least 95 percent calcium carbonate and less than 3 to 5 percent magnesium carbonate. Limits for other impurities are alumina, 1 percent; silica, 2 percent; sulfur 0.05 percent; phosphorous, 0.02 percent; and iron oxide, about 1 percent. Chemical and physical requirements differ slightly depending upon the ultimate use.

Jan 1, 1995

By J. F. T. Agapito

Energy West Mining operates the Deer Creek and Cottonwood/Trail Mountain coal mines in the Wasatch Plateau about 40 km (25 miles) southwest of Price, UT. The Deer Creek Mine extracts the Upper Blind Canyon seam and the Cottonwood/Trail Mountain Mine extracts the Hiawatha seam 12 to 36 m (40 to 120 ft) below. Both seams average about 2.8 m (9 ft) in thickness. Cover depths exceed 550 m (1,800 ft) in a large portion of the unmined reserve. Stability problems at Deer Creek are mostly due to coal bursts caused by high stresses associated with deep cover and sandstone channels. Most of the bursts have occurred in gate pillars and, to a lesser extent, at the longwall face and during development. The introduction of a two-entry gateroad system with 9-m- (30-ft-) wide yield pillars has been a major factor in controlling and minimizing gate pillar [ ] bursts (Agapito et al., 1988). However, some bursting began to occur in the 9-m- (30-ft-) wide pillars as cover depths reached 550 to 610 m (1,800 to 2,000 ft). This was due to more rapid and higher abutment loading in areas with very strong roof and stiff floor.

Jan 1, 1997

Traditional fine-grinding mills in mineral processing rely on the use of steel medium for particle size reduction. The IsaMill (a horizontal stirred mill with a 3, 000-L net chamber volume and a rated motor power of 1,120 kW) has successfully adopted a novel product-separator design, which has led to a major revision of medium use in fine grinding. The IsaMill separator has successfully operated with a wide variety of medium types, such as silica sands, river gravel, smelter slag, run-of-mine ore fractions and steel shots, with sizes ranging from 0.5 to 10 mm. Great flexibility in the IsaMill operations has been achieved for processing feed as coarse as 120 µm to a product as fine as 5 µm. This paper discusses the performance of two inert grinding media in the IsaMills that are used at Mount Isa Mines Ltd. for the processing of galena- and sphaleritebearing ores to below 10 µm. They are the copper reverberatory furnace slag (CRFS) and the heavy-medium plant rejects (HMPR). A methodology was also demonstrated for comparing the medium performance and for scaling up the IsaMills from a 1.5-L laboratory batch mill to a full-scale 3,000-L mill.

Jan 1, 2002

By Louis W. Cope

INTRODUCTION Various methods for sampling placer deposits have been mentioned by Wojcik in Chapter 2. Here, a brief description and comparison of these methods will be given as related to bulk versus drill sampling. The advantages and disadvantages inherent to each will also be given. The means of sampling can be grouped into bulk or drill samples. As a generality, drill samples over a five-foot length will run from I/,, to 1 /, cubic yard, depending on the diameter of the drive shoe on the drill casing. Bulk samples can be expected to be in the range from one to many cubic yards each. SAMPLE METHODS Bulk Bulldozer-dug trenches and dozer or front-end loader pits are two methods to excavate large bulk samples. Smaller bulk samples can be obtained by digging small dimension shafts through the deposit, by hand or caisson-like drills. It is not recommended to split samples by alternate bucket-loads or by other means, as the effect of a nugget falling into one or the other fraction will seriously alter the sample.

Jan 1, 1992

By William H. Dresher

World trade has increased significantly during the last quarter century. However, a new rational for protectionism is emerging which argues for the restriction of trade as a means of preserving and protecting the environment. Fearing lower environmental standards in the Third World, environmentalists are calling for new trade barriers between the developed countries and the developing countries to combat what they see as "eco-dumping." The "greening" of protectionism and the merging of environmental standards into international trade agreements could fundamentally change the world trading system as well as seriously impact the availability of raw materials to provide for the needs of the peoples in both the developing and the developed worlds. This discussion will deal with the agreements and regulations that promise to influence the trans boundary shipment and recycling of scrap metals and wastes containing metals and their projected impact on world trade and metal prices. Emphasis will be placed on the Base1 Convention, whose restrictions concerning trans boundary shipment of scrap metal and metal-containing wastes for recycling took effect on December 31, 1997.

Jan 1, 1998

By A. Unal

Coal resource characterization usually calls for estimating more than one variable over a block or node simultaneously. Within the realm of geostatistics, each variable has been evaluated independently from the others assuming a lack of significant correlation. Research conducted with coal seams, however, has shown that the variables of immediate interest, such as seam thickness, ash, sulfur content, and density depict some correlation schemes in distinct zones, if not throughout the entire area. The above findings have two immediate consequences : (1) correlation analyses provide guidelines to determine the geologically distinct zones, and (2) where possible, cokriging should be used instead of kriging. This will maximize data utilization decreasing the frequently criticized high estimation errors. The cokriging formulation will also provide more accurate estimates for under sampled variables using better-sampled ones. This is a common case with coal with regard to the non-cored reconnaissance drill holes for which only very few variables were recorded. A case study illustrates the improvements that may be obtained by taking advantage of the intervariable correlations.

Jan 1, 1986

By Leonhard Schmid

INTRODUCTION In the region of Zurich several of the Swiss Interstate Highways meet and have to be linked to form a continuous network. The subalpine glacial topography with hills, ridges and lakes requires the construction of many tunnels (Figure 1). The Milchbuck Tunnel forms part of the inner arterial highway system of the city of Zurich. It passes underneath the ridge separating the Limmat and Glatt valleys. In its final configuration the tunnel will consist of two parallel three-lane tunnels (Figure 2). For the time being only one tunnel is constructed. This tunnel will be operated with two outbound (climbing) lanes and a single inbound (descending) lane (Figure 3). The owner, the Canton of Zurich, awarded the contract for the construction to a joint venture with the following three contractors: Locher & Cie AG (leader), Prader AG, A. Brunner's Erben, all located in Zurich. The actual freezing was performed by subcontractor Philipp Holzmann AG, Mannheim, West Germany. Electrowatt Engineering Services Ltd, Zurich, was design engineer and performed the construction supervision.

Jan 1, 1981

By J. R. Dillon

Today more than ever, there is an increased demand for higher plant production capacities and efficiencies to offset the increasing costs for labor and materials. Plants involved in processing large volumes of bulk materials are particularly interested in more efficient material handling systems to (1) reduce labor and maintenance costs, (2) improve blending of non-uniform raw material feed to processing facilities, (3) improve blending of finished bulk materials from storage. DragScraper systems are being used effectively for handling a variety of bulk materials in both indoor and outdoor storage. Materials being handled include ores, chemicals, coke, clay, and stone, to name a few. Handling capacities these machines can provide vary from a few tons to over 1500 tons per hour. The basic components of a DragScraper machine consist of a bottomless Crescent scraper, a two or three-drum DragScraper hoist assembly including gas, diesel, or electric power unit, operating cables, guide blocks, and either fixed or mobile head and tail structures. They are presently available in sizes through 15 cubic yards, for operating spans up to 1000 feet.

Jan 1, 1969

By Alan Fricker, Bill Owers

Cyprus Gold NZ Ltd will be recovering residual cyanide from their CIT, operation in New Zealand. The process will use air to strip the cyanide from the acidified barren pulp. DSffi. Industrial Development, who were involved in the bench and pilot studies for Cyprus, have extended the concept to pregnant pulp. The stripping of pregnant pulp eliminates the substantial loss of cyanide through carbon catalysed oxidation during the adsorption stage. A 50% increase in cyanide recovery was obtained from an extensive laboratory investigation. The presence of a cyanide recovery circuit enables leaching to be conducted, without detriment, at pHs at least as low as 9, with consequential 50% reductions in the consumption of lime and sulphuric acid. There should be a small reduction in carbon consumption, and a significant improvement in the quality of the final effiuent, at least in terms of cyanide, cyanates, copper, zinc and sulphur. A small but significant increase in gold recovery can be expected too. There is a net economic advantage of NZ$1.20/tonne of ore by stripping pregnant rather than barren pulp.

Jan 1, 1990

By William B. Thayer, James H. Meinholz

The Milwaukee Metropolitan Sewerage District (MMSD) has been working since mid-1977 on a fast track to meet a court-imposed schedule to rehabilitate a large wastewater collection and treatment system at an estimated cost of $1.7 billion. Because of glaciation, the Milwaukee area has an extremely complex geologic environment. The rock surface ranges from outcroppings in the northern and western parts of the area to 76 m (250 ft) below the surface at the mouth of the Milwaukee and Menomonee Rivers. Bedrock beneath the glacial mantle is a thick sequence of early to middle Paleozoic sedimentary rock. To cope with the many complexities of this large public works project, a Program Management Office (PMO) concept has been employed. A Geotechnical Engineering Group was established within the PMO to provide a continuous , unified approach to geotechnical engineering and full disclosure of all geotechnical information in the construction contract documents. It provides qeotechnical engineering to design and construction, develops and maintains a qeotechnical data base, and participates on the claims resource team.

Jan 1, 1983

By M. R. Yalamanchili, W. H. Jang, Y. Ye, J. D. Miller

Typically, rougher molybdenite flotation and recovery from bulk copper/molybdenum concentrates involves the use of alkalisulfides, Nokes reagents, cyanides, oxidants, and/or thermal treatment to depress copper sulfide minerals. The bulk copper/molybdenum feed generally varies from 0.2% Mo to 1.0% Mo, and with traditional reagents the single-stage rougher flotation recovery of molybdenite varies between 40% and 90% at a concentrate grade of 5% to 10% Mo. With ozone conditioning for copper depression, however, improved separations appear to be possible, as demonstrated by tests with Cu/Mo concentrates from both the Phelps Dodge Morenci Operations and the Kennecott Copperton Operations. Single-stage rougher flotation after ozone conditioning can provide a molybdenum concentrate at a recovery of more than 90% and a rougher concentrate grade higher than 20% Mo in some cases. Subsequent cleaner flotation with additional ozone conditioning resuIts in relatively copper-free molybdenum concentrates containing as much as 52% Mo. Preliminary analysis indicates that, with a multistage ozone conditioning/fotation strategy, the process is technically and economically viable and should be suitable for industrial ap¬plication.

Jan 1, 1991

By D. V. Professor Keller

The production of premium coal-based fuels (<3% ash) and ultra clean coals (<1% ash) using the process of selective agglomeration requires proper selection of raw coal, rough preparation procedures, milling equipment, product coal size distribution, water purity, agglomerants, agglomeration equipment and operational procedures. Each of the variables can contribute a small fraction to the impurity load in the product coal or limit the ability of the process to separate mineral matter-free coal. Each of the variables and their importance will be examined from data produced at the bench by batch and continuous agglomeratons as well as the results from pilot plant and tonnage production units. The results are discussed which have indicated that some standard commercial coals can be produced with ash contents as low as 0.2 % ash (batch/bench) and several tonnage lots of 0.6% ash in as 200 lb/hr pilot plant. In most cases iron pyrite released from the coal matrix and with proper pH control is rejected from the product coal agglomerates.

Jan 1, 1995

By David Oliveira

"INTRODUCTIONOne of the key drivers for the selection of a mechanized tunneling method in good quality rock masses is a good excavation advance rate. In order to achieve satisfactory advance rates, a good geotechnical performance of the rock grippers in main beam open tunnel boring machines (TBM) is required, besides other factors related to ground support and the performance of the cutter head.One well known potential issue of main beam gripper TBM is associated with the bearing capacity of the tunnel side walls while crossing fault zones or poor rock masses in general. Such a mechanism is similar to that of footings on rock and perhaps the most common problem associated with gripper performance. Depending on the quality of the rock, the rock under the gripper contact may experience significant damage and crushing (Figure 1), eventually affecting the TBM advance rate due to a lack of tunnel wall reaction/support. Such a mechanism is primarily dependent on rock quality, applied loads and gripper size.In the case of large diameter TBMs (e.g., D > 12 m), a second potential failure mechanism may arise associated with the loss of confinement within a rock pillar between twin tunnels, even in good quality rock but particularly in bedded sedimentary strata. Punching of the rock pillar may develop due to excessive shear along bedding partings and sub-vertical joints (Figure 2), particularly under a low stress environment. As a result, this mechanism is dependent on both the rock pillar width between twin tunnels and stress conditions around the tunnels, in addition to the previous factors described for the first failure mechanism."

Jan 1, 2016

By T. K. McCranie, A. H. Tousley, A. H. Kackman, L. R. Gregory, A. Jr. McElrath, R. J. Krekel

In Roman and earlier civilizations the term cement was applied only to mixtures of lime, pozzolana, sand, water, etc., used as a mortar to bind larger stones. Today, portland cement, the subject of this section, can be briefly defined as follows: The product obtained by finely grinding clinker produced by calcining to incipient fusion (i.e., sintering) an intimate and properly proportioned mixture of argillaceous and calcareous materials. History The Egyptians were probably the first to join building stones with a mixture of sand and a cementitious material (i.e., having the property of or acting like cement). It is generally accepted that the cement used by the Egyptians on such structures as the Great Pyramid was calcined gypsum, Later the Greeks began to calcine limestone for use as a mortar with sand and water. Still later, broken brick and tile were added to the mortar to make the first concrete. The Greeks and Romans found that some sands produced mortars that were especially resistant to the action of water. Hydraulic (i.e., underwater-hardening) cements formed by combining slaked lime, water, and finely divided siliceous materials (e.g., pozzolana) possess superior strength and are capable of resisting the destructive action of water. They were used on the Pantheon, Colosseum, and other structures, some of which are still standing. In 1756 an English engineer, John Smeaton, found that an argillaceous limestone (i.e., containing an appreciable amount of clay as an impurity) produced a cement with greater resistance to the action of water. Despite Smeaton&apos;s findings, the use of the old mixture of lime and pozzolana long retained its popularity. Significant contributions in cement technology from England, Swe¬den, France, and Holland were made in the next 68 years. However, the invention of portland cement is generally credited to Joseph Aspdin, an Englishman, who in 1824 patented "portland cement." The name was selected because, on hardening, it resembled the natural building stone from the Isle of Portland, England. The patent features mixing ground limestone and argillaceous materials in appropriate proportions and calcining (i.e., expelling CO2 by roasting) the mixture. This superseded the existing practice of calcining naturally occurring argillaceous limestone. In about 1845 Isaac Johnson, also English, conducted experiments on proportioning the components and calcining them at higher tem¬peratures. His accomplishments are accepted as the beginning of the present-day portland cement industry. The U.S. cement industry originated with the demand for good hydraulic cement for building structures such as the Erie Canal, which was started in 1817. The first discovery of cement rock (i.e., naturally occurring argillaceous limestone with near-optimum ratios of calcium carbonate, alumina, and silica) near Fayetteville, N.Y., was made by C. White. In 1818, White secured a patent for the manufacture of natural cement from that deposit. Subsequently, several natural cement plants were built in 1830-1840 at Rosendale, N.Y., and in the Lehigh Valley of Pennsylvania. David Saylor, who participated in establishing a natural cement plant at Coplay, Pa., in 1850 discovered that a superior cement could be produced by calcining the rock at higher temperatures than hith¬erto. In 1871, Saylor obtained a patent and commenced the manufac¬ture of portland cement. By 1890, there were 17 portland cement plants in the United States with a combined annual output of 62,300 tons. At the end of 1970, the number of plants producing portland cement in the United States (including Puerto Rico) was 169, down from a maximum of 185 in 1967, with total annual shipments of 73.4 million tons valued at $1,298 million. (Fig. 1). In 1970, annual world production of hydraulic cement (which includes pozzolanic materials, hydraulic limes, natural cement, alumina cement, and portland cement, all of which are in current use in various parts of the world) reached 630 million tons (Table 1). Flowsheets of typical U.S. cement plants are shown in Chapter 13. Chemical Composition and Physical Properties It is generally accepted that portland cement clinker consists of a mixture of compounds or synthetic minerals. The four principal compounds are:

Jan 1, 1985

By G. Wayne Clough

During shallow tunneling in an urban environment, deposits or pockets of saturated soil or fractured, weathered rock are often encountered. Under such conditions, special problems with tunnel support, underpinning of structures adjacent to the tunneling, and/or flow of groundwater into the tunnel occur. If the ground conditions are appropriate, i.e., the soil is sandy, silty or fissured, or the rock is weathered or fractured, the solution to these tunneling problems may be chemical stabilization of the ground. Injection stabilization as an aid to tunneling is practiced extensively in Europe and its use is increasing in the U.S. The advantages of this technique over conventional solutions can be substantial in terms of cost and time, especially in mechanized tunnel boring where even a small zone of soft ground can bring the tunneling to a complete halt. In this paper European practice in using chemical ground stabilization for urban tunneling will be reviewed. In contrast to previous papers which have dealt with specific applications (1,5,8,9) this paper will broadly cover the subject, addressing itself to grouting techniques, costs, the reasons for grouting, philosophy of the users towards grouting, design of grouting solutions (or lack thereof) and methods of quality control. Differences with U.S. grouting practice are also noted. The information presented is derived from several visits to Europe, discussions with European and U.S. grouting personnel, and the available literature (2). The author&apos;s most recent European trip was made under the auspices of the U.S. Department of Transportation in conjunction with a research study being performed at Stanford University; a detailed report of this visit is available in reference (6).

Jan 1, 1976