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By Ruirui Wei, Yanhui Liu, Fangqing Yin, Meilong Hu

In China, Basic Oxygen Furnace (BOF) slag is traditionally used as an aggregate for civil engineering, for road engineering and fertilizer. In order to make full use of BOF slag, the experiments of BOF slag with high temperature roasting has been carried out and the phase transformation is studied. The BOF slag from Chongqing Iron & Steel is roasted in the electric muffle furnace at three different temperature. The influences of the high temperature roasting on change the phase composition of BOF slag was characterized by XRD. The results revealed that SFCA was produced at the high temperature in air atmosphere and melting temperature of slag was lowered. Therefore, if the BOF slag which treated by roasting was utilized in the sintering process, it is advantageous to improve the sintering strength and the formation of the liquid phase and reduce fuel consumption in the sintering production process.

Jan 1, 2015

By Ullrich Kammer

Metaleurop's secondary lead smelter at Oker produces 60.000 mtpy of lead and lead alloys. More than 8O2 % of the raw materials are spent lead acid batteries. The other 2O2 % consists of drosses, ashes, scrap lead, type metal, sludges, etc., and is processed in a short rotary furnace (SRF). Also, industrial batteries not fitting in the battery scrap treatment plant are processed in the SRF provided with gas/oxygen-burner. Till Sept. 199O2, a soda ash slag was used in the SRF-smelting similar to the rotary kiln-smelting at Oker. Facing the future problems of handling and dumping soda ash slag, Harz-Metall GmbH has improved SRF-smelting with a non¬hazardous slag, insoluble in water, easy to dump and cheap in fluxes. This slag is based on a CaO-SiO2 -Fe0-type. Aim of the slag smelting is to be within the temperature range of 2 1100° and 1200°C - the eutectic line of Olivine in the corresponding ternary system. Since Sept. 199O2 Harz-Metall GmbH has operated the SRF with an "Olivine-type slag" with good results. Although the material is a "leady" slag. HMG is optimistic of using it as a filling material for construction purposes.

Jan 1, 1993

By G. Diáz

The PLACID process applied to the recycling of spent lead-acid batteries is being developed by an European Consortium within the Brite-Euram II programme. The status of the project entitled "Lead Recovery from Lead Oxide Secondaries" is described in this paper. The main laboratory and batch experimental results and the preliminary feasibility study are summarised. The description of the demonstration pilot plant and continuous campaigns programme for 1995 are also included. An interesting global approach is proposed, integrating the Placid process in the existing spent battery recycling pyrometallurgical facilities. This yields important improvements in the overall process. Grids would be easily treated by the conventional pyrometallurgical route, obtaining lead alloys,, while battery pastes, slags and fumes would be fed to the Placid process, obtaining pure electrolytic lead (>99.99 %), ideal for battery paste manufacturing. The implementation of the Placid process into the existing battery recycling pyrometallurgical facilities is analyzed from technical, environmental and economical viewpoints. Greater overall lead recovery, lower operating costs, reduced waste production, environmentally safer residues and much better lead product quality are the key advantages. The authors draw the following final conclusion : Integration of the Placid process with conventional pyrometallurgical treatment is a feasible and very attractive alternative route for spent lead-acid battery recycling.

Jan 1, 1995

By Frank R. A. Jorgensen

Flash smelting is used to smelt a large proportion of the world's copper and nickel and some lead/zinc concentrates. Understanding the factors controlling the ignition of these concentrates is an important consideration in designing burners and maximising the throughput of the flash smelting process. The literature on the subject is briefly reviewed and techniques for the measurement of ignition temperature discussed. The mineralogy of the concentrates and the role of thermodynamics and phase diagrams in interpreting and predicting ignition behaviour are emphasised and applied to interpreting results obtained on a nickel concentrate.

Jan 1, 2002

By Heikki Jalkanen

Oxygen converting of hot metal (LD/BOF) is contemplated as an object of simulation. Oxygen converting is a highly complex thermo-chemical process comprising a series of matter and energy transformation and transportation steps that makes the simulation very challenging. The basic principles of CONSIM 5 oxygen converter simulator are presented. Simulator is a comprehensive combination of a physical model with several empirical submodels describing all properties and processes that affect the final result of a converter blow, final mass and composition of steel, slag, dust and converter gas as well as the end temperature of steel. CONSIM simulator is used for simulation of series of high and low carbon steel blows. Simulated steel temperatures, oxygen consumption, blow time and iron oxide content of slag are compared with measured values. Problems of simulation and requirements for quantitative simulation of oxygen converter process are discussed.

Jan 1, 2006

By Huang Rui

The coal asphalt is combusted at different temperature in a heating cabinet with the temperature limit by 1200°C. By comparing the mass of the remainder of each experiment, the completely combusting temperature of asphalt smoke can be determined. Based on the experimental process of asphalt smoke, a discrete mathematical model of the asphalt smoke combustion is set by theoretic analysis. Through computer programming, the dynamic combustion process of asphalt smoke is calculated to simulate the experimental model. The result of experiment shows that coal asphalt can mostly react upon 500°C and the mass of remainder is 49.41% to initial mass of sample in the condition. The computing result shows that the temperature and the concentration of asphalt smoke influence its burning temperature approximating linearity. The consumed quantity of fuel to ignite the asphalt smoke needs be considered with the two factors.

Jan 1, 2006

By Toru Taniguchi

In the Mitsubishi smelting furnace, copper concentrate, silica sand and water granulated slag from the converting furnace are injected through the process lances, together with oxygen enriched air, into the melt. Because bath smelting is used, the rates of particles/melt and gas/melt reactions are high enough and therefore tine grinding of the solid materials is' not necessary. Among these reactions, the dissolution rate of silica sand is the slowest and limits the overall reactions in the smelting furnace. Information on the dissolution rate of silica sand plays an important role for design of a new furnace. Theoretical calculations of the dissolution rate .of silica particles have been reported elsewhere. The authors conducted cold model experiments and could verify the calculation. In this paper, the dependence of dissolution rates of particles on the gas blowing rate, particle size and solid penetration depth in the bath is discussed.

Jan 1, 2002

By J. Tang

The major problem with the Nd-Fe-B magnet is its low operating temperature, i.e., the coercivity decreases so rapidly with increasing temperature that the practical maximum operating temperature-is only 100 °C. Meanwhile, it has been reported that nitrogen addition can drastically increase the Curie temperature of both R2Fe17 and RTiFe11 (R = rare earths). A reasonable question is, then, can one see a similar effect in Nd-Fe-B system? Experiments have been conducted to examine how magnetic properties of Nd-Fe-B magnet are affected by the nitrogen addition. Our results show that part of Nd2Fe14B maintains its original crystal structure and no substantial change in To, due to such N2 treatment is found. However, part of the sample decomposes into a-Fe and, possibly, Nd nitride as a result of nitrogen treatment.

Jan 1, 1992

By J. C. Riani

The release of heavy metals into the environment is increasing among others due to human activities such paint and pigment industries, tanneries, and metal finishing industries. Among metal releases, chromium is notable because this metal is carcinogenic. Thus, the aim of this work is to use an ion exchange system composed of one cationic resin column and one anionic resin column in order to adsorb the chromium (III, VI) from chromium electroplating effluents with the objective of recycling the water. The methodology consists of chromium adsorption tests using the ion exchange resins system with Purolite the 850 (polystyrene matrix, functional group quaternary amine) and Purolite C 150 (polystyrene matrix, functional group sulfonic acid). The contaminated solutions were passed through the columns with the assistance of peristaltic pump. Samples of the outgoing solution were taken in order to control the conductivity and pH and analyze the metals. The effects of the feeding outflow on the chromium adsorption were evaluated. The results show that the quality of the water collected at the end of the process is within the Brazilian standards about the discarding of toxic substances in the environment (CONAMA 357/05). This makes possible the recycling of water into the process and also its discharge in the rivers.

Jan 1, 2006

By Frank Field, Randolph Kirchain, Elisa Alonso, Richard Roth, Nathan Fleming

"High material prices and price uncertainty can be harmful to manufacturing firms. Increased use of recycled materials, industry-wide, can lower both material prices and price variability; moreover, increased recycling decreases the use of primary material, which mitigates price increases due to scarcity effects. These stabilizing and price lowering effects are explored using an Aluminum industry model. We show that (a) increased recycling leads to smaller price fluctuations in the presence of a primary metal supply perturbation, and (b) that the more substitutable the secondary metal is for the primary metal, the lower the overall material price is.IntroductionThe price of an industrial metal is expected to be a function of both the marginal cost of extraction and its scarcity[l-2]: where scarcity can be defined as the degree to which anticipated demand exceeds the known supply. Recycling end-of-life metal increases the apparent supply of the metal, or-in a functionally equivalent, but alternative conception-lowers the demand for primary metal; this lowers primary metal scarcity and should, theoretically, reduce its price. To the extent that this theoretical prediction holds true, recycling can provide benefits to consumers of industrial metals in the form of lower prices.Using a platinum industry model, prior work by Alonso[3] has shown that increased industrywide recycling can reduce metal price volatility because the secondary metal production (a) offsets virgin metal depletion, and (b) responds to supply-demand balance fluctuations more rapidly than the primary market. However, Platinum is not a typical industrial metal in the sense that secondary metal is perfectly substitutable for primary metal: Both primary and secondary platinum metal are functionally equivalent and have a common price. Other metals, such as secondary aluminum which is used as an example case in this study, contain varying degrees of other elements that were either intentionally added, or were inadvertently mixed in with the metal during the scrap recovery process. Consequently, different grades of scrap exist that have different profiles of elements in their composition. Depending on their particular profile of elements, more or less of a given grade can be used as a mass fraction of the final alloy-the secondary metal is not perfectly substitutable for the primary metal. For the purposes of this paper, the aluminum mass fraction of the final alloy that can be made up of secondary aluminum is termed the secondary substitutability of that grade in that alloy."

Jan 1, 2011

By Vinay Kumar, Jae-Chun Lee, Abhishek Kumar, Manis Kumar Jha

However, India is rich in ores and mineral, but E-waste recycling is necessary due to the report of national and international studies, which cautioned on the generation, treatment and accumulation of e-waste in India. Current data indicate that the total domestic e-waste generation including imports is around 382979 MT, however waste available for recycling and actually recycled are 144143 MT and 19000 MT, respectively. In which recycling by non-formal and formal sector are 95% and 5%, respectively. On the other hand, India has developed expertise in handling verities of metallic wastes in an organized and safe manner. The development of individual process or combined processes for handling the e-waste is underway. Eco- friendly and energy-saving processes are necessary to comply with stringent environmental regulations. The paper includes the recent trend of e-waste generation, recycling process and its future prospects particularly in India.

Jan 1, 2011

By Dao Su, Kelang Mu, Yufeng Guo, Jinghua Zeng, Tao Jiang

"The influence of high pressure roller grinding (HPRG) on sintering of iron concentrate fines was investigated. Results of mini-sintering tests showed that assimilation temperature of iron concentrate fines decreased from 1230 ? to 1220 ? and assimilation time was shortened from 10 min to 5 min when the iron concentrate fines was pretreated by HPRG. Sinter pot tests showed that the yield of sinter increased from 60.33% to 72.92% , tumble index increased from 44.35% to 46.66%. The investigation indicated that, after being pretreated by HPRG, iron concentrate fines are improved in ballability and the fraction of fine particles increased, resulting in the improvement of granulation property and reactiveness in solid state reaction. As a result, sintering of iron concentrate fines were strengthened.IntroductionWith the rapid development of iron and steel industry and the decrease of high-grade ores, the imports of iron ore are increasing continually. It is of immensely strategic importance for development of iron and steel industry and energy security in our country to make good use of iron concentrate fine which is low price, high grade and has a refractory sintering property. When iron concentrate fine is used in sintering, granulation property of sinter mixture and permeability of sinter bed get poor. As a result, yield and quality of sinter fall down. Many researches show that, when HPRG is used in pelletization, quality of pellets is improved dramatically. Meanwhile, HPRG has a low energy consume, a large handing capacity and it is benefit for environment protect. At this theme, strengthening of sintering of iron concentrate fine pretreated by HPRG was investigated in this paper."

Jan 1, 2012

By Zhiqiang Han, Anil K. Sachdev, Baicheng Liu, Guomin Han, Alan A. Luo

The growth of precipitate phase ,B-Mg11Al12 in Mg-Al alloy is closely related to interface anisotropy and elastic interaction. The aim of this work is to investigate the effects of the interface anisotropy and elastic interaction on the morphology evolution and growth kinetics of the precipitate. In the work, the precipitation of ,B was studied using phase field modeling. In the model, the chemical free energy of the precipitate and the matrix were obtained via thermodynamic calculation. It is demonstrated that the interface anisotropy results in lath-shaped precipitate and the elastic interaction affects the shape of the end of the precipitate. The interface anisotropy causes uneven growth in different directions and the elastic interaction influences its preferential growth orientation. By combining the interface anisotropy and elastic interaction in the phase field modeling, the results showed that the precipitate phase has a lath-shape with lozenge ends, which is in agreement with experimental observations.

Jan 1, 2013

By D. Georgiou

Direct sulphuric acid leaching of nickeliferous limonites is the process of choice to recover nickel and cobalt from equatorially located lateritic ores. These ores are rich-in-iron (-45 wt%) existing in the form of goethite enriched with nickel. The merit of this process is due to its high nickel selectivity because of simultaneous iron separation and acid regeneration. Under acid leaching conditions (-250 to 270°C) iron follows an acid dissolution-hydrolytic precipitation path yielding a very low concentration level depending on temperature and acidity of the final leach liquor. The primary precipitation product of iron is hematite which also forms as a scale on reactor internals along with co-existing aluminum. In this paper, an overview of the behaviour of iron solid products under process conditions is made. The evolution of goethite to hematite transformation, as well as the role of iron in reactor scale production, are studied using SEM/EDX characterization techniques.

Jan 1, 1995

By S. Redik, C. Wenzl, D. Gregurek, A. Spanring

Zinc is a component of many input materials used in various pyrometallurgical processes, for example primary lead and zinc production from Pb/Zn ores and recycling processes dealing with zinc-containing residues (e.g., copper recycling, WAELZ process). Hence, zinc and its compounds are present in the respective metallurgical vessels and interact with the refractory lining. In the present work the zinc attack on the refractories out of various primary and secondary furnaces is briefly introduced and discussed. At the prevailing processing temperatures in the metallurgical vessels, zinc oxide is highly corrosive for the brick components. The knowledge of the wear behavior is based not only on a detailed chemical and mineralogical characterization carried out on provided post mortem samples, but also on FactSage calculations. This together with results obtained by practical testing in the RHI pilot plant represents an important prerequisite for product development and brick selection for the individual customer application.

Jan 1, 2016

By Mao Chen, Baojun Zhao, Zhixiang Cui, Leonel Contreras

Viscosity is one of the important physiochemical properties of metallurgical slags which is important for slag tapping, metal loss in slag, freeze lining and fluid dynamics. High temperature viscosity measurements are time- and cost-consuming and the number of experiments is limited. Viscosity model is an effective way to predict the viscosities of the complex slags at high temperature. However, a reliable viscosity model can only be developed on the base of accurate experimental data. A unique high-temperature viscosity measurement apparatus developed at The University of Queensland enabled accurate viscosity data to be measured for the “FeO”-SiO2-CaO-MgO-Al2O3 system in equilibrium with Fe. An accurate viscosity model has been developed based on Eyring’s theory and extensive viscosity measurements. The viscosities of copper smelting, converting and cleaning slags over a wide range of compositions and temperatures can be predicted and applied in the process control.

Jan 1, 2016

By Sharon L. Eyer

"FTIR spectroscopy is employed to define mineable ore deposits based on exploration samples. The RAMBO (Robotic Assessment of Mineable Bauxite Ore) technology is operating successfully at an alumina refinery in K winana, Australia, for assessment of a number of critical ore attributes including available alumina, extractable organic carbon and total iron. Classical methods of analyses for these properties require laboratory-scale digestion of alumina ore (bauxite) or XRF analyses.Multivariate calibration is used in the RAMBO system to generate robust mathematical models that are able to estimate classical data from FTIR spectral data. Furthermore the models can highlight regions of ore that are relatively unusual. Unusual ore may be investigated for potential impacts on refinery processes well in advance of mining.The components of the technology are described and some results for an example application (bauxite) are presented. Challenges and difficulties are discussed. The potential to apply the technique to process control is introduced."

Jan 1, 1999

By José Roberto de Oliveira

Based on literature review one can see that the main objectives of MnO reduction is the comprehension of slag interactions and reactions with other elements beyond carbon. That's because it is worthwhile to study pure MnO reduction, where there will be not oxides interaction and just carbon will be the reduction agent. By a thermodynamic analysis we know that Si can react with MnO, then it's important to study this influence, so as Mn content. Our work aims to develop kinetics parameters for the MnO reduction, varying Mn and Si contents in bath. This has been given by pressure measure of CO in a Fe-C bath. The CO is generated by the oxide reduction with carbon. It has been proved that: - Mn content decreases the MnO reduction; - the MnO reduction is mainly influenced by Si content in a bath containing Iron, Carbon and Manganese so as Silicium

Jan 1, 1997

By Junji Shibata

Through-hole copper plating is performed to make a multi-layer printed circuit board. The through hole plating is first carried out by Pd catalyst treatment, followed by copper non-electric plating. The amount of Pd catalyst used in one plant is about 0.25-2 m3/month (8 g/dm3 PdCl2 base) depending on the plant scale, and the cost of the catalyst reaches 17,000¬I35,000 US$/month. In this study, the flow and material balance of a Pd in Pd catalyst treatment process was investigated. About 60% of Pd catalyst adheres on the through-hole and other part of setup, while 25% is released into the washing liquor. Pd in the washing liquor should be collected by a suitable method like a pressure filtration using diatomite. The material balance of Pd in Pd catalyst treatment process and the recovery method of Pd from waste solution containing Pd catalyst was investigated.

Jan 1, 2003

By K. L. Hardee

A recent development has emerged which produces a retrofittable, low cost anode by attaching disposable, electrocatalytically active titanium mesh over the existing lead anodes. The coated titanium mesh anode operates at potentials of several hundred millivolts lower than the lead anode, providing significant power savings. The exposed lead surfaces are stabilized since most of the current flows through the titanium mesh. With the minimal lead corrosion, the sludge formation is virtually eliminated and the purity of the plated copper is greatly enhanced. Further savings may be realized by the elimination of non-essential chemicals such as cobalt. Since the combination anode is stable and uniform, the plated copper is also more uniform with minimal formation of dendrites, reducing the shorting. Full-size anodes have been tested for over 6 months in commercial copper electrowinning cells. The laboratory and field performance of the stabilized lead anode will be reviewed, including the voltage characteristics, the lead stability and the copper cathode purity.

Jan 1, 1999