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By Raquel Dei Agnoli

Membranas a base de polímeros perfluorosulfonados, como o Nafion® (DuPont), vêm sendo extensivamente usadas como membrana de troca protônica em células a combustível. Contudo, o elevado custo e a baixa condutividade em temperaturas superiores a 80oC restringem o uso destes dispositivos. Em opção ao uso da membrana Nafion®, membranas a base da blenda polindeno sulfonado/polifluoreto de vinilideno (SPInd/PVDF) foram desenvolvidas, investigando o efeito da composição na performance das membranas. As membranas foram produzidas por evaporação de solvente da solução dos polímeros precursores. As blendas foram caracterizadas por termogravimetria e calorimetria exploratória diferencial. A caracterização das membranas eletrólito envolveu medidas de grau de inchamento, capacidade de troca iônica e condutividade protônica. Foi possível observar que o PVDF confere boa resistência mecânica e aumento da estabilidade térmica das membranas. Membrana com 50% em peso de PVDF apresentou a maior condutividade protônica (1,89.10-3S.cm-1). Membranas de SPInd reforçadas com PVDF mostraram resultados promissores para uso como eletrólito em células a combustível.

Aug 17, 2017

By W. B. Evans, D. P. Taylor

"ANFO has two major disadvantages as an explosive low density and no water resistance. ANFO can be blended with more dense, water-resistant explosives to form ""Heavy ANFO"". The use of emulsion or slurry explosives as a matrix is an attempt to correct deficiencies on the basic ANFO while maintaining cost effectiveness.This paper will deal with four main topics.1. Product description, general properties, strengths and weaknesses.2. Technology of ""Heavy ANFO"" , the emulsion matrix concept and the range of products.3. Relative performance and economics in various rock types.4: Current status in Canada and worldwide, and the expectations for future use.IntroductionANFO has been in use for roughly three decades and remains the explosive of choice where conditions are suitable. ANFO has not become the universal explosive - despite its undoubted superiority in cost effectiveness - because it has serious flaws as an explosive. The most serious of these flaws are the low density and absence of water resistance in ANFO. Low density implies a low concentration of explosive energy in a borehole. The amount of energy available can be increased by. adding an energetic material, generally aluminum, or by drilling more holes. Both solutions add considerably to the over-all costs. The absence of water resistance in ANFO is inherent and can only be overcome by changing the fundamental nature of the product. The history of research in the explosives industry since the advent of ANFO is mainly the story of the various attempts to overcome one or both of ANFO's shortcomings.Many technologies and products have been developed to compete against ANFO, among them slurries, emulsion s and the so-called Dense ANFOs (ANFO with an extra nitroalkane liquid sensitizer). None of them was cost-competitive with ANFO so their market penetration has been limited to wet holes or specialized applications. The exception to this result is Heavy ANFO. The aim here was to have the best of both worlds, the high density and water resistance of emulsions or slurries plus the low cost of ANFO. The concept is very simple. ANFO is about 50 % air, roughly 30% in the prills and 700,10 between the prills . The air in the prills provides the necessary sensitivity but the air between them is waste volume. If one fills this volume with a high density, waterproof product, the resultant mix will be denser and more water resistant than ANFO and with very little added cost. This basic concept was invented by B. Clay in the 1970s and is covered by Canadian Patent No. 1 115 959. The water resistance and/or density of the mix can be tailored by changing the emulsion level. Because Heavy ANFO is relatively inexpensive while providing good in-hole densities and water resistance, it can compete successfully against all other bulk products. It competes against ANFO and Al / ANFO by allowing pattern expansion and reducing over-all costs while it competes against emulsions and slurries on price."

Jan 1, 1987

Aspects and anomalies in the present Standard Specifications for Blended Cements which may have operated in Australia against the development of the greater use of Slag Blended Cements are noted. Estimates of slag and ash usage in Australia are given and the need for further research with local materials stressed.

Jan 1, 1979

By G. Ward Wilson

Waste rock and tailings may be combined through intimate blending to create new materials with superior physical and hydraulic properties. The new material, termed Co-Mix, has high shear strength characteristics, low compressibility, low hydraulic conductivity, and a high water retaining capacity. Co-Mixed tailings and waste rock may be used to construct cover systems, internal barriers and seals, confinement structures and full depth waste repositories. Field scale test trials using Co-Mixed blends of waste rock, tailings and slag have been constructed at the Copper Cliff Mine in Sudbury, Canad. These lysimeters will be used to evaluate the performance of the new material for cover systems that may potentially be constructed on the tailings impoundment upon closure. In this sense, the paper point out the construction of the lysimeters with respect to expected field performance during the spring snow melt period and summer to produce cover systems for closure.

Sep 12, 2005

By C. Pace, D. Darlington, A. Montera, C. Lingren

"A phosphate beneficiation plant in Utah is using isotope-based Prompt Gamma Neutron Activation Analysis (PGNAA) technology to analyze the entire slurry streams of the incoming feed and final product in order to adjust the flotation circuits in near real time and optimize the plant output. The plant has gained greatly improved visibility/control and has reduced product variability for improved profitability and product quality. This paper takes a look at the economics as well as application details and the difference this technology provides in a phosphate application. SIMPLOT PHOSPHATES INTRODUCTION Simplot’s Vernal, Utah Phosphate Mine and Mill are located in the northeast corner of the state in the Uinta Mountains along US Highway 191, eleven miles north of the town of Vernal. The phosphoric acid and fertilizer plant fed by the Vernal mine is located 94 miles Northeast of Simplot Phosphates in Rock Springs, WY.At the Vernal plant, loader and shovel mining to 85 Ton capacity trucks is done at an annual rate of 3.8 Million tons of ore. Run of mine ore is crushed in a mineral sizer to minus 14 inch diameter at the rate 11,500 tons a day and transported to the SAG Mill’s 130,000 ton surge stockpile by overland belt. ORE RESERVES The ore is a Phosphoria Formation of sedimentary rock type dating to the Permian Age. The ore body rests over a 25 mile area on Weber Sandstone from the Pennsylvania and Permian geologic period. Layers of Phosphate Rock can vary in thickness from 0.3 up to 2.1 feet, alternating with layers of Mudstone. The eastern edge of the ore’s body Panel “G” runs 16 feet deep with a feed grade of 21.5% P205 with lower MgO diluents of less than 2.79%."

Jan 1, 2016

It is no longer satisfactory to assess the value of a coking coal on its intrinsic properties alone; its value depends upon its behaviour as a component in a blend. No single test can be used to make this assessment, it can only be made by carrying out a suite of tests. The quality parameters which are considered desirable, and which have widespread acceptance, have been discussed and their application to the blending of coals from New South Wales and New Zealand has been reported and discussed. Blending can be utilised to offset deficiencies, or capitalise on advantages, of the individual coals making up a blend. Coals can be blended, which alone are poorly, Coking, but which have compensating features. Blending also allows better exploitation of coking coal reserves. Several applications of blending have been reviewed with regard to coal producers and exporters, as well as coal users. The possibility of extracting a coking coal fraction from fuel coals is discussed. Blending systems and the coking of coal are also briefly reviewed.

Jan 1, 1971

It is no longer satisfactory to assess the value of a coking coal on its intrinsic properties alone, its value depends upon its behaviour as a component in a blend. No single test can be used to make this assessment, it can only be made by carrying out a suite of tests. The quality parameters which are considered desirable, and which have widespread acceptance, have been discussed and their application to the blending of coals from New South Wales and New Zealand has been reported and discussed. Blending can be utilised to offset deficiencies, or capitalise on advantages, of the individual coals making up a blend. Coals can be blended, which alone are poorly coking, but which have compensating features. Blending also allows better exploitation of coking coal Reserves..

Jan 1, 1980

By William J. Maloney

OVERVIEW Blind drilled shafts are becoming increasingly popular, particularly in the Appalachian coalfields, as a secondary and sometimes primary means of ventilation. The reasons for the rebirth of the blind shaft are mainly due to it's economics, timeliness, safety characteristics and inherent independence from underground operations. Historically blind drilling has been used to a limited degree in hard rock and tunneling ventilation. With the recent advances in cutters, bit design, equipment and lining systems, particularly in the Appalachian coalfields, blind drilled shafts are once again the shaft construction technique of choice to the educated ventilation specialist. [ ] HISTORY OF BLIND DRILLING Blind drilling has it's roots in numerous places, including the Nevada Test site, the coalfields of Appalachia and Germany along with the uranium mines of Arizona. Early technology was developed using a variety of equipment mainly of oilfield origin with oilfield drillers entering the industry on a project basis only to "pull in their horns" and return to the oil patch. Shafts completed by oilfield equipment range from the shallow 5' and 6' lined shafts on the Nevada test site to two (2) 10' lined, 730' deep shafts in Alberta for heavy oil development. Several of these shafts were completed to extraordinary depths with the record being a 90" diameter, 6,150' deep shaft being completed in the Aleutian Islands of Alaska in 1969. EQUIPMENT Oilfield equipment is still being used on the Nevada test site but elsewhere specialized blind hole equipment has been developed to enhance the efficiency of particular applications. Where steel liners are required the A-leg derrick with a simple hoist and rotary system is used. The largest user of this type equipment in the world is the former USSR where blind drilling for mine ventilation is the norm. On applications where trip time and cutter changeout are a priority, top drive hydraulic rigs have been developed which are highly automated, efficient and mobile. These rigs are particularly well suited for tunneling applications where shafts are shallow and sites are usually tight.

Jan 1, 1993

By Ray W. Amstutz

The shaft was drilled on US government land m the Piceance Creek basin and was funded by the US Bureau of Mines (USBM). It was drilled to 723 m to provide access to rich deposits of oil shale, nahcolite, and dawsonite for geotechnical test work and environmental mining research. Rotary drilling and dual-string, reverse-air, jet-assist circulation methods were used. Drilling required eight months. Site preparation, running, and cementing the casing required another four months. A 2.44-m ID steel welded casing, 508 mm thick was installed and 2.7 kt of cement were slurried and pumped into the annulus.

Jan 1, 1982

By R. W. Amstutz

Abstract. The shaft was drilled on U.S. Government land in the Piceance Creek Basin and was funded by the U.S. Bureau of Mines. It was drilled to 723 meters (2 371') to provide access to rich deposits of oil shale, nahcolite and dawsonite for geotechnical test work and environmental mining research. Rotary drilling and dual string, reverse-air, jet-assist circulation methods were used. Drilling required 8 months. Site preparation, running and cementing the casing required another 4 months. A 2.44-meter (96-inch) ID steel welded casing, 5.1 cm (2 inches) thick was installed and 2 700 tonnes (63 000 sacks) of cement were slurried and pumped into the annulus.

Jan 1, 1980

By William J. Maloney

Blind drilled shafts are becoming increasingly popular as a secondary and sometimes primary means of ventilation. This is particularly true in the Appalachian coalfields. Some reasons for the rebirth of blind shafts are economics, timeliness, safety characteristics and their inherent independence from underground operations. Blind drilling has had limited use in hard rock and tunneling ventilation. Advances in cutters, bit design, equipment and lining systems have made blind drilled shafts the shaft construction technique of choice for ventilation specialists. History of blind drilling Blind drilling's roots include the Nevada test site, the coalfields of Appalachia and Germany, and the uranium mines of Arizona. Early technology was developed using a variety of equipment mainly of oilfield origin. Shafts completed by oilfield equipment ranged from the shallow 1.5 and 1.8 m (5 and 6 ft) lined shafts on the Nevada test site to two 3 m (10 ft) lined, 222 m (730 ft) deep shafts in Alberta for heavy oil development. Several of these shafts were completed to extraordinary depths. The record, completed in 1969, is a 2.28-m-diam (90-in.-diam), 1875-m (6150-ft) deep shaft, located in the Aleutian Islands of Alaska.

Jan 1, 1993

By James H. Cobbs

Blind boring of shafts is becoming an increasingly important part of shaft sinking. Blind-bored shafts have reached diameters of 25 It in Europe and 16-1/2 ft in the United States. Much of the technology developed for blind boring has evolved from the technology of drilling wells for oil and gas production. Blind boring offers economic advantage in a number of situations where conventional shaft sinking either is extremely difficult or very expensive by virtue of large-capacity aquifers which must be penetrated, unstable ground or where very rapid sinking is required. In sedimentary rocks, blind boring is cost competitive with conventional sinking, in diameters of about 12 ft or less. Blind boring is not competitive with raise boring where conditions are favourable for raise boring. Blind boring does, however, offer greater flexibility than raise boring and can be performed in situations where raise boring is inefficient or impossible. Combination machinery has been developed to perform both blind boring and raise boring, so that the machine can be used effectively in situations where only the near-surface portions of the shaft are unfavourable for raise boring. Development work is being supported by the United States Bureau of Mines for blind boring equipment capable of boring shafts up to 30 feet in diameter.

Jan 1, 1979

By Justus Deen, Paul V. Sterk

Through the 119 year history of the Homestake Mine various methods of raise mining have been used, these include conventional, bored, and drop raises. These raises provide passage for men and supplies, provide ventilation, transfer broken rock from level to level, and serve as emergency escapeways. As the 1980’s came to a close, many of the larger ore bodies in the mine had been mined out. This has resulted in many crown pillar situations that required a method to mine them. In addition, the Homestake ore body also contains numerous ore reserves that have short vertical height. The ore itself can be from vertical to 50 degrees in dip. Due to the high cost of drift and ramp development many of these ore bodies are subeconomic using conventional mechanized cut and fill mining.

Jan 1, 1996

By Justus Deen, Paul V. Sterk

Through the 119 year history of the Homestake Mine various methods of raise mining have been used, these include conventional, bored, and drop raises. These raises provide passage for men and supplies, provide ventilation, transfer broken rock from level to level, and serve as emergency escapeways. As the 1980s came to a close, many of the larger ore bodies in the mine had been mined out. This has resulted in many crown pillar situations that required a method to mine them. In addition, the Homestake ore body also contains numerous ore reserves that have short vertical height. The ore itself can be from vertical to 50 degrees in dip. Due to the high cost of drift and ramp development many of these ore bodies are sub-economic using conventional mechanized cut and fill mining.

Jan 1, 1996

By James E. Friant

The technology applied to shaft sinking has lagged far behind other construction activities. While surface oriented construction and mining have made great strides with new processes and equipment, the majority of shafts sunk currently still follow a drill, blast and muck-out cycle developed in the 16th century. Today, in 1979, the shaft sinking industry is in the midst of its own private industrial revolution. Millions of dollars are being spent annually by industry and government alike to spring the art of shaft sinking into the 20th century. The objective of this paper is to review a few of the newest mechanized schemes for shaft sinking. This is not a theoretical review, however, but a practical one, and deals only with hardware and projects which are currently on jobsites. Figure 1 shows the equipment. On the left is the 241SB 184, a 24 foot diameter blind shaft borer. This machine is currently at about 200 feet, constructing a coal mine shaft in Alabama. It is built and utilized in a manner similar to a tunnel borer. In the upper center is the 1211SR, a 12 foot diameter blind shaft reamer. This machine follows a 6 foot pre-drilled blind pilot hole, and is at work in Chicago. On the upper right is the 121BR, a powerful new blind drill. Just below it is the conical drill head for the 121BR which can utilize either carbide or standard disc cutters. At the center bottom is an expandable back reaming head which can be used to enlarge a drilled shaft up to a maximum of 16 feet diameter, or can be used to produce a shaft having several diameter changes. This equipment is also in use in Chicago.

Jan 1, 1979

The Agnew Mine No. 1 Ventilation Shaft is the largest diameter shaft blind drilled in a hard rock mining environment. The selection of this method of shaft development was based on achieving an accelerated mine development and exploration programme. Drilling the shaft from a pre-sink depth of 73m commenced on March 22, 1982 and the shaft was stopped due to rig structural problems at a depth of 750m, 280m from the designed depth, on February 12, 1983, 137 days behind schedule. While problems with rig mechanical availability, cutter life and lost drilling tools in the hole hindered progress and escalated costs, penetration rates above prediction were achieved and both the speed and safety aspects of the method were well demonstrated.

Jan 1, 1983

By Don Runge, John T. Zeni

Cuprex Limited is currently developing a small gold mining operation in Central Australia in the Tennant Creek field. In February 1984, the company undertook a feasibility study on the project and operations commenced in August 1984. Ore reserves are located between 230 and 280 metres (755 ft and 919 ft) below surface and ore extraction required the establishment of a shaft network for access, ore hoisting and ventilation. Zeni Drilling Company from West Virginia, U.S.A. was contracted to blind drill two shafts for the project. Blind drilling was selected for various reasons, including timing which related to cost efficiency. The blind drill shaft technique has proved successful in this application and with enthusiastic and innovative support from the mining industry, will prove an efficient and cost effective means of accessing and operating underground mining projects of all sizes in the future.

Jan 1, 1987

By R. C. O’Ferrall, W. G. Goulding

This paper describes the performance of a Robbins 52R Boxhole Borer from its introduction into the mine in July 1975 until late in 1977. As indicated by the costs involved, the performance has increased considerably and is expected to be even better once further envisaged modifications have been made. The average cost for the first half of 1977 was R275 per metre bored as against an average of R628 for 1975.

Jan 1, 1978

By Jukka Tuominen

The history of making blister copper in an Outokumpu Flash Smelting Furnace dates back to the late 1960?s, when Outokumpu first piloted the Outokumpu Direct Blister (ODB) process. The first commercial scale applications have been in use at Glogow, Poland, since 1978 and at Olympic Dam, Australia, since 1988. These applications utilize special concentrates, which are low in iron, and thus the formation of slag is also low. In 1995 the same principle was applied to smelting copper matte into blister copper in industrial scale at Kennecott Utah Copper. This application, the Kennecott-Outokumpu Flash Converting process, will celebrate its 10th anniversary of commercial scale operation this year. This paper outlines the development in efficiency and flexibility of Blister Flash Smelting processes compared to other smelting and converting options. The focus is on the economical aspects i.e. on the total feasibility of both greenfield investment projects and revamping of existing smelters.

Jan 1, 2005

One of the critical challenges facing the mining industry ? and not just in the United States ? is the looming labor shortage. A significant percentage of the industry?s professional workforce is, well, getting old, and many will be retiring in the next 10 years or so. This is not a new issue to the industry. It has been discussed at various industry meetings and conferences for many years. How does mining, with its largely negative public image, attract young people to mining schools? And, equally important, who is going to teach them? Mining schools, what?s left of them in the United States, are beginning to lose qualified faculty to retirements, and no one is available to replace them. SME addressed this issue during the keynote session at its annual meeting in February in Denver, CO. This year?s theme was ?Mining: It?s About the People.? Despite a blizzard that blanketed the city on the day most attendees were to have arrived, the meeting still attracted a record 7,202 people. And the accompanying exhibit sold 822 booths, also a record. The U.S. Department of Energy?s National Energy Technology Laboratory contracted with the National Academies? National Research Council to complete a study concerning the availability of skilled workers to meet the energy and mineral security requirements for the United States. The National Research Council, in turn, asked SME to collect and analyze workforce trends in these industries. The result of SME?s analysis is the report ?Emerging Workforce Trends in the U.S. Energy and Minerals Industries.? It is available on the SME website, www.smenet.org. Click on Government Affairs. While the report did not paint a completely dismal picture, there were some disturbing results. It concluded that within 20 years there will not be a sufficient number of skilled professionals to satisfy the labor demand. That said, the report said that most of those positions would likely be filled. However, the U.S. mining will go through a period of time when the workforce will be made up of very young and senior workers.

Jun 1, 2013