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By Neil S. Fishman

Tabular uranium ore in the Grants uranium region, New Mexico, occurs as tabular layers of a urano-organic mixture suspended within host sandstones of the Morrison Formation. The intimate urano-organic association points to the organic material as the main ore control. Petrographic evidence indicates that the organic material was postdepositionally introduced into the host sandstone, probably as humic acids; however, the mechanism by which these acids precipitated from solution remains uncertain. A model, the cation scavenging model, is proposed in this paper to explain humic acid precipitation. The model, supported by evidence from regional alteration studies of the host sandstones, proposes that cations responsible for humic acid precipitation were scavenged from framework grains which altered during passage of the humic-rich fluids through the host sandstone. This process, coupled with the affinity of organic molecules for each other, caused flocculation of humic acids into tabular zones. The precipitated humic substances then continued to concentrate uranium to form the orebodies. The cation scavenging model requires only one solution, the humic-bearing solution, in the precipitation process. All cations necessary for humic acid precipitation originated in the host sandstones. This model contrasts with a previously proposed model--the brine interface or two solution hypothesis--in which it was proposed that a cation-rich brine introduced into the host sandstones provided the cations necessary for humic acid precipitation. The brine hypothesis has several drawbacks, one of which is unrealistic hydrologic reconstructions necessary to accommodate mineralization at various stratigraphic horizons in the Morrison Formation. Moreover, no mineralogic evidence exists to suggest a brine occupied the host sandstones at the time of mineralization. The proposed cation scavenging model for humic acid precipitation not only readily accounts for humic acid precipitation, but also is consistent with geologic observations and regional alteration studies.

Jan 1, 2013

By P. Somasundaran

An experimental and theoretical treatment of the depressing effect of inorganic electrolytes on the amine flotation of quartz is presented. Experimental data obtained for the amine flotation of quartz as a function of pH with potassium nitrate as depressant was used to test the models for the effectiveness of inorganic ions as depressants. The validity of commonly used assumptions are examined. The surface tension data obtained for dodecylammonium acetate solutions as a function of KNO3, concentration indicated that the collector adsorption on bubble cannot be neglected in the treatments, since this adsorption changes significantly with the addition of the inorganic electrolyte. It also indicated the possibility of significant changes in the specific adsorption potential of the collector occurring with the addition of inorganic electrolytes.

Jan 1, 1975

By J. C. Williams

THE operations described in this paper are those of the flotation plant of the Valley Forge Cement Co. at Conshohocken, Pa., and concern the use of a particular cationic reagent-namely, DP-243. The role of this reagent in this plant may be better understood by first considering the purpose of beneficiating cement rock in general and the specific problems at the Valley Forge plant. The ultimate purpose of beneficiating cement rock is to obtain a kiln feed of the desired chemical composition in a form suitable for the most efficient kiln operation. The chemical composition is governed by the type of cement to be made. Before government restrictions (the purpose of which is to simplify operations during wartime) limited the types of portland cement a manufacturer is permitted to produce, five principal types of cement were generally recognized by the industry. They are based upon chemical and physical specifications proposed by the American Society for Testing Materials, federal and other governmental agencies, state highway departments, water boards and other users of large quantities of cement. The physical as well as chemical specifications for any particular type of cement necessitate proper proportioning of the major components-that is, the silica, alumina, iron and lime-and it is necessary to establish and maintain definite limits for each in the raw mix. The manufacturer must then prepare a kiln feed of a composition that will yield a final product that will fulfill the desired specification. This step is further complicated for kilns using coal as fuel, by the amount and analysis of the ash introduced. The amount and nature of the dust lost during burning will also affect the composition of the kiln feed. The problem of preparing a kiln feed of the desired chemical composition is not a simple one, and it is the final product that governs the methods used to obtain such a feed. For example, in starting with a material deficient in lime for the mix sought, it may not be sufficient to raise it to the required lime content. The other constituents must also be present in the proper proportions. In some cases, it may be necessary to raise the lime content to a point greatly exceeding that of the final mix, then, by addition of one or more other materials lower in lime, obtain the mix. The rock used at the Valley Forge plant is a metamorphosed argillaceous limestone of the Jacksonburg formation, the same formation as that of the Lehigh Valley cement rock (which occurs approximately 50 miles north), and its oxide composition is similar to that of the latter. The only practical differences between the two are that, as a result of metamorphosis, crystallization of the Valley Forge rock is considerably coarser and it contains less carbon than the Lehigh Valley rock as well as slightly more magnesia in the form of magnesian mica. The calcium carbonate content of the various strata in the Valley Forge quarry ranges from about 65 per cent to over 85 per cent, the average for the entire quarry being somewhat under the requirement for manufacture of cement, which usually is from 75 to 76 per

Jan 1, 1946

By P. R. G. Brandão

In this investigation, the differences in the absorption spectra of etheramines, fatty amines and condensates, mostly present as acetates, from several suppliers are characterized by means of infrared spectrometry. Sharp differences were observed in the absorption spectra of three types of amines and derivatives. Etheramines show a characteristic and well-defined peak at 1,114 cm-1. This peak is due to the ether C-O group and differentiates etheramines from the other classes. The absence of such a peak indicates that the species is not an etheramine. The distinction between condensates and fatty amines is made by the presence of a sharp peak around 3,200 cm-1. This peak is probably due to the proximity of the N-H amine groups and C=O carbonyl groups in the amide portion of the condensate's molecule and by different and better-defined bands in the 1,800- to 1,500-cm-1 range. The flotation performance of these amines was evaluated by means of the laboratory-scale flotation of an itabirite ore. The etheramines proved to be the most effective collectors for this system. Monoamines presented better performance than diamines for the ore under investigation.

Jan 1, 2002

By Arthur F. Colombo, Donald W. Frommer

With the opening of the Tilden mine near Ishpeming, MI, a new era in iron ore beneficiation was begun. A description of a U. S. Bureau of Mines investigation is summarized to illustrate the selective flocculation-deslime-flotation process developed by the Bureau and used at the Tilden concentrator, which is also briefly described. The operating parameters for the selective flocculation-cationic flotation of an oxidized taconite from the Mesabi range are discussed. A water reclamation system using lime and a cationic flocculant was applied to reclaim the effluents from a 900-pound-per-hour flotation pilot plant. About 80 percent of water requirements were recovered, and the calcium content of the reclaimed water was found to be more important than clarity in influencing the selective flocculation and flotation processes. Although reclaimed waters with about 10 ppm calcium registered turbidities of approximately 5,000 ppm SiO2 equivalents, the concentrates produced using these waters contained 64 percent Fe and 55.0 percent SiO2 and had accompanying iron recoveries of 75 percent. Lower grade concentrates resulted from using reclaimed water with higher calcium contents and lower turbidities.

Jan 1, 1976

By G. Rinelli, Arthur F. Colombo, Donald W. Frommer

With the opening of the Tilden mine near Ishpeming, MI, a new era in iron ore beneficiation was begun. A description of a U. S. Bureau of Mines investigation is summarized to illustrate the selective flocculation-deslime-flotation process developed by the Bureau and used at the Tilden concentrator, which is also briefly described. The operating parameters for the selective flocculation-cationic flotation of an oxidized taconite from the Mesabi range are discussed. A water reclamation system using lime and a cationic flocculant was applied to reclaim the effluents from a 900-pound-per-hour flotation pilot plant. About 80 percent of water requirements were recovered, and the calcium content of the reclaimed water was found to be more important than clarity in influencing the selective flocculation and flotation processes. Although reclaimed waters with about 10 ppm calcium registered turbidities of approximately 5,000 ppm SiO2 equivalents, the concentrates produced using these waters contained 64 percent Fe and =5.0 percent SiO2 and had accompanying iron recoveries of 75 percent. Lower grade concentrates resulted from using reclaimed water with higher calcium contents and lower turbidities.

Jan 1, 1976

By Ross W. Smith, Salim Akhtar

INTRODUCTION Flotation of oxide minerals, particularly silicates, with cationic collectors differs substantially from classic flotation of sulfide minerals using sulfhydryl collectors. In the case of cationic flotation of these minerals, in general: 1. There is a greater importance of electrostatic interaction between mineral and collector. 2. Longer-chained collectors are required; as a rule at least 10 carbons must be present in the hydrocarbon chain. 3. Moderate concentration of collector is required. 4. Attachment between collector and mineral appears to be less strong even though the system may exhibit a large contact angle. 5. Required conditioning time before flotation is usually relatively short. 6. There is sensitivity to slimes. 7. The collectors usually possess frothing power. 8. Selectivity of cationic collectors for specific minerals is usually poor. Almost any of the oxide and silicate minerals may be floated using cationic collectors. However, specific response to these collectors varies with mineral type. The following classes and minerals are

Jan 1, 1976

By Ross W. Smith, Salim Akhtar

Flotation of oxide minerals, particularly silicates, with cationic collectors differs substantially from classic flotation of sulfide minerals using sulfhydryl collectors. In the case of cationic flotation of these minerals, in general: 1. There is a greater importance of electrostatic interaction between mineral and collector. 2. Longer-chained collectors are required; as a rule at least 10 carbons must be present in the hydrocarbon chain. 3. Moderate concentration of collector is required. 4. Attachment between collector and mineral appears to be less strong even though the system may exhibit a large contact angle. 5. Required conditioning time before flotation is usually relatively short. 6. There is sensitivity to slimes. 7. The collectors usually possess frothing power. 8. Selectivity of cationic collectors for specific minerals is usually poor. Almost any of the oxide and silicate minerals may be floated using cationic collectors. However, specific response to these collect- ors varies with mineral type. The following classes and minerals are

Jan 1, 1976

This paper describes the results of a laboratory study on the upgrading of Algoma siderite by the amine flotation of silica and silicate gangue. The experiments indicate that a virtually complete removal of silica is possible in a rougher flotation con-ducted in tap water at natural pH, without prior desliming of the ore. Grinding considerably finer than the apparent liberation size is essential for maximum silica rejection. A cationic collector, Aeromine 3037, gave best results when used in combination with a modifier. Of the several modifiers tested, a Dutch potato dextrin, Dextrin 4356, was found to be the most effective. Both iron recovery and the grade of the final iron product are enhanced by floating the pyrite contained in the ore prior to the amine flotation of the silica, and by scalping the magnetics from the silica concentrate. F OR over twenty years, the Algoma Ore Properties Division of The Algoma Steel

Jan 1, 1963

By David L. Gefvert

A general review of the role of cationic flotation reagents in the beneficiation of phosphate, iron, and potash ores. The three major types of cationic collectors-amines, ether amines, and condensates will be compared and contrasted. The effect of particle size, water chemistry, and water temperature on the choice of cationic flotation reagents for each industry will be discussed.

Jan 1, 1986

By K. E. Hjelmstad

Solution mining operations often encounter difficulty maintaining adequate leach solution flow into the ore formation because of loss of formation permeability near the injection well. Permeability loss caused by swelling and breakup of clays and fine particle migration can often be the cause of the problem. Combined permeability and leaching tests were done in the laboratory on samples of clay bearing ores to evaluate a clay-stabilizing polymer's effectiveness in preventing the problem. Test results indicate that treating the ores with cationic polymers could maintain permeabilities two to five times greater than the long-term permeabilities present in untreated ores. Both alkaline (pH 8.5) and acidic (pH 2.0) leaches were used in the permeability leaching tests. To determine the reasons for the success of the clay stabilizing polymer, clay swelling tests and zeta potential measurements were made on untreated ore samples and on ore samples treated with the cationic polymer. Test results indicate the cationic polymer could reduce the degree of negative charge on fine particles and their tendency to disperse, as well as reduce clay swelling. Test results indicate a potentially beneficial effect on operating parameters such as capacity and injection pressure during leaching, if clays and fines are kept stabilized. This may be done by treating the zone of high fluid velocity near injection wells with cationic polymers.

Jan 1, 1991

By K. E. Hjelmstad

Solution mining operations often encounter difficulty maintaining adequate leach solution flow into the ore formation because of loss of formation permeability near the injection well. Permeability loss caused by swelling and breakup of clays and fine particle migration can often be the cause of the problem.

Jan 1, 1989

Inn mining communities throughout the western United States, cows have always been part of the landscape as they graze on surrounding rangelands. Until recently, mining companies regarded these animals as something to be kept off their properties — especially any freshly reclaimed lands. During the last few years, though, this situation has begun to change. Today, cattle can be seen in a handful of mine settings, moving up and down the slopes of mine tailings and waste rock. These animals are being used by several companies to do some of the reclamation work once performed by large earth-moving equipment, mechanical spreaders, rippers and seed drillers. This is because cows can contour slopes more naturally and produce and spread soil nutrients in ways that tractors and ripping machines cannot.

Jan 1, 1999

By Peter Babik

"Cable TV networks are extensively used throughout Canada for TV signal distribution. Mobile/portable radio communications are also used extensively throughout all sectors of industry. There are numerous manufacturer supplying these industries with a wide variety of equipment and accessories.IAL's underground radio communications system combines the techniques of cable TV and mobile radio to produce a flexible communications system with most of the advantages of both systems. Standard off-the-shelf mobile, portable, base-station and repeater equipment can be used. The equipment may need modification to be customized to particular end user requirements, but does not require a complete new unit redesign. Likewise, the cable TV distribution equipment is off the-shelf, with some items requiring modification for underground system application.Radio communications can be provided wherever the cable system is extended. Where traffic or type of activity warrants it, multiple radio channels can be provided on the same cable. Certain radio channels could also be used with data channels for control or supervision of remote equipment or environmental conditions. In addition, the same cable can be used to distribute or monitor signals from remote TV cameras in selected or dangerous areas. The system can be interfaced to a telephone system, if required, to provide extended communications to above-ground workshops, offices, medical stations or even hospitals and other emergency services.IntroductionReliable communications among personnel throughout an underground mine area have long been the dream and goal of various mine operations personnel. The system to be described was designed to meet this objective."

Jan 1, 1983

By Les Philips

National Institute for Safety and Health?s (NIOSH, USA) Office of Mine Safety and Mine Safety and Health (OMSHR) has definitions for: -Proximity Detection as detection of personnel, vehicles and other objects near a machine using some type of sensor technology -Proximity Warning (aka Collision Warning) as detection of personnel, vehicles and other objects near a machine resulting in alarms that ?Warn the operator only ?Warn the operator and nearby personnel (two-way) -Collision Avoidance as the processing of sensor information resulting in control signals or actions that alter machine status/movement to avoid a collision by ?Computer control ?Human control

May 1, 2013

By Huasheng Chen, Gaifeng Xue, Jing Zhang, Mingsheng He, Bin Liu, Yexian Ouyang, Shoujun Peng

Based on the investigation and study of the topography, microstructure and composition of the buildups which form in the surface of carbon sleeve in continuous annealing furnace for lowand medium-grade non-oriented silicon steel produced by CSP process, combined with production process of silicon steel, the mechanism and major causes for forming buildups of carbon sleeve are discussed from the factors such as CSP process, the quality of carbon sleeve and so forth. Meanwhile, some countermeasures to reduce the formation of the buildups are put forward.

Jan 1, 2015

By Thos Stroup

RECENT contributions to the literature relating to the problems of coal mine management have discussed the pros, and cons of unionism among the miners as bearing upon the immediate problems of the industry, but have devoted singularly little thought to the underlying causes, and the fundamental reasons. for the remarkable growth of union sentiment among the miners, a growth paralleled only in the case of the railroad workers. It is all very well to revile their organization, its obvious stupidity and stubbornness, its multitude of economic and social crimes, but it is also well to realize that there have been deep-seated causes for all these things, causes that, while operating in all industries and amongst all workers, have in none of them found the optimum conditions for development such as exist in the coal mining industry. The rise of the United Mine Workers of America to a position of importance in the industry synchronizes roughly with the introduction of short-time operation; of course seasonal shutdowns and slow-time working have always been evident in our bituminous fields, but these evils have grown steadily worse since 1895 and the U. M. W. of A. has grown steadily stronger; yet short-time operation alone cannot account for this tremendous growth for, witness the signal failures that have always attended the attempts to organize the harvest workers, the fruit packers and other highly seasonal workers.

Jan 9, 1923

By Charles T. Holland

This discussion is concerned with those comparatively infrequent bumps that eject material from the failed mass with enough energy to wreck heavy machinery and seriously injure or kill people. In such cases there is a loud report, and the pressure waves set up in the mine atmosphere wreck ventilation controls several hundred feet from the site of the failure. Vibrations are induced in the earth's crust which may be detected several miles from the point of origin, and explosive gases may be released in large quantities.* Usually a dense suspension of dust is produced from the failed mass, together with dust placed in suspension by the resulting air blast. These rock bursts or bumps have also been called mountain shots, bounces, pillar bursts, and crumps. Such occurrences, when extensive, are serious catastrophes, and may force abandonment of the mine.1

Jan 9, 1958

By L. B. Lindemuth

TO those who are in a position to carry the thought to a conclusion, I would like to present a theory of the cause of blisters in ' galvanized sheets. Blisters that are caused from piping and shrinkage cavities will not be considered, because the reason for their formation is entirely obvious. Blisters that periodically occur, with no apparent system of location, number, size or grouping, and then disappear with no apparent change in manufacturing method, are the ones to which this theory would apply. Examination of blisters of the latter type has shown that they contain hydrogen gas at atmospheric pres-sure, and that occasionally traces of oxide or sulfide are found on the inner surface of the blisters. These two characteristics have led to the rather general idea that hydrogen gas generated in pickling, and that iron oxide supposed to be inherent in the ingot and causing weak spots, were, in some manner, responsible for the development of blisters in galvanizing. The theory which I wish to advance is that these blisters are caused by moisture that has penetrated the steel after the annealing operation. This moisture comes from the atmosphere, or from pickling or wash-ing, and when it is suddenly expanded into superheated steam in galvanizing, the increase in volume is so great that it cannot escape with sufficient rapidity through the small opening which it entered as moisture. The pressure so generated forces the sheet apart along those lines of lamination that may be found in practically all flat sections of steel rolled comparatively cold.

Jan 5, 1927

By A. W. Khair

This paper deals with the causes and mechanisms of pillar failure in a southern West Virginia coal mine. The conclusions are based on in-mine observations and analysis of mining methods, eyewitness account of the sequence of events, topographic and geologic conditions, and mechanical properties of mine roof, coal, and floor. The study indicated that massive pillar failure was caused by the collapse of the mine roof. The collapse of the mine roof was due to the combined effects of high lateral compressive stress and high extraction ratio causing excessive bending of the roof beyond its limit. It was assumed that the higher lateral compressive stress under such a shallow cover was probably due to the drastic change in the structural geology of the area and possible residual stresses. Eased on the analytical study it was concluded that the sudden release of elastic energy (shock) due to the rupture of the roof caused the squeezing of approximately eighty mine pillars.

Jan 1, 1983