Search Documents

By Paulo Castillo, Cesar Gomez, Jaime Alvarez

Operations using flotation to produce mineral concentrates require testing of frothers to characterize their ability to preserve bubble formation size and to build a stable froth. Many techniques have been proposed to measure parameters associated with these two roles. These techniques focus, in general, on only one of these roles and are based on special equipment operated at conditions quite different from those existing in industrial cells and columns. Both roles have been simultaneously characterized in a laboratory flotation column, but the requirements associated with the installation and operation of one of these units, are a serious limitation for its use on-site. A technique based on the use of a laboratory mechanical cell, a common piece of equipment in operations, will have wider application. Establishing the ability of a frother to control coalescence by preserving bubble formation size is done through bubble size measurements as a function of frother concentration. Froth build-up and stabilization is associated with the amount of water carried by bubbles into the froth layer, which has been demonstrated to correlate with the gas holdup in the collection zone. Procedures devised for determining the critical coalescence concentration (CCC) from measurements of bubble size as a function of frother concentration, and the gas holdup by collection of water displaced from the cell by the presence of bubbles at different frother concentrations, were tested. Three analytical-grade frothers were utilized: a straight-chain (1-heptanol) and a branched (MIBC) alcohol and a polyglycol (PPG425). The results obtained at a standard set of conditions, demonstrated consistent differences between these frothers, and the ranking from least to most effective for reducing bubble size or decreasing water drainage followed the same sequences found when more complex frother characterization techniques are used.

Jan 1, 2014

By J. A. Finch, T. Weber

"Bubble size in flotation is strongly influenced by frother concentration in the pulp liquor. There is no accepted method of judging the dosage and thus how effectively frother is being distributed to control bubble size is not known. This will hamper certain plant test work where constant bubble size (e.g., when comparing reagents) is implicit. Bubble size is not easy to measure in plant and gas holdup is suggested as a surrogate in the development of a proposed “meter” to estimate frother concentration. The meter is calibrated to enable frother concentration to be estimated on samples drawn from any location in the flotation circuit. The meter and its calibration are described.As general background the action of frothers in reducing bubble size by retarding coalescence is discussed and the bubble generation systems for which the effect will be important are considered.INTRODUCTIONBubble size is an important variable in flotation. The flotation rate constant k has been related to mean bubble size Db by k % Db -n with n ranging up to 2 (Ahmed and Jameson, 1989) and even 3 (Yoon, 1993). Recent work has introduced k % Sb, the bubble surface area flux, given by Sb = 6 Jg / Db (where Jg is the superficial gas velocity or volumetric gas rate per unit cell cross-sectional area), i.e., n = 1 (Gorain et al., 1998). Regardless of the exact value of n, the significance of bubble size in flotation remains. In many plant trials it will be implicit that bubble size has not changed and attention will focus on other process variables. The measurement of bubble size, or a surrogate, would be useful addition to any test work.The size of the bubbles is influenced by several variables, gas rate, gas injection system (e.g., impeller design and rotation speed in a mechanical cell) and pulp composition (chemicals added, percent solids), but the most important is frother concentration (Harris, 1976). The frother functions by retarding coalescence (see appendix), which acts to preserve the small bubbles generated in the pulp (and permits a stable froth to form on top of the pulp). The measurement of bubble size is thus related to measuring frother concentration. The distribution of frother and whether sufficient (to control bubble size) is reaching the intended parts of the circuit then become important considerations. At present there is no simple way to judge frother concentration in a plant. In this communication we introduce a possible methodology, a “frother concentration meter”."

Jan 1, 2003

By Marco Olper

The CX-EW technology, developed by B.U.S Engitec, is improved introducing besides the battery paste electrowinning, the direct electrorefining of metallic lead (grids and poles) obtained from CX breakers. This new concept of electrorefming the antimonial lead scrap is aimed to the production of 99.99 lead and of slimes with high antimony content, avoiding gaseous emissions in melting lead scrap, and expensive and pollutant thermic refining operations. In this way, practically all lead content in the battery is available as 99.99 lead, hence with a wider market for the lead recyclers. This paper will describe the tests performed on a pilot plant scale with special reference to the relatively low energy consumption of the process.

Jan 1, 1993

By Magnus Gynnemo

The primary purposes of drilling and blasting in hard rocks is to fracture solid rock and prepare it for excavation and subsequent transport to the crushing plant. Using explosives in excavation operations without counting for the geology gives no consideration to the quality of the macadam product or the excess production of waste material (fines).

Jan 1, 1997

A nine-month investigation was conducted into the effect on coke quality and blast furnace operation of the addition of bentonite and southern coal to the northern coal fed to the coke ovens at the Newcastle steelworks.Additions of 0·3 per cent bentonite or 25 per cent southern coal to the northern coal increased the coke strength from 15-20 A.S.T.M. stability to 25-30 A.S.T.M. stability. It is likely that improved mixing and blending facilities would, in both cases, give a coke of over 30 A.S.T.M. stability.For the same coke strength, the use of 0 3 per cent imported Wyoming bentonite was considerably cheaper than the use of 25 per cent southern coal, but the use of Australian bentonite promises the same coke strength for still lower costs. Other additives such as coke breeze, charcoal, iron ore fines, and certain other finely divided materials, gave relatively minor improvements in coke quality.There appeared to be sufficient improvement in blast furnace operation and production to justify full scale addition of bentonite to improve coke quality, although other variables, particularly iron ore physical quality, overshadowed on many occasions the effect of coke quality. Further coke trials with southern or bentonite will be carried out when ore quality has been improved by the introduction of ore sintering at Newcastle.INTRODUCTIONDuring the period of operation of the Newcastle coke ovens and blast furnaces from April 1960 (when No. 3 blast furnace was blown in after rebuilding) to December 1960, a bentonite coke trial was carried out based on earlier research findings (Gregory, 1959a, 1959b; Felton and Gregory, 1960; Gregory, 1960) that as little as 0 3 per cent to 05 per cent bentonite clay added to northern N.S.W. high volatile coking coals gave a significant increase in coke strength. The bentonite coke trial was followed by trials...

Jan 1, 1962

By J. A. Sanchidrián, P. Segarra, S. Gómez

Blasting is a common activity in mining that can cause significant damage in the remaining rock mass. The most commonly used method for predicting vibrations is the Swedish or Holmberg-Persson approach. It is a simple and fast method that uses empirical formulation to estimate the vibration levels based on the explosive charge weight, distance to the source, and other parameters. However, it has limited accuracy and does not consider the effect of free surfaces or other boundary conditions. On the other hand, recently developed methods as the full-field solution (FFS) can provide more accurate predictions of vibrations due to excitations provoked by cylindrical columns of explosive, but the inclusion of free surfaces in analytical methods is a challenging problem. This paper presents a new approach that includes free surfaces in the FFS to predict vibrations analytically in the near-field. The main obstacle to including free surfaces in the FFS was the belief that the solution was non-decoupleable in P- and SV-waves separately. The Heelan's approach was previously used to decouple them, but it only provides valid radiation patterns in the far-field and does not account for intrinsic attenuation. In this paper, we address this problem successfully, allowing for the inclusion of free surfaces in the FFS.

Jan 1, 2024

By A. L. Hinde, A. A. Bradley, K. H. Stanton, P. J. D. Lloyd, G. K. Schymura

As part of its programme to develop methods for concentrating minerals underground, the Chamber of Mines of South Africa in conjunction with Lurgi evolved and tested a I MW centrifugal mill. The machine is capable, in the autogenous mode, of grinding more than 25 t/h of minus 75 plus 44 mm hard quartzite to a minus 3 mm product containing over 50 per cent minus 75 µm material, and as a ball mill of grinding more than 60 t/h of minus 19 mm quartzite to a minus 3 mm product containing over 35 per cent minus 75 µm material. Extrapolation of computer models of the process suggests that these limits can be comfortably exceeded. Long-term continuous testing is in hand, aimed at proving that this I m in diameter by I m long mill is in every respect the equivalent of a conventional 4 m by 6 m ball mill.

Jan 1, 1982

By H. Hayashi, M. Yamaki, H. Hashimoto, T. Yamanashi

"In an experiment on a trial embankment, the deformation mode of the improved ground at the toe of the embankment was compared with the deformation mode of the unimproved ground. This comparison showed that the behavior exhibited by the improved ground was the same as that exhibited by the unimproved ground, despite the low improvement rate (ap = 10%) of the ground improvement. Thus, the improved ground and the unimproved ground were found to be functioning as composite ground. Further, the strain that developed in the geo-textile used for the crushed-stone mat was considerably less than the strain specified by the design strength. As a result, it was found that a crushed-stone mat can serve as a mattress.OVERVIEW OF THE TEST CONSTRUCTIONLow Improvement-Rate Soil in Combination with Crushed-Stone MatIn Hokkaido, approximately 2,000 km2 of the land is peat land, an area almost as large as Tokyo. Such land accounts for 6% of Hokkaido’s plains and 2.4% of its total land area. The peat layer is normally 3 to 5 m thick and underlain by a layer of soft, cohesive soil whose thickness may exceed 20 m. In such a ground, consolidation using cement may generate differential settlement between improved soil as a result of embankment construction or lateral deformation caused by the slipping of unimproved ground. Therefore, the improvement ratio (ap) is designed to be at least 50% by the Manual for Construction on Soft Peaty Ground (CERI, 2011 [1]). Consolidation of ground with a low improvement ratio in combination with crushed stone-mat installation is a measure for soft ground (Figure 1). In this method, soil with a lower Improvement ratio than that of conventional improved soil (e.g., ap=10%) is placed beneath the entire embankment and a “crush stone mat”, a layer of crushed stone (t=0.5 m) enclosed by geo-textile, is then placed between the embankment and the soil."

Jan 1, 2015

By L. Shwydiuk, A. Chrzanowski, W. Newcomen, G. Bastin, R. Wilkins

Automated monitoring of steep embankments allows the early detection of instability and can be used to avoid or mitigate possible slope failures. A system that uses multiple and different types of sensors has been created and successfully tested at the Highland Valley Copper mine in British Columbia. The system uses robotic total stations (RTSs) as the primary measurement sensor, with surveys repeated at predefined intervals selected to optimize operational efficiency. A methodology has been developed to improve the system’s accuracy and reliability by reducing the effects of systematic errors created by atmospheric refraction and unstable instrument and reference point positions. The inclusion of GPS sensors to monitor the RTS positions creates additional operational flexibility and maintains system integrity when insufficient reference stations are available.

Jan 1, 2003

By Christian Hoyme, Jochen Maurer

Most of the current foundation projects are suffering from disconnected information silos. In the first silo there is the planning of the project with corresponding data, presented by paper or digital drawings. Here will Building Information Modeling (BIM) be one of the trends for the future. We will see more and more projects leaving the “old way” of 2D drawings and moving into 3D planning including metadata of the foundations. But even with a perfect BIM model of a jobsite, we are not at final end of digitalization. While execution of the project at the jobsite, a second data silo is evolving. Data collected directly from construction equipment and manual measurements is currently undervalued in most projects. Paper is passed to the equipment operator and major data from measurements on site are noted on paper and digitized afterwards. Automatically collected data is not be used to create site progress reports or similar report. So, the real “data” just flows around without connection to any other data already existing in projects. And then the third silo arises: The documentation of the project. Data collected on paper es reentered to create some basic documentation of the work handed over to the client. Spreadsheet software is still the “tool-to-be-used” to create at least some documentation. Finally, the documentation is not connected to the data created while planning and not connected to the automatically collected data from the jobsite. A connected jobsite in the foundation industry must link these information silos and have to create a full data-workflow from the design through the execution to the as-built documentation. INTRODUCTION Building information modelling (BIM) is currently the most popular term of construction business in Germany and probably all over the world. But as often there are many different definitions out there and everyone has his own definition or at least understanding what BIM is about. But for sure it is the most relevant for the construction industry in the near future. Most popular is the digital twin for the upper structure of a building. In most cases the BIM models just shows the building itself, but there is more to be implemented. For example: projects where a special foundation is needed, BIM should include also the foundation elements with meta data. There are several advantages. Not only the clash detection of anchors, but also the possibilities to check the interaction with neighbor constructions, power lines and so on are a use case. For sure most of the special foundation elements are not relevant for the whole lifecycle of a building. But during construction and later the demolition the information about the hidden elements is important and gives a benefit to all stakeholders. In the future there will be not the question: “What is already in the ground?”. The risk for following construction projects on the same ground will be minimized.

Jan 1, 2019

This paper examines the complex interplay of deposit characteristics, mining plans, tailings disposal techniques and rehabilitation requirements on planning for mineral sands operations. All component parts of this mining cycle are interdependent and cannot be evaluated in isolation when optimising a mineral sands operation. This is most evident when projects are large-scale or involve resources that contain complexities such as high slimes content, consolidated hard band materials, acid forming materials and radioactive materials. Projects located in environmentally sensitive areas add further to the need for more stringent planning. This paper describes the analysis techniques adopted by Hatch to evaluate mining and tailings placement options for a dredging and floating concentrator system. The principles and methods used in the analysis are applicable to any mining system involving the complexities listed above. The focus of this paper is on the reconstitution of mined material as tailings and the impact of this process on mining schedules and tailings construction and placement options.

Jan 1, 2001

By Veena Sahajwalla

The cupola furnace is a coke-fueled shaft furnace used as a primary melting unit in iron foundries. Control of chemical composition of the iron tapped from the cupola is a key factor in productivity and quality control. In an effort to develop a control model for the cupola, a fundamental approach based on physical and chemical principles has been taken to describe the melting process. The behavior of oxidation of the solid charge in the stack of the cupola has been studied. Sulfidation of the charge materials by sulfur-bearing components released to the furnace gases from the coke has been described. Carburization of metal droplets of iron and of steel in separate molten streams has been characterized. Finally, reactions with alloying elements in the hearth (well) of the furnace have been defined. These reactions have been described in a computer-implemented model developed to predict the composition of the iron tapped from the cupola. The model has utilized the thermodynamics and kinetics of the oxidation, sulfidation, and carburization reactions, including temperature and physical aspects, in the various zones of the melting unit. The model predictions have been compared favorably with operating results.

Jan 1, 1992

By Milton E. Wadsworth, Jeffrey S. Thompson

The effect of an activator on gold dissolution in clear solution is examined using a rotating disk gold electrode. Steady state polarization curves for anodic dissolution of gold and cathodic reduction of oxygen indicate that the dissolution rate increases in the presence of the activator. The activator enhances gold disso­lution under standard cyanidation conditions; however, optimum activator concentration at the maximum dissolution rate is a function of the cyanide level. In the presence of an activator, the gold dissolution mechanism is controlled by surface kinetics and may be explained by a metal dissolution over-potential model. The dissolution rate with activator is higher than the dissolution rate at a higher cyanide concentration but without activator. The dissolution rate measurements indicate that 3 PPM of activator in a 500 PPM NaCN solution provides a higher dissolution rate than 1000 PPM NaCN alone. Activator technology may be a cost-effective means to reduce cyanide concentration.

Jan 1, 1998

By A. M. Simons

Cyanide destruction by Caro’s acid is one process commonly employed by gold operations to meet regulatory requirements and/or the International Cyanide Management Code compliance for weak acid dissociable (WAD) cyanide in cyanidation tails or waste water from such operations. Typically smallscale bench tests to evaluate and assess the suitability of the Caro’s acid destruction process are conducted. Additionally, the experimental procedure used during these preliminary investigations may also differ from that implemented at the full-scale. This paper presents the results from a fundamental investigation of the Caro’s acid process to establish a more detailed understanding of the impact that the experimental procedure has on the destruction of cyanide. In particular, it was found that the control of pH was important to avoid copper(I) cyanide precipitation at low pH and maximise WAD cyanide destruction. Residual peroxide in the preparation of Caro’s acid has the potential for subsequent cyanide destruction and could be exploited.

Jan 1, 2014

By H Yuan, H Tian, Y Zhang, Z Wang, C Wang

Submerged arc welding (SAW) is one of the significant metal-joining processes for manufacturing marine vessels, steel pipes, and offshore structures with high deposition rate and engineering reliability. Welding flux serves several essential functions, including atmospheric shielding, arc stabilisation, bead morphology control and weld metal (WM) refinement. Therefore, from a thermodynamic point of view, the focus for flux design and WM compositional/microstructural modification has been placed to elucidating the transfer pathways and mechanisms of major alloying elements, such as Si, Mn, Ti and O during welding. To this end, a thermodynamic model has been established to predict alloying element contents in the WM. Such functions are enabled by the physicochemical properties of the fluxes, which are inherently rooted in the nature of the fluxes. A unique yet systematical investigation, including physicochemical property changes and structural evolution behaviours, has been conducted over the wide range of fluxes applied to actual welding of EH36 shipbuilding steels. Combined with spectroscopic methods, structural behaviours of network formers such as SiO2, Al2O3 and TiO2 and network modifiers such as MgO, MnO and CaO have been illustrated. Viscosity and ionic conductivity have been found to be positively associated with the degree of polymerisation.

Aug 21, 2024

A new concept central to the search for sample correctness is presented. In spite of its simplicity, this concept has already unknowingly formed the implicit basis of already established, current limiting rules of use for certain types of samplers, used as mere examples in this paper. Once explicitly enunciated though, this fundamental principle gives immediate, simple and new practical rules for the design of predictably correct sampling equipment and for sampling device auditing. Examples of application are offered as an illustration, including an earlier, important, albeit unpublished, idea found in Pierre GyÆs earlier works.

Jan 1, 2005

By SIMON TIMBILLAH

The chalcopyrite-molybdenite (Cu-Mo) flotation industry is increasingly turning to organic depressants as suitable replacements for inorganic reagents, such as NaHS, due to environmental and safety concerns as well as high consumption rates of the inorganic reagents. This presents an opportunity for improvements or design and synthesis of alternative reagents. Disodium carboxymethyl trithiocarbonate (Orfom® D8) depressant is an organic depressant with a carboxylate group on one end and a trithiocarbonate group at the other end. Fundamental results are shown regarding the interaction of the Orfom® D8 depressant in the bulk flotation of a Cu-Mo concentrate from an operating North American mine. Cyclic Voltammetry on pure copper and Fourier Transform Infrared Spectroscopy (FT-IR) and X-ray Photoelectron Spectroscopy (XPS) measurements on pure chalcopyrite with Orfom® D8 depressant treatment are also reported. Through such characterization techniques a potential adsorption mechanism of Orfom® D8 on the mineral surface was identified and its depressant characteristics in the Cu-Mo flotation systems explained.

By G. S. Rao

Levitated drops of Fe-18%Cr-2%C were reacted with oxygen-argon mixtures to study the reactions that occur in the AOD process, where the gases are injected into the melt and form bubbles. In the laboratory an argon-oxygen pulse, followed by pure argon, was flowed past the levitated drop to simulate the transient conditions in the gas phase as the bubbles rise in the melt. Oxide layers formed on the drops immediately when they came into contact with gas pulses containing 75% or more oxygen. Once the oxygen flow had ceased, the oxides reacted with the carbon in the drops to form CO gas and eventually disappeared. The de-carburization reaction occurred without oxide formation when the gas contained 50% oxygen or less. Melts that were sampled after EAF tapping, ready to be charged into the AOD, showed a higher tendency to oxide formation and consequent carbon boil than pure ternary Fe-18%Cr-2%C alloys made in the laboratory. The actual steel samples contained significant impurities, such as 0.25% Si and 0.56% Mn. A similar effect of oxide-forming impurities had been observed previously with binary Fe-C alloys. Movies were taken of the oxide formation and decomposition, and the results will be presented, along with data on the experimental conditions, including temperature and oxide compositions. The results are important because they give an insight into the reaction mechanisms in the AOD, which must be understood in order to improve and model the process.

Jan 1, 2006

By Z. T. Bieniawski, R. K. Zipf

"Zipf Jr., R.K. and Bieniawski; Z.T., 1989. A fundamental study of respirable dust generation in coal. Min. Sci. Technol., 9: 87-99Black lung disease in coal miners induced by the formation of fine fragments of coal imposes very high human and direct costs. A fundamental understanding of the fracture processes leading to fine-fragment formation in coal by applying principles of fracture mechanics is presented. A four-step hypothesis is proposed which sequentially describes the mechanics of fine-fragment formation during a generic coal material—coal cutting tool interaction. These steps include: (1) development of a crush zone under the tool tip, (2) macrocrack propagation. (3) shear movement along macrocracks, and (4) additional fragmentation from shear. This model contains two sources of fine fragments, namely crushing under the tool tip and shearing along the macrocrack surfaces. Three critical assumptions are made that require experimentation. First, the coal material must contain flaws of sufficient density and sufficiently small size to liberate fine fragments by crushing. The following conceptual relationships are proposed between flaw size, spacing and fragmentation: first, the active flaw size must be less than the desired particle size and second, the spacing (or density) must be in the order of the particle size. The second major assumption is that a mixed mode fracture theory will describe the initiation and crack growth direction for the microscopic inherent flaws. The third assumption is that some degree of roughness damage, and interlocking exist along the newly formed macrocrack surfaces such that a small amount of shear movement along that surface leads to additional particle formation at a microscopic scale. Preliminary analysis of the mechanical regime under a cutting tool tip places order of magnitude bounds on the stresses strains, cycle time, stress rates and strain rates. Even though the tool moves and loads the coal material with considerable speed, a quasi-static stress analysis is applicable in this region.Introduction.The generation of fine fragments (respirable dust) during various coal mining processes may lead to the incidence of coal workers pneumoconiosis (black lung disease). The human and direct cost of dust-induced illnesses in coal miners is very large. By several. accounts [1,2] the Federal Government paid out about $12 billion to almost 500,000 coal miners and their beneficiaries between 1970 and 1980. In addition, several states and many coal operators have established their own compensation programs at costs ranging from a few cents to several dollars per ton of coal mined [2]. Since 1980, 'the present liability of the Federal disability trust fund has approached $20 billion and the benefit payments exceed $1 billion per year. There .are also hidden costs due to dust, in the form of increased equipment wear and decreased operator productivity, both of which are due to the poor operating environment. Quantifying these costs may be difficult; however, they may be in the same range as the present pneumoconiosis costs. These high human and direct dollar costs may be prevented or reduced through long term research efforts directed at understanding the generation and control of respirable dust and the incidence of black lung disease."

Jan 1, 1989

By Michael J. Nicol

This paper summarizes some of the results of a study of the reactions involved in the Caron leaching process and identifies the roles of the major dissolved species in the kinetics of dissolution of iron alloy particles formed during reductive roasting. Using rotating disk electrodes and synthetic leach solutions, the reduction of water with the evolution of hydrogen was found not to occur on a dissolving iron surface under typical leach conditions. It has been established that the oxidative dissolution is governed primarily by a reaction involving reduction of Co(III) to Co(II) ions. The reduction of oxygen was also found to make a significant but largely indirect contribution to the kinetics of the dissolution process. The dissolution rates of various iron-nickel-cobalt-copper alloys which simulate the dissolving alloy particles in a Caron plant were measured in synthetic leach solutions under aerobic and anaerobic conditions. The initial dissolution rates of iron, nickel and the iron alloys were found to increase in the presence of thiosulphate, whereas the thiosulphate had a negative effect on the dissolution rates of cobalt and copper. It is shown that the eventual passivation of the iron occurs sooner in solutions rich in Co(II) ions. Whilst these conditions are present in the quench slurry, on-site measurements have shown that due to the very high concentration of reduced dissolved species, passivation does not occur until the slurry is strongly aerated. In the light of these fundamental findings, options for optimizing the rate of dissolution and minimizing the extent of passivation of the iron and iron alloys are discussed. Keywords: Ammonia, leaching, alloy, kinetics, passivation.

Jan 1, 2004