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By Michael S. Moats, Scott C. Campin, J. Brent Hiskey

"Electrochemical techniques are a valuable means of analyzing the passivation of commercial copper anodes. Electrochemical impedance spectroscopy (EIS) provides information concerning transport and reaction phenomena occurring at an electrode surface. Commercial. copper anodes of varying compositions have been examined using EIS. Experiments were conducted in a flat cell with an electrolyte of 40 gil Cu2 + and 160 gil H2S04 maintained at 65 DC. Impedance spectra were obtained at the potentials characteristic of the open circuit voltage and passive region for each anode. The spectra of the passivating films exhibited a flattened resistive/capacitive loop at middle to high frequencies and an inductive loop at low frequencies. An equivalent· circuit utilizing an inductor-resistor series in parallel with the double layer capacitance and charge transfer resistance was adequate in modeling the impedance data. The influence of anodes impurities on the components of the equivalent circuit is discussed and correlated with a hi-layer passivation model.IntroductionPassivation of copper anodes during industrial electrorefining has received considerable attention in the past few decades. Great strides have been made in understanding the roles of anode impurities [1-25], electrolysis parameters [20,26], and electrolyte chemistries [20,26]. Even so, passivation still occurs even in the most modem of refineries. The exact cause of passivation is not fully understood. It is known that the anode surface becomes covered by a passivating film. This film has been proposed to be CuS04'&5H20, Cu20, or mixed oxides. The localized concentrations of Ft, Cu+, and Cu2+ ions determines which phase is more favorable. The presence of these ions is controlled by the reaction kinetics and diffusion of species through the slimes layer.Reaction kinetics between Cu, Cu +, and Cu2+ are based on the dissolution mechanism of copper. There exists four different models to describe the dissolution of pure copper. The classical model of Mattsson and Bockris [27] involves two single electron transfers with the cuprous-cupric reaction being the rate detennining step. More recently, Wong, Collier, and MacFarlane [28] used ac impedance to elucidate a more complex mechanism involving the affect of pH and anions. Their findings indicate that the formation of cuprous ions in solution, Cu(I)so~ is favored over Cu(1I) ions adsorbed to the electrode surface in the presence of sulfate and as pH increases from pH 1 to pH 5."

Jan 1, 1997

By B Crossley

Self-cleaning fluidised bed heat exchangers have demonstrated unparalleled performance internationally for the implementation of indirect heat transfer in severely fouling fluid environments. Recent advances in equipment design have increased the scope of application to include indirect heat transfer in slurry environments, including fouling, scaling and viscous slurries. The ingenious configuration of recirculated cleaning particles through the tubes of vertical shell and tube heat exchangers provides the ability to solve heat transfer problems that arise as a consequence of tube-side fouling during indirect heat transfer to process fluids or slurries. In most cases, the cleaning particles consist of chopped metal wire, however other process-specific materials may be used.

Jan 1, 2004

The introduction of a new mining method to Australia is not without its risks and challenges. This paper discusses the processes of planning a new operation, with particular emphasis on block caving and its Northparkes adaptation. As well as applying advanced technologies, here also is the opportunity to develop the art and science of block caving for its application to a wider range of geotechnical conditions than previously Envisaged.

Jan 1, 1995

The goal of the Bureau of Mines diesel engine research program is to reduce exhaust emissions and minimize the risk of fires and explosions caused by the use of diesel- powered equipment in underground mines. This program has led to a fundamental understanding of the problems and to solutions that allow diesel equipment to be used safely and effectively. This volume contains reports of the presentations made at the Bureau Technology Transfer Seminar on Diesels in Underground &fines given in Louisville, KY, and Denver, CO, on April 21 and April 23, 1987. It also contains three reports of related research, not presented at the seminar, which highlight the significant achievements of a joint US.-Canadian research program on diesel emission control technology for underground mines. Topics covered in this volume include discussions of industrial hygiene problems associated with the use of diesels, accident statistics, fire and explosion control systems, measurement of diesel pollutants, emission control techniques including engine maintenance, fuel additives, diesel particulate filters, and ventilation of diesel sections. An alternative to diesel power, the hydrogen-powered mine vehicle, is also described.

Jan 1, 1987

The Institute has prepared a list of Societies' publications, magazines, . etc., which were duplicates and were discarded at the time of the consolidation of the libraries of the three Founder Societies. These books will be disposed of about March 1, 1916 by the Board of Directors of the Institute through the Library Committee. If, meanwhile, members who have incomplete sets of these books, or for any other reason desire to secure some of them, they are asked to communicate immediately with the Secretary, as this is in unusual opportunity to secure books at a very low price. American Gas Light Journal, viols. 31 to 39. American Institute of Electrical Engineers, Transactions, vols. 5 to 26. American Machinist, vols. 3 to 20, 22 to 29. American Society of Civil Engineers, Transactions, vols. 2 to 10, 21 to 24, 26 to 33, 39 to 49, 52, 55, 58, 74. Index, viols. 1 to 21. American Society of Mechanical Engineers, Transactions, vols. 1 to 28. Index, vols. 1 to 20, vols. 1 to 25.

Jan 1, 1916

By Robin J. Batterham, Dave J. Robinson

The history of mineral processing in general and flotation in particular is long and has always been tied to mining methods of the day. Building on the ever-improving fundamental understanding of the underlying science, the most significant trend in flotation has been the putting into practice the learnings from trailblazers such as Professor Fuerstenau that has given the confidence that enabled an ever-increasing scale of operations. There is, however, doubt this ongoing trend is enough to maintain the economics against global trends such as that of falling grades, increasing mining costs, pressure on water supply and demand, rising energy demands needed for mineral processing, and a focus on whole of life value and mine legacy issues. In addition, we see that globally, the social license to operate for mining (and hence mineral processing) is far from secure and, at the very least, is under much more rigorous scrutiny. In this paper, we comment on the ramifications of broader uptake of more sustainable mining for mineral processing methods and address the specific question of whether recent progress in in-place recovery will lead to a timely breakthrough. The answer proposed is that this is possible in the next 10–20 years but in the meantime, the focus is just as likely to be on removal of waste (beneficiation) much earlier in circuits. Either way, mineral processing and flotation, as we know it, will change significantly.

By Marco D. Boscardin, Paul A. Roy, Kevin J. DiRocco, Andy J. Miller

The North Shore Connector Project for the Port Authority of Allegheny County involves TBM mining a pair of subway tunnels through soil and rock under the Allegheny River and a narrow city street. Along the tunnel alignment are a historic building on shallow foundations and modern buildings on deep foundations, one constructed directly over the alignment during the latter phases of design. This paper provides an overview of the general site conditions, and technical basis for excavation support and tunneling decisions. Deformation limits, ground improvement, monitoring and mitigation plans, geotechnical baseline report development, and risk management will also be discussed.

Jan 1, 2007

By Michael I. Brittan, Craig M. Sams

"Economies of scale and the variable characteristics of many large ore deposits have resulted in grinding installations using very large SAG mills fitted with variable speed drives. Low-aspectratio single-stage SAG mills were introduced in South Africa to process the consistent gold bearing Witwatersrand quartzites. Elsewhere, circuits were patterned after the more conventional North American circuits with high-aspect-ratio SAG mills followed by ball mills. This paper provides information on two recent Gold Fields group installations covering both types of SAG mill in large, single-stage applications. While these operations process similar tonnages, the mills represent opposite ends of the aspect-ratio spectrum. The Tarkwa mine in Ghana employs a low-aspect 27’ x 42’ 14MW SAG mill. The St Ives mine in Australia operates a conventional 36’ x 18’ 13.4MW SAG mill.INTRODUCTIONGold Fields is one of the world’s largest gold producers with annual production of approximately 4.2 million ounces. The Gold Fields group has operations in South Africa, Ghana and Australia, along with numerous exploration sites and advanced projects in several other countries. This paper discusses new milling operations in Ghana and Australia.TarkwaThe Tarkwa Gold Mine is located in Ghana, West Africa, approximately 350 kilometers west of the capital city of Accra (Figures 1 and 2). The site conditions are tropical with an average annual rainfall of 1,930 mm and a maximum temperature of around 35°C."

Jan 1, 2006

By Yan Yuan

Stable Nitroxyl polymers, such as poly (2,2,6,6-tetramenthyl-1-piperidinyloxy-4-yl methacrylate) (PTMA), are known to be effective as cathode active materials for lithium rechargeable betteries.The nitroxide radicals displayed a reversible and very rapid redox performances.We present a new synthesized method to get PTMA powder, then a doctor-blading method was used to prepare the PTMA composite electrodes, enabling successful production of homogeneous electrodes. It was characterized through FT-IR and SEM methods.The organic radical battery consists of lithium metal anode and PTMA cathode with an active material content of 65wt%.The best performance is achieved with a thin cathode that shows nearly 100% utilization of the active material (111mAh/g) at 0.1C.Through the electrochemical tests, it was found that there was a stable plateau at 3.5V while discharging. Besides, the cycling stability and rate capability were measured in detail. Although they showed a certain quantity of irreversible capacity on the first cycle, the capacity stabilized after the second cycle.

Jan 1, 2009

By J. Tanner Blackburn, James R. Gingery, Lisheng Shao

Rigid inclusions consist of grout columns installed using displacement auger or vibrated tooling. The columns are typically installed in an array to provide support for footings, mats, or embankments. Due to the relative small column diameter and low replacement ratio, the surrounding soils typically have minimal densification or improvement. A gravel load transfer platform is commonly used above the rigid inclusion head to distribute stresses more broadly to the supported structure. The axial stiffness and geotechnical engineering mechanics of rigid inclusion design are similar to those of deep foundation systems, but they are typically only lightly- or un-reinforced and are not structurally connected to the above-grade structure. The popularity of rigid inclusions is increasing in the Western U.S., where many urban areas are subject to moderate to high seismic hazard levels. However, the performance of rigid inclusions under seismic loading is poorly understood, and seldom addressed in current designs. The elements are brittle, with limited or no ductility and relatively low moment capacity, and therefore may be prone to damage under seismic loading. Three modes of seismic loading should be considered: inertial loading from the structure, kinematic loading from vertically propagating shear waves, and kinematic loading from ground failure- related permanent ground deformation. This paper focuses on the first two modes. A simplified procedure for evaluating kinematic and inertial loading of rigid inclusions is described, and its use is illustrated through application to a site in Southern California. The results show that moderate to severe kinematic loading can generate plastic hinges in the rigid inclusions. Engineering consequences of this hinging could include settlement or bearing failure. INTRODUCTION In this paper the term ‘rigid inclusion’ (RI) refers to grout or grouted aggregate columns that are installed using either drilled or vibration displacement techniques. They are commonly installed in arrays to support vertical loads from footings, mats, or embankments. RIs are not structurally connected to footings they support. Rather, it is typical for a dense gravel load transfer platform (LTP) to be installed as a cushion between the RI head and supported footing or new fill. In cases of RI support of fill embankments, the LTP may be reinforced with horizontal layers of geogrid.

Jan 1, 2018

By Z. J. Hladysz

A Deep Underground Science and Engineering Laboratory (DUSEL) is being planned at the site of the former Homestake Gold Mine in Lead, South Dakota, under the sponsorship of the National Science Foundation (NSF) in cooperation with the Department of Energy (DOE). This national facility will host a variety of multi-disciplinary science and engineering experiments including physics experiments that require shielding from cosmogenic radiation. Current plans include construction of large rooms (up to 55 m in width) at depths of 1.48 km (4850 ft) and 2.25 km (7400 ft) below the surface. Preparation of the preliminary design required the development of a geotechnical characterization program including: preliminary drilling and coring, core logging, drill hole mapping with a televiewer, drift mapping of the geology and rock structure, in-situ stress measurements, and laboratory testing of the mechanical properties of the rocks and discontinuities. Overall rock quality is very good to excellent. Site investigations were followed by geotechnical assessments for the construction of caverns and laboratory modules. The results are favorable and reaffirm selection of the Homestake site for establishment of a Deep Underground Engineering and Science Laboratory.

Jan 1, 2011

By James Tarr, Matthew Eichler, Brent Tardif

ANFO was being used as one of the blasting agents on a construction site in New England. Groundwater was encountered in numerous blast holes. The blasting contractor was employing typical explosives loading procedures for wet conditions. An abutter to the project complained that blasting caused her well water to have an odd taste and smell. Through testing, it was determined that there were hydrocarbons and nitrates in the well water. Several days later a second neighbor complained of foul tasting water; again it was determined that hydrocarbons and nitrates were present.

Jan 1, 2003

By H. Y. Sohn

The considerable progress made in the sulfide smelting technology since the first International Sulfide Symposium of 1983 is discussed. The new developments and innovations have largely been driven by the recognition of environmental concern as well as the need for increased productivity. The smelting technologies for various nonferrous metals are reviewed, with an emphasis on the industry trend towards larger plants and continuous processes. The tremendous advances made in process modeling and computer simulation to describe the complex smelting processes are also reviewed. The goal of these mathematical models is the quantitative description of the processes and the reactors that will provide a means for the control and optimization of smelting operations as well as the optimal design of the operating conditions and the reactors. Environmental issues remain a key consideration in the smelting industry. One of the most remarkable improvements made in the last fifteen years since the 1983 Sulfide Smelting Symposium is the rapid increase in the sulfur capture by nonferrous smelters. This and other related issues are briefly discussed. Finally, the challenges that the smelting industry faces as the new millenium approaches are discussed. The industry continues to face technical challenges to improve productivity and efficiency, while being responsive to ever-increasing public pressure for environmental protection. It also faces external challenges from factors that may cause the reduction of metal uses as a result of substitutions by other materials. Another serious challenge and dire consequence that the primary metals industry is expected to face is the serious diminution of university-educated manpower as well as basic-research output. To remain competitive and healthy, the industry should take up the void left by the complete disappearance, at least in the U.S., and the reduction in other nations, of the governmental support of higher education and basic research in the field of primary metals production.

Jan 1, 1998

By G. Lipsett, S. Dessureault

Information technology (IT) initiatives in the past have tended to be sold on their ability to maximize resource output and return on capital by allowing assets to be used more effectively and efficiently. Many IT projects fail, not delivering return on their investment. This is known in the IT industry as the “productivity paradox,” where increasing investments in IT do not result in comparable increases in productivity. Experiences and studies of most business sectors reveal that this paradox is rooted in the false assumption that more IT spending automatically results in financial benefit, whereas the benefits are in how effectively IT is used. Most business sectors have accepted that re-engineering of processes is required to gain the full benefits promised of IT. A mining operation has organizational processes similar to most business sectors, but unique operational processes. The lessons of changing business practice in more common business processes, such as inventory control and customer-supplier relationships, can be adequately transposed into a mine setting. The unique operational processes in mines, in turn, require unique redesign efforts. Several enabling information technology opportunities have recently become available, such as more integrated mine production management systems and tactical manager training simulators. This paper reviews some of the latest IT products and outlines the processes and kinds of change that will be required in order to benefit from these new investment options.

Jan 1, 2009

By Mark R. Svinkin

Construction vibrations may adversely affect surrounding buildings and their effects range from human discomfort and disturbance of sensitive devices to visible structural damage. There is no unique conclusion regarding the effect of construction vibrations at every site. Measurement is usually made to monitor vibrations and control them with the vibration thresholds for disturbance of sensitive objects as well as damage to structures. To prevent potential litigation and mitigate the vibration effects on sensitive devices, people and structures, it is necessary to manage and minimize vibration problems before the beginning of construction activities or installation of vibrating machine foundations, and during construction. Pre-construction damage survey and engineering vibration investigations, including the prediction of anticipating vibrations, have to be made at most construction sites in advance of construction activities. Vibration monitoring and control have to be provided during construction. The instrumentation feedback of vibration prediction, monitoring and control provide the basis for choice of measures to prevent or mitigate vibration problems and settlement damage hazards.

Jan 1, 2002

More than 400 academic, Government, and industry representatives attended the third symposium on ash utilization and technology held in Pittsburgh, Pa., March 13-14, 1973. Sponsored by the American Public Power Association, Edison Electric Institute, National Coal Association, National Ash Association, and Bureau of Mines, the symposium Featured 26 formal presentations by leading experts from Europe and the United States on all major phases of ash production, utilization, and research. Abstracts of all the papers are grouped right after this introduction, and the full symposium proceedings follow. Sponsoring organizations and their chief representatives were the National Coal Association, James R. Garvey, Bituminous Coal Research, Inc.; Edison Electric Institute, C. E. Brackett, Southern Electric Generating Co.; American Public Power Association, Herbert Blinder, Columbus (Ohio) Electricity Division; National Ash Association, Inc., James N. Covey, Rochester Gas and Electric Corp.; and the United States Department of the Interior, Bureau of Mines, William L. Crentz.

Jan 1, 1974

By Randy Vranes

Sophisticated information technology, quality management systems and a commitment to the environment has allowed Solutia’s Soda Springs phosphate mine and elemental phosphorus plant to reduce operating costs, improve product quality and contribute to the sustainable development of Idaho’s industrial minerals. Soda Springs background The Soda Springs phosphate mine and plant is a joint venture between Monsanto and its operating partner, Solutia Inc. The operation is based in southeastern Idaho in the Western Phosphate Field. The plant is located about 275 km (170 miles) northeast of Salt Lake City, UT and about 4 km (2.5 miles) north of the town of Soda Springs.

Jan 1, 1999

By M. G. Fleming

The professional mineral engineer is an individual of personal integrity who has undergone rigorous intellectual instruction in the scientific disciplines fundamental to his vocation; he has learnt to apply these disciplines to the discovery, mining and treatment of mineral resources and, through practical training and experience, has acquired competence and judgment to fulfil his undertakings. In the course of this development he has recognised and accepted a threefold responsibility to society, to his employer and to his profession

Dec 1, 1971

By Baha Abulnaga

Slurry pipelines are used in a number of countries to convey processed ore mixed with water over long distances from remote mine sites to ports or plants for further processing. In Egypt and Sudan, numerous mineral resources are scattered in remote areas. Through the years, Egyptian geologists have identified 268 sites for metallic ores and 386 sites for industrial nonmetallic minerals. A large portion of these sites are in the Eastern Desert in an area called the Nubian Shield. Similar sites are found in the Sudan where mining contributes to less than 1 percent of the gross domestic product (GDP). There are three important components of infrastructure needed to develop these resources ? power, water and transportation. While Egypt is able to satisfy 70 percent of its needs in iron ore from the Gadideh Mine in the Western Desert, it needs to expand its other resources to reduce imports heavily sedimented. Dredging of these sediments and transporting them by slurry pipelines would enhance an industry of bricks or agricultural development based on tailings technology often used in mining. This article explores the potential for slurry technology for opening new mines in the desert or recuperating the sediments of the Nile. The technology by itself would be new to both countries and would benefit from collaboration, particularly to de-silt the Nasser-Nubia Lake.

Jan 3, 2010

By S. Ali Bastani, Ashley Varni

Design acceleration response spectra (ARS) are directly correlated with dynamic forces and estimated dynamic bridge displacements, which make them a critical aspect of dynamic bridge design. Nonlinear site response analyses are performed for a 1,400-linear-foot bridge site with a SC soil profile at the sides and a SF soil profile in the middle to evaluate the soil profile effects on the bridge analyses. One-dimensional seismic response analysis is commonly performed for site-specific response analysis. SHAKE or similar one-dimensional total-stress equivalent-linear approaches have been used since the 1970s. However, the equivalent linear method has deficiencies when the subsurface soils are susceptible to strain softening. Therefore, various assumptions are made when using the equivalent linear method by practitioners to estimate the SF soil profile site response. With recent advancements in constitutive models, effective stress models have become more popular. Although the effective stress models are generally more complicated and require additional input parameters, they shed further light on the liquefaction mechanism and its effect on the surface ARS. An equivalent-linear one-dimensional seismic response analysis and a non-linear effective-stress seismic response analysis, using DEEPSOIL, were performed to evaluate the ground surface ARS for a proposed bridge site in Orange County. The soil shear strengths were estimated based on cone penetration test results using empirical relationships. The shear modulus degradations (backbone curves) of soil layers were adjusted to match the estimated soil strength at failure. The ARS curves developed from each method were compared to determine the most suitable method for estimating a site-specific design ARS curve for a liquefiable site. Considering that the bridge abutments and the outer bents are founded in bedrock, while the middle bents are founded in liquefiable soils, ARS curves were created for each subsurface condition. Taking into account limitations of the structural analysis software, recommendations were made to combine the multiple ARS curves into a single ARS curve for the structural bridge design.

Jan 1, 2018