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By V. H. Wilhelm

The outstanding event in the California petroleum industry during 1931 was the continuance of curtailment of crude oil production, which directly reduced drilling and well repair activities. Although all objectives were not attained, a very close balance between supply and demand was maintained during the period of maximum requirements, but the decline in intercoastal and export shipments caused an overproduction during the last half of the year, which indicated that California production would necessarily suffer further curtailment after the end of the year. A new peak in potential crude oil production of 1,187,600 bbl. per day was reported in August and at the close of the year the California potential was 1,069,000 bbl. per day, the shut-in light oil amounting to practically 425,000 bbl. per day and the shut-in heavy oil amounting to about 150,000 bbl. per day. Fig. 1 depicts these conditions and also shows the production and curtailment situation since the inception of proration in California. The December, 1931, potential figure of 1,069,-000 bbl. per day was arrived at after the most careful deliberation by a number of committees, selected to check the potential of practically every well in the state. Continued overproduction in the first three months of 1931 and the inadvisability of building more storage, together with the inability to obtain the proper amount of curtailment in town-lot fields, such as Long Beach, Santa Fe Springs and Playa del Rey, prompted the major oil companies to inaugurate a price reduction in crude oil. This cut caused prices to reach the lowest levels since 1915, and instigated the formation of an oil sales agency, composed of independent operators, which is known as the Oil Producers Sales Agency. The purpose of this organization is to procure a market for its members at reasonable prices, advise them of market conditions and aid them in controlling the amount of oil available for sale. Marketing of oil produced by members began on June 1 and independents controlling" about 160,000 bbl. per day of production had become members by the end of the month.

Jan 1, 1932

By M. T. Worley

This paper reports investigative work conducted to develop a method of estimating the groundwater influx from a homogeneous permeable formation into a vertical mine shaft during sinking. A method of analysis was developed using data obtained from pumping tests and a modification of the Theis non-equilibrium interpretation technique. Excess influx of groundwater into mine shafts has long been one of the more important problems encountered in the development of a mining property. Much work has been done on methods of preventing such influx and on pumping schemes to control inflow if preventive measures fail. The fundamental aspects of the problem, on the other hand, seem to have been neglected. The purpose of this paper is to review the fundamentals of groundwater flow and to propose a rapid method of analyzing hydrologic data in order to estimate influx from a homogeneous permeable formation into a mine shaft. Such an estimate of the quantity of water to be encountered is of value in planning grouting, pumping and other programs designed to control that influx. It is emphasized that the proposed method of analysis should be regarded only as a tool to be used in evaluating the problem before investing the capital necessary to begin development of a property. FUNDAMENTALS OF GROUNDWATER FLOW In order to effectively approach the problem of estimating influx into a mine shaft, a knowledge of the fundamentals of fluid flow through a porous medium is necessary. Darcy, in 1856, developed an empirical relationship to explain the flow of water through sand filters. This relationship V = k (dh/dl), is the basis for all other flow formulae. It has been shown that Darcy's relation is a solution of the Laplace equation and thus is analagous to other natural phenomena such as heat flow. Theis, using the analogy of heat flow by conduction, developed an expression for determining the transient or time-dependent groundwater flow through a homogeneous, isotropic medium. The resulting equation Was also derived by Jacob using hydrologic considerations alone.' The individual terms in the equation are described in Table I. It is important to understand the assumptions upon which this equation is based. 1) The medium through which the fluid flows is infinite in areal extent, homogeneous and isotropic. 2) The well into which the fluid discharges completely penetrates the medium. 3) The characteristics of the medium remain constant at all times. 4) The initial pressure surface is horizontal. 5) The confining media are impervious and horizontal. 6) Fluid is removed from storage instantaneously by a decline in pressure. 7) The diameter of the discharge well is infinitesimal with respect to the drainage radius of the medium.

Jan 1, 1962

By C. E. Agnew

The Eastern district, composed of New Jersey and eastern Pennsylvania, with its native ores, was the cradle of the iron industry of the United States. The district attained and held the leadership in production of pig iron for over 100 years, from pre-Revolutionary days to approximately 1875. The first shipment of Lake hematite ore was made in 1853. It was a small shipment, transported by a sailing vessel and a canal barge, but it was the beginning of the end of the supremacy of the Eastern district, although at that time the ore was supposed to be too rich to be successfully smelted with the block coal then in use at western furnaces. The iron made from the first shipment of Lake ore was worked into nails by the Sharon Iron Co., at Sharon, Pa. The writer's great-grandfather, David Agnew, and his brother, John P. Agnew, owners and operators of the Sharpsville furnace, Sharpsville, Pa., worked the shipment through a furnace. Because of this, the writer feels some satisfaction in having been one of a group that solved the problem of making profitable an operation using Eastern district ores exclusively. With the development of Lake mines, and the production and use of coke, the Middle West district gradually assumed the position of leadership in production; because, even though the ores were transported 1000 miles by water and rail, its cost figure on pig iron was better than that of the eastern producer whose furnace was next to his mine. Such a cost figure was possible because the ore was naturally rich in iron and reduced easily. It was possible to carry a heavy burden on the furnace, which resulted in large tonnage and low coke per ton of iron. This paper is in no sense a technical one. The purpose is to show that with the proper physical preparation of the Eastern magnetites they will reduce as easily as the Lake hematites, and because of the high iron concentration give the Eastern producer just as much advantage as formerly he was at a disadvantage in comparison with the Middle West producer.

Jan 1, 1938

By M. W. Dumais, E. P. Abrahamson

In a paper by Abrahamson and Alexander concerning a series of correlations between electronic structure and property changes, it was hypothesized that each solute atom in a dilute solution had a characteristic volume of solvent atoms over which some form of electronic interaction occurred. From this description it is possible to picture the solute atoms as occurring in an ordered array for the most efficient arrangement. A recent review article2 has shown that some form of anomaly exists for a whole series of properties when dilute additions of tungsten are made to iron, of. Fig. 1. Any mechanism to fit one property must also be amenable to mechanisms for the other properties. The possibility of some structural change in this region appears to offer the best hope. The system chosen for investigation was the iron tungsten system. Zone-refined iron with zone-leveled tungsten additions were supplied by Materials Research Corp. as 3/8-in.-diam bars. Transmission electron microscopy was used to study the structure. One-quarter inch specimens of each alloy were cold-rolled to 10-mil sheets, cleaned, punched to electron-microscope specimen-holder size, and annealed in vacuum for 2 hr at 800°C and 2 hr at 700°C followed by a furnace cool. The specimens were attached to a platinum wire and the specimen edge and wire were painted prior to thinning in a solution of 10 pct perchloric acid in glacial acetic acid. It was believed that if ordering were present due to electronic interactions the polishing procedure chosen would provide a simultaneous combination of chemical attack and electropolishing to exhibit the ordered structure. The chemical attack would be expected to penetrate those areas equidistant from the tungsten atoms, while the electropolishing would serve to "plane off" the volumes where the chemical attack had taken place. If one of the ordered tungsten planes were parallel to the specimen face at the edge of the thinned hole, a plate or micalike structure would be expected. A typical result of this polishing is shown in Fig. 2. Here a series of plates can be seen lying one upon the other. In several other specimens the plates parallel to the electron beam have been observed, behaving like slices of bread in a loaf. These edge views coupled with moire patterns indicate that the minimum plate thickness is 37 to 42A. This is equivalent to a concentration of 455 at. ppm of W if a simple cubic superlat-tice exists, or one tungsten atom every twelve iron atoms on the ordered plane. It was further noted that the base iron exhibited no signs of platelike structure. As the concentrations increased above 100 at. ppm W the amount of plate material increased. Among the specimens investigated was that shown

Jan 1, 1967

By Robert W. Hunt

The American Institute of Mining and Metallurgical Engineers was the first American technical organization to consider steel-rail specifications and sections. If I am not mistaken, the first contribution on those subjects to the Proceedings of the Institute was presented by Prof. Thomas Egleston, in 1874, and was entitled "Investigations on Iron and Steel Rails made in Europe in the Year 1873.1" The next contribution was Dr. C. B. Dudley's report of his investigation for the Pennsylvania Railroad of the wear of steel rails in their tracks, in 1878, which contribution led to a very memorable discussion that extended through several meetings.2 In 1880, Mr. C. P. Sandberg3 presented an article on rail specifications and inspection and rail sections. This was followed, in 1881, by A. L. Holley,4 in his exhaustive report on the then used American rail sections. The next contribution, I believe, was made by myself5 at the Buffalo meeting, in 1888, on steel-rail specifications, which I followed,6 in 1889, by a paper on steel-rail sections. Since that time there have been numerous contributions to the Transactions of the Institute in relation to the manufacture of steel rails. The American Society of Civil Engineers officially took up the investigation of the relation of rail sections to the wear of car wheels in 1888. In the prosecution of this work, the Society appointed a special committee, whose labors extended through several years and resulted in an exhaustive report to the Society in 1893.7 Later, another committee was appointed to consider specifications for the manufacture of steel rails; the labors of this committee extended over a period of several years, a final reporta being made in 1910. It was my fortune to be the secretary of both of those committees. The American Society for Testing Materials, organized in 1899, took up the consideration of rail specifications and is still giving attention to that subject through its established procedure of investigations by committees. In 1900, the American Maintenance of. Way Association was organ-

Jan 1, 1920

By H. M. Howe, A. G. Levy

§ 1 Introduction.—This paper gives the results of our micro-graphic determinations of the position of Ae3 in a series of 14 hypo-eutectoid steels of varying carbon content, one of them very rich in phosphorus, and of SEe for one hyper-eutectoid steel. We have proceeded chiefly by noting the temperature at which the reabsorption of the pro-eutectoid element is found to be complete after a 30-min. holding, but in part also by noting the temperature at which its precipitation begins. Observations on these same steels by Messrs. Burgess, Crowe, and Rawdon, of the United States Bureau of Standards, are given in a paper1 issued simultaneously with this, while in a third paper2 one of us compares these data with those of earlier observers. These three papers are treated as one whole by numbering their sections, tables, and illustrations continuously, and by setting the folding plates of micrographs at the end of the last paper. The Composition of the Steels Experimented On is given in Table I. § 2. Notalion and Definitions.—Following Osmond's development of Tschernoff's notation, in which " Ac3 " is the upper limit of the hypo-eutectoid part of the transformation range as observed in heating up, and " Ar3 " is that same limit as observed in cooling down, and following the usual custom of calling the upper limit of the hyper-eutectoid part of that range " SE," we may go farther and call this latter limit " SEc" when observed in heating up and " SEr " when observed in cooling down. Further, we may call the equilibrium position of these lines, i. e., the position which they would have in pure iron-carbon alloys if all

Jan 1, 1914

By Morris Cohen

It has been known for several years that in certain age-hardenable alloys precipitation of finely divided particles occurs simultaneously with the changes in physical properties; while, in other alloys, these changes take place prior to, or without any, precipitation. The silver-copper alloys are generally considered to be the classical example of the first group, and the aluminum-copper alloys (duralumin) are typical of the second group. The two types of aging are explained by the precipilation theory and the knot theory respectively.‡ It is well recognized now that these theories do not conflict with each other; the one used for a given aging system depends upon which way the alloy in question happens to age-harden. However, previous work on the aluminum-copper al1oys1,2 has shown that if the aging temperature is raised sufficiently the hardening will be accompanied by actual precipitation. In fact, it is quite probable that all of the so-called knot-hardening alloys will harden by precipitation at elevated temperatures. Therefore, a combination of the knot and precipitation theories is necessary to give a complete picture of the agehardening of these alloys, and indicates that knot formation and precipitation are not independent processes. To test the generality of this concept, it is necessary to show that the alloys that commonly harden by precipitation will harden prior to precipitation if the aging temperature is sufficiently lowered. For this reason, it would be well to carefully re-examine the aging characteristics of the silver-copper alloys at aging temperatures somewhat below those used by previous investigators. If hardening can be detected prior to precipitation in these alloys, it will lend great weight to the idea that knot forma-

Jan 1, 1937

HAVING promised you to write concerning the nature of ores in particular, I must tell you some general facts, especially those concerning the places, kinds, and manner of their existence as well as the tools which are used. However, you must know that according to good investigators these ores are found in many parts of the world. They show themselves almost like the veins of blood in the bodies of animals, or the branches of trees spread out in different directions. Indeed, careful investigators of minerals, wishing to show by analogy how ores are located in mountains, have drawn a large tree with many branches, planted in the middle of the base of a mountain. From its principal trunk extend various branches, some thick, some slender, exactly like real trees in mature forests. They think that these grow and enlarge continually and draw themselves toward the sky, ever converting into their own nature the most disposed adjacent materials so that finally the tips arrive at the summit of the mountain and emerge with clear sign, sending forth, in place of leaves and blossoms, blue or green fumosities,* marcasites with small veins of heavy mineral, or other composition of tinctures. From these things, when they are found, it is possible to make certain inference that such a mountain contains ores, and as the signs are more or less, so are the minerals plentiful and rich or poor. For this reason the prospectors for these things take heart according to the manifestations that they find, and with hope and certainty of profit they take all possible pains to mine with skill and expense those things that the signs have indicated. Often there are ores of such a kind and quality that they raise a man in wealth to the skies. For this reason men penetrate with eyes of appraisal and judgment within the mountains and see almost exactly the places where there is ore and the

Jan 1, 1942

By Thomas A. Edison, John Birkinbine

The Transactions already contain many valuable papers on the subject of ore-concentration, but with reference more to the treatment of other ores than those of iron. In this country much money, labor and thought have been devoted to the enrichment of iron-ores by roasting to drive off sulphur and carbonic acid, eliminate water, or make the ore more friable, and by washing and screening to remove the clay and sand from earthy ores. In concentrating magnetites and hematites more has been done than is generally believed; but, unfortunately, the results up to the present time have not been encouraging. On the contrary, so many attempts have proved unsatisfactory that any system of concentration is now unjustly looked upon with doubt, and the problem presented to individual mines must therefore be approached with caution. For many years the magnetites of the Adirondack region of New York State have been roasted, reduced to proper size by means of gang-stamps, and jigged on screens in water. Latterly plunger-jigs and rotary-jigs have been introduced, and in some places crushers and rolls have taken the place of stamps. In one instance in that region a plant for reducing the ore by crushers and rolls and separating it by magnetism was put up to treat a titaniferous ore; but, the titanium occurring as ilmenite, the result was unsatisfactory, and the plant is now being reconstructed at another mine, where apatite and silica are to be separated from the magnetite. A large concentrating works was erected at Negaunee, Michigan, in the Marquette region, Lake Superior, to enrich the leaner specular ores. This consisted of crushers, Cornish rolls and rotary-jigs. The results ohtained weye not satisfactory, and it has been abandoned. Another plan to treat the lean magnetites from a large dump-pile at Republic, Michigan, by means of pulverizers and water-jigs also

Jan 1, 1889

By Marshall D. Himes

The Pima mine, Pima County, Ariz., a 53,500-tpd copper mine, is located 17 miles south of Tucson, Ariz. The mine is in a sequence of Paleozoic and Mesozoic sediments striking east-north-east and dipping southeasterly. These sediments are intruded by a Tertiary quartz monzonite porphyry. The Paleozoic Permian (?) dolomites, limestones, and sandstones have been altered to calc-silicate skarn, marble, and quartzite. The overlying Mesozoic Triassic (?) clastic sediments have undergone some recrystallization and hydrothermal alteration. The clastic metasediments are divided into three distinct lithologic units: lithic arenite, arkose, and interbedded and overlying black argillite. Three types of hydrothermal alteration in the clastic rocks are propylitic alteration (epidote, chlorite, and quartz, with or without sericite), quartz-sericite alteration, and potassic alteration (K-feldspar, quartz, and sericite, with or without chlorite and calcite). The porphyry has undergone potassic alteration. Dominant structures are an east-west postmineral fault in the western part of the pit, and strong low angle faulting and shearing which truncates the ore body at depth. The two joint sets, one parallel to bedding and the other at right angles to bedding are prominent in the mine. Faulting is in two dominant directions, one striking northwest, dipping northeast, and the other striking northeast, dipping northwest. Economic mineralization is prediminantly disseminated pyrite and chalcopyrite, and molybdenite-quartz veinlets. There are less important amounts of magnetite, hematite, sphalerite, galena, tennantite, and bornite. Mineralization is believed to be both structurally and chemically controlled.

Jan 1, 1974

By Horace Knerr

The term. "high-yield-strength," used in the title of Dr. Gillett's paper (p. 40) is obviously relative. His discussion is limited to improved steels intended to compete with the low-cost, low-carbon, hot-rolled, sheet and plate steels of commerce made and used on a tonnage basis, without heat-treatment. In his list of about three dozen steels, only three have a yield strength of 70,000 lb. per sq. in., or over. Double such values are not uncommon in aircraft steels. Dr. Jeffries (p. 21) refers to "light-weight metals," obviously meaning strong alloys of low specific gravity; namely, aluminum alloys of the duralumin type and certain magnesium alloys. In a structural material, "lightness" is determined by two factors, strength and specific gravity. They must always be considered jointly. The basis of comparison is a strength-weight ratio, obtained by dividing the desired strength value, such as tensile strength, yield strength, or endurance limit, by weight per unit of volume, such as specific gravity or pounds per cubic inch1. For example, aluminum is a heavy metal, structurally, unless alloyed and heat-treated to give it high strength. When the strength of a structural metal is raised by heat-treatment or by cold-work, its specific gravity is not appreciably changed, but it is made lighter in direct proportion to the increase in strength because less of it will be required to carry the load. The lightness of the finished structure of adequate strength is the real point of interest. This structure must not only carry designed load, but "stand the gaff" of service, which includes the effects of accidental overload, fatigue, corrosion, loosening of joints, and so forth. Neither Dr. Gillett nor Dr. Jeffries mentions the true "lightest material of construction," which is alloy steel, tubular in form (Fig. 1), assembled by welding and heat-treated to a yield strength in excess of 150,000 lb. per sq. inch.

Jan 1, 1936

By W. F. Brace, James D. Byerlee

Although prediction of failure of rocks may be ultimately possible without knowing in detail how failure occurs, understanding of this process is certainly of fundamental interest in rock mechanics. Of the various failure mechanisms, probably brittle fracture is of greatest interest. Recent reviews have brought this subject nearly up to date (Hock,1 Price,2 and Jaeger 3) and here, we summarize certain recent developments. As our understanding of brittle fracture is derived almost solely from laboratory studies this will amount to a review of certain laboratory experiments. New studies in four areas are pertinent; these concern 1) the volume changes which accompany brittle fracture, 2) the propagation of cracks in compression, 3) certain frictional characteristics of rocks and minerals at high pressure, and 4) the law of effective stress for crystalline rocks. Our objective here is less to present an entirely consistent, complete picture of how a rock fractures than it is to emphasize gaps in our understanding and, thus, suggest areas that need further study. Progress is still painfully slow in this field and perhaps this approach will stimulate new work. OBSERVATIONS Although the behavior of large rock masses is most often the concern in rock mechanics, the number of large-scale experimental tests is still vanishingly small. Our experimental observations arc, by and large, still made on small, relatively flaw-free, rock samples. Here also we report the behavior of small samples.

Jan 1, 1967

By E. T. Turkdogan, L. S. Darken, R. G. Olsson, H. A. Wriedt

Several aspects of the calcination of Michigan limestone were investigated: the rate of calcination of limestone spheres with diameters from 1.8 to 14 cm at temperatures from 800° to 1200°C by a thermogravimetric method; the temperature profile across limestone during calcination; the excess pressure developed in the interior of the stone during calcination; the pore surface area, pore volume, and effective gas diffusivity in burnt lime; and the microstructure of polished and fracture surfaces. It is found that, over a wide range of experimental conditions, the difference between the surface and center temperatures remains essentially unchanged during the latter half of calcination. From the rate of weight loss after about 50% calcination, the value 0.00126 cal per cm sec degree is found for the effective thermal conductivity of burnt lime. From the excess internal pressure measurements, i.e., 0.4 to 6 cm Hg at 800° to 1200°C, the permeability of burnt lime is estimated to be within the range 8 X 10-' to 5 X 10' sq cm. With increasing temperature and time of calcination, the pore structure of burnt lime coarsens as indicated by a decrease in the pore surface area, pore volume, and an increase in the average pore size. For the temperature range 600° to 835°C the ratio (effective gas diffusivity/molecular diffusivity) is about 0.18.

Jan 1, 1974

By R. J. Wensley

The use of small substations for the supplying of 275-volt energy to the locomotive and cutting machines in coal mines is a well-established practice. A few years ago, when labor costs were lower, these substations were located as near to the load as possible, and an operator was provided for each station. This practice has now become so expensive that substations are being located with reference to other mining machinery, such as hoists or pumps, so that one operator can look after both. Sometimes the substation is operated by one whose duties make him traverse quite a large area. In such cases the interruption of alternating-current supply may produce a long interruption in the direct current, as the station cannot resume service until this man reaches it. Such interruptions interfere seriously with production and may easily counterbalance the supposed saving gained by such operating methods. The grouping of substations for convenience in operating may also result in excessive copper loss and consequently poor trolley voltage, with its attendant evils of low locomotive speeds and increased locomotive motor maintenance. The speed of the coal-cutting machines will also be reduced. By relieving the substation of its burden of the operating labor cost, the most economical location, from an electrical standpoint, may be chosen. The matter of machine insurance should also be considered. If an attendant is caring for several kinds of equipment, he cannot watch the machine continually for signs of trouble; therefore, continued overload, phase failure, low alternating-current voltage, bearing trouble, etc. may result. Some partly automatic equipments have been installed; these have protection against low voltage, reverse current, and bearing trouble and are provided with automatic reclosing circuit breakers. This is a step in the right direction but it does not go far enough to give first-class machine insurance. The saving in maintenance costs is often the smallest item, when considering the automatic substation as machine insurance. When the coils in a machine are roasted out, due to continued overload or to opera-

Jan 1, 1922

By Oliver Bowles

WHILE vast quantities of limestone and dolomite. are used in metallurgy, the estimated production in 1926 being 23,860,000 tons, there are many problems connected with their use which have not received adequate study. The literature of metallurgy is notably lacking in comprehensive discussions of fluxing or furnace stone. Approximately 900 lb. of limestone is used for every long ton of pig iron produced in the blast furnace, but this important constituent of the charge receives little attention compared with the intensive study that has been applied to ores and fuels, the other important constituents of the charge. In an effort to elucidate some of the doubtful points, the writer has made a wide review of metallurgical literature, and has had the disappointing experience of finding not more than a paragraph or two on metallurgical stone' for each two or three thousand pages of literature reviewed. Furthermore, the limited information supplied is in some instances contradictory and even absurd. For example, a correspondent in a reputable metallurgical magazine classifies magnesia and silica together as impurities in flux "that must be melted and run off as slag." From the furnace operator's viewpoint it is desirable that as complete knowledge as possible be obtained concerning the effects of chemical composition and physical character of the stone on its action in the furnace and on the quality of the metal produced. A better knowledge of these features is advantageous also to the quarry operator in that it enables him to work more intelligently in producing stone that will best satisfy the metallurgists' requirements. The following pages comprise a brief compilation of data now available. Much of the information is well established and probably acceptable to most metallurgists. On some points there is room for debate, and the chief purpose in presenting a paper at this time is to arouse discussion which will throw more light on controversial points and thus assist the author in preparing a more comprehensive and accurate discussion of metallurgical limestone problems.

Jan 1, 1928

By M. G. F. Söhnlein

IN THE metallurgical treatment of sulfide silver-tin ores mined at Oruro, Potosi, and Chocaya, the most important and difficult step is chloridizing-roasting. The ores are chiefly mined from veins in rhyolite, a detailed description of which can be found in most textbooks on ore deposits. The chief gangue minerals are Pyrite and quartz, and the silver content is derived from tetrahedrite, jamesonite, stibnite, and cylindrite. Most of the tin is present in the form of a rather impure cassiterite, which forms microcrystalline aggregates of varying richness with quartz and pyrite; occasionally, some tin is found as stannite, cylindrite, and other complex sulfantimonates. The silver content of the minerals that compose the ore is approximately as follows: Pyrite, 3 to 5 oz. per ton; jamesonite, 30 to 50 oz. per ton; stibnite, 30 to 150 oz. per ton; cylindrite, 200 to 300 oz. per-Jon; tetrahedrite, 500 to 3000 oz. per ton. Occasionally, some ruby silver ore is found, but it is very rare. In the mines of Oruro, which are the deepest in the sulfide zone, tetrahedrite has nearly disappeared, stibnite, jamesonite, and, in the deepest levels, cylindrite taking its place. At present, there are six mills treating this ore, two at Potosi, two at Chocaya, one at Poopo, and one at Machacamarca. The ore is crushed dry, given a chloridizing roast, leached with water and hyposulfite solution (or with brine) to extract gold, silver and copper, and concentrated for tin with or' without regrinding.

Jan 8, 1920

By A. R. Elsea, E. E. Fletcher

This paper describes a metallographic investigation of the influence of tungsten or molybdenum additions upon the transformation and precipitation reactions occurring in Co-rich Co-Cr alloys. It is shown that tungsten has little effect upon the a-ß transformation temperature range, while molybdenum tends to raise it. Both elements tend to promote the formation of ? phase, molybdenum being more potent in this respect than tungsten. HIGH temperature alloys, that is, alloys which have load-carrying ability at elevated temperatures, have been developed at an increasing rate during the past few years. This has resulted from the requirements in the design of modern aircraft engines. Although many alloys of this type are available, they have been developed on an empirical basis. Metallurgists do not have a clear understanding of the phases or structures that are responsible for these high temperature properties. In order to determine why these alloys possess this particular ability, a project was started at Battelle Memorial Institute with the object of learning more about the fundamental factors which promote high temperature strength in alloys. This study was to include a correlation of microstructure and the high temperature properties of Vitallium, an alloy which is widely used for high temperature service. Vitallium is a complex material both from the standpoint of composition and microstructure. Consequently, it was necessary to obtain informa- tion regarding the phase relationships in this alloy. The Co-Cr binary diagram was determined as the first phase of this investigation.' A second paper described the effects of iron, nickel, or nitrogen on the reactions occurring in the Co-rich end of this system.' The present paper covers a continuation of this investigation in which the effects of tungsten or molybdenum on the reactions occurring in Co-rich, Co-Cr-base alloys were determined. Preparation of 'rest Materials Two series of ternary Co-Cr-base alloys, representing Co-Cr ratios of 80:20 and 68:32 ( Cr x 100 =20 and 32 ) , were prepared containing ( Co + Cr = up to 6 pct W and up to 12 pct Mo. Melting stock consisted of electrolytic Co, electrolytic Cr, 99.9 pct pure W, and 99.9 pct pure Mo. Table I lists the chemical analyses of these materials. The melting furnace was a vertical porcelain tube

Jan 1, 1952

By L. E. Porter, H. P. Hassel

The state of California produced 310,-996,696 bbl. of oil and about 415,832,000 M cu. ft. of gas in 1944. Such oil production represented 18.5 per cent of the nation's production, as compared with 19 per cent in 1943 ,The tremendous demand placed upon the California fields is indicated by the monthly production in 1944, as follows: Month Barrels per Day Jan................... 809,262 Feb.................. 820,712 Mar.................. 824,592 .4pr ................. 829,973 May.................. 832,068 June.................. 846,038 July.................. 849,231 Aug.................. 858,932 Sept.................. 885,823 Oct................... 877,667 Nov.................. 876,613 Dec.................. 883,847 In all, 2100 wells in proved areas and 269 wildcats were drilled in California during the year 1944. At the end of the year, approximately 270 wells were drilling in the state, as compared with 156 wells at the same time in the preceding year. Nine new fields or new zone discoveries were made during the year, which, according to best estimates, will contribute some 77,000,000 bbl. of new reserves; in addition, the extensions of old fields will increase the new reserves about 165,000,000 bbl., or a combined total, through dis- coveries of new fields, zones, and extensions, of 242,000,000 bbl., offsetting to the extent of about 78 per cent the total oil produced during the year. Geographically, the reserves from these new field and zone discoveries and extensions are distributed as follows: Per Cent San Joaquin Valley........ 72 Coast Area............... 24 Los Angeles Basin Fields. . . 4 100 The state's reserves of crude oil at the end of the year have been estimated to be distributed as follows: The outstanding development project for the year was that of the United States Navy in the Naval Petroleum Reserve No. I, Elk Hills field. During the year, 115 wells were completed in this field, and at the close of the year an average of 19 strings of tools were drilling. This program is being jointly conducted by the Standard Oil Co. of California with the Navy and is designed to increase the production of Naval Petroleum Reserves from approxi-

Jan 1, 1945

By J. W. Spretnak, G. W. King

THE crystallography and morphology of 0-Al,Fe precipitates in an A1 + 0.5 wt pct Fe alloy have been studied by transmission electron microscopy. The alloy was cast in cylindrical ingots, 15 cm in diameter and 60 cm in length, and cooled slowly. The measured composition was 0.527 wt pct Fe, 0.001 wt pct Mg, and 0.003 wt pct Cu. Spectrographic analysis revealed no additional trace impurities. Thin slices were cut from the ingot and reduced by more than 95 pct by rolling to a thickness of 0.1 mm with no intermediate annealing treatments. These thin sheets were then vacuum-annealed for 1 hr at 612°C and air-cooled in their capsules. Thin foils for examination in the electron microscope were prepared by electropolishing. The precipitate is found in the form of oval platelets on the (110) planes of the matrix. The major axes of the platelets are parallel to the (110) directions of the matrix, and vary in length from 1/2 to 2 p. The thickness is about 1/10 p. Examples of platelets, both in the plane of the foil and normal to the foil, are shown in Figs. l(a) and l(b), respectively. lack' found that ?-A13Fe (more correctly All13Fe4) belongs to the monoclinic system. Using Black's structural data and simultaneous electron-diffraction patterns from the matrix and precipitates, the habit planes and directions were determined to be: (00l)? || (110)Al [100]? || [001]Al The orthogonal crystallographic axes of the precipitates are accurately in the habit plane, while the measured coincidences of the directions are only within 10 deg. The major axis of the platelet is parallel to [010] in the 0. This orientation corresponds to the direction of nearest registry of the lattices.

Jan 1, 1964

By P. E. Baker

A paper by A. S. Odeh' expounds a capillary-flow theory which purportedly provides a mechanism whereby relative permeability depends on oil-water viscosity ratio and may be greater than unity for high viscosity ratios. Core-measurement results are presented to support the theoretical development. This paper presents arguments to indicate that (1) the theoretical treatment is basically incorrect, (2) data reported are insufficient to support the conclusions and (3) literature cited does not support the theory or the conclusions. PROPOSED MECHANISM The essence of Odeh's theory is that oil flows as a filament along the central portion of a straight, uniform capillary of radius r filling the tube to a radius ri. Surrounding the filament of oil is an annulus of water in which exists vortex motion but no net flow. The water is described as being in "microscopic but not macroscopic" motion. The oil filament is aided in its flow by moving upon the water vortexes as if on roller bearings. This process is presented as a steady-state flow condition. The first objection to the existence of vortexes in the presumed water layer is that the theory provides no mechanism whereby they can be established. This fact was mentioned by C. F. Weinaug in a discussion published with Odeh's paper. The capillary contains no irregularities or obstructions, and the water is not presumed to be in turbulent flow. Apparently, cylindrical symmetry is assumed; therefore, the supposed vortexes must be toroidal, the line of zero velocity being a circle concentric with and in a plane perpendicular to the axis of the capillary. This is a rather difficult picture to accept. The author referred to Yuster's statement' that he had observed the "spinning in place" of otherwise immobile water. Yuster's article does not describe the conditions under which this motion was observed or the means used to observe it. However, the article does make clear that the observed motion was not in a straight, uniform capillary but, rather, apparently oc-cured in some kind of dead-ended pore space. Obvious- ly, such a report cannot be considered as support for Odeh's concept of two-phase capillary flow.