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By A. West, F. Mohammadi

Growing awareness of selenium bioaccumulation has resulted in selenium management becoming an important environmental issue for mining operations. Selen-IX™ is a novel ion exchange based technology developed by BioteQ to provide an effective solution for removing selenium oxyanions from mine impacted water to single-digit µg/L levels. The technology offers significant potential benefits when compared to incumbent biological treatment processes, including substantially reduced capital and operating costs and significantly reduced production of a selenium-containing sludge for final disposal. This paper reviews the key features of the Selen-IX™ process and presents the results of recent pilot testing on selenium impacted water.

Jan 1, 2014

By J. L. Luo, D. G. Ivey, A. H. Adeleke

Double-edge-notched flat tensile samples of X70 steel were used for both slow strain-rate testing (SSRT) and cyclic loading testing with the notch located in the zone of interest, i.e., the weld metal (WM), base metal (BM) and heat affected zone (HAZ). By using both optical and scanning electron microscopy, the stress corrosion cracking (SCC) behaviour with respect to crack morphology and various forms of microstructure was investigated. In all the samples considered, the mode of failure was predominantly transgranular with cleavage facets around the edges of the fracture surface. The BM, with a bainitic microstructure, had the highest resistance to SCC when compared with the mixed microstructures of acicular ferrite-primary ferrite and acicular ferrite-grain boundary ferrite observed in the WM and HAZ, respectively. The effect of microstructure on stress corrosion cracking behaviour is discussed based on experimental observations.

Jan 1, 2005

By M. Mahfoud

The effect of grain refinement on the tensile and fatigue crack propagation behavior of sand cast magnesium alloy AM60B has been investigated in the present study, C2Cl6 in the amount of 0,3% was used to grain refine the melt, The fracture toughness tests were conducted in laboratory air at room temperature (25°C) using a sine-wave cyclic frequency of 20Hz and a load ratio of R = 0,1, The response in the Paris's regime and the critical stress range were determined, Preliminary findings have shown that C2Cl6 has a significant effect on both the tensile properties and fatigue crack propagation of the alloy tested, Grain refinement increased both the yield and ultimate tensile strength by more than 46%, and decreased the crack growth rate from 2,7 to 1,4 MPa Vm , However, the grain size seems to have a smaller effect on threshold stress intensity factor range. The fracture surfaces of specimens were examined optically and under the scanning electron microscope (SEM) to determine the relationship between grain size and fatigue properties.

Jan 1, 2005

By Dong-Hyeun Koh, Yun-Soo Lee, Min-Seok Kim, Hyoung-Wook Kim

High strength AA7068 (Al - 7.88 wt.% Zn - 2.68 wt.% Mg - 2.07 wt.% Cu) aluminum alloy strip was successfully fabricated by horizontal-type twin roll casting. A simulation technique was used to obtain the range of casting conditions for fabricating strip without defects. The cast strip with thickness of about 5 mm was hot rolled, intermediate annealed, cold rolled to final thickness and subsequently annealed at various temperatures. Tensile properties of annealed and the aged specimens were evaluated at ambient temperature. Tensile strength and elongation of the annealed sheet are about 365 MPa and 28%, respectively. Also, the tensile and yield strength after the aging at paint baking condition (180 °C x 0.5 h) are 586 MPa and 551 MPa, respectively. Therefore, it is expected to show good formability prior to press or stamping and also provide high dent resistance after paint baking treatment.

Jan 1, 2015

"Ore deposits containing rare earth elements normally contain small amounts of the radioactive elements thorium (Th) and/or uranium (U). These are the naturally-occurring isotopes U238, U235, and Th232 (and associated decay-series daughter products) that are ubiquitous in nature, and that contribute a small percentage of the natural background radiation exposure encountered by humans. The presence of these radioactive materials in the ore deposit creates potential hazards to human health and the environment that must be dealt with properly in the mining, processing, and refining of the ores, as well as management of waste streams and residues. This paper presents an overview of the environmental and safety issues associated with U and Th, with particular emphasis on rare earth mining, processing, and refining projects; the regulatory approaches followed to ensure that rare earth deposits are developed, operated, closed, and decommissioned safely; and the development of information during the project predevelopment work and permitting processes that feed into the design, operation, and closure of tailings impoundments and milling/separation/refining facilities. Case studies will be presented subject to the availability of relevant public information. INTRODUCTIONNearly all ore deposits containing economically-recoverable rare earth minerals also contain small amounts of the radioactive isotopes for the elements thorium (Th) and/or uranium (U) and their associated radioactive decay products. Therefore, the handling and management of these materials in mining and mineral processing operations must be performed so that workers and the environment are protected from harm from Th and/or U (and their radioactive decay products), just as they must be protected from any other potentially harmful constituents present in the ore or introduced in processing. Examples of these might include ores with high sulfide content, which may pose a risk of acid rock drainage, or chemicals used in ore processing and metals production.The purpose of this paper is to present information on how rare earth mining and processing projects with ores containing Th and/or U can be developed, operated, and decommissioned safely according to applicable regulations intended to protect worker health & safety and the environment.It should be noted that some countries are considering developing Th as a feedstock for producing nuclear energy, which could have some effect on future development of rare earth ore deposits. To avoid confusion, that issue is not discussed in this paper."

Jan 1, 2012

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004

Thermal barrier coating (TBC) systems provide thermal insulation to high temperature for aero¬propulsion. A fracture mechanical model developed earlier for multilayer systems is applied on TBC to realize superior performance by enhancement of fracture resistance. Functionally gradient materials (FGM) solution concept is the basis of approach followed here. A few realistic FGM TBCs are considered in the analysis in addition to a conventional TBC as the base case and a hypothetical worst case with YSZ-YSZ interface. Parameters like number, composition and thickness of graded layers and elastic modulus are considered for the analysis and quantitative improvement of fracture resistance of TBCs. The analysis is confined to deep crack with crack size to width ratio as 0.5.

Jan 1, 2010

By K. J. G Hedges

"Once a health based guidance limits for exposure to diesel exhaust have been established, and as part of a multi-disciplinary team, the program for exposure reduction should incorporate the plan-do-check-adjust cycle. Setting a suitably protective (health based) occupational exposure limit (OEL) for diesel particulate matter (DPM) and nitrogen dioxide is a key driver to reduce exposure. It is important to go beyond regulations and reduce exposure to diesel exhaust, DPM, as low as reasonably achievable (ALARA) such as that prescribed under the Australia, Queensland Mining and Quarrying Safety and Health Regulation 2017 where under section 135 Limiting workers exposure, the workers exposure must not exceed the exposure limit applying to the worker for the hazard; and is ALARA. It appears that previously acceptable OELs are no longer safe. Therefore it is important that the internal responsibility system be implemented and the precautionary principle approach be followed, especially as it may be some time before a suitably protective OEL specifically for DPM is in place. One leading multi-national mining company BHP Billiton has acknowledged a significant lag that exists between regulatory action and the level of science that informs health risk. This company is managing exposure to diesel exhaust to as low as technically feasible. This same company that has set an interim target for managing diesel exhaust to 0.03 mg/m3 is achieving these levels which paves the way for other mining companies and general industry including construction. The Occupational Cancer Research Centre 2017 recommends reducing personal exposure to within 0.02 mg/m3 (EC) for underground mining and 0.005 mg/m3 for other workplaces. Controlling DPM is important to prevent cancer however it is also important that that nitrogen dioxide (NO2) be reduced (ALARA) and that careful selection of control technology be considered such as the proper selection of a diesel oxidation catalyst so that the level of NO2 does not in fact increase. The example from BHP Billiton provides a leading practice including using a multi-disciplinary approach and the importance of controlling emission at source and having an auditable diesel emissions based monitoring program in place."

Jan 1, 2019

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By B. Arsenault

Aluminum coatings can provide galvanic cathodic protection for several metals and alloys, In order to be a suitable protective solution on structural components, the mechanical integrity of the component must be preserved, In particular, fatigue properties are a challenge for thermal-spray protective coatings on mechanical structures, To address the issue of the fatigue integrity of 7075 aluminum alloy with an arc-sprayed protective coating, different surface preparations prior to arc spraying were considered, In the present work, a feasibility study was performed using laser ablation as a surface-preparation technique before or during arc spraying of coatings, This was collaborative effort between the LERMPS laboratory in France, the National Research Council Canada and the Royal Military College of Canada, Both fatigue and adhesive properties of aluminum coatings were evaluated in relation to substrate-surface-preparation techniques including laser ablation (Protal® process), grit blasting and shot peening. Results indicate that a combination of key conditions, including the use of nitrogen as the arc spray gas, shot peening, and proper laser energy density for ablation, provide high fatigue resistance of metallic coated 7075 alloy substrates. Specimens prepared under these conditions show a similar fatigue resistance to uncoated substrates.

Jan 1, 2005

The mechanism of thiosulfate decomposition and the products formed were investigated in the presence of pyrite or pyrrhotite in copper-ammonia solutions used for leaching gold. The presence of the sulfides significantly increased the decomposition of thiosulfate. The sulfide-surface-catalyzed oxidation of thiosulfate to tetrathionate by dissolved oxygen or the cupric tetra-ammine complex was proposed to be the dominant thiosulfate decomposition mechanism. The catalysis of the sulfides in this reaction could originate from their strong affinity for aqueous sulfur species and their semiconducting properties. Oxygen was found to be the initial driving force for thiosulfate decomposition in the absence of cupric ions and the driving force for the continuous decomposition of thiosulfate in the presence of cupric ions. Under an oxygen free atmosphere, the decomposition of thiosulfate was limited to reduce the cupric ions and the catalytic effect of the sulfides was also marginal. The dominant oxidative product of thiosulfate was trithionate in alkaline solutions especially in an oxygen rich or cupric ion rich environment. Tetrathionate was found in relatively smaller amounts in an oxygen and cupric ion deficient environment. Tetrathionate was not stable and would further decompose after extended periods. Trithionate concentrations increased almost linearly with time.

Jan 1, 2005

By Jeremy Breker

Cameco aligns its social and environmental responsibilities with its vision, mission and values. Environmental Leadership is established as a corporate objective that emphasizes the triple-bottom-line and a systematic approach to understanding environmental, social and economic issues, risks and opportunities. These are ingrained in the project culture, systems and processes and used to influence solutions derived by the project teams to achieve Cameco&apos;s objectives. This paper traces the organizational objectives from the early stages of a project through to implementation and turn over to Operations. A case study is used to demonstrate how an asset is influenced by Cameco?s strategy.

Aug 1, 2010

By Eric J. Grimsey, Don C. Ibana, David E. Grimsey

The segregation process as applied to nickel laterite ores involves the formation of gaseous nickel and iron chlorides which are subsequently reduced to form ferronickel on the surface of a solid carbon reductant. A fundamental study of the process has been carried out using limonite, nontronite and garnierite ores. The study highlighted the significant impacts that ore mineralogy and carbon addition have on the amount of nickel which is segregated rather than retained within the ore due to in-situ reduction. These important aspects affecting nickel recovery and the success of the process are discussed in this paper.

Jan 1, 2017

By P. A. Tichauer

Arbitration is a flexible method for dispute resolution that gives control to the disputing parties while still maintaining a clear and well-structured decision making process. It responds to the desires of the parties for a resolution that is fair, binding and enforceable and is guided more by pragmatism, efficiency, effectiveness and equality than by a need to comply with the legal procedures and practices of any single country or jurisdiction. Arbitration is particularly well suited for the resolution of disputes pertaining to international commercial agreements which are often present in the metallurgical sector. This paper provides a simplified outline of the features and advantages of arbitration as well as commentary regarding certain prerequisites in order for arbitration to be binding and enforceable.

Jan 1, 2015

By John C. Luck Jr.

"DEVELOPMENT of oil emulsion mud dates back to the early days of rotary drilling when oil was added to the drilling mud solely for the purpose of freeing stuck drill pipe. After the drill pipe was freed, and drilling resumed, this oil was considered a contaminant. Efforts were made to remove the oil but some of it remained and was emulsified with the drilling mud, thus forming a mechanical emulsion.During the late 1930's, operators found that adding crude oil to drilling muds seemed to alleviate 'sticky-hole' problems and so oil was allowed to remain in the mud. This practice was adopted when it was found that faster drilling rates and longer bit life were obtained. These observations led to the development of emulsion drilling muds. During the past five years their application has become more widespread because of the lower fluid losses obtained, greater lubrication qualities, faster penetration rates, and generally better hole conditions.An emulsion may be defined as a two-phase system consisting of a mixture of either finely divided oil droplets in water or of finely divided water droplets in oil. The surrounding liquid is known as the continuous phase. The emulsifiers reduce the interfacial tension, making the droplets tend to repel each other so that they remain dispersed and stabilized. These emulsions are classified as oil-in-water or as water-in-oil, depending upon whether water or oil, respectively, is the continuous phase. Briefly, close inspection shows that they consist essentially of globules of• the one liquid suspended in a continuous mass of the other liquid. Oil emulsion muds are usually of the oil-in-water type. Two basic types of emulsifiers •commonly used in Canadian muds are soaps and lignites."

Jan 1, 1954

By Damien Gaboury

"Two practical methods for correlating two or more diamond-drill core intersections, using a stereographic projection software are presented. The first may be used to establish if two or more vein intersections are correlative, based on their core angles and diamond-drillhole attitudes. The second method allows prediction of main vein attitudes from numerous intersections, based on a spherical density contouring projection. The methods are suitable for: (1) correlating veins in complex orebodies; (2) ascertaining lateral continuity of ore for reserve estimations; (3) demonstrating the hidden complexity of an orebody; and (4) correlating and interpreting various planar elements.IntroductionModern mineral exploration relies on diamond- drill core data and on the ability of geologists to interpret them. Drill core generally yields unoriented information, unless an expensive orientation device is used. As a consequence, strike and dip of planar elements such as lithological contacts or mineralized veins cannot be determined easily. This is particularly true for blind deposits (covered by thick overburden) and complex orebodies, where field data cannot support drilling interpretations. Such a problem has been addressed previously using two and three diamond drillholes and several solutions were proposed based on trigonometry, and geometric and stereographic projections (Mead, 1921; Wisser, 1932; Fischer, 1941; Stein, 1941; Bucher, 1943; Gilluly, 1944; Addie, 1962; Mills, 1963; Lyons, 1964). However, these solutions are time consuming and not relevant to present day computerized data plots."

Jan 1, 1997

By L. C. DeCory

"Concrete is a common denominator to the building process and portland cement is an integral and necessary component of concrete. The cost of portland cement is nominal and its cost comprises, in most instances, a small portion of the total cost of ""put-in-place"" concrete.The domestic demand for portland cement in Canada is projected to be slightly less than 11 million short tons in 1980. In order to achieve this projected goal, stabilization or lowering of the cost of put-in-place construction is necessary. This enhancement of the cost of building can be achieved by:(1) improving the building process;(2) refining and improving design techniques; and(3) developing improved and economical concrete products.Some of the techniques and materials that will lead to building cost stabilization include systems building in its broadest sense, slipforming, precasting, prestressing, computer design, lightweight aggregates, fibrous concrete and integration of building components."

Jan 1, 1973

By K. Bunney, R. Pleysier

The deportment of a suite of elements through representative gold ore processing unit operations in cyanidation has been investigated. Chromium and lead are not soluble in alkaline cyanide solutions. Arsenic, antimony, cobalt, molybdenum, selenium, tellurium and vanadium are soluble, but typically do not adsorb onto activated carbon to any appreciable extent. Silver, copper, cadmium, mercury, nickel and zinc to varying extents report along with the gold to the carbon eluate. Cadmium, mercury and zinc can report to the carbon regeneration kiln off-gases. Strontium is soluble and adsorbs on carbon where it remgins.

Jan 1, 2011

By L. K. Daneshmend

The mine of the year 2020 will need to be based on a new way of mining. It will employ technology in a paradigm that assumes responsibility for sustainable development: taking account not only economic but also ecological and social issues. This will require a holistic approach to mine design and planning, considering all controlling factors and impacts (technical, economic, environmental and social). A national collaborative strategy is required to address the several options that exist for the development and application of 2020 mining technology. Key issues in implementing 2020 mining technology will also relate to human resources, in terms of employment, skills and education. A need exists to proactively prepare for 2020 through development of a comprehensive education and training strategy.

Jan 1, 1998