Search Documents

By D. Nie, M. Ren, T. Mo

This paper studied the phenomenon of room temperature creep deformation at crack tip and its effect on fatigue crack growth rate of a X-70 pipeline steel using compact-tension (CT) specimen on a MTS 810 testing machine. Time-dependent deformation at the crack tip under constant load was observed in this steel at room temperature and the amount of deformation produced was seen to depend on loading rate and the magnitude of stress intensity factor. It is found that there exists a critical stress intensity factor below which the deformation decreases with time when the applied load remains constant. It is also found that the occurrence of room temperature creep obviously affects the subsequent fatigue crack growth rate. The observed behavior was explained based on dislocation theory.

Jan 1, 2005

By L. M. Guayacán-Carrillo, G. Armand, A. Noiret, D. Seyedi, S. Ghabezloo, J. Sulem

"The main purpose of this paper is to analyze the convergence measurements in a drift excavated in the Callovo-Oxfordian claystone. The drift axis is in the direction of the major principal horizontal stress whereas the stress state is quasi-isotropic in the drift’s section. The initial geometry of the drift being circular, the anisotropic character of the deformation is taken into account by assuming that the drift shape evolves in an elliptical shape. The convergence measurement data on six different points around the drift are analyzed to identify the main axes of the deformation ellipse, following the methodology proposed by Vu et al. (2013, Rock Mech Rock Eng, 46, 231-246). Then, using the semi-empirical law proposed by Sulem et al. (1987, Int J Rock Mech Min Sci, 24, 145–154), the convergence evolution is fitted independently for each axis of the ellipse. This method permits to distinguish two effects: the face advance effect and the time-dependent behavior of the ground. The results for the two directions of the ellipse axes show very close values for the parameters describing the time-dependent properties of the ground, the distance of influence of the face, and the extension of the decompressed zone around the gallery. Such model can provide valuable insights for predictions of the convergence evolution in the long-term. INTRODUCTIONDeep disposal of radioactive waste has been studied in France for more than two decades. The French National Radioactive Waste Management Agency (Andra) began in 2000 the construction of an Underground Research Laboratory (URL) with the main goal of demonstrating the feasibility of a geological repository in Callovo-Oxfordian claystone. Several research programs have taken place to improve the knowledge of the rock properties and its response to the excavation progress. The optimization of supports design for long-term behavior is an important point to develop. A network of experimental drifts has been constructed with variations on: excavation method, structure geometry, supports system and orientations with respect to in-situ principal stresses’ directions. In each drift different sections have been instrumented to monitor the convergence evolution and the rock deformation. Continuous monitoring of the excavated zone around the drifts revealed the development of a fractured zone (extensional and shear fractures) induced by the excavation. The extent of this fractured zone depends on both the drift orientation and the in-situ stress field (Armand et al., 2014). Indeed, the fractures distribution has an important influence on the convergence of the drifts."

Jan 1, 2015

By A. Galibois, R. Singhal

"This paper highlights some of the potential application areas of knowledge-based systems in the mining industry. The basic theoretical principles associated with knowledge-based systems are discussed and the justification for mining applications is given. The paper concludes with a brief description of a prototype knowledge-based system applied to scraper selection that was developed at Université Laval on a LISP machine. IntroductionThe beginning of Artificial Intelligence coincided with the conception and development of the first computer systems some thirty years ago. At that time researchers were euphoric about the possibility of modelling the human reasoning process. Soon, however, they discovered that the combinatorial aspect of the set of possible solutions to a particular problem did not permit an in-depth evaluation.In the mid-60s researchers started to look at the heuristic approach because it was more suited to human behaviour with its congnitive abilities (i.e. representing, reasoning, problem solving and advising). The heuristic approach allows possible results rather than exact solutions and it is more rapid and cost effective than the exhaustive combinatorial analysis. The heuristic approach did allow some noticeable progress in the seventies with the development of the first expert system called MYCIN with the objective of diagnosing blood infection diseases."

Jan 1, 1988

By L. J. Visentin, J. G. Rickaby

"Audiometric testing is a key element in hearing conservation in the mining environment. This paper gives the history of the audiometric testing program carried out by Inco Metals Company, including the program objectives the personnel and equipment involved, calibration and testing, the test procedure, and the classification and evaluation of the test results.IntroductionThe operations of the Ontario Division of Inco Metals Company are located primarily in the Sudbury District. They also include a refine ry at Port Colborne and a mine and concentrator at Shebandowan near Thunder Bay.The company operates nine underground mines, and one open pit, while maintaining six underground mines on a standby basis. Ore from these operations is processed in four concentrators. The metallurgical facilities include a smelter, a matte processing plant, a copper refinery, a nickel refinery and an iron ore recovery plant at Sudbury, and a nickel refinery at Port Colborne. Inco Metals currently mines roughly 9,000,000 tons annually and produces IS elements.Excessive noise in the work place has been a serious problem in the mining industry since the introduction of compressed-air-powered machinery in the last century. At the same time, growing levels of noise inherent in our social environment can threaten the hearing of employees and their families.Only in the last 20 years, however, has the extent of this problem and its implications for people working in the industry and their families been recognized. Since the industry has become aware of the situation it has taken steps to implement comprehensive noise reduction and hearing conservation programs."

Jan 1, 1982

By P. O. Rag, Daniel E. Walsh

"Gravity concentrators are evaluated either in closed or open circuit. The process developed by MIRL employs the use of neutron activated gold (/98Au) and radiation detection circuits which monitor the concentrator's product pulp streams. Concentrator recovery is determined from the ratio of the number of gold particles detected as passing into the concentrate to the total number of gold particles detected over all monitored pulp streams. This system eliminates the experimental errors introduced by sampling, sample reduction, and assaying and allows recovery to be evaluated for gold particles of specific sizes, shapes, and flatness. In addition to allowing for a more accurate and detailed recovery analysis, this process significantly reduces the time and cost required for unit evaluation when compared to other gold recovery analysis procedures. This system enjoys its greatest utility where a large number of tests are to be run in order to evaluate a concentrator over a variety of operational settings, i.e. factorial designs, and allows accurate testing of concentrators operated in closed circuit systems.IntroductionThe surge in gold prices of the late 1970s and early 1980s was followed closely by a renewed interest in gravity concentration processes, especially in concentrators claiming efficient recovery of fine placer gold. Cones, spirals, spinning bowls, jigs and cyclones are all considered potential fine gold concentrators. Fine gold, in this context, is defined as not only that gold finer than 250 um (60 mesh""), but also coarser gold, whose low shape factor may decrease its recovery by conventional, large-scale sluicing operations.Adoption of fine gold concentrators by the Alaskan placer milling industry was retarded by the lack of reliable, accurate, and reproducible data on concentrator efficiency with respect to fine placer gold recovery. In most cases, concentrator performance was based on a limited number of tests run on placer material, about which only slight knowledge of gold size and shape characteristics existed. In order to be prepared for the resurgence of interest in fine gold concentrators, which will follow the next upturn in gold prices, a detailed study of the fine gold recovery characteristics of gravity concentrators needs to be conducted."

Jan 1, 1986

By A. Sacit Saydam

"Induced polarization/resistivity and magnetometer surveys have been carried out over the Casmo molybdenite deposit in mountainous terrain of northern British Columbia. Molybdenite occurs in quartz-bearing fractures with or without pyrite along a zone of hydrothermal alteration and intense fracturing, believed to be a northerly dipping fault zone, within medium-grained equigranular and porphyritic quartz monzonite.The molybdenite-bearing zone is characterized by a significant resistivity low, a metal factor high and a subtle IP low flanked by highs outside the mineralized area. Magnetic trends, indicated by a magnetometer survey, generally parallel the zone and strike direction of the different intrusive phases, and have been helpful in delineating contacts and faults in the area.IntroductionThe Casmo molybdenite deposit is 6 km southwest of the asbestos mining town of Cassiar in northern British Columbia, at an elevation of 1,550 metres. Molybdenite was first discovered during the early 1950s and the first important exploration work was done in 1964. Between 1964 and 1971, about 25,000 feet of drilling was done by various operators, as a result of which 33.7 million tons of molybdenite ore was drill indicated at a grade of 0.123%. In 1979, Shell Canada Resources entered into an option agreement with the former operator, New Jersey Zinc Corporation. Shell completed 27,000 feet of diamond drilling between 1979 and 1980 and ha s reported 75 million tonnes of drill-indicated ore with an average grade of 0.13% MoS2• This paper is a case history of IP I resistivity and magnetometer surveys done over the Casmo deposit during 1979 and 1980."

Jan 1, 1983

By Andrew J. Neale, Brian C. Flintoff

"In most mineral processing operations the term ""audit"" is usually reserved for the exercise of checking financial records and/or safety practices. While these activities are time-consuming, no one disputes their necessity or value. If these areas are subjected to such careful scrutiny, why is it that the same principles are not normally applied to critically examine process operation. After all, the operating efficiency of the plant impacts directly on the measures of profitability.A mineral processing plant is a complex system that has a number of distinct, but mutually dependent elements: process equipment, instrumentation, operating policies, maintenance policies, control strategies and people. To ensure maximum economic performance in the dynamic environment that characterizes a concentrator, requires a periodic review of each of these areas. However, to be useful, the study must be based on sound metallurgical principles and be conducted in a highly focussed manner. Experience has shown that the exercise is very revealing and rewarding.This paper will discuss the plant audit process and illustrate its potential value through examples taken from plant studies."

Jan 1, 1992

By L. Xu, A. Vazirnegad, R. Bhaskar

"Respirable dust samples are collected by the U.S. Mine Safety and Health Administration (MSHA) and mine operators as part of the requirements of the Federal Coal Mine Health and Safety Act of 1969. About 1.85 million respirable dust samples collected by MSHA were analyzed for the period 197/ to 1990 f or the states of Alabama, Colorado, Illinois, Kentucky, Ohio, Pennsylvania, Utah, Virginia, and West Virginia. Trends in coal dust exposure of continuous miner operators, helpers, and roof bolters were analyzed. The reported production in each of the nine states was analyzed. The relationship between average dust exposure and coal production was evaluated. In addition, the differences between mine operator and MSHA inspector collected data were examined for each state. The average exposure levels for the three occupations - miner operator, miner helper, and roof bolter were also compared.The data indicate that the dust exposure levels have significantly dropped over the last twenty years, while at the same time production has increased, attesting to the ability of the U.S. mining industry to adapt successfully to the stringent dust control regulations. In terms of coal production, it appears that some states, such as Utah, Illinois, and Kentucky, were able to increase their production significantly relative to others, such as Pennsylvania and Virginia. The relationship between dust concentration and coal production is, at best, tenuous. 11 implies that existing dust control technology has assisted several mine operators to meet dust standards, while, at the same time, enabling mines to produce more coal than before. Comparison of data collected by MSHA and mine operators indicate that MSHA inspectors recorded higher dust levels and lower shift production relative to mine operators."

Jan 1, 1993

By Lionel Roberge, Borge J. G. Fredriksson

"Late in 1981, a six-rope friction hoist was installed in the Number 2 shaft at Les Mines Seleine Inc. on the Madeleine Islands in Quebec. This paper deals with the reasoning behind the selection of hoisting equipment from the economical point of view, safety point of view, future needs point of view, etc.After establishing the basic parameters for the hoisting system, features of the most common types of hoists (i.e. single-drum hoist, double-drum hoist, Koepe hoist) are briefly laid out. The reasons for selecting a friction (Koepe) hoist are summarized. However, why go for a six-rope hoist rather than the (in North America) more common four-rope hoist? As the subject hoist is the first six-rope hoist in Canada, this question is studied in more detail, covering initial cost, maintenance cost, etc., as well as practical aspects, such as safety, physical dimensions, etc.In summary, experiences from other multi-rope hoist installations world-wide are presented.BackgroundIn 1980, Seleine Mines Inc. was established as a subsidiary of SOQUEM. The new mining company was to develop and operate a salt mine and associated harbour on the Madeleine Islands in the Gulf of St. Lawrence. The Madeleine Islands form part of the Province of Quebec. The mine has a planned annual output of 1.2 million metric tonnes of salt, with reserves in sight for over 20 years. Mining will be by room and pillar, with an underground primary crusher and treatment plant. From the underground treatment plant, the salt will be transferred via conveyors to a 5.5-metre-diameter circular shaft and hoisted to the surface. Surface transportation to the warehouse will again be via conveyor, and a conveyor will also transport the salt from the warehouse to the point of shiploading."

Jan 1, 1983

By N. E. Chaouai, M. Lavigne

"Indicator kriging is one of the non-parametric geostatistical techniques, ideal for estimating the reserves of irregular mineralizations (e.g. gold, uranium, platinum, diamonds, etc.). Such mineralizations are characterized by variograms which are very sensitive to extreme values (outliers) and very difficult to model.The classical approach to this problem in the industry is to trim off these high grades using arbitrary empirical upper limits established either from practice or subjectively. Contrary to this simplistic approach, indicator kriging discretizes the histogram of the grades (usually log normal) in several classes and carries out interpolation separately for each class. This paper gives an overview of the differences between ordinary and indicator kriging along with the steps required to carry out indicator kriging. The paper concludes with a case study involving a gold deposit estimation.IntroductionParametric geostatistics (ordinary kriging) has given us satisfactory results over the years in estimating the reserves of well behaved deposits with coefficients of variation close to 1 (e.g. sedimentary and porphyry type deposits). However, numerous problems have been encountered in estimating irregular mineralizations (e.g. small vein deposits of precious metals) with high coefficients of variation in the range of 2 to 5. Such deposits are characterized by a very small proportion of extreme values (outliers) which create distortions on the variograms (pure nugget effect) and render them useless(1,2).The solution often followed by the mining industry today is to trim off these values based on empirical limits. These limits are derived either by comparison with production results (or bulk samples) or by geological interpretations. Needless to say that such manipulations can lead to serious errors in estimating ore reserves (usually underestimation of total metal quantity), especially when production results or bulk samples are absent.On the other hand, the solution followed by the geostatisticians in the past was to smooth out the data using transforms (e.g. normal-score or natural logarithms). Such transforms are nonlinear and they required non-linear estimation techniques such as disjunctive kriging (DK) or multivariate gaussian kriging (MG) which require normal related hypotheses, not necessarily true in geology.Nonparametric geostatistics (indicator and probability kriging) have been -developed in order to handle these problems related to highly skewed distributions."

Jan 1, 1990

By Ferri P. Hassani, Riadh Bouzaïene

"Selected methods of pressure loss predictions in horizontal slurry flow in pipelines are presented. For a given combination of flow velocity, solids concentration and particle size, the slurry and its flow conditions are described, and an appropriate method of pressure loss prediction is outlined. The wide range of conditions treated in this paper may be found in practice in areas varying from the hydraulic transport of low concentration slurries to dense-phase conveying of paste backfill in underground mines.IntroductionThe hydraulic conveying of solid particles in pipelines is a major component of the mining and mineral processing industry. Whether the objective is to transport ore to the processing plant or to make use of mill tailing as backfill material; the need for well designed, economical hydraulic conveying systems is recognized.The contribution of this paper is part of an on-going research program at McGill University involved in optimizing and developing techniques for total mine waste disposal. One of the main concerns in the conveying of solid-liquid mixtures is the prior knowledge of the pumping power input required. This energy requirement is directly proportional to the pressure losses incurred in the pipeline system. Understanding the sources of such pressure losses and predicting their magnitudes should enable the system designer to make informed decisions regarding the optimum mode of hydraulic transportation commensurate with the over-all requirements of the operation.This paper is an attempt to classify pressure loss prediction methods encountered in the literature for solid-liquid mixtures. In spite of the large number of publications spanning thirty years of research in the field of slurry transportation, it is sometimes difficult to correctly identify the appropriate methods applicable to a given situation. This is partly due to the inherent complexity of the mechanics of slurry flow and the ensuing uncertainty about the nature of the flow regime under investigation.Our approach is to use three fundamental parameters, namely: flow velocity, solids concentration and particle size (for solid particles with a given density) to characterize the slurry and the flow conditions, and to match them with an adequate pressure loss prediction method. For each combination of flow velocity, solids concentration and particle size, a description of the most likely prevalent flow conditions and some known methods of dealing with them will be presented. Qualitative definitions of ""high"" and ""low"" magnitudes of the aforementioned parameters will be given as a general guide to the classification scheme presented in this paper."

Jan 1, 1992

By Scott K. Palm, Neil D. Pearson, Jr. Read

"Uncertainty is an important feature of many investments, but it is especially important for mineral properties. Mine properties often entail large investments and fixed commitments. Managers in the mining industry often view price uncertainty as undesirable, due to the possibility that the price of the mined commodity will fall to a level that prevents the firm from recovering its investment and fixed costs. This paper identifies pitfalls in conventional valuation methods and outlines a new approach to valuation based on option pricing theory and dynamic programming. In the process, it identifies generic strategies for organizing mine production in ways that allow the owner to benefit from the uncertainty in mineral prices. IntroductionRisk is pervasive in the mining industry. The operation and maintenance of a mine may involve high, and unavoidable, fixed costs. A mine owner can only begin to recover these fixed costs if the price of the mined commodity is greater than the incremental cost of production. But the prices of many minerals are extremely volatile. The price volatility of copper has been significantly higher than the price volatility of a typical stock, for example. A mine owner cannot be sure that the price of the mineral product will remain high long enough for the firm to recover its capital and fixed costs.Mine owners are able to minimize their losses during periods when the output price is below the incremental cost of production by temporarily closing operations. During these periods they incur only fixed costs. While shut-downs help minimize losses, the y do not help the firm recover its initial investment. If output prices remain low long enough, the fixed costs and original investment may never be recovered. High fixed costs, therefore, lead to substantial downside risk."

Jan 1, 1986

By B. E. Jones

"The area of uranium deposition is situated within the Churchill Province on the western edge of the Wollaston Iithostructural domain where it underlies the eastern edge of the Helikian Athabasca Formation. The Collins Bay deposit is 6 miles north-northeast of the Rabbit Lake mine. Two principal zones of uranium mineralization are described.The ""A"" zone is a partly eroded, high-grade pod of metal oxide and arsenides sheathed by clay-like minerals. It trends north-northeast and lies under 25 to 40feet of water. Uranium mineralization is localized at or adjacent to the unconformity between the Athabasca Formation and the basement rocks. The basement comprises a granitoid Archean terrain overlain by paragneisses of the Aphebian Wollaston Group. ""A "" zone ore contains phyllosilicates, quartz, pitchblende, rammelsbergite, pararammelsbergite, carbonaceous material, galena, gersdorffite, niccolite, carbonate and a trace of sphalerite.The ""B "" zone lies 6,000 ft south of the ""A "", and subcrops under till cover. It is a partly eroded zone composed of metal oxide and arsenides which occur within variably altered Athabasca Formation. Minerals recognized are phyllosilicates, pitchblende, niccotite, gersdorffite, millerite, carbonaceous material, pyrrhotite, skutterudite and a trace of galena. The Athabasca Formation varies from 90 to 160ft thick. Granitoid gneisses of probable Archean age and paragneisses of the Wollaston Group underlie the deposit. An easterly dipping thrust fault transects its length.The deposit is typical of the ""unconformity-type"" uraniumnickel deposits of the Athabasca Basin. Observed features fit well with the ""diagenetic-hydrothermal"" model for such deposits, as envisioned by Hoeve and Sibbald (/978)."

Jan 1, 1980

By M. H. Moys, J. A. Engelbrecht

"Large-diameter flotation columns are subject to severe axial mixing which has reduced column recovery and has generally limited it to cleaner applications. It has been assumed that columns with diameter greater than 1 m should be baffled to reduce axial mixing, but little work has been reported quantifying the effectiveness of baffling. Tests were done on a 0.2 m by 2 m column fitted with baffles of different geometry. It was generally found that the inclusion of baffles in the column worsened rather than improved mixing conditions in the column. This is explained in terms of a model for the effect of poor gas distribution on the behaviour of the column; this showed that under typical conditions a 16% excess of gas flux in the one compartment of a two-compartment column could result in one of the compartments being ""dead"" (i.e. with no net flow of slurry through it), resulting in a substantial loss of performance. The quality of mixing in the laboratory column was only reliably improved when the baffle was raised so that its top was positioned above the froth-slurry interface level. It should be possible to increase column recovery substantially with this configuration. The improved residence time distribution also means that columns can be used more effectively in roughing and scavenging applications. IntroductionFlotation columns have generally been used in cleaner applications, starting with their dramatic success at Mines Gaspe(1). Their lack of applications as roughers and scavengers is probably due to their poor residence time distribution (RID) when compared to the conventional cells they would replace. Espinosa-Gomez et al,(2) recently used them in rougher applications but installed three columns in series, presumably to cope with this disadvantage.Dobby and Finch in their seminal papersl(3,4) on the scale-up of flotation columns were the first to quantify the impact of axial mixing on the performance of industrial flotation columns. Laplante et al.(5) collected further data from the literature for column diameter D, ranging between 5 cm and 183 cm, gas superficial velocity Jg ranging between 0.7 cm/s and 2.8 cm/s and per cent solids in the feed S ranging between 3% and 52%. These data were analyzed with reference to the axial mixing model using the boundary conditions for closed vessels (the latter are more appropriate for flotation columns but the model is more difficult to use because analytical solutions for the RID are not available). The data were correlated by:"

Jan 1, 1993

By David A. Grieve, David E. Pearson

"A rank-map of Crowsnest coalfield, showing the distribution of the bituminous coal measures and the locations of major structures, has been produced from vitrinite reflectance measurements on over600coal samples. The timing of coalification in relation to these major structures has also been determined.In the west-central portion of the coalfield a complete stratigraphic succession of coal measures which rides on major thrust surf aces is all of high-volatile bituminous rank, but despite the structural discordance no break in rank is discernible across these structures. The thrust faults therefore predate much of the coalification.Three major valleys expose cross sections of the folded coal measures and in each an increase invitrinite reflectance is demonstrable as individual seams are traced from ridge crest to valley floor. Thus, in these sections, a significant amount of coalification post-dates folding. The proportion of this post-folding coalification is found to increase toward the south of the coalfield.A late gravity-fault, exposed along the east crop of the coalfield, places high-volatile coal-bearing successions in contact with low-volatile coal and demonstrably is a reactivated thrust fault. Coalification at this locality occurred between these two different ages of faulting.The variations in rank and the subtleties of the coalification pattern have, together with systematic changes in the maceral composition of coal seams, had a profound effect on coal quality in the coalfield. Coking coals with a variety of properties occur together with some coals that have no caking capacity."

Jan 1, 1985

By J. Boulton

"Nuclear energy is an established and proven energy source. Today, CANDU-PHW nuclear-electric generating stations produce over one third of Ontario's total electrical supply: safely and economically. In many parts of Canada, where economic hydro resources do not exist or are fully developed, coal and nuclear energy are the only alternatives for future large-scale electrical generating capacity.Recent analyses have suggested that, in the f ace of increasing energy demands and decreasing reserves of hydrocarbon fuels, Canada must depend on electricity to provide an expanded fraction of its energy budget. Nuclear energy is likely to play an increasing role in the generation of electricity; there are also potential applications as a supplier of process heat in industry and in the in-situ recovery of bitumen fro m tar sands.The future supply of nuclear fuel, reactor safety and radioactive waste management are briefly discussed. In each case, the benefits to be gained from a controlled expansion in the use of nuclear energy outweigh any uncertainties which may exist."

Jan 1, 1981

By H. D. S. Miller

"This paper introduces a new approach for the design of rib pillars. The approach involves an empirical method for pillar design and a discussion of the pillar stability used for open stope mining methods.The empirical method predicts the degree of stability of rib pillars. Pillar load is estimated using two and three dimensional numerical modelling. Rock strength and the shape effect of pillars are used to account for pillar strength. The method has been calibrated with case histories from Canadian open stope metal mines and is compared with other methods used [or pillar design.INTRODUCTIONThe role of rib pillars in open stope mining is to provide stability to a mining block by limiting rock mass displacements and restricting the exposure of a rock mass in stope backs and stope walls. They also provide flexibility in ore extraction by dividing a stope block into multiple working faces.The use of backfill in open stope mining methods has reduced somewhat the need for optimum pillar design. In contrast to permanent pillar methods, the dimensions do not need to be minimized because the pillars are usually recovered in a later stage of mining. However, the consequences of poor pillar design are often overlooked and can still be severe. A pillar that does not perform its intended role may result in excessive stope or pillar sloughing, difficult and expensive pillar recovery, loss of permanent access and remedial costs such as development rehabilitation, artificial support or low productivity.Pillar design concepts of the past were not developed for open stope mining conditions and generally have not been confirmed for open stoping. The focus of this paper is to introduce an empirical design relationship specifically for open stope pillars. It provides a stable, yielding or failed pillar assessment for a given design."

Jan 1, 1989

By K. Enns, J. J. Byerley

"While thiocyanate (SCN-) is used in a number of industrial processes (production of polyacrylonitrile filaments, synthesis of agricultural chemicals and certain metallurgical solvent extraction and flotation circuits) it is recognized more as an undesirable by-product associated with ' the metallurgical industry. Thiocyanate is present at low concentrations in some waste streams from the iron and steel industry. Of particular significance is the formation of thiocyanate during cyanidation of gold and silver ores, concentrates, tailing s and residues. The thiocyanate levels present in the resulting effluents may range from a few mg/I to several thousand mg/I.At present, thiocyanate does not appear to be as hazardous in the environment as cyanide (CN-) at the same concentration although its interaction with other species and resulting decomposition of products may be unacceptable. Of course the presence of thiocyanate in the leaching circuit and ultimately in the effluent streams may add considerably to the oxidative requirments of any non-selective treatment process for cyanidation wastes.With respect to the thiocyanate as it relates to the cyanidation process, two aspects are evident. Thiocyanate forms and persists in the cyanidation circuit resulting in a ""fouling"" condition with subsequent loss of leaching activity. In order to reduce or control this problem, it is common practice for some mills to discharge daily as much as 20% of the barren leach liquor. Besides contributing to fouling of the leach liquor the formation of thiocyanate represents an irreversible loss of reagent cyanide. It is noteworthy that in some present or proposed mill practice reagent cyanide loss through thiocyanate formation may reach 50%(1). The purpose of this paper is to discus s the application of controlled electrooxidation of thiocyanate with the view of suggesting a process for regenerating cyanide from waste thiocyanate(2). The paper describes the important theoretical aspects and presents experimental data obtained for thiocyanate electrooxidation using both small and large scale electrochemical reactors. Some economic conclusions are presented."

Jan 1, 1984

By M. Ghiani, P. Carbini, R. Ciccu, C. Del Fà

"This paper is concerned with the problems inherent in the efficient and economical processing of the fine fractions of a coal from the Sulcis basin (Sardinia, Italy) whose characteristics are typical of low-rank coals occurring in the Mediterranean region. Three different techniques, based upon surface properties, are examined. Flotation can be very efficient from both a technical and economic point of view, provided care is taken in the modulation of the flotation pulp. Interesting results have been obtained with oil agglomeration and this method could be economically feasible. Finally, electrical separation has proven a viable technique, although it entails preliminary drying.Besides discussing the problems encountered in the experimental research, some significant results of general validity are also given. They demonstrate that cleaned products can be obtained with fairly interesting recoveries, thus opening the way to advanced research aimed at setting up the most suitable technique for industrial application. IntroductionAs a result of the oil crisis, which caused a major upset in world energy supplies, the last ten years have seen a revolution in the energy policies adopted.In particular, the status of coal, which seemed destined to decline in view of the availability of liquid fuel, has had to be re-examined. The need to meet energy demands under improved reliability conditions and controlled prices through a broader and more flexible diversification of sources of supply has evoked, especially in highly industrialized countries, a renewed interest in coal. The result has been a consistent increase in demand and production as well as investments in new mines and the reinforcement of the infrastructure.This turn of events has also lead to a re-evaluation of young low-rank coals, hitherto considered uneconomical and thus neglected, because of their low heat value. In fact these coals, which have a high ash content, may also be relatively highly contaminated with sulphur. The above drawbacks, which still today preclude the widespread use of these coals, are bound to create even greater problems in the future as increasingly restrictive environmental control imposes, without exception, recourse to cleaner fuels."

Jan 1, 1986

By M. Nagamori, A. J. Plumpton

"A low-grade concentrate from the Crevier Township, Quebec, containing 1.8% Ta205 and 13.7% Nb205 was reduced with carbon at 1600°C, and niobium and tantalum were selectively absorbed in liquid iron. To slag off the zirconia-rich gangue, some silica and lime were added as flux. Metallic iron was added in such a way that the combined contents of TaC and NbC did not exceed 20% in the ferroalloy . Up to 95% of the niobium, and up to 80% of the tantalum contained in the concentrate were recovered in the metal. The ferroalloy was ground finely and dissolved in 2 wt % sulphuric acid to leach out iron and silicon preferentially. The insoluble residue consisted principally of NbC and TaC, the calcination of which yielded an enriched concentrate comprising 80% Nb2O5 and 8% Ta2O5. The insoluble residue could also be chlorinated to obtain an impure liquid of Nb2Cl5 and TaCl5. Process variables and their effects are discussed in terms of higher metal recoveries in the smelting.IntroductionPresently, about one-third of the world production of tantalum comes from the pyrometallurgical reprocessing of tin slag, a by-product of tin smelting, containing sometimes 2 to 10% Ta205 and about the same amount of Nb205. Upon heating tin slags with carbon at about 1600°C in an electric furnace, tantalum and niobium oxides are converted to TaC and NbC, which are absorbed by the coexisting phase of molten metallic iron(1,2). The Fe-Nb-Ta-C melts cannot be decarburized by oxidation because of the preferential formation of Nb and Ta oxides over CO gas(3). So, the ferroalloys containing tantalum and niobium carbides are commercially treated by acid-leaching and I or chlorination to eliminate iron and thus permitting the eventual recovery of purified tantalum and niobium oxides(2).Absorbing Ta and Nb carbides in molten iron was first proposed and demonstrated by Zimmerley and Back(4) in 1957 in order to recover selectively tantalum and niobium from lowgrade concentrates. The process was successfully applied to the electric furnace smelting of tin slags by Hunter and Fursmant(5) over a period preceding 1965."

Jan 1, 1985