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By John C. Edwards

A fire location computational model was developed by the U.S. Bureau of Mines. The model can determine all the possible paths in a mine that smoke can travel from a fixed fire source to a smoke detector. The associated FORTRAN computer program can be utilized to determine the minimum travel time from a source fire to a smoke detector. The difference in travel time from an isolated fire source to two or more detectors can be used to isolate those airways in which the source fire is located.

Jan 1, 1990

By Kevin Malone

Mercury, or quicksilver as it is often called, has many applications in modern technology. Used principally in electrical apparatus, industrial contol instruments, insecticides and fungicides, electrolytic preparation of chlorine and caustic soda, chemical processes, pharmaceuticals, and dental preparations, the liquid metal has unusual properties that make it a preferred material for many industrial uses. United States consumption of mercury during the past 40 years shows a rising trend. In all except 4 years, U.S. production has been less than the domestic requirement, and imports, principally from Spain, Italy, and Mexico, have supplied most of the deficit. After World War II, domestic output decreased rapidly until 1950, when it was the lowest in the 100 years covered by production records. Higher mercury prices since 1950 have reversed the decline in domestic output and reduced the gap between U.S. production and consumption. Domestic output in 1958 was the highest in peacetime since 1883; however, the nation still imported 28 percent of its mercury requirements from 1950 to 1960 the price of mercury was high as a result of industrial applications of the mercury cell, the impact of the cold war and the Korean war, and the Government stockpiling program. The stockpiling program, in effect, put a floor under mercury prices even though only 9,428 flasks of domestic mercury went into the stockpile under the original program which ran from July 1954 to December 31, 1957. Under an extension of the program, an additional 17,463 flasks was purchased.

Jan 1, 1962

By V. F. Parry

[Approximately 7-1/2 million tons of subbituminous coals are mined annually in Colorado, Wyoming, and Montana, of which 50 percent probably reaches domestic consumers. The moisture of these subbituminous coals is high, averaging about 25 percent when they are mined. The coals are non-caking end stack to a variable degree when exposed to normal atmospheric conditions. They are good domestic fuels, are considered to be smokeless in most furnaces, and have been used for many years in hand-fired domestic furnaces in which the practice is to employ large lutes for efficient combustion.]

Jan 1, 1941

By R. F. Waters

Laboratory-scale selective volatilization methods developed by the Bureau of Mines to recover germanium and gallium concentrates from coal fly ash and phosphorus furnace flue dust are summarized. In the better experiments between 85 and 98 percent of the germanium was recovered as the lower oxide and as sulfides, and between 75 and 97 percent of the gallium was recovered as the lower oxide and as the trichloride. Grades of the condensates were inconsistent and varied between a few tenths of a percent and 8 percent, depending on the method used. In the primary extractions of germanium alone the degree of enrichment surpassed 100 to 1, and for gallium the best ratio was 30 to 1. Upgrading of condensates by vaporization retreatment and by leaching and precipitation is discussed. An appreciable degree of mechanical preconcentration by attrition scrubbing and elutriation was possible on two fly ash samples.

Jan 1, 1967

By R. E. Mussier

This investigation was made to study new methods to prepare high-purity yttrium metal, Various methods were used to prepare pure intermediate compounds, primarily chlorides, bromides, and iodides, which were subsequently reduced to metal. The process found most suitable for the preparation of pure anhydrous yttrium chloride involved thermal dehydration of a mixture of hydrated yttrium chloride and ammonium chloride while under vacuum. Yttrium bromide and iodide were prepared most effectively by the direct halogenation of yttrim carbide. Yttrim carbide was obtained by reacting and melting yttrium oxide-carbon mixtures in a carbon-arc furnace. Yttrium halides were purified by vacuum distillation and reduced by alkali or alkaline-earth metals. Lithium and sodium proved to be the best reductants from the standpoint of yield (>95 pct) and purity (>99.8 pct) of the yttrium. The product of the reduction step was sponge metal, which was consolidated readily by conventional cold-mold, arc-melting procedure. The purest yttrium obtained in laboratory scale work was prepared by sodium reduction of yttrium chloride and contained only 125 pp oxygen; other impurities did not exceed 1,000 ppm. In larger scale tests yttrium containing only 800 to 1,000 ppm total impurities was obtained by lithium reduction of yttrium chloride. The tensile properties of high-purity yttrium were determined. Mechanical tests showed that yttrium can be forged, extruded, rolled, spot welded, and deep drawn.

Jan 1, 1963

By A. D. Marcy

The Midnite Mine is an inactive, hard-rock uranium mine in Stevens County, WA. Oxidation of sulfide-containing minerals, primarily pyrite, in the ore body produces large quantities of acidic water. An interception system installed by the mining company limits the discharge of contaminated water from the mine. The U.S. Bureau of Indian Affairs (BIA) and the U.S. Bureau of Land Management (BLM) have been actively involved in planning remediation of the disturbed areas. To assist in remediation, the U.S. Bureau of Mines (USBM) initiated research to determine water quality and to define ground water flow characteristics. USBM personnel designed a monitoring network, supervised installation of sampling wells, and collected and analyzed water samples. This Report of Investigations describes interpretation of data collected between December 1989 and April 1992. The computer program WATEQ4F was used to identify aqueous species distribution and to calculate potential solid phase controls of solubility. To assist in interpretation of changes in water quality between sampling locations and to develop models describing proposed flow paths, the computer program BALANCE was used. Using output from these programs and field observations, a description of the chemistry along proposed ground water flow paths at the mine is presented.

Jan 1, 2010

By Staton L. Tainter

"The Johnny Bull and Silver Knight claims were selected for exploratory diamond drilling after having been examined by the Bureau of Mines 3./The property was considered attractive for two reasons: (1) A prominent outcrop, recognized as an extension of the Tennessee vein, persisted over a distance of 2,000 feet across the claims; (2) its proximity to the known ore shoots in the Tennessee-Schuylkill mine, one of the largest zinc-load producers in Arizona.Actual drilling was started September 18 and was terminated December 8, 1943. Eight holes, aggregating 2,979.5 feet, were drilled with two machines. ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resource to the end that they make the greatest possible contribution to national security and economy. I is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R.G. Knickerbocker, chief, analyses samples and performs beneficiation tests."

Jan 1, 1947

This report summarizes the cost of U.S, mining and milling industry compliance with the Environmental Protection Agency (EPA) interim water quality guidelines for waste discharges. Applicable excerpts from Public Law 92-500 are stated and interpreted in conjunction with the guidelines being used for implementation of the law. Over 200 U.S. Army Corps of Engineers applications for discharge permits were used to develop the quality and quantity data base needed to estimate the cost to comply with EPA guidelines, Cost of three basic treatment methods were considered: Aeration, addition of lime, and sedimentation. From the process design, cost-capacity graphs were developed to consider maximum flow rate, maxi lime addition, and average flow rates. The graphical method used in this evaluation should provide a reasonable guide to the effect of waste treatment and, therefore, Public Law 92-500 and corresponding EPA guidelines on the mineral processing industry. The cost of complying with the EPA guidelines will have the effect of prompting the mining industry to minimize the production of waste water and of undertaking some additional treatment, Two case studies are presented to illustrate efforts that might be fruitful for minimizing waste water production and for treatment of combinations of acid mine drainage, mill wastes, and metallurgical process wastes when treatment is deemed necessary.

Jan 1, 1975

By J. L. Eakin

Systematic flooding was introduced into Nowata County, Okla., in May 1931. The results of this means of stimulating the nearly depleted Bartlesville reservoir in the county has been the subject of four Bureau of Mines Reports of Investigations.2-5/ This report presents a discussion of four full-scale water-flooding projects in the Delaware-Childers field and 1 pilot project in the Curl Creek field (fig. 1). All five plants have been in operation for only a few months. Although substantial increases in the rates of oil production have been obtained 1 by the injection of water, the projects are of particular interest at this time because of the novel methods of operation and new equipment that are being employed. One project utilizes a portable "package" plant designed for a pilot operation. All of the controls for this project are centrally located. The design makes it possible to remove the test plant to another location if the project is unsuccessful or if the unit is to be replaced by a larger plant. This project also utilizes diatomaceous-earth filters successfully for the first time and makes use of plastic pipe. Another novel feature of the operation is the aeration of Arbuckle limestone water through an airlift in the supply well.

Jan 1, 1955

By James R. McVey

A new method for measuring deformations of rock surfaces in underground excavations has been suggested by Dr. James Powell of Brookhaven National Laboratories (BNL) and subsequently developed and successfully demonstrated in a mining environment by the Federal Bureau of Mines, Spokane Mining Research Center (SMRC) and Brookhaven National Laboratories. The system uses 35-mm photography of targets strategically located on surfaces of interest, such as across the roof and on the sides of a mine drift or tunnel. The optimum tar-get, as determined in this investigation, consists of a white ?X? made with 1/8-inch-wide reflective tape on a black 6-inch square. Photographs, taken in pairs from two separated camera positions and at regular time intervals, were analyzed at the Bureau by hand and at Brookhaven National Laboratories using techniques and equipment similar to those used in cloud chamber film analysis. Test results show that deformation-measurement accuracies of better than ±0.020 inch in a drift that is 20 feet wide can be expected. This degree of accuracy, plus providing displacement data in the X, Y, and Z directions (rather than the one direction formerly possible), makes this a noteworthy and useful tool for industry as well as for mining research.

Jan 1, 1974

By T. A. Klinefelter

ONE OF THE many services rendered by the Federal Bureau of Mines is the identification and general examination of ore and mineral samples. Many of these, coming from almost every State in the Union, are clay and shale samples. Other Government agencies, State geologists, universities, and other laboratories are often requested to make similar examinations. This publication describes methods of testing these samples. An earlier paper, published in 1943, described Bureau of Mines methods of testing such clays.3 This paper was to be followed later with another (part II) that would describe much more thorough testing than did the rather general outline of part I. Part I has been out of print for some time and needs revision, and part II was never written; hence, the present publication is designed to include part I and also those additions intended as part II. The tests presented in part I were simple, requiring only the ordinary equipment to be found in any good chemical laboratory. The second publication was to include a greater number of test procedures and information on increasing the accuracy and precision of those previously given.

Jan 1, 1957

By Louis C. Brichta

"The O'Jack Mining Co.'s zinc and lead deposits in Jasper County, Missouri, have been worked intermittently since the early nineties; production from these deposits was greatest during World War I and II - 4,668 tons of zinc and lead concentrates. The deposits are in a sink-hole structure in which intense deformation has taken place and in areas of disturbance in the sheet-ground horizon.While high-grade ore was being mined, the operators sank seven churn-drill holes for the purpose of extending reserves. They then asked the Bureau of Mines to explore the deposit with the object of developing a reserve of lower-grade ore that could be mined by open-pit methods. Twenty-two holes were sunk. The methods of drilling and sampling and the logs of the holes, as of those drilled by the operators, are given later in this report.INTRODUCTION AND ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mined has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts development by each exploratory project as soon as practicable after its conclusion. Preliminary examination, conduct of exploratory work, and preparation of final reports are functions of the Mining Branch, Lowell B. Moon, chief, under the supervision of Dr. R. S. Dean, assistant director."

Nov 1, 1946

By H. B. Jensen

STUDY of the thermal-solution process was begun by treating crushed oil shale in a small autoclave at temperatures of 700° to 950° F. The effect of temperature, reaction time, type of solvent, and richness of shale upon the amount of organic matter that was removed from the oil shale was thus determined. Following this orientation work a semicontinuous, bench-scale apparatus was built so that heated solvent could be pumped through a bed of shale under elevated pressure, thus removing the converted organic matter from the spent shale. After some operating experience had been gained, a continuous unit was constructed. This permitted treating a slurry of shale oil and pulverized oil shale at about 300 p. s. i. and temperatures of 750° to 850° F. for various retention times. Considerable cracking and polymerization of the shale oil were found to take place during the process. In an attempt to prevent this, a study was made of extraction of the shale in batch-type autoclaves under high partial pressures of hydrogen at total gas pressures of as much as 4,300 p. s. i. at 850° F. The thermal-solution process was found to convert over 90 percent of the organic matter in oil shale to oil and gas. The highest yields of gas and oil obtained without hydrogen pressure were equivalent to 119 weight-percent of those obtained from the same shale by Fischer assay. With a high partial pressure of hydrogen, yields equivalent to 126 weight-percent of Fischer assay were obtained. However, the oil produced by thermal solution has a higher boiling range than that obtained by other retorting methods, particularly so if the thermal-solution process is used without a high partial pressure of hydrogen. Nondistillable oil (all benzene-soluble material that would not distill under 2 mm. Hg absolute pressure without cracking) equivalent to over 100 percent of the organic matter in the shale was obtained without hydrogen pressure in the system. When the process was carried out under hydrogen pressure, the yield of nondistillable oil amounted to 60 to 70 weight-percent of the organic matter. Part of this heavy material is formed partly by polymerization and condensation of the shale-oil solvent used. These reactions, as well as cracking of the solvent to form gas and a carbonaceous deposit on the shale, are unfavorable features of the process.

Jan 1, 1953

By H. L. Gilbert

Zircon sand may be reacted with sodium hydroxide at 600° C. to form sodium zirconate and sodium silicate. Sodium zirconate is water insoluble and so may be washed free of sodium silicate. The sodium zirconate may then be converted to zirconyl chloride by the action of hydrochloric acid and the zirconyl chloride crystals separated by cooling the solution. This approach produces zirconyl chloride of satisfactory purity with less cost than is involved in buying anhydrous zirconium chloride and converting it. A proposed design for a plant is given, INTRODUCTION This work was conducted by the Rare Metals Branch as a part of research on zirconium at the Bureau of Mines Northwest Electrodevelopment Laboratories, Albany, Oreg., under the guidance of S. M. Shelton, Regional Director. The work was supervised by W. W. Stephens, head of the Rare Metals Branch (now with Carborundum Metals Corp.).

Jan 1, 1954

By E. Chin

Under the seventh 5-year plan (1986-90), the Chinese Government continued to implement reform and to open the country further to the outside world in order to accelerate the growth of its national economy. As a result of expanded foreign economic exchanges and domestic achievements in education, science and technology, and cultural and public health undertakings, the national economy was strengthened. In 1988, there was impressive growth in the Chinese economy. The gross national product (GNP) grew by 11.2070 reaching $373.4 billion; 2 the national income grew by 11.4070 to $310.9 billion. The major problem in the Chinese economy was the imbalance between high demand and insufficient supply. Chronic shortages resulted in price increases and high inflation, which averaged 19% for China as a whole and about 30% in urban areas. Macroeconomic stability took precedence over market-oriented reform initiative. Because of rapidly growing inflation, the Government re-imposed price controls and rationing in major cities in the fall of 1988. China continued to be a major world producer of minerals, metals, and fuels. Output of the principal commodities continued to rise. The largest in-crease in production was salt which rose 24% in output in 1988; followed by sulfuric acid, 14%; cement, 12%; soda ash, 9%; caustic soda, 7%; and steel, 6%. For fossil fuels, the increase in output of natural gas was 14% in 1988; followed by coal, 3%; and crude oil, 2%. The output of electricity by thermal-fired powerplants rose by 9% while that for hydroelectric power-plants rose 7%. Although China's overall energy output has increased annually since 1980, the growth in demand continued to outstrip the supply.

Jan 1, 1990

By Mackenzie Burnett

An inducer-type pump, capable of injecting dry coal into a hydraulic transport pipeline has been developed and installed in a specially designed and fabricated slurry injector vehicle. The full scale prototype injector system can deliver up to 11 ton/min of coal into an 8-in pipeline t pressures up to 95 lb/in2. The Helical Inducer Injector operates on centrifugal principles with flow passing axially through helical pitched conical rotor. Water is delivered to the pump through an annular slot at the atmospheric pressure coal inlet. The spinning rotor maintains an air-core vortex of water which pressurizes the discharge housing. A screw feeds coal through the open inlet into this vortex. The inner radius of the vortex contracts as pressure is increased, giving a limiting maximum pressure which is proportional to the square of the rotor speed. Below this limit, flow rate, discharge pressure, und rotor speed re independent variables. The self-powered, 4 -in high slurry injector vehicle follows and receives ROM coal from a continuous miner, reduces the top size to 3-in, and delivers the sized coal to the injector feed screw for slurry formation and pumps it through a mobile hose attached to the vehicle's outby end.

Jan 1, 1983

By H. P. Greenwald

[For sarno years past the Safety in Minbr. Resaarch J30ard of Great Bri tr-dn ha:1 been making ar.. intensive Gearch for, traterials that \.'ould be 1!\ore ef-ficient than rock dust and th t 'could l1eplace it Jholly or in El:}rt as a muans of prevEll'ltine the propa 'tion' of 'c63.1~dust exnlosions in. mines21 In the course of this \o.'ork several rock c.ur--ts md numerous inorganic compounds I,/ere tested. The result w place incombus.ti ble substFlnces in two main groups~ (1) r.:ho se who sa effect' in suppre aeina Jlihe cor.lbustion of coal dUDt i 0 pro-]

Jan 1, 1940

By H. W. Kilau

The Bureau of Mines tested chromium-bearing waste slags from industrial stainless steel and other chrome alloy operations to determine their chromium leachability characteristics under acid precipitation conditions and to devise measures to prevent any pollution originating from this source. Two critical slag composition factors were found to control the chromium leachability: (1) CaO:Si02 ratio and (2) magnesium content. Above a 2.0 CaO:Si02 ratio, chromium exists in slag as CaO·Cr203, which can be vulnerable to leaching by acid precipitation especially if oxi-dized to CaCr04 when exposed to the environment over an extended period. Maximum chromium leachability from industrial slags occurred when the composition of the slag had about a 2.0 CaO:Si02 ratio. Between a 1.0 and 2.0 CaO:Si02 ratio, in the presence of sufficient magnesium, MgO ·Cr203 was formed, which is very resistant to oxidation and to dissolution by simulated acid precipitation. Addition of magnesium silicates to molten slag to fix the chromium in the MgO·Cr203 form was successful in preventing chromium leaching in simulated acid rain solutions. Experiments showed olivine and waste taconite tailings were suitable for this purpose. Olivine addition to a waste slag having a composition vulnerable to leaching (CaO:Si02 > 2) reduced the chromium leachability more than 80 pct.

Jan 1, 1984

By R. D. Leitch

"REASONS FOR AND PURPOSE OF WORKIn 1924 the United States Public Health Service was requested to undertake a special study of stream pollution. At that time the proposal that the United States Bureau of Mines take up the study was made by the Public Health Service because in point of training and experience the personnel of the latter was considered not to be as well, suited to this type of investigation as was that of the Bureau of Mines. H. Foster Bain, then Director of this bureau, promised to undertake the work, and, accordingly, field investigations were begun in the spring of 1925. The problems of mine-drainage wastes and of gas-house and coke-oven waste were investigated in the laboratory, and a method of treatment by sodium hydrate and benzol was found to be promising. The idea was obtained by A. C. Fieldner, chief engineer of the Bureau of Mines experiment stations, while in Germany in 1924, where he was shown a practical application of the process, but no information was obtained as to definite chemical or mechanical processes. Because of the then pending American patent application by the German firm, we made no attempt to develop our findings further. Shortly after, a similar method of treatment was developed in the United States, and since that time we have devoted our attention entirely to mine drainage. This paper is a presentation of some general facts and information gathered during the past five years on coal-mine drainage.SCOPE OF WORKAt the time our work was begun there was such a diversity of opinion on the whole subject and apparently so little was accurately known, that it was decided to undertake a basic study from which (1) certain definite information might be evident, and (2) what might be considered side issues of the original investigation would be suggested for subsequent study.A stream in a district thought to be representative of those in low to average sulphur bituminous coal fields and another in a high sulpbur district were selected for study, A fair (weber of factors entered into the tentative selection of these streams, the chief ones being their accessibility and freedom from other industrial or domestic pollution, besides, of course, the presence of mine drainage in these streams."

Apr 1, 1931

By Arcy R., D&apos George

A process for removing sulfate from Great Salt Lake brines and other natural brines, including sea water, has been developed. Sulfate is quantitatively removed by precipitation as barium sulfate in a cyclic process employing ion-exchange techniques. Barium is continously recovered and recycled, and sodium carbonate and sulfur or sulfuric acid are produced as byproducts in quantities sufficient to more than defray the cost of desulfation.

Jan 1, 1967