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By Farrel W. Lytle

Instrumental analysis has become an indispensable tool in research and production of the rare-earth elements. This development can be attributed mainly to a combination of two factors--the marked chemical similarity of the rare-earth elements, which excludes classical methods of analysis, and the speed and accuracy of instrumental-analysis techniques. With continued improvements in methods of producing high-purity rare-earth elements, keeping pace instrumentally is becoming much more difficult. Accordingly, greater emphasis is being placed on improving instrumental limits of detection and accuracy. The methods employed most frequently for determining impurities in rare-earth elements involve use of the optical-emission spectrograph (3, 4)4/ and the spectrophotometer (9). Although numerous X-ray-emission spectrographic methods (6-8) have been developed for analyzing rare earths, these techniques have not included detection of low-level impurities. This investigation was conducted to find the precision and accuracy of X-ray fluorescence in deter-mining impurities in rare-earth oxides in the 0.01-to 1.0-percent-concentration range.

Jan 1, 1959

By Floyd G. Anderson

The Federal Bureau of Mines promotes the use of safe and effective dust-collecting devices for rock drilling in coal mines. To insure that such devices are available to the coal-mining industry, the Bureau issues certificates of performance for dust-collecting systems and certificates of approval for dust collectors and rock drills or other mining equipment with integral dust-collecting systems that meet the requirements of an established Schedule.4/ Investigations are conducted under the provisions of the current revision of this Schedule by engineers of the Branch of Health Research. This circular describes briefly the requirements and procedure for obtaining certificates of performance or approval and lists equipment that has been certified as permissible under Schedule 25 or its revisions as of January 31, 1961. The names and addresses of companies to which certificates have been issued are listed alphabetically at the end of this circular.

Jan 1, 1961

By J. H. Johnson

The report references reports and publications from 1975 to the present related to diesel underground mine air quality research undertaken by Michigan Technological University. Research results obtained on this contract are summarized in 5 different sections as follows: Section 1 - Development of a Systematic Approach to Monitoring, Data Analysis, and Interpretation for Diesel Mine Air Quality Control, Section 2 - Experimental Evaluation of LHD On-Board Air Quality Control Systems, Section 3 - Development of a Portable Self-Contained LHD Tailpipe Emissions Measurement Apparatus for NO , N0, CO, CO , and Particulate Matter, Section 4 Quantitative Analysis of Diesel and Coal particulate Matter by Laser Raman Spectro¬scopy and Section 5 - Development and Application to Detector Tubes of a Laboratory Method to Assess Accuracy of Occupational Diesel Pollutant Concentration Measurements.

Jan 1, 1985

By W. H. Oppelt

To provide a relatively structurally stable form of dried lump lignite, two North Dakota lignites from Mercer County were dried by the Fleissner process in an atmosphere of saturated steam at 200, 300, and 370 p.s.i.a. pressure, corresponding to steam temperatures of 382°, 417°, and 437° F., respectively. Two series of experiments were made at each test pressure with the individual lignites. In one series, the autoclave was preheated to the processing temperature before charging the lignite; in the other the lignite was charged into the autoclave at room temperature. In each case, heat losses were determined by blank tests of steam consumption over a similar operating cycle with the empty autoclave. The degree of moisture removal and net steam consumption were calculated from material balances. The amount of water removed as a liquid from the two North Dakota lignites during the heating and steaming periods was compared with results calculated from previously published data on drying Austrian lignite and Australian brown coal. These lignites, covering a wide geographical area, had original moisture contents ranging from 35 to 49 percent. The Austrian lignite and Australian brown coal are considered to be of Miocene Age, and the Dakota lignites belong to the Paleocene.

Jan 1, 1955

By G. H. Keith

Oxygen and nitrogen cause strain aging in electrorefined vanadium, as evidenced by maxima in yield and tensile strengths and by Snoek internal friction peaks. Alloys containing up to 0.22 percent oxygen and 0.11 percent nitrogen were investigated. Tensile strengths of oxygen-and nitrogen-containing alloys were 66,000 and 68,000 psi at 300° to 400° C, compared with 53,000 and 62,000 psi, respectively, at room temperature. Total elongation decreases to about 7 percent at the temperature of maximum strength. At 600° C, strain aging is not evident. Based on interstitial contents calculated from internal friction measurement, the increases in strength caused by nitrogen and oxygen were 440,000 psi per weight-percent nitrogen and 260,000 psi per weight-percent oxygen. Application of the Schoeck and Seeger treatment to the Snoek effect in these systems results in a calculated lattice distortion of 0.24 and 0.15 caused by the presence of an interstitial nitrogen or oxygen atom, respectively. Alloys containing boron or carbon were also investigated. Both elements refine the grain size but have no other effect because of their low solubility in vanadium.

Jan 1, 1969

By R. V. Ramani, J. Qin, R. A. Jankowski

"Longwall mining is generally recognized as safer, more productive and economic when compared to room and pillar underground coal mining. There has been, however, increasing concern for the control of airborne coal dust concentrations in long wall faces. The airborne dust cloud at a longwall face is a complex aerosol system containing particles of varied size, density, shape and state of aggregation. For the development of more effective dust control practices in longwall faces, it is necessary to understand more clearly the characteristics of the longwall dust cloud.In this paper, results of a research study on dust concentration distributions along longwall faces are presented. The objective of this study is to characterize the longwall dust cloud behaviour and provide necessary fundamental data for a better understanding of the longwall dust problem. MSA personal samplers and gravimetric total dust samplers were employed to collect respirable and total airborne dust samples. The size distribution of these samples was determined by MicroTrac SPA. The instantaneous respirable airborne dust concentrations were recorded using RAM-I. The dust concentrations are related to face operations, particularly the shearer location and activities. The size distribution of airborne dust, instantaneous respirable airborne dust concentration, and air quantity distributions along longw all faces reveal a complex dust flow phenomenon. Additional fundamental studies are needed for characterizing the temporal and spatial behaviour of the dust cloud at longwall faces.IntroductionModern mechanized longwall mining was introduced in the United States in the 1960's and has become more common in the last twenty years. United States longwalls are multiple-entry retreating faces. According to a recent survey, 91 of the 102 longwall faces employ double-drum shearers (1). Several recently installed longwall faces have consistently produced over 4 000 to 5 000 tons per shift over extended periods of operation. The trend in under-ground coal mining in the U.S. certainly is toward the introduction of longwalls. This trend is true not only for new mines but also for renovation of existing mines. While longwall mining has many advantages over other mining methods, including improved safety, such as higher pro-duction. greater productivity and enhanced reserve recov-ery, it is associated with severe problems of dust control. The increase in longwall production has been accompanied by an increase in respirable dust problems which limit realizing the full potential of the longwall mining system. Despite the efforts to develop improved equipment and operational procedures to control the dust levels at longwall faces, it is still difficult to bring several double-drum shearer operations into compliance with the Federal stand¬ards of 2,0 mg/m 3 respirable dust without loss of produc¬tion. In fiscal year 1987, fifty-eight of the longwall sections were found to be in non-compliance once, and an additional 31 were cited two or more times'''. If the full potential of the longwall mining method is to be realized, new measures must be implemented to control the dust concentration to mandated levels. There is a need for detailed and extensive sampling of longwall faces to understand the dust source-sink relationships and the transient ambient concentrations. These must be related to the mining activities on the face. This paper is to characterize the longwall dust cloud behavior through a series of experiments in operating faces and provide necessary fundamental data for further studies to develop improved dust control practices."

Mar 1, 1992

By W. I. Nelson

This paper which describes the milling practice of the Engels Copper Mining Co., is one of a series on milling methods being prepared for and published by the United States Bureau of Mines. ACKNOWLEDGMENTS Acknowledgment is made of the assistance rendered by J. Casagrande, mill foreman of the Engels concentrator, in collecting much of the data presented in this paper.

Jan 1, 1932

By X. C. Shi

Bacterial mutagenicity and mammalian cell chromosomal and DNA damage in vitro assays were performed on a diesel exhaust particulate material (DPM) standard in two preparations: as an organic solvent extract, and as an aqueous dispersion in a simulated pulmonary surfactant. U.S. National Institute for Standards and Technology DPM SRM 2975 expressed mutagenic activity in the Salmonella reversion assay, and for in vitro genotoxicity to mammalian cells as micronucleus induction and as DNA damage in both preparations: as an acetone extract of the DPM mixed into dimethylsulfoxide, and as a mixture of whole DPM in a dispersion of dipalmitoyl phosphatidyl choline. Dispersion in surfactant was used to model the conditioning of DPM depositing on the deep respiratory airways of the lung. DPM solid residue after acetone extraction was inactive when assayed as a surfactant dispersion in the micronucleus induction assay, as was surfactant dispersion of a respirable particulate carbon black. In general, a given mass of the DPM in surfactant dispersion expressed greater activity than the solvent extract of an equal mass of DPM.

Jan 1, 2009

By D. Montagna

This Bureau of Mines report describes a salt-free, fluxless method for reclaiming metallic aluminum from aluminum dross. The dross is smelted under argon, nitrogen, or carbon dioxide, instead of a salt flux, in an externally heated pot furnace. Aluminum recovery, using argon, is equal to recoveries reported from commercial smelters that process dross in rotary-type furnaces This salt-free method could offer a reduction in air pollution, lower energy requirements by elimination of salts, and the production of up to 60 percent less solid waste for disposal than the salt method.

Jan 1, 1978

By James S. Browning

Research by the Bureau of Mines demonstrated that organic heavy liquid adhering to or adsorbed on fine mineral particles can be effectively removed by a novel method embracing pulping or displacement washing with hot water alone or in combination with a detergent. Displacement washing with steam alone or in combination with a detergent also was effective for removing the heavy liquid. In tests of sized minus 48-plus 200-mesh mineral charges, both the hot water washing with detergents and detergent steaming effectively reduced the heavy liquid losses on the particles to about 0.2 pound per ton of mineral or less. Centrifuging of the wash solutions permitted an almost complete recovery of heavy liquid from the solution as a pure heavy liquid product.

Jan 1, 1966

By W. A. Grosh

In 1951 the Federal Bureau of Mines became interested in the reports of copper-nickel mineralization in northern Minnesota. Several outcrops on the north side of the Duluth gabbro in the Kawishiwi River area were sampled by the Federal Bureau of Mines and George M. Schwartz of the Minnesota Geological Survey. Because these samples showed appreciable amounts of copper and nickel, a 100-pound sample of an un-altered outcrop was obtained for metallurgical testing. Results from this preliminary work were all favorable; therefore, in the fall of 1953 the Bureau of Mines diamond-drilled three holes near the outcrop of the con-tact between the Duluth gabbro and the Algoma granite. A total of 686 feet of NX size hole was drilled, and 100 percent of the core was recovered. Each hole intersected the contact, and the strike and dip for that locality were established. The core was split, and half was used for analyses and further metallurgical tests; the remainder was retained for permanent record in the Bureau of Mines core-storage warehouse.

Jan 1, 1955

By Walter W. Kaufman

This report summarizes a study conducted to determine the state of the art of various rock removal systems and their capabilities. The Objective of the study was to determine if currently manufactured equipment can adequately accomplish rock removal in surface mine reclamation applications. Evaluations of state reclamation regulations, with regard to topsoil rock content, were made to determine the rock removal requirements. The major categories of equipment studied are rock pickers and rock rakes. The impact of rock removal implementation on the reclamation operations is discussed in detail.

Jan 1, 1979

By Eric R. Bauer

This U.S. Bureau of Mines study was conducted to gain a basis for recommending methods to predict and prevent the occurrence of cutter roof failure, a common ground control problem in mines of the Northern Appalachian Coal Basin. This was accomplished by determining the geologic and engineering factors responsible for cutter development at six mines affected by cutter roof failure. Three distinct factors were found to be initiators of cutter roof failure: (1) high horizontal roof stress, (2) surface topographic variations, and (3) geologic anomalies. Effective control of cutter roof was obtained through improved bolting techniques, entry and mine reorientation, and entry and pillar size modifications, but only when selected based on the actual cause of failure.

Jan 1, 1990

By G. R. Hopkins

"A new record in fuel efficiency at petroleum refineries was achieved in 1935, when an average of only 615,000 B. t. u. was needed to refine a barrel of crude oil, compared with an average of 638,000 B. t. u. in 1934 and 829,000 B. t. u. In 1925. (See fig. 1.)Refiners have made almost uninterrupted progress in firing efficiency during the last decade although much of this gain was brought about by improved technique and greater use of heat exchangers and pipe stills, the determining factor was the trend in crude runs to stills. Most plants can increase their crude throughput materially with but small increase in fuel consumption. Consequently, in years in which crude runs have increased substantially, average requirements have declined; but in years in which crude runs have decreased, the average has tended upward. This conclusion is confirmed by figure 1, which shows that there has been but one minor exception to this rule in the last 10 years.Technical progress in fuel efficiency may be illustrated by comparing crude runs and total B. t, u. consumed. Between 1925 and 1935 crude runs to stills increased 31 percent, but the total quantity of heat required did not increase; in fact, it declined slightly.The trend of modern still construction is from shell stills, in which a large body of oil is heated, to tube stills, in which the heat comes into much closer contact with the oil. In 1935 the total capacity of operating pipe stills increased about 4 percent; this increase, though small, probably was related to the gain in average efficiency.The Increased use of heat exchangers and their role as fuel savers have been discussed in previous reports of this series. It is sufficient to say that refiners with insufficient exchange capacity added as much in 1935 as their budgets would permit."

Jan 1, 1937

By John E. Kelley

The Bureau of Mines conducted a study to determine the feasibility of joining refractory metal compounds to each other and to oxide ceramics by a vacuum hot press-diffusion bonding method. Very satisfactory joins were made of ZrC to ZrB2, ZrN to ZrB2, ZrC to ZrN, and of ZrC, ZrN, and ZrB2 to Al203. Each of these join assemblies contained a mixture layer comprising 50 weight-percent each of the two end compounds. The mixture layer, sandwiched between each end compound, enhanced bonding and smoothed out the thermal expansion gradient between the two end members. Strength and thermal shock tests showed that the join areas of the ZrC, ZrN, and ZrB2 joins were stronger and more shock resistant than the parent materials. Also included in the joining tests was one each of TiC to TiB2, TiC to TiN, TiB2 to TIN, and TiC to ZrB2 joins. Each of these was well bonded, showing that the vacuum-hot-press method can be used for a variety of systems.

Jan 1, 1969

By C. E. Henning

The total number of petroleum refineries in the United States on January 1, 1958, was 318 and their total crude-oil throughput capacity was 9,407,707 barrels per day, according to the Bureau of Mines annual survey. During 1957, 3 new refineries began operating while 4 refineries were retired. Although there was 1 less refinery, the total crude-oil throughput capacity at the beginning of 1958 was 284,033 barrels per day, or 3 percent, more than the January 1, 1957, level. During 1957 all refinery districts showed increases in capacity. The largest increase, 27 percent, occurred in the West Coast district followed by the Indiana-Illinois-Kentucky district with 14-percent increase and the Texas Gulf Coast district with 13-percent increase. The national increase in capacity had the effect of raising the capacity of the average refinery from 28,601 to 29,584 barrels per day. New crude-oil capacity under construction on January 1, 1958, totaled 185,265 barrels, and an additional 297,885 barrels capacity was reported building as replacement for existing facilities. Included in total new construction were 2 new refineries, 1 in Washington and another in Texas, with planned processing capacities of 45,000 barrels and 8,550 barrels per day, respectively.

Jan 1, 1958

By J. M. Singer

Quenching distances for flames of methane-coal dust mixtures were determined with air and oxygen-enriched air. Coals used were Pittsburgh, Sewell, and Pocahontas No.3. Quenching distances were greater for flames of hybrid mixtures of coal dust and methane than for methane flames of corresponding stoichiometry. From the data of quenching distances and methane-coal dust concentrations was calculated the quenching equivalence, which is the increase in coal dust concentration required to maintain a given quenching distance value as the methane concentration decreases. These equivalences could be useful in identifying hazardous methane-coal dust mixtures in mines.

Jan 1, 1966

By John A. Breslin

Size distributions and concentrations of particulates emitted from diesel engine exhausts were measured with cascade impactors. Samples were taken from the exhaust of two types of engines using three types of fuel and operating under five different engine speed and load conditions. The measured mass median diameters of the diesel particulates were typically about 0.3 um. There was no significant difference in mass median diameter between engines or fuels and only a slight dependence on operating mode. Concentration measurements ranged from 14.2 to 250.9 mg/cu m, and calculated mass outputs, from 52 to 3,443 mg/min. Significant differences in mass output were found between engines, fuels, and especially between different operating modes. The quantity of clean dilution air that would be required to reduce the particulate mass concentration below the 2.0 mg/cu m respirable dust standard for coal mines was greater than the dilution air required to meet the standards for noxious gases for both engines tested.

Jan 1, 1976

By W. W. Weller

Low-temperature heat capacities of scandium sesquioxide (Sc203) and a mixture of cerium sesquioxide (Ce203) and cerium dioxide (CeO2) were measured over the temperature range from 50° to 298° K. The entropy of scandium sesquioxide at 298.15° K was evaluated directly as S°298.15 = 18.4 ± 0.1 cal/deg mole. That of cerium sesquioxide was extracted by combining the heat-capacity data for the mixture with those for pure cerium dioxide; the result was S298.15 36.0 ± 1.0 cal/deg mole.

Jan 1, 1963

By L. R. Burdick, R. Wiggers, J. F. Berkley

"INTRODUCTION On February 23, 1944, Solid Fuels Administrator Harold L. Ickes stated that the existing fuel shortage made it necessary to utilize a great surplus of freshly mined anthracite ranging in size from Barley (No. 3 Buckwheat) downward through the smaller sizes. As a part of the program to increase the use of such coal, field trials of mixtures of bituminous slack coal and anthracite Barley were made on industrial-size stokers at many fuel-burning plants. The following covers the test information it was possible to accu-mulate during the work of initiating the use of these mixtures at the plants.SUMMARY AND CONCLUSIONSField tests of various mixtures of bituminous slack coal and anthracite Barley on industrial-type stokers show that the use of such mixtures is very practicable and that it is possible to change and usually to adjust to an improved condition the characteristics of a fuel bed of eastern bituminous slack coal by the addition of proper amounts of anthracite. The improved uniformity of the fuel bed of single-retort stokers makes possible less manual attention to the bed. Air flow through the fuel bed is affected.Smoke is decreased. In general, the fly ash and also the unburned combustible in the fly ash and refuse are increased. Clinkering in the fuel bed is generally lessened. The peak-load carrying capacity of the stoker is definitely affected, usually adversely for the higher percentages of anthracite."

May 1, 1946