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By Seth C. Schaefer

The Bureau of Mines studied thermodynamic properties of Al-Ni alloys con¬taining 0.54 to 30.04 atomic percent nickel with the aid of the high-temperature galvanic cell Al(1) // Al+3 (AlCl3 in NaCI.KC1) // Al-Ni alloy (1 or s). Activities of aluminum and nickel (compared with pure liquid metals as the standard state) show pronounced negative deviation from Raoult's law at 1,273 K. The properties [?G, ?Gxs, ?G ideal, ?GA1, AGxs1, ?Gni , and ?GNixs] have been derived from the experimental data and are summarized in tables and illustrations. At 1,127 K, the thermodynamic stability for the invariant three-phase equilibrium consisting of a saturated liquid, A13Ni, and A13Ni2 has been uniquely defined by an activity for aluminum of 0.751. A free energy of formation at 1,127 K of -7,940 cal/g-atom was derived for the compound A13Ni.

Jan 1, 1975

By A. R. Mumford

The fuel economy ot a. plant m be better than ite anxious friend.a J'ealize. A watchful a-aper1.ntend.ent of a Goverment plant, kn.owing that improvements in plant equipment bad. been made since hie atOkel'e were installed, was almosi per­ suaded to aubatitute a new t.,pe. The Bul'eau. of Mines was asked to aaoertain the a.cti.i&l performance ot the old stokera and tound. the plant alr doing from three to five per cent better than was promieed for the new egp.ipment. Tbe va.1.ue ot accurate knowledge of plant perfoimarice, am the need. ot eqm.pment to weigh and measure quantities is thus demonstrated. The boiler and ,tour ett1c1enc, was found to be 75 per cent, and the overall efficiency of the boiler, etoker• and economize, wae 78 per cent. Both records are high, and are to be attributed to ce in operation, to good working condition of the plant, and to the low rate ot evaporation, which was only aboui two-third., et the botler'e rated. capacity. The plant teated conaiated ot two la.boock & Wilcox boiler, tired b1 means of over teed 1toker1 and equipped wi t,b. a fuel economiaei- 1n the uptake. The bo1lel'a ,upplied ateam to two large water pump being used only intermittently.

Jul 1, 1922

By Doris M. Hyde

The economy of Belize continued to be relatively unaffected by activity in the minerals sector. Mining production consisted of limestone, marl, and sand and gravel. All production was used for domestic construction projects. By the end of 1979 the major oil companies had, temporarily at least, ceased active exploration efforts. Esso Ventures, Inc., after drilling three dry holes in southern Belize, planned to reappraise its activities. The Reef Exploration, Ltd., concession was acquired by Anschutz Oil Co. (81.25%). with minority interests held by Anglo Oil Co. and Carolina Oil Co. The Anschutz group drilled offshore in the Gulf of Honduras and in Belize Harbor. Echo Exploration has a con-cession along the Mexican border and Spar-tan Petroleum Corp. obtained seven exploration licenses covering 768,000 acres in northern Belize. Spartan's concessions included about 130,000 acres offshore, with the remainder along the southeastern rim of the Yucatan Peninsula. Placid Oil Co. took an interest in the Spartan acreage and became operator. Seismic exploration was underway in 1979. A Mexican company, Pan American Oil and Gas, S.A., was awarded two exploration concessions, one in southern Belize and one near the Mexican border.

Jan 1, 1981

By Eugene V. Cilento, R. Clark Lantz, K. A. DiGregorio

"This laboratory bas developed a sensitive electro-optical method to quantify the initial rate (R) and total amount (MAX) of superoxide (02) produced by single pulmonary alveolar macrophages (PAM). The method uses a microscope-based TV system to visualize PAM in culture, and to video record the images during the time the cells produce 02. MAX and R are calculated from measurement of temporal changes in optical density in the images due to precipitated diformazan formed by the reaction of O2-, produced by each PAM, with nitroblue tetrazolium present in the culture medium. To date, values of Rand MAX, measured due to adherence of PAM to the dish, have been compared to values obtained when quartz, coal mine dust (CMD), and kaolin . were added to the medium (in vitro). Rand MAX have also been calculated for PAM lavaged from animals exposed to quartz and CMD in the WVU Inhalation Facility. Presently, experiments are being done using which will permit PAM to be restirnulated by different dusts to help establish a dose response relation~ p and a means to study the role of lung surfactant on modifying the acute toxicity of inbaled dusts. Ultimately, this methodology should provide useful insight into establishing the role of 02 in PAM dysfunction due to inhalation of dusts, and in lung diseases such as pneumoconioses. INTRODOCTIONPAM are free cells found in the lungs which protect the lungs by removing foreign debris and bacteria. This is accomplished, in part, by the process of phagocytosis, whereby foreign matter is internalized into vesicles known as primary phagosomes. Phagocytosis also involves the chemical breakdown of inhaled dusts and the killing of microbes. Detoxification is aided by the respiratory burst, which is a metabolic response of the cell to foreign substances, that results in the production of highly reactive oxidizing agents from the partial reduction of extracellular oxygen to superoxide (02) at the surface of the plasma membrane. Superoxide undergoes either spontaneous or enzyme catalyzed dismutation reactions to form hydrogen peroxide (H202) and subsequently hydroxyl radical (OH•) and singlet oxygen (02 t ). However, while these oxygen metabolites aid in the killing of microbes they also may destroy endogenous tissue. For example, 02 has been linked to the aging process and to many diseases including emphysema, diabetes, and cancer.'' Therefore, a better understanding of the production of 02 is extremely important since an abnonnally low production could result in damage by inhaled dusts and bacteria while an abnormally high production could result in direct damage to the lung tissue by the phagocytes. Inhalation of respirable sized mineral dusts, such as quartz (silica), coal mine dusts (CMD), and asbestos, results in various pulmonary disorders. PAM are thought to play an important role since evidence suggests that the first step in fibrogenesis is an interaction of dust particles with PAM. Generally, in vivo exposure of animals to mineral dusts results in increased respiratory burst activity, migratory patterns, phagocytic behavior, and secretory potential of PAM, and for this reason these have been implicated to be pivotal events in the pathogenesis of pulmonary diseases.1 In addition to stimulation of resident PAM, an influx of monocytes into the lung and/or production of new macrophages generally occurs in response to fibrogenic dust inhalation. Further, PAM may attract and stimulate fibroblasts, which normally synthesize proteins and collagen during rep~ of tissue, by secreting chemoattractants and enzymes. Thus, PAM may be involved in pulmonary disorders through failure or partial loss of their defensive capability, or indirectly, through release of other mediators."

Jan 1, 1990

By Phyllis Lyday

Mining did not contribute significantly to the economy of Benin, a small country on the coast of West Africa, during 1978-79. During these years, Benin continued to be rated by the United Nations as one of the 25 least developed countries in the world; its gross domestic product was under $200 3 per person per year. Salt from seawater, sand and gravel, bricks, and imported clinker for cement were the only minerals which contributed to the economy. Minerals were not expected to play an important role in the commercial sector of Benin's economy during the next decade. Joint projects included infrastructure development to create a coordinated road and rail system between Niger and Benin that was begun in 1960 as ?Operation Hirondelle." In 1976, an agreement for the construction of a rail link from Niamey, Niger, to Parakou was signed. At Parakou, the rail line would join the existing line to the port at Cotonou. Construction of the rail line was expected to take 6 years, and the cost was estimated at $287 million in 1979. During late 1979, the Federal Republic of Germany granted Benin a loan of $12 million for reconstruction of the port at Porto Novo. Benin and Nigeria were discussing a joint adventure in crude salt exploitation.

Jan 1, 1981

By J. Roger Loebenstein

Demand for arsenic trioxide exceeded supply in 1978 and 1979, and the major domestic and foreign producers allocated available supplies to customers. Major demand has been from the cotton-growing and wood-preserving industries. Ample supplies of arsenic metal produced in the United States and Sweden were available in 1978 and 1979. Major demand for metal was from the automobile battery industry in Japan, Europe, and the United States. Legislation and Government Programs.-The Occupational Safety and Health Administration (OSHA), promulgated the final standard on the occupational exposure to inorganic arsenic, effective August 1, 1978.2 The need for the standard was a result of OSHA's conclusion that inorganic arsenic is a human carcinogen. The purpose of the standard was to minimize the incidence of lung cancer among workers exposed to inorganic arsenic. The maximum exposure to arsenic was lowered from the previous ceiling of 500 micrograms per cubic meter of air to 10 micrograms per cubic meter over an 8-hour time period. OSHA had originally recommended a ceiling limit of 4 micrograms per cubic meter in January 1975. Provisions of the new standard require exposed employees to wear respirators and undergo continuous medical monitoring. Other provisions establish regulated areas limited to authorized employees and require the construction of special lunch-room and worker hygiene facilities and the posting of signs and labels warning of the presence of arsenic. The new arsenic standard will have a significant economic impact on copper, zinc, gold, and lead smelters as well as consumers of arsenic trioxide. A number of copper companies have joined together to contest the standard in court. However, measures to comply with the standard have been initiated by ASARCO Incorporated at its Tacoma, Wash. plant.

Jan 1, 1980

By E. S. Burnett

The temperature entropy (T, S) chart? of thermodynamic properties of nitrogen herewith presented is a complete (1949) revision and a considerable extension of similar charts prepared by the author for use of the helium section of the Bureau of Mines about 25 years previously on the basis of inadequate data then obtaining. During the interval since that early effort, much experimentally determined information on nitrogen properties and behavior has been published, which now permits a more nearly accurate layout and more extensive charting of these relations.

Jan 1, 1950

By Franklin D. Cooper

The value of nonfuel mineral raw materials produced in the United States in 1978 was $20 billion. In 1979, total value increased to an estimated $24 billion, up 20% from 1978. Of the principal metallic ores produced in 1979, about half showed increased quantitative output and all showed increased value per ton compared with that of 1978. Most nonmetallic commodities showed increases in quantitative output and in average value per ton. Because of its decreasing share of the world market, the domestic mineral industry's concerns were the increasing costs of capital, labor, and energy; withdrawals of public lands from mining; and the increasing cost of environmental regulations that tended to deter or delay investment in the Nation's capacity for producing essential minerals.

Jan 1, 1980

By l.J Prosser

from 1990 to 1996, 16 states reported 92 injuries from falls of roof, rib or face in the more than 90 underground stone mines in the United States (Fig. 1). Missouri, Pennsylvania and Kentucky accounted for 48% of the total number of injuries (Fig.2). Of this total, 11 miners were killed. Of the 11 fatalities, 10, or 91 %, were associated with unrecognized loose or failed rock within the roof beam. Additionally, unrecognized roof beam failures resulted in a majority of the falls of ground injuries occurring in underground US stone mines from 1990 to 1996.

By T. M. Kohler, G. L. Finfinger, D. M. Hyman, A. T. Iannacchione

The Bureau of Mines measured methane emission rates from an advancing salt face ranging from 15 to 56 ft3/ton (0.5 to 1.8 m3/t). Small room size, use of a continuous miner, and a well-defined ventilation system made possible air velocity and methane concentration measurements, These measurements, representing data from 18 production days, were con- ducted in an area of abnormally low grade salt, Methane emissions occurred primarily during the advance of the salt face by continuous miner.

Jan 1, 1982

By N. S. Dalal, X. Shi

"The oxidation of NADPH by vanadate(V) in the presence of glutathione reductase showed typical enzymatic kinetics. The oxidation was inhibited by N-ethylmaleimide, a glutathione reductase inhibitor. Superoxide dismutase had no significant effect on the oxidation, indicating non-involvment of the superoxide radical. The vanadate(V) reduction was found to be a one-electron transfer process. These results suggest a new pathway for vanadate(V) metabolism and a new function of glutathione reductase. Compounds of vanadium(V), such as NaV03 , exert potent toxic effects on a wide variety of biological systems (1-3). Despite intense current activity, however, the biochemical mechanism of vanadate(V) toxicity is still not well understood (1- 14). It is believed that one of the important pathways involves the oxidation (by vanadate(V)) of NAD(P)H (15, 16), but, to our knowledge, there has been no report of the identification of any vanadate(V) reductase. With a view to finding if there exists any vanadate(V) reductase, we have investigated the oxidation of NADPH by vanadate(V) in the presence of glutathione reductase. Glutathione reductase (GSSG-R)2 was selected because our previous studies have shown (17) that GSSG-R can act as a reductase for chromate(VI), which is isoelectronic with vanadate(V). We find that GSSG-R does indeed function as a NADPH-dependent vanadate(V) reductase, thus pointing to a new pathway for the metabolism of vanadate(V), as well as to this property for GSSG-R. MATERIALS AND METHODSSodium metavanadate (NaV03 ), henceforth vanadate, was purchased from Aldrich and its solution was always freshly prepared. The GSSG·R used was from bovine intestinal mucosa and was purchased from Sigma. The oxidation of NADPH was followed photometrically as the decrease in absorbance at 340 nm. The spin trap, 5,5-dimethyl- pyrroline-N-oxide (DMPO), was purchased from Aldrich and used without further purification, since very weak or no spin adduct signal was obtained from the purchased sample when used alone.ESR spectra were obtained at X-band (9.7 GHz) using a Bruker ER200 ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR gaussmeter (Bruker, Model ER035A) and the microwave frequency was measured with a digital frequency counter (Hewlett-Packard, Model 5340A). An ASPECT 2000 computer was used for data storage and analysis. The concentrations given in the figure legends are the final concentrations. All experiments were carried out in the phosphate buffer solution (pH 7.2) and at room temperature."

Jan 1, 1990

By Doris M. Hyde

The petroleum sector continued to dominate Ecuador's economic activity in 1978, accounting for nearly 10% of the gross domestic product (GDP) and 42% of total export earnings. In 1978, a more flexible petroleum export price was adopted which permitted an expansion of foreign market opportunities. During 1979, Ecuador took advantage of disruptions in the world petroleum supply and renegotiated existing export contracts to accomodate the rapidly escalating world market price. Petroleum sales on the spot market were maximized, and prices reached unprecedented levels. By taking royalty payments in-kind, Ecuador increased its volume of petroleum available for term and spot sales. Although the volume remained about the same as in 1978, the total value of 1979 petroleum exports increased to about $920 million, reflecting a 76% increase over the $523 million received for 1978 crude oil exports. Concerned about its steadily decreasing petroleum reserves (recently estimated at about 1.1 billion barrels), rapidly increasing and heavily subsidized domestic consumption, and the prospect of having to import substantial amounts of petroleum by 1983, Ecuador announced plane which it anticipates will double reserves within the next 5 years. The Government plans to spend $1 billion over the 5-year period. Plans include drilling 325 exploration and development wells and establishment of a secondary recovery program for the Sachs and shushufindi fields. Some exploration wells are expected to reach a depth of 17,000 feet. It is thought that substantial reserves exist in the southeast Amazon region. Late in 1979, it was announced that some 10 million hectares will be available for exploration tenders-probably in blocks of about 200,000 hectares each-in the Amazon jungle of the Orients and in the coastal and offshore regions. The Government planned to commission a private, independent analysis of Ecuador's petroleum reserves that would also include recommendations on efficient production levels.

Jan 1, 1981

By Andrew B. Cecala

While various types of equipment are used in bulk material processing plants to control respirable dust, the equipment often doesn't adequately protect workers. One cost-effective way to supplement your existing dust control equipment is to install a whole-plant ventilation system. This article outlines research by the National Institute of Occupational Safety and Health (NIOSH) on using whole-plant ventilation in two mineral processing operations to reduce respirable dust levels. Information also covers how to design a ventilation system for any bulk material processing plant.

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies for syn¬thetic Cu2S and CuS were measured. This investigation is part of the Bureau of Mines goals to provide thermodynamic data essential to the more efficient processing of copper ores, and thereby minimize the current dislocations in energy, environment, and mineral supply. Heat capacities were measured with an adiabatic calorimeter from 5 to 310 K, and resulted in S°298 = 27.76 for Cu2S(c) and S°298 = 16.05 cal/deg mole for CuS(c). Low-temperature values are tabulated for Cp°, S°, -(G°-Ho°)/T, and H°-Ho°. Enthalpies were measured with a copper block calorimeter from 298.15 to 1,600 K for Cu2S(c,1) and 298.15 to 780 K for CuS(c). The thermal behavior of CuS showed no transitions or other significant anomalies for the low- or high-temperature investigations. Cu2S showed reversible transitions at 376 K with an isothermal heat absorption of 0.865 kcal/mole, 720 K with an isothermal absorption of 0.280 kcal/mole, and approximately 1,400 K (congruent melting point) with a heat of fusion of 3.070 kcal/mole. High-temperature data are tabulated for H°-H°298, Cp°, S°, and -(G°-H°298)/T. Enthalpies are also expressed in equation form. The low¬and high-temperature data were combined with data from the literature to cal¬culate and tabulate ?Hf°, ?Gf°, and log Kf as a function of temperature.

Jan 1, 1978

By John R. Benham

The Blue Joint Mtn. RARE II area may contain barite resources. One claim, the Woods Creek Barite No. 1, contains two veins of barite of drilling mud quality. The quantity of barite present could not be determined due to limited surface exposures. Sections 1, 2, 11 and 12 of T. 2 S., R. 23 W. in the study area are classified by the U.S. Geological Survey as prospectively valuable for geothermal energy resources. These sections border Blue Joint Creek Hot Springs, which are outside the study area.

Jan 1, 1981

1. Data from the Mine Safety and Health Administration (MSHA) indicate that a total of 241,502 employees worked in surface mining locations in 2003, corresponding to 212,113 full-time equivalent (FTE) workers. • Surface employees accounted for 84.6% of all mining employees. • The majority of surface employees (73.7%; n = 177,927) were mine operator employees as opposed to contractor employees. • Stone operator employees comprised the greatest percentage (27.2%; n = 65,743) of surface employees.

Feb 1, 2005

By Oliver C. Fursman

The Bureau of Mines undertook this investigation to study methods of utilizing red mud residues from production of alumina from bauxite. Pilot-plant tests were conducted using Jamaican and Surinam red muds. Both the carbon-lime-soda sinter process and electric-arc smelting with coke and limestone were employed to recover iron and alumina. Alumina recoveries of 85 to 90 percent were obtained by the sinter process; although iron recovery was about 80 percent, the magnetic product was finely divided and difficult to separate from the gangue. Smelting red muds in the electric-arc furnace produced a pig iron with 98-percent recovery of iron; up to 84 percent of the A1203 was recovered by leaching the calcium aluminate slag with Na2C03 solution. A titania product assaying 96 percent TiO2 was recovered from the nonmagnetic portion of Surinam red mud sinter by extraction with H2SO4. Leached calcium aluminate slags and brown mud (from the combination Bayer process) are possible raw materials in the manufacture of portland cement.

Jan 1, 1970

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

APPENDIX G TABLE IX MINE A 1 General Total Employees 3000 Maximum No, of Men Underground/Shift 800 Shifts/Day 3 Type of Ore Copper Daily Production (TPD) 25,000 Mining Method Room and Pillar Vein Dip/Thickness l0°/l5 ft Number of Levels/Max Depth 1/0 to 1800 ft 2 Haulage, Conveyances and Travelway Main Haulage Rubber Tire/10 miles belts Man-Ways - Typical Route of Travel to most Remote Sites Rubber Tired Vehicles Hoists - Capacity/Speed/Depth Depth under construction 3 Ventilation 2,500,000 cfm - 5 surface fans 4 Compressed Air N/A cfm 10" and 12" lines 5 Incendiary Storage 2 day powder 1000 gal fuel oil 6 Communications 1 complete system - all shops, dinner areas, and feeder/breaker stations 2 partial systems 7 Escapeway- Systems Man Check System Section boss log and punch cards Alarm System Mine phones with paging system Posting of Escape Route Maps No Escape Signs Every intersection, fluorescent paint Evacuation Drills 2/yr/shift Refuge Chambers - 1 cinder block - No longer required

Jan 1, 1976

By McHenry Mosier

A skull breaker has demonstrated its advantages for secondary breaking in a limestone quarry by entirely displacing secondary blasting . It has reduced safety hazards to workmen, increased the number of quarry operating days , and has lowered mining costs by 2.7 cents a ton. It is believed that the application of the skull breaker can be made economically advantageous in the surface mining of other commoditics .

Aug 1, 1948

By M. H. Rinkenbach, C. A. Taylor

The detonating compound cyanuric triazide was discovered*** and patented**** by Erwin Ott, and on account of his claims, the Bureau of Ordnance, U. S. Navy, desired more complete data, so an investigation was made. The results obtained were such that the Bureau of Crdnance recommended publication thereof for the benefit of the explosives industry. Some of the patent claims regarding cyanuric triazide are as follows: 1. It is not poisonous in contradistinction to fulminating mercury and lead azide. 2. In contradistinction to the hitherto employed priming agents it is fusible, and its fusion point (94°C) is so low that the product melted by a single heating in water or steam bath, can be poured without danger in the capsule shell. It solidifies therein after cooling, and shows the density of 1.5. 3. It has been determined that the cyanuric triazide, in spite of its very much higher priming actions, is much less brisent then ful- minating mercury and lead nitride. 4. The chemically pure cyanuric triazide (C3M2) constitutes colorless crystals melting at 94°0., and is not volatile. It is not affected by cold water, and only slowly saponified by hot water. It is relatively insensitive to friction and not too strong concussion, but explodes by impact or when hea ted to 170°C., or when heated suddenly. It is not more sensitive to friction and shocks then fulminating mercury. 5. The preparation of the triazide is preferably carried out by acting with an excess of sodium azide in an aqueous solution; in the cold, on cyamric chloride gradually suspended in the said solution.

Aug 1, 1923