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By J. P. Matoney

In recent years, the diminishing supply of natural gas has led energy suppliers and consumers to consider making synthetic natural gas from coal. A number of processes have been devised to produce gas from coal; many of these have been operated at the pilot stage and some have been operated commercially. Each process has specific coal feed stock requirements with respect to size consist and moisture content. The purpose of this presentation is to compare the estimated costs for coal handling, live storage, size reduction and drying facilities that would be required for delivery of coal feedstock to different gasification processes.

Jan 1, 1977

The dissolution kinetics of cobalt in iodine/iodide solutions was investigated using a rotating disc technique. Variables studied here included temperature, rotating speed, concentration of lixiviants, and pH of the solution. The overall dissolution reaction was found to be limited by mass transfer of tri-iodide through the diffusion boundary layer with Arrhenius activation energy of less than 16.2 kJ/mol (4 kcal/mol) over the temperature range, 2-42°C. The pH of the solution had little effect as long as the pH of the solution was less than 8. However, when the pH of the solution became greater than 8, the dissolution rate decreased dramatically due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1994

By H. C. Harrell

The Tennessee Valley Authority began employing geophysical well logging for foundation investigations in October 1973. Since that time more than 3,000 holes have been evaluated for engineering purposes. The Tennessee Valley Authority has not actively used geo-physical well logging for exploration of construction materials, but we feel that much of the information derived from geophysical logs for foundation exploration is applicable to the construction materials industry. This paper will then discuss geophysical logging as applied to foundation engineering and, by implication, the feasibility of use in construction materials exploration. The use of geophysical logging and percussion drilling instead of coring has greatly expanded TVA's data acquisition capabilities and has also resulted in substantial savings in time and money. Economical boreholes are obtained through the use of large percussion track drills (Figure 1). This equipment is capable of drilling through the overburden, setting steel casing on the top of rock, and drilling the rock beneath the casing. Holes as deep as 400 feet (121.9 m) have been drilled by this method.

Jan 1, 1977

By Jr. Gambrell

For more cost effective strata control, a fundamental understanding of the behavior of the support system is needed. To assist in this understanding for shield supports, behavior of a four-leg shield design used on a soft floor in an operating longwall system is presented. The shield was constructed having a split base and a split caving shield. Attention is focused on other-than-normal loading on the canopy and its effect on deformation of the lemniscate links. Examples of the typical bending and twisting deformations are given. Schematics of the canopy, caving shield, and lemniscates showing important forces and moments are presented. Approximate minimum values of the forces and moments are calculated. The need for use of more inclusive three-dimensional design techniques is demonstrated.

Jan 1, 1990

By Bernard A. Grand, Gary A. Almeraris

This project involves the reconstruction of a 1,100 ft. long by 75 ft. wide segment of an existing 4 to 5 track subway under Northern Boulevard in the Borough of Queens in New York City. The project includes widening the existing subway to permit the construction of new inbound and outbound subway (T1 and T2) ramps adjacent to and under existing operating tracks. The plan of the project is shown in Fig. 1. Existing tall buildings along the job site and a contaminated groundwater plume under an adjacent rail yard required construction of slurry concrete walls along the east and west construction limits. Groundwater cutoff across the north and south construction limits of the subway was achieved by jet grout walls built across the subway invert slab between existing track and third rails. The work involved dewatering the construction site to a depth of about 50 ft. below street grade. This is a four year project and includes extensive work to maintain and protect subway and vehicular traffic of over half a million commuters a day through the work area. The project cost was $160,000,000.

Jan 1, 1999

By J. Roth

PROLOGUE Nowadays, where production costs and energy costs are increasing and at the same time requirements in fineness and purity of industrial mineral products are getting higher and higher, industry has to look for more efficient grinding systems and developments to produce these products more economically. Therefore lots of new developments in high energy jet mill pulverizing have been made. In the main, however, these developments involved more or less just the new principle of fluidized bed jet pulverizers but not the older spiral jet mill principle. In some cases, especially in the filler industry where laminar minerals are used and higher aspect ratios are required, the spiral jet mill principle has advantages in a better delamination of these minerals. To comminute minerals down to products with a d97 < 3 µm, the specific energy consumption increases up to 2,000 kWh/t – 3,000 kWh/t or even more, depending on the grindability of the mineral. So the production of these fine materials is quite an expensive task. But jet mill grinding is and will be the most favorable method to produce micro-products and in the near future nano-products, despite the high energy consumption.

Jan 1, 2000

By D. G. Krige

I read the paper “The jackknife approach” with interest. There appears to be a widespread misunderstanding of the kriging variance as a measure of the error variance of the kriged grade estimate of an ore block. Virtually all mineral deposits display skew frequency distributions and are subject to the well-known proportional effect. Thus, it is usual to find in an ore body, when subdivided a really into subpopulations, that the variances of the grades (or the total sills of the variograms) for the subpopulations will be correlated with the corresponding mean grades (usually linearly with the squares of the mean grades). Thus, the variogram will be stationary.

Jan 1, 1996

By William A. Rehrig

During recent years, there have been frequent investigations on the geochemistry of biotite. This work has emphasized, and no doubt was prompted by, factors related to mineral exploration, particularly for those deposits of the porphyry copper type. A large number of papers have been devoted to the obtainment of trace-element data from plutonic biotite. These data have been used to extract primary geochemical information pertaining to the parent magna and the hydro-thermal system which together give rise to porphyry copper deposits. In two early works, Putman and Burnham (1963) and Parry and Nackowski (1963) analyzed base metal contents of ferromagnesium minerals, primarily biotite, from various barrenfmineralized plutons of the Basin and Range Province. One similar conclusion from the two studies was that the Cu, Zn, and Pb contents of magmatic biotite served as indicators of ore development within the granitic rocks genetically related to ore. This theme was then pursued vigorously by a number of authors until the present time. Results, however, have been contradictory, as reviewed by Coope (1974). For example, studies by A1 Hashimi and Brownlow (1970), Lovering et a1 (1970), Putman (1972), and Graybeal (1973) continued to support positive primary relationships between the trace-metal content (usually copper) of biotite and associated sulfide mineralization. By studying biotite in close spatial association will sulfide occurrences, Putman (1972) and Graybeal (1973) developed models for base metal partitioning in magmatic systems based on their discovery of inversely distributed copper between silicate (biotite) and sulfide phases. Conversely, research by Bradshaw (1967) and Blaxland (1971) plus the recent findings of Parry and Jacobs (1975) and Kesler et a1 (1975) found little if any evidence to support a correlation of biotite base-metal or

Jan 1, 1976

By John A. DesLauriers

INTRODUCTION This paper will update the status of small sized tunnel boring machines used in both the Mining and Civil Industries. I will mention a) new developments in small size hard ground tunnel boring machines, b) review North American performance records of the Atlas Copco Mini/Midi Fullfacers, and c) compare relative costs in driving a 1200m (4000 ft) typical utility tunnel using a leased TBM versus the conventional drill and blast method. NEW DEVELOPMENTS JARVA MACHINES Of all small rock tunnel boring machines currently in use, the Jarva MARK VI and MARK VIII are receiving the most enthusiastic acceptance. These circular fullface borers using usually 15 inch single disc cutters (manufactured also by Jarva) are designed on the &apos;T&apos; bracing principle. Previously, Jarva&apos;s line of tunnel boring machines, even their smallest, was designed on the &apos;X&apos; or double diagonal bracing configuration with a gripper in each quadrant. In small tunnels where net room is so very important, the &apos;T&apos; scheme with gripping only at the spring line nets precious room around the cutter unit for passage of men and supplies. It allows freer un-

Jan 1, 1981

By Hassan Madani, A. Malek Mohammadi

Dorreh barite mine located in the central part of Iran is one of the largest barite mines, in the country. The mine is subdivided into three blocks, which are called block 1,2,3 according the barite quality. In the central part of each block, a heavily concentrated grid of exploratory drill holes have been drilled and the reserves of area was calculated based on these holes, some years ago. It was decided to compute the reserve of the area by geostatistical methods, in the form of an M.Sc. project. In order to study the area, three regionalized variables including density, thickness and density-thickness (accumulation) was studied and the spherical variograms were fitted to these variables. These models were evaluated by cross-validation method. The optimized block size was chosen in order to compute the reserves by kriging method. The reserves of explored parts of each block of mine was calculated and the results were extended to the whole area of the blocks. The reserve of the explored parts and the total reserve of the area were calculated to be 96,000t and 1,670,000t respectively.

Jan 1, 1996

By Darryl J. Butcher

The Akjoujt Project is operated by MORAK SA, a company incorporated in the Islamic Republic of Mauritania. MORAK is jointly owned by General Gold International SA (A wholly owned subsidiary of General Gold Resources NL.), SAMIN, and the International Finance Corporation. The project was devel­oped to treat approximately 2.1 million tonnes of TORCO (Treatment of Refractory Copper Ores) tailings containing an average 3.2gAu/t, and 0.75%Cu/t. The process involves the use of ammoniacal cyanidation for gold extraction, and conventional carbon adsorption, and eventual desorption, of gold values. This is believed to be only the second commercial application of this leach chemistry in the world. The other being a small vat leach operation on the Paris Mine Dumps. (This operation was described by Mr M Ruane in a paper to a previous Randol Forum.) Initial work on the process, and the Akjoujt process design assumed that the reaction involved was anaerobic. This paper describes the operating experience, plant trial, and eventual installation which has lead MORAK to the conclusion that the process is not anaerobic, but requires oxygen, or an oxidant to proceed.

Jan 1, 1995

By Norbert Patzelt, Hans Knecht, Wolfgang Baum

Future ore reserves of major gold producers in North America and elsewhere will consist of refractory gold ores. About 60 % of the current U.S. gold production is mined in Nevada. Several of the large gold operations in this state indicate that 40 to 90 % of their future ore feeds will contain refractory gold. To compound problems, average head grades for refractory U.S. gold ores have fallen from 8 - 9 g/mt to about 4 g/mt by 1991. In Latin America, 52 % of the gold operations will require milling for optimal recovery. Deeper reserves are, like in North America, refractory. Particularly in hard, (semi)refractory sulfide ores, many operations may experience substantial decreases of gold recov­ery. For example, Martins et al. (1991) report that at an Austra­lian mine, sulfide ore treatment led to 4 - 10 % lower gold reco­veries as the work index increased from 8 kWh/t to 14 kWh/t and the grind coarsened. Many refractory ores should actually be classified as semirefractory since a fine sulfide fracturing and liberation would make 80 - 90 % of the gold cyanide leachable. However, conventional comminution is often prohibitively expensive for these ore types.

Jan 1, 1995

By K. A. McDonald

Hibernia de Mexico SA de CV, based in Durango, Durango, Mexico built and put into operation a 700-t/d (770-stpd) agitated cyanide leach plant in Guanacevi, Durango. Plant construction began in March 1993 and operations began in November 1993. Hibernia de Mexico, a wholly owned subsidiary of Hibernia Holdings, Inc., is a privately held Tucson, AZ-based company. The startup procedures described here deal with Mexico&apos;s legal, import-export and finance requirements, and labor and security requirements. The 700 t/d (770 stpd) Guanacevi project is located next to the town of Guanacevi. The project is an agitated cyanide leach plant built to process about 2 Mt (2.2 million st) of flotation tailings over its life. The plant is operated by Servicios de Guanacevi, Asociasion en Participacion. It is owned jointly by Hibernia de Mexico and Metalurgica Guanacevi SA de CV. Legal, importation of equipment and financing For a foreign company to operate in the mining industry in Mexico, it must form a Mexican company. A Mexican company presently must be at least 51 % owned by a Mexican entity. The other 49% may be owned by non-Mexicans.

Jan 1, 1994

By J. G. Groppo, B. K. Parekh

A series of performance studies were conducted using countercurrent column flotation to recover a marketable clean coal product from existing preparation plant fine waste streams. The test work was conducted at several preparation plant sites in Kentucky and Virginia using a 150-mm (6-in.) inside diameter column that was 5.8 m (19 ft) high. Both thickener feed and classifying cyclone overflow with a typical size distribution of 150 µm (100 mesh) X 0 were tested. The percent solids of the column flotation feed varied from 1.5% to 15% while the ash content ranged from about 30% to 60%. The concentrates produced contained 2% to 10% ash with Btu recoveries of nearly 90% using 0.12 to 1.25 kg/t (0.25 to 2.5 lbs per st) fuel oil and 0.12 kg/t (0.25 lbs per st) MIBC. These results were consistent with or better than results obtained in preliminary laboratory scale column flotation evaluation. Test results from seven different seams are discussed as well as scale-up relationships used to design a full-scale installation presently in operation.

Jan 1, 1991

By Jr. Smith

Silver-gold ratios were studied at the Tayoltita epithermal vein deposit using channel sample, channel sample line, stope, ore body and vein sample populations. The ratios are highly variable among individual channel samples (25:1 to greater than 500:1) with both high and low values randomly distributed within ore bodies and veins. Whole vein ratios for the fourteen most important ore producing structures range from 44:1 to 105:1, and show zonal distribution relative to two small granitic stocks, low values closest to the intrusives. The zoned nature of the deposit suggests that the stocks, apophyses of an underlying batholith of Late Eocene age, were the heat engines which powered the hydrothermal system responsible for ore deposition.

Jan 1, 1978

By James B. Fletcher

The Miami mine is located near the town of Miami, Gila County, Arizona. The Miami mine started mining in 1910 and finished in July, 1959. The orebody was divided and mined as follows: Tons High Grade 24,400,000 - Top slicing, sub-level caving, etc. Low Grade 105,100,000 - Block caving Mixed ore 9,800,000 - " Low Grade #2 13,100,000 - " Total Mining 152,400,000 GEOLOGY Ore minerals are largely in pre-Cambrian Pinal schist intruded by tertiary Schultz granite porphyry and covered to some extent by Quarternary Gila conglomerate. The structures are highly faulted and shattered. The Miami fault on the east cuts off the ore and the Pinto fault on the southwest caused re-oxidation of enriched sulphides producing mixed ore. MINERALOGY The chief mineral is chalcocite, with chalcopyrite, bornite, covellite, malachite, azurite, chrysocola, cuprite, native copper, and molybdenite as minor minerals. The ore minerals occur in seams, veinlets and disseminated particles. In block caving there is always some dilution, and drawing of ore stops when the grade drops past an economical point. This results in a small amount of copper left in the stopes below the capping. There is some copper in the capping, probably below 0.03% or less than 0.6 lbs. per ton. Over the low grade #2 orebody and portions of the high grade there was an oxide capping which was not mined. The crushed pilars are another source of copper. The leaching at Miami is an attempt to recover this last remaining copper of a worked-out mine. The enrichment at the Miami mine had gone more nearly to completion than most ore bodies in the southwest. There is practically no pyrite in the capping and very little in the ore.

Jan 1, 1971

By Harold L. Lovell

The areas of application, the limitations imposed by water chemistry as well as the advantages and disadvantages in the use of limestone for the treatment of coal mine drainage have recently been described by the authors (1),(2), (3). The process has been demonstrated in continuous, full-scale operation to yield a treated water meeting specifications established by the Pennsylvania Sanitary Water Board and containing excess alkalinity. Their final pH levels are usually less than seven, a condition which avoids consumption of excess neutralization reagents, but which occurs with lime-based processes and results from unwanted side reactions. Operating experience has been cited by Calhoun (4) using ferric waters while others (5), (6), (7), (8), (11), have reported on related research efforts. Despite the advantages including ?the relative simplicity, and minimal costs of the process, there have been very limited industrial applications of mine drainage neutralization with limestone. Although any treatment of these waters may be considered as a temporary control measure (9), the lack of feasible, immediate alternatives, the extensive magnitude. of the waters and the high cost of treatment requires that optimum processes should be utilized and that operating experience in their use be developed as is feasible. This paper will review treatment experience with a ferrous water of moderate pollution loading .

Jan 1, 1972

By M. Z. Mubarok, Z. T. Ichlas, A. T. Sugiarto, K. Sukamto

The use of ozone as an oxidant for the direct leaching of zinc sulfide (sphalerite) concentrate in sulfuric acid medium under atmospheric pressure was explored. The influence of acid concentration, feed gas injection rate, particle size distribution, stirring speed, temperature and slurry density on zinc extraction efficiency was examined. The experimental results showed that the leaching efficiency depends on all of these operating parameters except for stirring speed. It was found that essentially complete dissolution of zinc from the concentrate with the present method can be achieved in only about seven hours under the conditions of sulfuric acid concentration of 2 mol/L, particle size smaller than 74 µm, slurry density of 50 g/L, stirring speed of 420 rpm and feed gas injection rate of 1 L/min at ambient temperature. The experimental results suggest that the dissolution reactions produce independent elemental sulfur that is readily floated and can be easily separated rather than forming a layer on the surface of the reacted particle, as usually observed in a system with ferric-sulfate as oxidizing agent. It was therefore determined that the dissolved ozone play a key role in improving the rate of zinc dissolution from the concentrate. Analysis of the leaching kinetics indicate that the leaching rate follows the shrinking particle model, and the overall dissolution rate of zinc is controlled by a surface reaction.

By A. K. Clarke

In any treatment process that requires a coarse feed material to be reduced to a fine size by crushing and/or grinding it must be determined whether a wet or dry comminution system should be utilized. All factors must be evaluated in reaching the decision. Among these factors are: 1) Ecology and Plant Environment: Unfortunately in many instances the decision on wet or dry is based on prejudice resulting from an unnecessary fear of dust. The writers submit that this fear, although once justified, is no longer valid because technology and equipment is now available to collect dust to meet any standard. When dry grinding is used it is very often possible to discard a portion of the waste product in a dry state. This will decrease the size of the tailing pond required. As pollution control standards increase it becomes increasingly difficult to clean up water from tailing ponds. 2) Operating Costs: Steel wear is often five or more times greater in wet grinding than in dry grinding. This is mainly due to corrosion. The evaluation of the economics of dry grinding must of course include the air system and dust collection; similarly in a wet grinding plant related pumping and material handling costs should be included. Pumping costs are often overlooked. This assumes water is made to flow for nothing. Pumping can account for 20 percent of the power consumption in the grinding plant. Large scale comparative tests were conducted in a wet and dry commercial plant in 1970. The same ore was used for both tests. With all factors included in both plants the dry system showed lower horsepower per ton.

Jan 1, 1971

By R. Kahrger

This paper is written to convey the latest developments in compact bucket wheel excavators (BWE&apos;s) operating in medium-hard rock and will serve to indicate that BWE and compact machines in particular do in fact have application in materials other than loose sandy soils and soft rock. A recently run extensive three month field test in hard marl, which was previously considered too hard and difficult to be handled by a BWE, is used as an example to explain some of the design requirements and problems associated with digging harder materials.

Jan 1, 1990