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By M. Moats, J. Young

Short term laboratory cell electrorefining experiments were performed to examine the impact of electrolyte composition, current density and temperature on deposit structure, roughness, and adhesion to 2B mill finished 316L stainless steel. Copper electrodeposits were produced using synthetic electrolytes with thiourea and the continuous addition of glue. Deposit structures were evaluated using X-ray diffractometry. Surface roughness was measured using profilometry and analyzed using scaling analysis. Finally, an internally developed method was used to measure the force required to remove the electrodeposited copper from stainless steel to determine adhesion strength.

Mar 2, 2022

By O. Lopez

"Stringent regulations and increased arsenic presence in ore bodies being exploited have created the need for cost effective and environmentally compliant technologies to remove selenium and arsenic from mine waters and metallurgical waste streams. Existing treatment methods have high life cycle costs and/or produce residues that, due to their unknown stability over the long-term, may represent future liabilities. This results in high compliance costs and uncertainties which negatively impact existing operations and projects in permitting. Selen-IX™ is a new ion exchange based process that selectively removes selenium from mine impacted waters down to 1 ppb while producing a stable inorganic iron-selenium product. Results of piloting completed on streams generated from coal and copper-gold deposits are presented along with preliminary equipment sizing and life cycle costs of full scale treatment. An example of a commercially available system for arsenic removal using sulphide precipitation is presented. The benefit of this treatment method is discussed based on recently completed technical feasibility assessment including laboratory testing and preliminary engineering design. INTRODUCTION Selenium Due to the chemical similarity between selenium and sulfur, selenium substitutes sulfur in many minerals that can be found in a wide range of deposits including coal, base metal, precious metal, phosphate, and uranium. One of the main environmental challenges facing the industry in North America today is related to the removal of hexavalent selenium, e.g. selenate, to ultralow levels, typically between 1 to 10 ppb, from large flows of often cold water containing less than 1,000 ppb of selenium. Recent studies commissioned by the industry identified biological selenium reduction systems as the best available technology. Although the biological selenium reduction process is commercially proven in certain applications to remove selenium to ultralow discharge levels, the technology has been primarily applied to relatively low and constant flows of warm water produced by the Flue Gas Desulfurization (FGD) scrubbers in the power generation industry. The wide spread adoption of this treatment method by the mining industry is hindered by high capital and operating costs associated with treating large flows of cold water, lack of data and knowledge about the long term stability of solid residues produced by this treatment, and limited capacity of biological systems to respond to sudden changes in flow and/or mass load of contaminants. Furthermore, it has been reported that reaching discharge limits less than 3 ppb could be a challenge and that polishing treatment for the removal of BOD and phosphate maybe required to avoid the impact of the biological treatment which requires organics and nutrients, on aquatic environment downstream of treatment plants. Alternate treatment systems are being developed to overcome and/or completely avoid some of the challenges of biological systems. One such treatment system is BioteQ’s Selen-IX™ process which is purely physico-chemical treatment system."

Jan 1, 2015

By Xinyang Yu

The flotation of diaspore, kaolinite, pyrophyllite, illite and the diaspore-kaolinite mixture were studied with a new cationic organosilicon quaternary ammonium collector entitled QAS222. The acting mechanism of the collector with the four minerals was analyzed by Zeta potential measurement and FT-IR spectrum analysis. The results indicate that the QAS222 was effective in the reverse flotation of the diaspore-bauxite mixture of different Al2O3 -to-SiO2 mass ratios (A/S ratio) at an optimum pulp pH of 11. The potentials of the four minerals increased when they were conditioned in the QAS222 solution; however, the potentials of the three aluminosilicate minerals increased faster than that of the diaspore, especially at pH>9. Furthermore, they were positive in a wide pH range, indicating that QAS222 has a strong adsorption on the surface of the aluminosilicate minerals and thus that these minerals can be floated. The FT-IR spectra analysis further indicates that, besides electrostatic adsorp-tions, formation of the hydrogen bond and ammonium absorptions, chemical adsorptions occur between QAS222 and the aluminosilicate minerals, which allow for the QAS222 to be strongly adsorbed on the aluminosilicate minerals. However, these reactions between QAS222 and diaspore at pulp pH=11 are weaker than those of the aluminosilicate minerals. Thus, surface adsorptions cannot be formed effectively, resulting in reduced floatability.

Jan 1, 2010

By M. Rodgers

Dow Water & Process Solutions (DW&PS) was approached by ASARCO Inc. to attempt to recover cobalt and copper from their copper solvent extraction (SX) raffinate. Cobalt is added to many copper electrowinning tankhouses to help to prevent lead electrode corrosion. With cobalt?s high price this can be a large expense. ASARCO has ore that contains a small amount of naturally occurring cobalt. Currently they have no way of capturing this high value metal from their leach or raffinate streams. DW&PS has some chelating resin technologies that should be able to help solve this problem.

Jan 1, 2010

By John S. Burton

Mineral policy in Canada has been in a state of transition and change over the past several years. 1976 has witnessed some settling of troubled waters and the pattern of the currents of change is becoming more clear. The provinces play a key role in this process and have provided much of the thrust for new initiatives. On the other hand, the federal government in Canada in recent years has taken a much more active interest in mineral affairs than previously and has asserted its powers on a number of key policy questions. Some of the initiatives from the two levels of government in Canada have come into conflict with each other and, thus, contributed materially to a state of affairs that includes change, uncertainty and conflict.

Jan 1, 1976

By A. B. Van Cleave

It was first pointed out in 1934 by Gaudin (1) that the "oily" oxidation product of the alkyl xanthate ion-dialkyl dixanthogen, might be the "active flotation agent" on sulphide minerals and there have been a number of studies supporting this hypothesis (2,3,4). However, all of these studies have relied largely on electrochemical evidence. Galena, being a semiconductor, may be used as an electrode in aqueous solution and it was shown that ethyl xanthate ion does not adsorb with charge transfer in the absence of oxygen unless the potential of the galena surface is above -100 mv versus the hydrogen electrode (H2 E). At this potential the galena surface is slightly hydrophobic but does not become strongly hydrophobic unless the potential is raised to 210 mv (versus H2 E). It is suggested that, at potentials of 210 mv or above, ethyl xanthate ions are oxidised to diethyl dixanthogen and that chemisorption of oxygen raises the galena surface to this potential. On the other hand, examination of xanthated galena surfaces by chemical or physical methods (5,6,7) has failed to detect dixanthogen and it has been shown that dixanthogen may be reduced to lead xanthate at a lead sulphide surface. (5,8)*. It was suggested by Leja and Poling (5) that, as dixanthogen is a neutral molecule it would not be repelled by the negatively charged galena surface so that the adsorption was envisaged as taking place through homogeneous oxidation of the xanthate ion to dixanthogen, adsorption and reduction of the dixanthogen to a chemisorbed lead xanthate species. In paper I of this series (11) it was shown that the thiosulphate ion, which forms on galena surfaces in slurries at the pH normally used for flotation, will reduce dixanthogen. There is, therefore, the impasse that the electrochemical evidence requires that xanthate ion be oxidised to dixanthogen at the galena surface while the chemical evidence shows that the reverse reaction takes place.

Jan 1, 1973

By William M. Greenslade

As the search for minerals leads to deeper mines the need to control water inflow into mine shafts and mine workings will grow. As shal¬lower more readily available minerals are exploited, ore bodies which were previously uneconomic be cause of their depth will now become attractive targets. In known mining districts new ore bodies are being discovered down dip of existing ones. In the west many metal deposits are being developed in rocks of the mountain front pediments, frequently covered by several hundred feet of saturated alluvium. Greater depth often means that workings are developed well below existing water tables, creating high hydrostatic heads adjacent to mine workings. The purpose of this paper is to review some of the methods available for determining if water control will be necessary and to present some of the techniques for locating water bearing zones and the amount of water to be expected. The paper will concentrate on problems associated with water control in mine shaft development, although many of the exploratory techniques are similar to those needed for assessing overall mine water inflow problems. A brief case history on water control problems in mine shafts in the Grants mineral belt of northwestern New Mexico is presented. Water control during shaft sinking presents some unique features. First, the problem is a relatively short term one, since water control is often necessary only while the shaft is being sunk. Control measures may be necessary only while the shaft is open into the water bearing zone and the lining installed and cemented. Secondly, limited working space within the shaft area presents difficulties in handling large amounts of water inflow. The presence of water in the shaft working area increases sinking time and the potential hazard to miners. Finally, there is the economics of shaft sinking. While the shaft is being sunk no ore is being produced and there is every incentive to minimize costs.

Jan 1, 1979

By Wendell H. Wiser

A comparison is presented of coal pyrolysis at temp¬eratures ranging from 4090 to 497°C and thermal dissolution of coal in tetralin at temperatures ranging from 350° to 450,°C, both utilizing a Utah high-volatile bituminous coal. The initial coal pyrolysis reactions are second order with an enthalpy of activation of 35.6 kcal per mole. The fraction of total product yield produced under second order conditions ranges from 67% at 409°C to 96% at 497°C. The process then gradually deteriorates to a first order reaction in the later stages with enthalpy of activation of 4.1 kcal, per mole. The initial reactions of solution of coal in tetralin are second order with an enthalpy of activation of 28.8 kcal per mole. The fraction of total product produced under second order conditions ranges from 63% at 350°C' to 94% at 450°C. The dissolution process then gradually changes to first order in the later stages with enthalpy of activation of 15.6 kcal per mole. A model is presented which relates the two processes and explains, the significance of the above similarities.

Jan 1, 1967

By J. M. Avasthi

Gulf Research & Development Company conducted the nation's first underground coal gasification test in steeply dipping beds near Rawlins, Wyoming. The geotechnical considerations played a major role in the initial site selection. The test plan included a detailed geotechnical program for site evaluation, test design, permitting, and environmental studies before the burn. During burn, the geotechnical activity continued in the form of monitoring surface subsidence and acoustic emission. The postburn evaluation included studies of the drill cores obtained from the burn zone and effects on the surrounding rock mass.

Jan 1, 1981

By R. Maurice King

In the operation of today's large scale ore-processing mills, it is extremely important to have some way of making an objective evalu¬ation of the performance of the available flotation reagents. Attempts to do this may often result in inconclusive findings since the magnitude of the difference in the mill results for any two reagents is apt to be quite small compared to the variability introduced by the process and 'the analytical procedures used to measure them. In cases where two reagents give vastly; different mill results, evaluation becomes a simple matter and as such deserves no further attention here. A question of primary concern, however, is how a mill can go about evaluating the performance of two reagents which may, for example, give a difference of only 0.001% copper in the-tailings or of 0.2% in copper recovery. The casual observer may feel that such small differences may be of little importance, but in a mill-whose daily tonnage is between 30 and 40 thousand, these differences could mean a substantial savings. Before the presentation of an actual example of a reagent testing scheme designed for just this-purpose, perhaps a few minutes should be devoted to a review of some statistical methodology to be used later in the discussion.

Jan 1, 1964

By R. L. Sundeen

Trackless vehicles, as the name implies, are machines not bound to rails, guide cables, or other direction controlling devices. They include, for the most part, vehicles which are wheel or crawler (track laying) mounted. Power sources may be self contained such as diesel or battery and can be defined as non-captive machines, while connected power sources such as compressed air or electric can be defined as captive machines. Trackless vehicles are used in all phases of underground excavation, loading, hauling and dumping. Early application found most machines with digging ability used to load those with payload hauling ability. As the versatility of trackless methods became more obvious the trackless vehicle has evolved to more productive machines such as the self loading haulers commonly referred to as Load-Haul-Dump equipment. Trackless vehicles find wide use in drifting and tunneling. Ability to negotiate adverse grades is especially noteworthy. Experience drawn from highly efficient room and pillar mining operations has lead to relatively wide application in drawpoint and cut and fill mining.

Jan 1, 1969

By Bo Arvidson

SALA MAGNETICS, INC. is now operating a 15 tph continuous high gradient magnetic separator, the SALA-HGMS® Mark III Carousel, as part of a complete mineral processing pilot plant installed at Sala's Cambridge headquarters. The Mark III can generate a maximum magnetic field of 18 kG making it possible to process even weakly magnetic, finely ground ores and ore tailings on a continuous basis at the performance level achieved in Sala's cyclic high gradient magnetic separators. Test results on iron ores, clay, and decoppering of molybdenum concentrate will be discussed. Bench scale tests have been performed on all of these materials using the SALA-HGMS® Model 10-15-20 Cyclic Magnetic Separator. A direct correlation may be made between cyclic and carousel results. Sala's Mark III Carousel high gradient magnetic separator is designed to permit scale-up to machines capable of processing two hundred (200) tons of ore per hour and more.

Jan 1, 1976

By John E. Edkins

Metal sulfides, chiefly pyrite and mFnor sphalerlte zssociated with che Herrin (No. 6) coal member of the Pennsylvania Carbondale Formation, have been concentrated in a coal refuse deposit in southern Illinois. Oxidation of pyrite has produced highly acid waters with high concentrations of iron, zinc (up to 200 parts per million) and toxic trace elements that have leached downward to a water system perched on glacial drift. Chemical, petrographic, low-temperature ashing and x-ray diffraction were performed on cores. The data show that economic recovery of zinc and other trace metals is unlikely at this site. Energy (coal) recovery at the Superior Washer site is possible if resultant environmental problems are considered in the planning.

Jan 1, 1981

By Barbara H. Carroll

In order to rapidly evaluate an area for its mineral potential, a reconnaissance exploration program generally includes the following: 1. Outlining an area of interest 2. Identifying known mineral deposits 3. Bibliographic search of the literature 4. Evaluation of geochemical and geophysical surveys 5. Compilation and review of geologic maps The information now available from various government agencies regarding the mineral deposits, geology, and geochemistry may be integrated and used as a tool to rapidly evaluate an area before the field season. The databases most commonly used in the United States are the USBM MAS/HILS system and the USGS MRDS system for their information on mineral deposits; GEOREF and GEOARCHIVE for bibliographic information; and NURE data for the geochemistry and geophysics. In conjunction with the project geologist, this information may be used to plot known deposits and their geochemical signature as well as any other areas of like signature for further examination.

Jan 1, 1985

By Adrian Brown

The primary method of slope stabilization is ground water-control. Recent research has established the properties which slope materials must exhibit in order for stabilization measures to be feasible, but there is little guidance in the literature about suitable field tests to develop the parameters needed for this evaluation. This paper presents a proven method for large scale testing which allows an evaluation of the feasibility of ground water pressure control in a reasonable cost and time frame. Methods of performance and analysis of the test are presented, and the method is illustrated by reference to case examples.

Jan 1, 1984

By Richard J. Fantel

The U.S. Bureau of Mines performed engineering and economic analyses on 130 domestic phosphate mines and deposits, all containing demonstrated resources, of which 73 are in the Southeastern states of Florida and North Carolina, to determine the domestic availability of phosphate rock. Of the total domestic resources studied (6.4 billion tons of recoverable rock) over 60 percent is found in these two Southeastern states. At an estimated cost of $30 per ton, in January 1981 dollars, approximately 1 billion tons of rock is potentially recoverable from Southeastern deposits, increasing to 3 billion tons at $45. In addition, there is nearly 6 billion tons of recoverable rock at the inferred level (some presently unmineable) in Florida and Georgia.

Jan 1, 1983

By Samuel S. Adams

The Grants uranium region of northwest New Mexico is the largest uranium district in the United States (approximately 50% of U.S. production plus reserves) and one of the largest In the world, with approximately 900 million pounds U308 production plus reserves. Deposits of the region are unusual among sandstone deposits for their high content of epigenetic carbonaceous material, generally interpreted but not proved to be of humic origin--that is, co-extensive with uranium in the primary deposits. Virtually all production in the region has been from the Jackpile Sandstone and Westwater Canyon Member of the Jurassic Morrison Formation. The tabular uranium deposits contain, in addition to humate and uranium, significant authigenic phyllosilicates, quartz overgrowths, humate-replaced detrital silicates, and a trace-metal assemblage typical of other sandstone uranium deposit types. Surrounding the deposits in the two sandstone units of the Morrison Formation is an alteration zone within which iron leaching has altered detrital ilmenite-magnetite to residual masses of titanium oxides. Feldspar alteration is locally present within this zone, below deposits in the Jackpile Sandstone, and above those in the Westwater Canyon Member. The feldspar alteration increases in inten¬sity toward the Brushy Basin Member which separates the two sandstone units, ranging from partial replacement to replacement and dissolution of plagioclase and sanidine. Spatial relations among the epigenetic humate, authigenic silicates, and the broad alteration zones that extend from the Brushy Basin Member to and including the uranium deposits suggest that (a) the organic material was involved in the unusual silicate alteration, transport, and authigenesis, and (b) that the humates originated in shales of the Brushy Basin Member. Stratigraphic relations among the Brushy Basin Member and the overlying Jackpile Sandstone and underlying Westwater Canyon Member suggest [in turn] that there was continuous, interfingering deposition controlled in part by contemporaneous basement subsidence along northwest- and northeast-trending zones. Following minor erosion of upper Jackpile Sandstone and deposition of basal organic-rich Cretaceous sediments, the silicates of the Jackpile Sandstone were once again altered by organic-bearing fluids, this time permeating down from Cretaceous sediments and partly obliterated ore-stage alteration.

Jan 1, 2013

By M. Ashraf Mahtab

In Louisiana salt mines a sudden erruption or outburst of salt and gas occurs when the heading face approaches a pressure pocket (altered salt with high pressure gas). The resulting cavity is semi-ellipsoidal, reaching lengths of 50m or more. Potential risks from the outbursts include loss of life and equipment. A gas outburst is initiated by "disking" of the salt in biaxial compression and propagates by spalling of the cavity walls and further disking. The outburst is terminated by a combination of dilatancy hardening, increase in stress along the cavity axis, and enlargement to boundaries of the pressure pocket.

Jan 1, 1982

By Peter T. Luckie

Up until the past couple of years, thermal coal dryers were only used to dry midwest and eastern United States bituminous coals. These dryers were primarily installed at coal preparation plants to freeze proof the coal and lower the transportation costs per BTU. Today thermal coal dryers are being specified to dry western sub-bituminous and lignite coals for these and other reasons brought about by the intense interest in coal gasification and liquefaction. One reason for drying western coals ahead of a coal gasification plant is the elimination of surface moisture which would prevent efficient sizing of the coal, since feed material size consist is very important in most commercial coal gasification processes. Thermal dryers are being proposed for liquefaction processes because of the need for a feed material containing approximately 4% or less total moisture Future coal gasification processes may also need to reduce feed material moisture content.

Jan 1, 1975

By Ronald G. Schmidt

AND SOME RIN UP HILL AND DOWN DALE, KNAPPING THE CHUCKY STANES TO PIECES WI' HAMMERS, LIKE SAE MANY ROAD MAKERS RUN DAFT. THEY SAY IT IS TO SEE HOW THE WARLD WAS MADE. Sir Walter Scott St. Ronan's Well - 1824 In the minds of many, geologic exploration has advanced little since the early nineteenth century. In truth, despite the development and refinement of new and potentially valuable technological tools, the approach or philosophy of the explorationist has received meager attention in professional literature. In many areas, the explorationist relies upon experience, subjective judgement and general intangible inspiration, often traveling together under the misleading pseudonym of "art," in achieving both an exploration plan and in making the myriad day to day decisions necessary to the execution of that plan. Without a solid, objective basis for decisions, exploration under this concept is little more than guesswork largely by intuition, and it is small wonder that many exploration programs flounder in a sea of over-expenditure inefficiency or fail to fulfill their expected goals within the funding which has been provided. From a rational management point of view, such a state of affairs is frustrating and inconsistent with the application of the same scientific principles which are presumed to be the basis for the exploration methods which are used. This somewhat presumptuous point of view cannot be extended as a general condemnation of the many exploration programs which are both technically and economically successful. On the other hand, the

Jan 1, 1968