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By Winthrop F. Watts, Robert W. Waytulonis

During the 1980's. the Mine Safety and Health Administration (MSHA) proposed new regulations for the use of diesel equipment in underground coal mines, and the National Institute for Occupational Safety and Health (NIOSH) recommended that whole diesel exhaust be regarded as "a potential occupational carcinogen", and that reductions in exposure to exhaust pollutants would reduce excess risk. During the same time, the Bureau of Mines tested new emission control technology to minimize diesel emissions. The objectives of this paper are to discuss the major issues regarding diesel exhaust emissions. especially diesel particulate matter (DPM) , and to highlight emission controls that will be available. DPM is a potential health threat because it is respirable in size and is composed of nonvolatile carbon with adsorbed or condensed compounds. These compounds include potentially mutagenic or carcinogenic hydrocarbons such as polynuclear aromatic hydrocarbons and sulfates. DPM contributes to the degradation of air quality in mines with typical mean concentrations ranging from 0.2 to 1.0 mg/m3. In addition to adequate ventilation, control of DPM can be achieved by implemention of improved work practices, regularly scheduled engine maintenance, and emission controls.

Jan 1, 1991

By Ora H. Rostad

Veins containing silver and gold values, with some associated values in copper, lead, and zinc, were discovered in 1890 by Will Kirwin in what was later designated the Kirwin mining district situated on the North Fork of the Wood River, about 56 km (35 miles) west of Meeteetse. (See Fig. I.) After considerable prospecting activity, including the driving of several short adits on veins, most of theclaims in the district were consolidated into two ownerships. One was held by the Galena Ridge Mining Co. which was organized on Nov. 18, 1902. The other was held by the Shoshone Mountain Mining Co. which was organized on Mar. 23, 1903. During the period from 1903 to 1907 inclusive, the two companies continued exploration on veins in their respective areas. The major exploration-development activity for the Galena Ridge Mining Co. was the driving of the Galena Ridge crosscut adit for 709 m (2327 ft), to cut veins at depth which had been explored by short adits high on Galena Ridge. Shoshone Mountain Mining Co. concentrated their work on the Bryan and Pickwick veins. Neither of the companies found ore that was rich enough to sustain profitable operations in that remote locality. Most of the major exploration and development activities were stopped in late 1907. A major snowslide in February 1907 killed three people and destroyed several buildings and may have contributed to discouragement in the area. From 1908 to the early 1920s, only minor exploration work was done. Galena Ridge Mining Co. was dissolved Aug. 5, 1922, and Shoshone Mountain Mining Co. was dissolved on Mar. 23, 1923.

Jan 1, 1991

By E. Grygiel, J. Haynes, T. McNider

Jim Walter Resources Blue Creek No. 3 Mine was opened in one of the most gassy coal beds in the United States. Although face ventilation requirements exceeded 14,000 cfm (6 .6m3/s) air, continuous miner sections experienced an unacceptable frequency of frictional ignitions. Modifications offered primarily by the U. S. Bureau of Mines such as diffuser fans, water spray fans, and slow speed cutting motors were used with little success. However, laboratory tests conducted at the U. S. Bureau of Mines indicated that an increase in bit attack angle from 50° to 55°-57° significantly reduced the chances of the bit causing a frictional ignition. An experimental miner drum was built using this concept coupled with a new bit designed by the Bureau and manufactured by Hughes Tool Company that better protected the bit steel shank with a carbide cap. It was installed on a continuous miner and placed in an area of the mine prone to ignitions. 50,000 tons (45,500 metric tons) of coal were cut without a frictional ignition. When the miner was withdrawn for rebuild and a machine with an unmodified cutting drum placed in service, two ignitions occurred before 10,000 tons (9,100 metric tons) were mined. Other machines have been rebuilt and are in service, and to date none have been known to cause an ignition.

Jan 1, 1987

By L. E. Krys, K. D. Harrison, C. G. Anderson

Since 1984, nitrogen-species catalyzed pressure leaching has been utilized at Sunshine Mining and Refining Company for the recovery of precious metals from a refractory sulfide concentrate. The process operates without the use of cyanide. The plant is now the only industrial-scale commercial application of this technology. Since the inception of the process, changes have been implemented to improve efficiencies and throughputs. Two of these changes, the replacement of nitric acid by sodium nitrite and a concentrate regrind, have recently been implemented. This paper discusses the development and potential mechanisms involved in these recently patented plant-process changes. A companion publication (Anderson et al., 1996) covers the plant integration and potential applicability of the technology.

Jan 1, 1997

By N. S. Tanious

The accuracy of vibrating wire stress meters has been questioned by various users in the mining industry. During an in situ coal pillar study, a laboratory evaluation program was developed to determine whether stress meters could produce reliable measurements in coal. More than $0 stress meters were tested for accuracy, repeatability, effects of setting pressure, and the concept of using a single curve for interpreting the stress-meter data. The testing medium was lucite, a material with a modulus of elasticity very similar to coal. The evaluation demonstrated that the stress meters did provide repeatable measurements, but that accuracy was lacking when the recommended interpretation technique was used. Therefore, a new technique was developed that required all stress meters to be calibrated in the laboratory before use in the field. This new technique reduced the average error to typically less than 10% and, in the worst case, to below 15%.

Jan 1, 1988

By Kirk H. P. E. McDaniel, Mark T. Strever, Keith G. Jr. Wallace

This paper presents the design and installation of an underground ventilation remote monitoring and control system at the Waste Isolation Pilot Plant. This facility is designed to demonstrate safe underground disposal of U.S. defense generated transuranic nuclear waste. To improve the operability of the ventilation system, an underground remote monitoring and control system was designed and installed. The system consists of 15 air velocity sensors and 8 differential pressure sensors strategically located throughout the underground facility providing real-time data regarding the status of the ventilation system. In addition, a control system was installed on the main underground air regulators. The regulator control system gives indication of the regulator position and can be controlled either locally or remotely. The sensor output is displayed locally and at a central surface location through the site-wide Central Monitoring System (CMS). The CMS operator can review all sensor data and can remotely operate the main underground regulators. Furthermore, the Virtual Address Extension (VAX) network allows the ventilation engineer to retrieve real-time ventilation data on his personal computer located in his workstation. This paper describes the types of sensors selected, the installation of the instrumentation, and the initial operation of the remote monitoring system.

Jan 1, 1995

By M. K. Gangal, E. D. Dainty

CANMET/MRL has been contributing to an industry/government program to assess the quality of air in mines, and improve the working environment for Canadian miners. The ultimate aim of this program is to recommend a sampling methodology and appropriate concentration limits for both the soot (diesel particulate matter - DPM) generated by diesel equipment, and respirable combustible dust (RCD) as measured underground. The program was conceived by the Canadian Adhoc Diesel Committee, which consists of representatives from seven major Canadian mining companies, three provincial inspectorates, one union representative, two manufacturers of diesel equipment, and CANMET, a Federal Canadian research agency. This paper describes the modification and laboratory confirmation of an existing methodology for the sampling and analysis of DPM/RCD, including: sampling problems, filter selection, filter efficiency, DPM size distribution, the approximate performance of fractionating devices, and it reports the results of current ambient measurements of exposure levels in Canadian underground mines. Because of the concern about the health impact of DPM/RCD on mine workers, North American agencies are in the process of establishing limits for these aerosols. So far, the Province of British Columbia is the only jurisdiction in North America to legislate the maximum exposure level of RCD in its underground mines, i.e. 1.5 mg/m3 interim level recommended by the Adhoc Diesel Committee. It has also recommended the use of the CANMET/ADHOC RCD sampling protocol.

Jan 1, 1993

By S. R. Bryan, J. D. Stephens, D. R. Rothbard

The distributions of gold and associated elements in mineral grains from a pyritic gold ore were studied by optical microscopy, and by SEM and SIMS imagery. Products studied were a sulfide flotation concentrate, a calcined sulfide concentrate, a cyanide leached calcine, and a cyanide leached pressure oxidation residue. Individual pyrite grains are compositionally zoned and solid solution gold occurs in some, but not all zones. Most of the gold in calcined products is present as metallic coalesced grains that are smaller than 100 angstroms. Gold lost into cyanide leached residues from the calcines tends to be in “semi-dense” grains that cannot be distinguished from gold-free grains except by SIMS analysis. The gold in cyanide leached pressure oxidation residues occurs as solid solution gold in unoxidized pyrite remnants.

Jan 1, 1990

By P. Riveros, A. Pratt, G. Deschênes

The effect of pyrite, pyrrhotite, chalcopyrite, realgar and arsenopyrite on gold dissolution in cyanide media was investigated. The cyanidation of synthetic gold ores in the presence of various concentrations of sulfides was studied under constant experimental conditions. A mineralogical analysis of the minerals was performed. The leaching kinetics were determined. The negative effect of sulfides on the gold dissolution rate varies with the sulfide mineral and decreases according to the following order: realgar > pyrrhotite > chalcopyrite > pyrite > arsenopyrite. The chemical characterization of gold and sulfide minerals surfaces using X-ray photoelectron spectroscopy (XPS) was undertaken to identify the mechanisms involved. XPS analysis showed that a passivation layer of sulfides, arsenic or iron compounds might form on the gold surface as a result of the dissolution of the sulfide minerals. Key words: Gold dissolution, Cyanidation, Effect of sulfides, Leaching kinetics

Jan 1, 2003

By K. I. Cunningham, C. S. Spirakis

Two types of native sulfur deposits have been found in Lechuguilla Cave: thin late-stage crusts and massive early- formed deposits. Most, if not all, of the crusts appear to have formed by remobilization of native sulfur contained within gypsum and sulfur masses. The process is occurring today and is slowly converting the sulfur to gypsum. The absence of primary gypsum or reductants in the cave indicates that the early-formed massive sulfur deposits did not form by in-place reduction of sulfate, which is the process that formed the commercial sulfur deposits in the Delaware basin. Instead, it appears that H2S dissolved in basinal brines was oxidized by oxygen in near-surface ground waters in the cave. Fluid- inclusion data, which suggest the presence of both fresh water and saline water as the sulfur formed, support this interpretation. Although individual sulfur deposits in Lechuguilla Cave are no more than several tens of metric tons, the abundance of secondary gypsum (as much as 10 meters thick) indicates that native sulfur may once have been much more extensive.

Jan 1, 1992

By Roe-Hoan Yoon

Froth flotation is widely used for separating particulate materials from one another in aqueous media. The basis of this important separation process is to control the hydrophobicity of particles. However, it is difficult to predict the kinetics of flotation based on contact angle (?), which is a thermodynamic property. A solution to this difficulty would be to develop a relationship between ? and the gradient of the hydrophobic forces across the solid-liquid and bubble-liquid interfaces. Such information can be obtained using the surface force apparatus (SFA), the atomic force microscope (AFM), and the thin film balance (TFB). The present communication reviews the results of the measurements conducted using these methods, and offers a methodology for deriving a rate equation for bubble-particle interactions

Jan 1, 1999

By H. Y. Sohn, R. D. Hagni, M. K. Kojo

Reflected light microscopy was used to study the mineralogy and textures of experimental reactions of a nickel concentrate with a slag. Such an interaction is an important step in the bath smelting of nickel sulphide concentrate. Concentrate particles in the central portions of the pellets are rounded and develop vermicular S02 gas porosity. In the outer portions of the pellets, the original minerals of the concentrate, i.e., pyrrhotite, pentlandite, pyrite, chalcopyrite and violarite, have agglomerated and reacted to form two intergrown phases: pyrrhotite solid solution (FeO.75Ni0.18Cu0.01S) and pentlandite solid solution (Fe0.58Ni0.51Cu 0.03S). Magnetite formed euhedral crystals, skeletal crystals and dendrites at the margins of the matte. Prismatic, ferrohypersthene and octahedral Mg-Al-Fe spinet crystals and dendrites are present in the glassy slag. Key words: Nickel sulfide concentrate, Iron silicate slag, Bath smelting, Mineralogy, Microscopy

Jan 1, 2003

By L. G. Austin

The general manner in which the liberation function must change during size reduction is described. Data from float-sink (washability) analysis of a coal is used as an illustration, and a Locking Index is defined and calculated. Ash is not distributed equally with respect to sieve size but is concentrated more in the finest sizes. On the other hand, the ash is less locked with coal in the finer sizes than in the larger sizes. Further crushing showed decreased locking in intermediate sizes, but the material in the fine sizes (produced from breakage of highly locked larger sizes) was more locked than material of the same size in the feed. Future work is also discussed.

Jan 1, 1995

By Terry L. Logan, Arfon H. Jones, James C. Seccombe

Deeply buried coal seams [greater than 3000 ft (914 m)] are difficult and sometimes hazardous to test and complete due to coal sloughing, formation pressure anomalies and coal fine generation. Data collected while stimulating two deep coalbed methane wells located at the Gas Research Institute/Resource Enter¬prises, Inc. "Deep Coal Sean Project" test site in the Piceance Basin, Colorado, is presented in this paper. A single thick coal seam was completed openhole in each well. Core data, reservoir data, in-situ stress measurements, and pre-stimulation calibration test data were collected at the site to use in the design of the fracture stimulation treatments for both wells. A nitrogen foam fracture fluid treatment was selected for the first well and a linear gelled water for the second well. Treatment pressures were monitored with a downhole quartz pressure transducer. Atypically high treating pressures were observed, possibly indicating coal fines plugging at the fracture tip or increase in fluid viscosity caused by interaction of the generated coal fines with the fracturefl uid. In addition, a comprehensive fracture diagnostic effort was employed during the fracturing of the second well; namely, triaxial borehole seismic, seismic televiewer, hydraulic impedance monitoring, gamma ray log (in conjunction with radioactive additives in the sand), and temperature log. The results indicate a vertical fracture was created parallel to the face cleat as expected.

Jan 1, 1986

By E. V. Manlapig, B. K. Gorain, N. W. Johnson, K. Ward

A flotation model developed at the Julius Kruttschnitt Mineral Research Centre was used to predict the performance of copper rougher and scavenger circuits at the copper concentrator at Mount Isa Mines. The model describes the kinetic response of an ore in a flotation cell in terms of ore floatability, cell characteristics and froth recovery. The floatability parameters of the rougher feed ore were obtained directly from a detailed plant survey. Flotation analysis was carried out for twenty different size-by-liberation classes to account for the effects of particle size and liberation on flotation. This paper investigates the capability of the model to predict the flotation behavior of 20 different size-by liberation classes in the rougher and the scavenger banks.

Jan 1, 2000

By J. A. Brierley, C. L. Brierley, R. C. II Blake, S. McGinness

A principal long-term goal of this laboratory is to achieve a detailed understanding at the molecular level of the microbial-dependent solubilization of minerals. Three recent advances in this research are summarized. (i) An in situ electrolytic procedure is described whereby large quantities of autotrophic iron-oxidizing organisms may be achieved for fundamental or applied studies. Over 600 grams wet weight of Thiobacillus ferrooxidans were harvested from a single 55-gallon growth vessel. (ii) A basis is presented for classifying some 70 different iron-oxidizing bacteria into one of 4 categories, depending on the type of redox-active electron transport proteins expressed during aerobic respiration on reduced iron. Comparative spectroscopic analyses indicated that different electron transport mechanisms exist in different genera and species of acidophilic bacteria that respire on iron. (iii) A method is introduced to investigate the binding interaction between bacteria and minerals, based on changes in the electrokinetic properties of the two species. Preliminary experiments indicated that the electrophoretic mobilities of pyrite and Thiobacillus ferrooxidans were both altered when the two colloid particles were mixed prior to the actual electrokinetic measurement. The need for more basic information regarding all aspects of the microbial-dependent solubilization of minerals is evident.

Jan 1, 1993

By John A. Herbst, William T. Pate

Column flotation is emerging as one of the most important new separation technologies of the decade. Attendant to this development is the need for a quantitative understanding of the dynamic characteristics of columns. An understanding of the many important sub-processes occurring in the cell makes possible the development of dynamic simulators for flotation columns which will aid in the design of control systems for dynamic and steady state optimization. This paper presents a dynamic model for the column flotation cell developed from a population balance point of view similar to that which has been successfully applied to conventional flotation cells. In particular, the mixing that occurs within the pulp is modeled with a distributed-volume, mixer-in-series model as an approximation to the axially dispersed plug flow transport that occurs in the cell. This simpler approach avoids the distributed transport model which often leads to mathematical intractability. Other phenomena dealt with are the attachment and detachment of particles from bubbles in the froth and pulp, the transport of water and the bubble volumes with the froth and pulp phases. Simulation of the flotation of an Illinois No. 6 coal in a pilot plant flotation column were performed to test control strategies.

Jan 1, 1989

By D. Altizer, E. Thompson, K. F. Unrug

Because of frequent sudden changes in the geologic composition of strata, the extrapolation of rock properties obtained from core samples to the surrounding areas can cause problems. To address this issue, a method of rapid strength testing in situ using a borehole penetrometer is being developed. This method, as opposed to conventional laboratory testing, does not require rock samples to be retrieved and handled/machined before testing. Rock strengths are determined di¬rectly on the drill-hole wall. The latest development is a borehole penetrometer that requires only a 38.1-mm- (1.5-in.-) diam hole. The small diameter of the penetrometer body allows for the drilling of test holes with production mine equipment such as a roof bolter. The new penetrometer allows for the possibility of a broad application in coal mines, as well as in hard rock mines and tunneling. The principles of the apparatus are described and are illustrated with examples of its applications.

Jan 1, 2002

All coal preparation unit operations in which fine coal is handled depend to some extent on wettability of coal surface by water. The wetting results from interactions between the coal surface and water molecules that are determined by the composition of coal matrix (interrelated with coal rank) and heterogeneous constituents such as oxygen functional groups, mineral impurities and pores. The contact angle of water on an unoxidized, homogeneous coal hydrocarbon matrix is calculated to be 100o, and much lower values measured on real coal specimens result from contributions from the heterogeneous constituents. While the effect of wettability is critical in flotation and oil agglomeration, suppression of respirable dust, and coal water fuels, it has been shown to play a significant role also in coal flocculation with semi-hydrophobic and totally hydrophobic flocculants.

Jan 1, 1995

By Malcolm Scoble, Sean Dessureault, Scott Dunbar

Budgets are key financial and behavior drivers for most businesses, including mining. Budgets are used to link strategic objectives to tactical decisions, to measure performance, and to provide basic financial planning. More accurate and pertinent budgets should result in improved strategic decision making and performance measures. This paper discusses how a process based production and cost database, based on activity based costing models and the one year production plan, can be used to create the annual budget for an operating mine as an Activity Based Budget (ABB). A case study is used to compare budgets derived from traditional methods and an ABB approach. It is evident that the ABB method is more accurate.

Jan 1, 2002