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By Terry Ramsey, N. Finkelstein

INTRODUCTION The Cyprus Pima Mine is located 20 miles southwest of Tucson, Arizona and about fifty miles north of the Mexican border. The Cyprus Pima orebody was discovered in 1950. Feasibility studies were begun in 1952 employing underground development. Economic studies showed open pit operations to be feasible and stripping of overburden was begun in late 1955. The first ore was reached in October of 1956. A 3,000 tpd (tons per day) concentrator was completed and began operation January 1, 1957. From these beginnings, Cyprus Pima Mining Company has expanded into a plant processing approximately 54,000 to 56,000 tpd. Four expansions were required to bring the plant up to its present capacity. Each expansion incorporated what had been learned in previous operation of the plant. The first expansion was completed in August of 1963 doubling design capacity to 6,000 tpd. In reality, because of softer than average ore, capacity was closer to 8,000 tpd. Expansion I1 was completed in July 1966 bringing design capacity to 18,000 tpd. Expansion I11 followed immediately. Completed in the summer of 1967, this expansion increased the design capacity to 30,000 tpd. The actual dry tonnage of this portion of the operation in 1974 averaged 38,400 tpd, again, primarily as the result of treating softer than average ore. The latest expansion (Expansion IV), completed in December 1971 and utilizing a semi-autogenous grinding circuit, is located in a separate building (Mill 11) approximately 200 yards southeast of the original mill (Mill I). Expansion IV was designed for 14,000 tpd, but after circuit modifications, averaged 16,500 tpd in 1974.

Jan 1, 1976

By S. Orr

Flow in heaps and dumps is a two-phase flow phenomenon, though for many applications it could be simplified as unsaturated flow. Unlike saturated flow (typical of ground water flow), where permeability is independent of other hydraulic parameters, unsaturated flow permeability depends on the degree of saturation and/or on capillary pressure. Several recent field studies suggest that flows in heaps and dumps tend to concentrate in preferred pathways, bypassing much of the ore. Different preferential flow phenomena are triggered, promoted and influenced by different heap structures, by pretreatment, by the composition of the leach solution and by application rates and schedules. The structure of heaps and dumps is determined and affected by every stage of their construction -from blasting to crushing to conveying and stacking of the material. History of heap construction and operation combined with monitoring, mapping and certain field tests can reveal patterns of flow and transport in a given heap and can shed light on the physical mechanisms behind it. Such insight can provide a first cut on heap leaching enhancement by either eliminating or bypassing physical barriers to flow and leaching. Based on the understanding of the heap structure, advanced flow and transport models can be constructed and further enhance the insight. This insight is essential for understanding cause and effect and can provide a basis for decision making. Further, based on the physically-based models, an intelligent control agent, such as MRDS1, can learn and build a self-learning representation (or a model) of the complex heap leaching system, followed by dynamic optimization and planning of heap leaching and heap rinsing.

Jan 1, 2003

By B. K. Parekh, R. H. Mehta

Handling of fine coal is an importance issue for coal as well as the utility industry. Reconstitution in form of pellet or briquet would be desirable if it could be done economically. This paper evaluates the effectiveness of three binders e.g., asphalt- emulsion, corn starch and Brewex, in forming pellets of ultra-fine clean coal. It was found that asphalt emulsion and corn starch were not effective binders for ultra-fine clean coal, however, Brewex provided excellent quality of pellets, which exceeded all the minimum quasi requirements of coal pellets. INTRODUCTION Advanced coal preparation techniques (physical or chemical) are designed to process ultra-fine (minus 200 mesh or 74 pm) coal. The average particle size of the clean coal product is about 25 pm. Currently available dewatering techniques are effective in providing a 25 to 30 percent moisture product of this size coal slurry (Parekh et al. 1989). Handling and utilization of this dewatered ultra-fine size coal is difficult. Reconstitution, which includes pelletization, briquetting, extrusion, etc., of the dewatered coal product provides an ideal answer to handling and transportation problems. However, reconstitution of fines in the coal industry has not been successful due to various reasons. The most important criterion for its unsuccessful application in the coal industry is the cost of the binder (Capes et al. 1965). Various methods of reconstitution, such as briquetting, disk pelletization, extrusion pelletization and roller and die-pelletization, have been tested for fine coal agglomeration (Conkle et al., 1991) (Richards, 1990). Conkle et al., (1992) have provided a detail analysis of each technique in terms of moisture and operating cost requirements. According to Conkle, briquetting requires a product containing very low moisture, whereas pelletization can be done with coal containing up to 30 percent moisture. Currently available dewatering technique provides about 25 percent moisture product, thus, pelletization appears to be an ideal route for reconstitution. In this paper, results are presented on the comparison of three different binders i.e., asphalt-emulsion, corn starch and Brewers condensed solids (BCS or Brewex), for fine coal pelletization.

Jan 1, 1995

By Susan T. Bagley, Linda D. Gratz, Kirby J. Baumgard

The extensive use of heavy-duty diesel engines in underground mines has raised concerns about the potential adverse health effects to miners exposed to diesel particulate matter (DPM) which contains mutagenic and carcinogenic organic compounds. The purpose of this study was to compare the levels of DPM, biological activity, and polynuclear aromatic hydrocarbons (PAH) attributable to diesel engines in underground coal mines and similar data collected in engine laboratory facilities to assess whether laboratory data could be used to predict in-mine levels of diesel emissions. Mean in-mine DPM and SOF concentrations varied from 0.90 to 1.9 mg/m3 and 0.08 to 0.40 mg/m3, respectively. DPM-associated mutagenicity (mean) levels at two of the mines varied from 400 to 970 revertants/m3. Concentations of three PAH differed by up to four-fold between two of the mines, largely reflecting differences in DPM and SOF levels. The laboratory raw exhaust data were divided by 100 to obtain expected or predicted values for in-mine concentrations. The predicted DPM, SOF, mutagenicity, and PAH values based on laboratory samples were not significantly different from many of the in-mine values. Using a potential in-mine dilution ratio range of 20 to 200:1, virtually all in-mine data fell within the predicted range. Therefore, an estimate of in-mine concentrations can be determined by evaluating laboratory data. This will allow for extrapolations from laboratory tests with particulate emission control devices to assess potential health-related benefits due to their in-mine use.

Jan 1, 1991

By Jack W. Eloranta, Michael J. T. Orobona, Peter R. VanDelinder

Ore blending for process optimization is becoming an increasing factor for managing cost and productivity. Economic mining and processing a very low value ore in an extremely competitive market results in constant cost-cummng initiatives. The inherent conflict between the lowest possible mining cost and the lowest possible milling cost is reviewed here in the context of blasting for autogenous mills. Iron ore blending focuses on a number of properties-liberation values, weight recovery and concentrate silica being the most important. Other chemical and metallurgical factors are also commonly controlled. Recent research has fueled an emerging interest in blending on physical ore properties as well. Fully autogenous mills rely on the large, competent fraction of crushed feed to act as grinding media. Previous test work indicated that Hibtac mills require specific amounts of 6- to 10-inch ore. High recirculating loads require a steady influx of large rock fragments. Blast designs, therefore, are presently characterized by wide patterns and low powder factors. Current efforts are aimed at improving mill throughput while reducing overall energy costs. Based on research and published case studies and the advent of optical measuring devices, Hibbing Taconite Company has embarked on a blast optimization program to identify optimum mill feed and to design blast fragmentation goals for each geological unit and each mining area. This paper outlines the preliminary findings of an ongoing, broad-based team effort which requires close cooperation of geologists, mine engineers, crushing and milling personnel. Three specific areas of investigation are reviewed: I) Historical relationships between powder factor and mill performance, 2) Blast fragmentation modeling using the Kuz-Ram model, and 3) Drill

Jan 1, 2004

By Adrian Smith

14.1 INTRODUCTION From the time the last recoverable gold is extracted from ore on a heap leach, the ore - now spent ore - changes from being the resource, indeed the raison d'etre of the operator, to a potential liability. The spent ore contains process chemicals and constituents leached from the ore both in the interstitial pore water in the heap and on the surfaces of spent ore. If these chemical species were released to the environment, it could have a potential impact on the quality of both surface water and groundwater resources. Accordingly, the spent ore must be left in a condition where it does not present a potential environmental liability. This can be accomplished either on a decommissioned pad or, if the heap leach is operated as a load/unload scheme, in a waste facility. In general, the residual cyanide level in the spent ore is the perceived controlling factor when determining whether the leached material is suitable for abandonment. Regulatory authorities set permit conditions for heap leach abandonment in terms of residual cyanide levels, for example, Smith and Struhsacker (1987). This chapter discusses cyanide degradation and methods for detoxifying a heap leach in order to meet regulatory limits/permit conditions for abandonment. Cyanide degradation and detoxification by "natural" processes are described initially, based on the chemistry and geochemistry discussed in Chapter 13. This leads to a review of chemical treatment processes for detoxification of spent ore. The advantages and apparent disadvantages are then appraised. 14.2 NATURAL DEGRADATION AND DETOXIFICATION For the purposes of discussion, "natural" detoxification processes can be divided into two alternatives: • Passive abandonment (the so-called "do nothing" option); and • Water In the first alternative, the spent ore is merely left on the leach pad to age; the second alternative involves the flushing of the spent ore with water.

Jan 1, 1988

By David R. Quigley, Patrick R. Dugan

First reports of microbial coal solubilization appeared in the early 1980's (Fakoussa, 1981; Fakoussa and Truper, 1983; Cohen and Gabriele, 1982). These degradations, which occurred at ambient temperature and pressure, resulted in a dark brown to black viscous liquid and required days to weeks to occur. Rates and degrees of coal biodegradation varied from coal to coal. Hard coals were not extensively degraded (5-7%) while low-rank coals such as Leonardite, a sublignite, were completely solubilized. A correlation between degree of weathering or oxidation of coal and the coals susceptibility to biological attack was observed. This led to oxidative pretreatments as a method to enhance microbial degradation of coal (Strandberg and Lewis, 1986). Products of microbial degradation of coal are water soluble solids that do not have significant solubilities in organic solvents (Wilson, et. al., 1987; Quigley, et. al., 1987; Quigley, et. al., 1988a). Solutions of solubilized coal did not separate or form precipitates which suggested that they were true solutions and not colloidal suspensions. Biosolubilized coal contained more oxygen than starting material suggesting that microbial attack of coals involved oxidative cleavage of carbon-carbon bonds. This small change in oxygen content was the only change observed in coal structure during the biosolubilization process. Many coal solubilizing microorganisms have been isolated. Some are lignin degrading organisms such as Phanerochaete chrysosporium and various Streptomyces species (Gupta, et. al., 1988; Wilson, et. al., 1987). This was not unexpected since the structures of lignin and low-rank coals are similar. These organisms produce an enzyme complex, ligninase, that utilizes hydrogen peroxide to oxidatively cleave the bond between a and ß carbons of an aliphatic chain bound to an aromatic nucleus. Another important organism is Trametes versacolor (syn. Coriolus versacolor, Polyporus versacolor). Even though this organism produces a ligninase (Dodson, et.al., 1987), coal solubilization has been attributed to the enzyme laccase (Pyne, et. al., 1987). Laccase utilizes molecular oxygen to oxidatively cleave a - ß bonds using a mechanism similar to that observed for ligninases (Kawai, et. al., 1988). Other coal solubilizing microorganisms have been isolated from coal outcrops (Ward, 1985; Ward, 1988), but enzyme activities responsible for coal solubilization have not been identified. Research at the Idaho National Engineering Laboratory has focused on those mechanisms involved in coal biosolubilization. An

Jan 1, 1989

By G. Fehr, B. B. Panda, R. Bansberg, K. Arnold, T. Freiman

To evaluate the potential for process solutions to contaminate groundwater outside of the area of the Oxide Pit, it is necessary to predict the ultimate maximum pit lake elevation once pit-related mining activities have ceased. A water balance model was developed based on the existing pit geometry, the groundwater flow equation, and assumed hydrologic input parameters. The model assumed that at any point in time, total inflow into the system (i.e., direct precipitation, surface water and groundwater) minus outflow from the system (evaporation from the lake surface) was equal to the change in the pit water volume. The pit lake depth over time was predicted by assuming a succession of steady- state water balance conditions over short time increments. An analytical method using a spreadsheet and computer model was employed in this study to model the filling of the lake in the Oxide Pit. A sensitivity analysis was performed to evaluate uncertainty associated with the input parameters in the model. The sensitivity analysis indicated that the model was most sensitive to values of precipitation and evaporation and to the static water table.

Jan 1, 2003

By R. F. Hüttl

The restoration of surface mining landscapes requires the (re)creation of ecosystems. In Lusatia (eastern Germany), large-scale open-cast lignite mining operations generated spoil dumps widely consisting of acidified, phytotoxic substrates. Amelioration and rehabilitation measures have been developed and applied to these substrates since the 1950s. However, it is still not clear whether these approaches are sustainable. This paper reports on collaborative research work into the ecological potential of forest ecosystem development on typical minesites in the Lusatian lignite district. At first sight, pine stands on minesites along a chronosequence comprising about 35 years did not show differences when compared with stands on non-mined sites of the general region. Furthermore, with some modification, conceptual models for flora and fauna succession in forest stands on non-mined sites seem to be applicable, at least for the early stages of forest ecosystem development. For example, soil organism abundance and activity at minesites had already reached levels typical of non-mined sites after about 20-30 years. In contrast, mine soils are very different from non-mined soils of the test region. Chemically, mine soil development is dominated by processes originating from pyrite oxidation. Geogenic, i.e. lignitic, soil organic carbon was shown to substitute for some functions of pedogenic soil organic matter. Rooting was hampered but not completely impeded in strongly acidified soil compartments. Roots and mycorrhizae are apparently able to make use of the characteristic heterogeneity of young mine soils. Considering these recent results and the knowledge accumulated during more than 30 years of research on minesite rehabilitation internationally, it can be stated that minesite restoration might be used as an ideal case study for forest ecosystem development starting at "point zero" on "terra nova".

Jan 1, 2002

By Robert Seal, James J. Rytuba, Michael P. Hunerlach, Roger Ashley, Dean Enderlin

Cessation of open pit mining in 1996 at the McLaughlin hot-spring type gold deposit has resulted in the development of two pit lakes that will be managed as permanent lakes with a total storage capacity of 10,000 acre-feet. The south pit lake developed from alkaline ground water infiltration and had an initial pH of 7.2. It contained high concentrations of boron and chloride, indicating that it consisted of a mix of meteoric and evolved connate waters. Numerous carbon dioxide gas vents were present initially in the shallow south pit lake, but as the pit lake increased in depth, gas venting ceased and carbon dioxide is retained in the lower layer of the chemically stratified lake. Continued increase of dissolved carbon dioxide in the lower layer increases the potential for a limnic eruption. A chemocliie occurs at a depth of 47 m. The upper layer of the lake has lower pH, temperature, and conductivity than the lower layer. Effluent from ore and waste rock piles directed into the south pit lake has contributed to high levels of antimony, arsenic, cobalt, copper, mercury, nickel, and zinc. Iron oxyhydroxide is abundant in mine effluent that enters the pit lake and adsorption onto this phase has lowered the arsenic and antimony concentrations. The north pit lake formed primarily from winter surface runoff. The acidic water, pH 4.56, initially had high concentrations of cobalt, mercury, and nickel derived from weathering products of pyritized serpentinite and shales. Buffering by wall rocks has established a slightly alkaline pH of 7.62. The concentrations of trace metals in the north pit lake have substantially decreased due to continued dilution of the lake by surface runoff and remediation of parts of the pit walls that have been covered by backfill.

Jan 1, 2000

By Carl E. Nelson

Shallow epithermal stockworks hosted by maar eruption craters contain over ninety percent of the bulk mineable gold identified to date in the Circum-Caribbean region. Pueblo Viejo (Dominican Republic) and Santa Rosa (Panama) contain combined gold reserves of over 600 tonnes. Bulk mineable gold deposits are also being discovered in and around veins that were formerly mined underground. Bellavista, El Recio and San Martin (Costa Rica) contain combined announced gold reserves of over 50 tonnes. Representative rock suites collected at 8 bulk mineable gold deposits include 291 samples of veins and vein stockworks, hydrothermal eruption breccias, sinter, variably altered host, unaltered host, nearby intrusive rocks and basement. Analyses completed to date show that Circum-Caribbean epithermal ores are enriched in arsenic, mercury and antimony as well as gold and silver. Exploration efforts in the region naturally focus on districts with past production. However, an order of magnitude more bulk mineable gold has been discovered in shallow epithermal stockworks outside of the old bonanza vein camps. Exploration guides include basal island arc volcanic sequences, hydrothermal and hydrovolcanic (maar) eruption breccias, thinly-bedded carbonaceous maar sediments, and hot spring-related silicification and argillic alteration.

Jan 1, 1990

By M. S. Kabibwa, E. K. C. Chanda

In planning for the future, Nkana Division deepened the Mindola sub-vertical shaft which was commissioned in 1994 in order to access the 30 Mt of ore between 1274 and 1570 m levels. The Nkana Synclinorium which is estimated to contain 250 Mt of ore is being accessed from the vicinity of Central Shaft. These areas are being planned with the intention of maximizing the use of computers in geological modelling and mine design so as to overcome the inadequacies of manual planning techniques. As a result, there is an increased demand for quality output from the computerized mine planning system the division has been developing over the last few years. A new workstation comprising the Hewlett Packard HP 71 51100 MHz and a CRX graphics monitor was acquired in 1995 together with the LYNX (version 3.09 and version 4.0) Mine Modelling System. Currently the workstation is being used for geological modelling and mine design for the Zerofold at Central Shaft and the Mindola mining at depth project. AutoCAD and Mine Works Planner have been added to the sys- tem configuration. Mine Works Planner is likely to replace Lo- tus123 for mine scheduling tasks. Computer applications in the area of mine planning at Nkana has led to considerable time savings and improved efficiency in areas formerly performed manually and has allowed speedy processing of data that would otherwise have proved too time consuming. Nevertheless, a lot of work still needs to be done in the areas of geostatistics, stope design and financial modelling of mining options. For the foreseeable future computer based planning will operate parallel to manual methods until such a time as sufficient personnel are proficient in the use of computer systems. This paper describes the program of computerization at Nkana Division, reviews current applications and the benefits and experience gained and discusses the promise of current and future developments.

Jan 1, 1996

By Drew F. Holbrook

Most of the siliceous rocks of the Arkansas Novaculite are novaculite, but they also include some chert, siliceous shale and, rarely, sandstone. Novaculite is defined as a homogeneous mostly white or light-colored rock, translucent on thin edges, with a dull to waxy Juster, and comprised almost entirely of microcrystalline quartz. The most plausible theory of origin for novaculite is that primary silica from submarine volcanism was picked up by organisms and deposited as amorphous silica, which was subsequently converted to microcrystalline quartz (novaculite) through diagenesis. The Arkansas Novaculite crops out over an east-west distance of 200 miles in the Ouachita Mountains of Arkansas and Oklahoma. Three divisions of the formation have been defined: a Lower Division, almost entirely massive light-colored novaculite; a Middle Division of interbedded dark chert and shale; and an Upper Division of massive calcareous novaculite. The Lower Division and most of the Middle Division are Devonian in age, and the remainder of the Middle Division and all of the Upper Division are Mississippian. The massive novaculites of the Upper and Lower Division attain their maximum development along the southern and central outcrop belts of the formation in Arkansas, and it is these rocks that are the source of current silica production. The calcareous novaculite of the Upper Division weathers readily to a light-colored, porous, less brittle rock, and in places to tripoli deposits. Currently tripoli is mined from a single deposit near. Hot Springs, Arkansas, and the rock is processed for highly specialized filler and abrasive applications. In the vicinity of Hot Springs, Arkansas, certain novaculite layers from the Lower Division with unique textural characteristics are quarried and processed into whetstones. Several small quarries produce this rock for two local and one out-of-state whetstone-fabricating plants. Chemical analyses of composite samples of novaculite from both the Upper and Lower Divisions taken at widely separated localities average 99 percent SiOz indicating a substantial resource of high-silica rock.

Jan 1, 1978

By Wayne Charlie, Joseph P. Martin

INTRODUCTION Typically, uranium mills produce slurred tailings which are transported by pipeline to a tailings impoundment. The slurried tailings contain about 250 solids (75% liquids) by volume and, depending on the milling process, have a high or low ph. Despite decanting water from the tailings pond and losses by evaporation and seepage, Staub (1978) estimates that for lined impoundments over half of the input water is stored in the tailings. As long as the impounded tailings remain in a loose and saturated state, potential hazards exist and include potential for short and long-term seepage from the impoundments and the potential for large scale release and movement of liquified tailings should an embankment fail. The breach of an earthen dam on July 16, 1979 at Church Rock, New Mexico, and the subsequent release of 100 million gallons of water and liquified uranium tailings, underlines the potential hazard. Loose saturated tailings also have a high potential of liquefaction during earthquakes (Charlie and Wardwell, 1979; Martin, Finn and Seed, 1978; and Mittal and Morgenstern, 1976). If the tailings could be dewatered, the liner's integrity would become less critical, longterm seepage and settlements would be greatly reduced. In addition, the potential for tailings liquefaction from an embankment failure or earthquake would be greatly reduced. This paper reviews the concept, criteria, and design of various proposed interior drainage systems to dewater the tailings after deposition. ADVANTAGES OF INTERIOR DRAINAGE The primary purpose of interior drainage systems for uranium mill tailings impoundments is dewatering the tailings as rapidly and as thoroughly as possible. The expected benefits of this new technology are: • Reduction of potential seepage losses by decreasing the hydraulic head. • Reduce earthquake liquefaction potential of the tailings by inducing non-saturated conditions and/or lowering the water pressure. • Reduce the potential for large-scale release and movement of tailings should an embankment fail. • Stabilize the tailings to permit early reclamation. • Recovery and potential recycling of tailings liquid. • Inhibiting long-term seepage out of the impoundment by inducing nonsaturated conditions to provide capillary suction in the tailings.

Jan 1, 1980

By D. P. Plute

The mechanization of the materials management function must contribute to the overall goal of optimization of profits. A computerized system contributes to the profitability of the company by saving more than it costs to operate. Design and implementation of the sys- tem must respond to the needs of users, the operating environment of the property, and must support the objectives of materials management. Three basic functions interact within the scope of materials management. They are inventory control, purchasing, and warehousing which have the following objectives: 1) Inventory control-to request materials in a timely manner and in quantities that provide the best level of support to users at the lowest cost. 2) Purchasing-to purchase requested materials and services at the required time and at the lowest cost. 3) Warehousing-to efficiently receive, store, and issue materials and to prepare accurate transaction documents for the activities. The development of the mechanized materials management system will require a plan and objective analysis by management and system users of system requirements. A typical plan would include: 1) System Design Objectives-the development of objectives that support mechanization of the materials management function. 2) System Characteristics and Concepts- the development of key system concepts and characteristics, which identify the needs of materials management. 3) System Inventory Item Classification- development and assignment of inventory category codes to inventory items. 4) System Order Decision Rules-the development of decision rules and forecasting techniques to minimize the inventory investment and to provide acceptable support levels. 5) System Report Structure-the development of a report structure to support the goals and objectives of materials management. 6) System Report Design-the development and design of reports for effective utilization of the mechanized system.

Jan 1, 1979

By D. C. Mahon, P. G. Sagert, M. R. Legeyt

INTRODUCTION Public opinion, over the effect of industrial development on the environment, has required government to institute guidelines for the protection of the environment both during the development of and after the decommissioning of mines. In no other area of mining has this requirement been more consistently applied in recent times than in the development of uranium mines. Uranium mines have been a focal point because of the very real uncertainties associated with the detrimental effects of radionuclides and the possible hazards of radiation. In order to determine if there is an environmental effect caused by a development or the storage of the mine waste as tailings, it is necessary to know what the quality of the environment was prior to the production of the tailings. This is the reason for baseline data programs. It is neither technically nor economically feasible to completely define the environment in any given region. Therefore, judgement decisions must be made prior to the development as to what aspects of the environment are more likely to be affected by the presence of the tailings, and to what degree. These decisions have evolved over a period of time based on information generated from existing facilities, scientific research, and the development of strong public opinions. This process is not static, but evolves with the growth of information and the technological developments which permit greater control of industrial pollution and waste management. A well-designed baseline program will reflect changes in science, technology and public attitude, even in advance of government regulations to enforce policy changes. RATIONALE FOR PREOPERATIONAL BASELINE STUDIES There are three distinct phases to be considered in the construction of an environmental assessment for a uranium mine tailings containment facility. I. Pre-operational 2. Operational 3. Post-operational (decommissioning and long term).

Jan 1, 1980

By H. Knorre, A. Griffiths, J. Loroesch

Introduction Hydrogen peroxide is known to the mining industry as a powerful oxidant. able to attack and to destroy cyanide, the most important leaching reagent (Knorre and Griffiths, 1984; Griffiths, 1988; Griffiths, 1988). [ ] The most recent development, however, is the use of H2O2 as an oxidant in the cyanidation of precious metals. This application may appear to be a contradiction to the above mentioned detoxification process. This can, indeed, be the case if certain conditions are not considered carefully. Degussa has developed a new process to enable the application of H2O, in this field without having any detrimental effect on the cyanide. The incentive to seek an oxygen supplier like H2O2 instead of air was the fact that one of the most important conditions for the fast dissolution of gold is the presence of physically dissolved oxygen in the pulp (Kydryk and Kellog, 1954; Warstell, 1987). [ ] Complete gold recovery within a reasonable leaching time may only be achieved if the pulp is saturated with dissolved oxygen. Gold losses in leach operations mainly occur due to the following reasons: In some cases, the saturation of oxygen in the pulp cannot be achieved by aeration due to the difficulty to transfer oxygen from the gaseous into the liquid phase. This happens, for example, in pulps with a high viscosity. In such cases, even violent aeration only results in a low concentration of dissolved oxygen in the pulp. In any case, the starting phase of leaching requires the highest amount of oxygen. Therefore, it is especially important to raise the dissolved oxygen level to saturation in the starting phase. Peroxide assisted leach process (PAL) The intention of the process is to introduce oxygen in a liquid form. As a result of intensive research work, it could be shown that hydrogen peroxide can be used as a source of oxygen in the leaching of gold ores. To avoid side reactions, the following conditions must be applied: Hydrogen peroxide must be diluted before it is added to the pulp. The dosage of H2O, must be properly regulated based on the oxygen level of the pulp. An important part of the continuous O, control is a special oxygen electrode, which resists the extremely abrasive action of the pulp.

Jan 1, 1990

By David Sainsbury, Bevan Thompson, Yuejun Cai

The practice of placing loose rockfill as passive support in open stoping voids, of narrow vein mineral deposits, lends itself to the sterilisation of substantial mining reserves in the requirement for regional crown/sill pillars. Significant benefits are to be gained by the Australian mining industry via the development of improved guidelines for the extraction of such sterilised mine pillars. The application of selectively injecting specifically developed ettringite (calcium sulphoaluminate hydrate) type cement grout into loose rockfill, enables an artificial pillar to stabilise the surrounding rockmass and prevent the caving of loose rockfill from the previously backfilled void during extraction of remnant crowdsill pillars. This paper presents the results of laboratory testing used to reduce the technical risks associated with the design of cemented rockfill pillars. A laboratory testing program was devised to investigate the critical parameters influencing the performance of a stabilised rockfill matrix, along with the critical parameters influencing the interpretation of laboratory test samples. The factors investigated include; sample size and shape, particle size distribution, curing time, water quality, cement : water ratio and the confinement effect.

Jan 1, 2001

By Stephen G. Hardcastle

CANMET has developed a simple yet very effective tracer gas method to test the efficiency of stench gas emergency warning systems which can easily be performed by mine personnel. This test method uses sulphur hexafluoride (SF,) as a surrogate for such stench gases as ethyl mercaptan. The test has many advantages: it is non-disruptive to production because SF, is odourless, colourless; it is safe to use as it is inert and only a small volume, insufficient to reduce oxygen levels, is necessary to dope the air with a measurable concentration; and most importantly it provides definitive results to assess the adequacy of the warning system. Specific findings of these tests have included, over doping sections of the mine and subsequent production loss due to sickness, the warning being ignored, the injection period being too short, excessive dispersion, and inadequate notification times. The simple test protocol involves releasing a known volume of the SF, under similar circumstances to those of the stench gas, and then sampling for its presence downstream. These samples are collected in air-tight syringes which are then analyzed in a laboratory with a gas chromatograph. By direct proportion, between the size of the stench and tracer gas releases, it is possible to convert the SF, concentration into equivalent stench gas concentrations profiles. From these, it is possible to define, the initial arrival time of the gas, the time it takes to reach a "target" notification concentration, whether the gas peak will exceed TWAEV, STEV and CEV exposure limits, and the duration of the peak above these levels. Since 1993, this test protocol has been employed a total of eight times on four different Canadian mine properties and the results are being used to optimize the stench gas release system with respect to volume of gas used, duration of injection, and number of injection locations.

Jan 1, 1997

By S. Chander

The use of various electrochemical techniques to study mechanisms of sulfide mineral- flotation reagent interactions is briefly reviewed in this paper. Prior to such studies it is desirable to thermodynamically determine solution conditions favorable for formation of hydrophobic species deemed to be responsible for flotation. The thermodynamic equilibrium involving both the stable and metastable species can be conveniently represented by an Eh-pH diagram. Thermodynamics can also be used to predict conditions where a mineral might not float if depressants are present. Under favorable conditions of flotation there is competition between reactions leading to formation of hydrophobic species with reactions that lead to formation of hydrophilic species. Due to the sluggish nature of the reactions involving sulfide minerals, a knowledge of the kinetic behavior of the system is necessary. Electrochemical methods of investigation are wed in laboratory studies to (1) control the state of oxidation, (2) determine the type and amount of electroactive species present at the mineral surface, and (3) study kinetics of electrode processes. By combining electrochemical techniques and wetting measurements the identification of hydrophobic species that might be present at the mineral surface could be achieved. Both contact angle measurements at mineral electrodes or flotation in a cell equipped with a particulate bed electrode can be used for the wetting measurements.

Jan 1, 1987