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By S. K. Kawatra, V. Claremboux, S. Valluri

Carbon dioxide capture from coal-fired power plant flue gas and subsequent sequestration is expected to play a vital role in mitigating global climate change. To meet the growing need for CO2 capture Technology, Michigan Technological University is researching CO2 capture and Utilization. We have successfully converted CO2 into oxalic acid using an electrochemical approach. If oxalic acid can be produced in bulk from CO2, it can be used to leach rare earth minerals at low cost. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. In this paper, we will present an idea of how the factors mentioned above will effect the electrochemical reduction of CO2 to Oxalic acid. INTRODUCTION. CO2 is thermodynamically quite stable, as shown by its highly negative heat of formation. Thus, it is expected that the formation of any useful chemical from CO2 will require the input of at least as much energy as geological sequestration. However, to be more effective the resulting economic value of the chemical need only pass the cost of the additional energy required beyond geological sequestration. This lends itself to two extremes: one where the quantity of energy required is low and one where the economic value of the additional energy is low. It is expected that CO2 can be reduced via electrolysis to several compounds. Of particular interest are formic acid, oxalic acid, methanol, ethanol, formaldehyde, and carbon monoxide (as a component to syn-gas). These chemicals have been reported as electrolytic products previously in literature and have considerable potential for application. EXPERIMENTAL Electrocatalytic Production of Oxalate from CO2 We are using membrane electrolysis cell to produce oxalate from CO2. A membrane electrolysis cell is a 2-chamber electrolysis cell where the chambers are separated by a selectively permeable membrane. To produce oxalate, a cation exchange membrane (which selectively exchanges cations) was used. Previous literature suggests that in the cathode chamber an organic electrolyte, such as tetraethylammonium perchlorate or tetraethylammonium bromide in dimethylformamide, are preferred3. In the anode chamber, a sodium hydroxide solution water is used. Carbon dioxide is then bubbled into the cathode chamber as a current is applied.

Jan 1, 2019

By S. K. Kawatra, S. Valluri

With increased CO2 emissions from steel and coal industry, there is great opportunity to capture CO2 and utilize the captured CO2 for economic advantage. The primary goal is to develop energy-efficient processes that reductively couple CO2, an abundant and renewable carbon source, for the production of value-added chemicals such as methanol, ethanol, and oxalic acid. These chemicals can be used elsewhere in the refining process or sold as valuable by-products. Geological sequestration, in comparison, has no economic return. Current CO2 utilization research at Michigan Technological University focuses on electrochemical reduction of CO2. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. This paper will present different ideas and their viability to utilize CO2 as a feedstock to produce several value-added compounds. INTRODUCTION Carbon dioxide (CO2) emissions into the atmosphere will need to be drastically reduced to curb the various undesirable effects of climate change. The large contribution in total CO2 emission originates from coal or natural gas power plants, and a considerable amount from steel plants. Average CO2 emissions in the US from steel industry is 2.9t CO2/t steel (Global CCS Institute 2013). Capturing the available CO2 from the steel and coal industries for economic advantage is a win-win situation for the industry. This technology is not only important scientifically but is also vital for a sustainable future. The various ongoing investigations can be categorized as biochemical, thermochemical, photochemical, and electrochemical approaches. Among these, the electrochemical method shows the most promise as an efficient form of CO2 conversion technology, because of its many advantages like high reactivity under ambient conditions and good extensibility from small- to large-scale processes1 BACKGROUND Extensive research has been done on the chemistry of transforming carbon dioxide into more useful products. Methods are known to convert carbon dioxide into a wide variety of substances, including methanol, isobutanol, carbohydrates, methane, carbonates, urea, formic acid, oxalic acid, carbon monoxide, epoxides, formaldehyde, and so on. Several of these (carbohydrates, formaldehyde, isobutanol etc.) are primarily results from biological processes. The rest are results of strong reduction reactions or electrolytic reduction. In short, electrolytic reduction can be used to form methane, methanol, formic acid, oxalic acid, carbon monoxide from carbon dioxide2. CO2 reduces at the cathode in an electrolysis cell. These processes have the general form of generating the carbon dioxide anion radical (2⋅−) and allowing it to react with itself or the electrolyte3. Catalysts can be added to influence the formation of the anion radical or to suppress side reactions3. The electrolyte, catalyst, voltage, electrode material and CO2 content are all known to effect the reaction pathway. Table 1 shows the overall reactions and energy requirements for electrochemical conversion of CO2 to chemicals

Jan 1, 2019

By A. MacRae

Campaign life of the converting furnace has been limited by break-outs through the hearth and walls. Throughput of concentrate has increased by 60% since start-up of the copper operations in 1981. The Furnace Integrity program was initiated at Kidd in 1993 to improve the reliability and safety of the smelting-cleaning-converting furnace line. The converting furnace is undergoing a series of upgrades to overcome severe refractory wear to the roof, walls and hearth. A recent shut-down was held in March 1997 to implement improvements to the roof, walls and slag outlet. Wall modifications included a new upper shell, wall coolers which can be supported during a shut-down from outside of the vessel, and an increase in the number of cooling blocks. Improvements to the roof included increased cooling, a novel brick/cooler suspension system, and roof compression for gas tightness. Design is currently underway to deepen the refractory hearth, to decrease hearth erosion and increase resistance to flotation.

Jan 1, 1998

By C. Ek

In bismuth metallurgy, low-copper high-sodium mattes are by-produced. Different charges containing mixtures- of crude mattes, oxidized matte, and/or copper sulfide concentrate and/or copper silicate ore have been smelted to give a rich matte and a disposable slag, then converted to obtain blister copper with high recovery and a rich slag to be recycled.

Jan 1, 1983

By G. T. Daware, M. J. Chaddha, S. P. Masurkar, P. G. Bhukte, A. Agnihotri

JNARDDC has evaluated bauxite deposits of India from the geo-technological point of view. During the evaluation studies, it was observed that bauxite deposits are associated with saprolite resources. During bauxite mining, various low-grade materials such as saprolite, laterite and low-grade bauxite are generated. These materials typically have low-alumina, high-iron oxide and high-silica content. Owing to their inferior quality, these materials cannot be used for alumina production and hence remain unutilized at the mine site. For the present study, the saprolite samples were collected from the Western Ghats bauxite deposits in India. The sintering studies were conducted on saprolite granules using a variety of parameters. The sintered granules were characterized, and their properties determined. The test results showed that bulk density, apparent density, porosity and refractoriness (PCE 1645–1659 °C) of the aggregates were within the range of refractory specifications. The feasibility tests carried out at the refractory industry indicated that the developed aggregates are suitable as refractory material and can substitute for calcined clay. Currently, high-purity clay resources used in the refractory industry are limited and fast exhausting; therefore, the industry is likely to face an acute shortage of raw materials, which will become more critical in the future. Therefore the sintered granules (aggregates) developed from saprolite, which is a mining waste, provide a low-cost, eco-friendly solution for the fast-exhausting resources of the high-purity clays. The developed process may change the Indian bauxite mining scenario because saprolite may substitute as a potential raw material for the refractory industry.

Apr 12, 2021

By A. A. Bustos

A model was developed to simulate the blow-by-blow operation of the converting process. From the weights, compositions and temperatures of all converter feeds the model calculates the composition and tonnage of both converter matte and slag as well as bath temperature at the end of each blow. The development of the model and its application to the converter aisle operation are described. There is good agreement between model predictions and observed results. At the present time the model is being used to investigate different converting schemes and their effect on pay metal recoveries, slag chemistry and temperature of the bath. Future work involves the use of the simulation model as a process control tool for the converting operation.

Jan 1, 1988

"The Key Lake mill was commissioned in 1983 to process the two Key Lake ore deposits. With the depletion of these ore bodies in 1999, the plant was converted to mill the exceptionally rich McArthur River deposit located seventy eight kilometers northeast of the Key Lake mine site. This paper describes in detail the Key Lake milling process. The mill consists of a grinding circuit, a leachkounter current decantation circuit, a solvent extraction circuit, a yellowcake precipitatiodcalciner circuit, an ammonium sulphate crystallization circuit, and a waste treatment circuit. The paper also describes process changes to handle McArthur River ore, including the ore receiving stationLOCATIONThe Key Lake mill is located 78 kilometres south of the McArthur River mine. It is located at latitude 57' N in northern Saskatchewan, within the southern boundary of the Athabasca formation. The nearest town is Pine House, located 240 kilometres to the south. Access to the mine is by an all weather road and by a private airstrip.HISTORYAND DESCRIPTION OF OPERATIONThe Key Lake mill was commissioned in October 1983 to process ore from the Gaertner and Deilmann ore bodies. The mill was designed to produce twelve million pounds of uranium oxide (U308) a year from a feed grade of 2.4% U3O8.Following grinding, the uranium is leached in a two stage leach circuit using oxygen and sulphuric acid. An eight-thickener counter current decantation (CCD) circuit is used to separate the uranium bearing solution from the solid waste residue. The uranium is further purified in a solvent extraction circuit and then precipitated using ammonia. It is then calcined at 840' Celsius, and packaged into drums for shipping to refineries. There is a crystallization circuit to recover ammonium sulphate produced in the process and a waste treatment circuit."

Jan 1, 2001

By J. S. Edwards

The ISASMELT? process is recognized worldwide as a modem, flexible, environmentally-friendly and low capital cost smelting technology. Due to the inherent simplicity, and the advanced process control that has been developed, personnel become competent within weeks of being introduced to the ISASMELT? technology. This compares with the years required to become proficient with alternative technologies. Copper smelters in Australia, USA, India, China, Peru and Zambia have installed ISASMELT? technology under licence from Xstrata Technology. In the secondary copper business, plants in Belgium and Germany are processing copper and/or lead materials in ISASMELT? furnaces in a two stage process. In a single furnace smelting is followed by converting. Both plants have exceeded design capacities and are continuously improving their performance. The next evolutionary step for the technology is the implementation of the continuous copper converting process on a commercial scale. The present work describes the design status of the continuous converting process - ISACONVERT?.

Jan 1, 2007

By W. L. McMorris, A. H. Brisse

IN the last several years the coal industry has intensified its effort to solve the growing problem of cleaning and recovering fine mesh coals. On one hand there has been increasing civic pressure for cleaner streams, and on the other hand there has been increasing production of fine mesh coal, resulting directly from adoption of the modern mining methods so essential to the economy of the coal mining industry. Cleaning fine coal with the same precision possible with coarser coals is a difficult task, and for coals finer than 200 mesh it has been impractical. Furthermore, the inclusion of -200 mesh material in the final product markedly increases costs of dewatering and thermal drying, which are necessary steps if coal is to meet market requirements. Consequently these extreme fines have generally been wasted. As a result, problems have been created in many districts because there has not been enough area for adequate settling basins.

Jan 2, 1958

By J. Evans

INTRODUCTION Section 209(b) of the Federal Land Policy And Management Act of 1976 (FLPMA-43 U.S.C. 1719 b) authorizes the Secretary of the Interior to convey mineral interests owned by the United States where the surface is or will be in non-Federal ownership. The objective is to allow consolidation of surface and subsurface (mineral) ownership. Certain major conditions must prevail for a conveyance to occur. These are: 1) There are no known mineral values (KMV) or 2) Where the mineral reservation interferes with or precludes appropriate non-mineral surface development and that non-mineral development is a more beneficial use of the land than the mineral development. Remember that allegation, hypothesis or speculation that the conditions could or may exist in the future will not be a sufficient basis for conveyance. Convincing factual evidence for an applicant’s case for mineral conveyance must be made in order to achieve that conveyance. See 43 CFR 2720 0-1 to 0-3, and 0-6. CONCEPT OF KNOWN MINERAL VALUES Known mineral values means mineral rights in lands containing geologic formations that are valuable in the monetary sense for exploring, developing, or producing natural mineral deposits. The presence of such mineral deposits with potential for mineral development may be known because of previous exploration, or may be inferred based on geologic information (43-CFR 2720.0-5(b).

Jan 1, 2007

The design and selection of components for belt conveyors is a well known procedure and many handbooks, catalogues and design manuals offer a wide range of detailed information which can be applied to most of the known conveyor problems. The aim of this paper, however, is to investigate the various methods of conveyor drive configurations, and incorporate the latest technical achievements in the control systems, particularly for high capacity conveyor systems carrying ore from pit to processing plants where the lowest maintenance, operating and initial costs are of major importance. Past experience has proven that multi pulley drives can reduce initial capital cost of a conveyor; this leads to the need for better torque control during startup, running, stopping and load sharing. Many methods of torque control are available and have been used in the past. All types have their advantages and disadvantages and must be considered when designing a conveyor or conveyor system. However the recently developed solid state electronic soft start controls utilising AC squirrel cage induction motors are gaining acceptance, especially for a conveyor system where the same control and logic system can be used to transmit startup commands to more than one

Jan 1, 1978

By Ian M. Thomson, Robert W. Greene

Last August, American Commercial Barge Line Co. (ACBL) began moving coal from mines on the old Camp Breckinridge property in Western Kentucky to TVA's new 2600 MW steam plant at Cumberland City, Tenn. By April of 1973, this movement will reach a level of 7 million tpy. TVA bought the coal rights to this property from the General Services Administration in 1965 for approximately $7 million and is now in possession of reserves containing about 120 million tons of recoverable No. 9 coal, and about the same recoverable amount of No. 11 coal. TVA then contracted through competitive bidding with Peabody Coal Co. to mine the No. 9 seam through two slope shafts. The mines are about 300-ft deep and are separated by the one major fault on this property. The mine portals are approximately 3 ½ mi apart, with the northern portal being over nine miles distant from the Ohio River.

Jan 1, 1971

The BHP Billiton Cannington Mine uses paste as the principal method of backfill. The paste consists of mine tailings and cement. The pastefill process at Cannington includes a surface plant where the thickened total tailings stream is filtered using two vacuum disc filters operating in parallel. The filter cake is mixed with Portland cement in a spiral mixer to produce a paste at a specified yield stress and cement content. The initial system design only required paste to be delivered under gravity. In July 2001, Cannington Mine expanded to 1.8 million tonnes per annum. In order to achieve this, production commenced on five new levels underground, 350 metres horizontally from the paste plant. Due to the high viscosity of paste, this distance was too far to transport by gravity. Traditionally, paste has been transported only short distances (50 m) using positive displacement pumps, with very limited success. At Cannington, a conveyor was installed which was designed to achieve zero spillage into the environment. This paper discusses the innovative design strategies used to attain zero harm on the environment whilst conveying a material, which is difficult to transport.

Jan 1, 2002

By P. W. Erickson

Development of the Twin Buttes mine entailed the largest known preproduction stripping job in the history of mining. It linked earthmovers and conveyor belts in a new approach to development of a pit that may reach, or even exceed, dimensions of 1 x 1-1/2 miles at the surface and go as deep as 1800 feet. The orebody to be stripped was covered by an average of 460 feet of alluvial gravels, which presented an initial stripping job of great magnitude. The initial pit layout and the original time schedule established early in 1965 called for the excavation and disposal of about 250,000,000 tons of alluvial overburden before the end of 1969. Allowing about a year for equipment delivery, this schedule left four years to do the job averaging about 62-1/2 million tons per year. In 1964 when The Anaconda Company undertook the development of Twin Buttes, it was recognized that special planning was necessary for the disposal of waste material and tailings. Environ- mental control was a prime consideration and is particularly sensitive in the Twin Buttes area due to the proximity to residential developments. Disposal of the 250,000,000 tons of alluvium, as well as future rock and tailing waste material, presented a problem which Anaconda engineers resolved by designing a plan to spread out much of the alluvium over an extended area, including a massive 11- 1/2 mile dike system which will impound mill tailing in three basins. The tailing will be impounded behind these-dikes to avoid wind exposure and blowing. The dikes also serve as a

Jan 1, 1974

By John K. Kellis

With the cost competitive nature of material mining, the ability to actively monitor the condition of the conveyor belt systems without personnel dedicated to that task is very desirable. This paper discusses the development of a conveyor belt condition monitoring system, which actively monitors the conveyor belt, without the need to install special antennas. A belt width map can be generated, as well as detection of three types of physical damages: (a) failure of mechanical fasteners, (b) reduction in belting strength due to reductions in competent belt width, and (c) longitudinal belt rips.

Jan 1, 2000

By Owens S. Roberts

The drive selected for any piece of machinery must adequately satisfy the application requirements both during the starting interval and at running conditions, All loading possibilities of the drive must be known and allowances made for any adverse limiting conditions such as extreme cold, or perhaps an intermittent excessive loading situation etc. In general, the drive must be selected to provide the required operating characteristics with maximum reliability and at minimum cost. Simplicity of overall design is always an advantage and care must be exercised to insure that systems incorporating unnecessary complicated parts are not indiscriminantly provided. Important non-technical considerations such as equipment avail-ability (on an overseas project) as well as standardization details also play a role in the drive selection process. Additionally, an assessment of the potential capabilities of the personnel that will have to maintain the equipment can have some influence on the final choice. Several types of prime movers are available but this article will restrict itself to the use of induction motors operating from an available alternating current power source. Many drive arrangements are possible, the most common being the direct coupled single motor arrangement. It is sometimes desirable to use more than one motor per machine, but these designs are usually more

Jan 1, 1971

By R. Todd Swinderman

Impact cradles are installed below the belt in conveyor loading zones to cushion the forces from material loading. In this paper, the author will discuss the need for and then explain the new CEMA standard for engineering of impact cradles. He will review the engineering theory and work through an example to demonstrate the assumptions used in the standard do not inappropriately affect the CEMA rating system.

Jan 1, 2002

By J. R. Thompson

It is common practice, and certainly good business as all of us know, to take care of plant operating equipment. Machinery of any type requires periodic inspection and planned maintenance. With this thought in mind a plant operator should at the end of every shutdown period make regular belt inspections and plan for later appropriate care and maintenance. The points mentioned below are understood well by all of us but are sometimes forgotten because belt conveyors are comparatively easy to operate. Maintenance of any conveyor belt is dependent upon the fundamental characteristics of the two component parts-cover and carcass.

Jan 6, 1950

By Jerome F. Sheldon

The earliest recorded history in the use of belt conveyors in the United States is in O. Evans' "Miller's Guide" published in Philadelphia in 1795. Evans defines a conveyor as a "broad endless strap of thin pliant leather or canvas revolving over two pulleys in a case or trough." (Ref. 1) In this definition, pulleys are being used in a bulk material belt conveyor application. Pulleys used in belt drives can trace their origin back to 1200 A.D. In fact, Engineers had considerable experience designing them into drives transmitting greater horsepower than those used in the early belt conveyors. In belt conveyor application, a pulley's purpose is primarily three-fold, 1) support the belt in directional changes, as designed in the conveyor, 2) transmit driving power to the belt, and 3) guide or train the belt. There are various types of pulleys used in belt conveyor systems and these are thoroughly covered in "Belt Conveyors For Bulk Materials" prepared by CEMA, 1966. For our discussion, however, the most common used in belt conveyors are drive pulleys, snub pulleys, head pulleys, tail pulleys, takeup pulleys and bend pulleys. The drive pulley imparts the driving force to the belt and may be located at the head or discharge end of the conveyor, in return strand, or at the tailor loading end of the conveyor. A snub pulley is located near the drive pulley to provide more arc of contact between the belt and pulley for maximum

Jan 1, 1971

By Edgar T. Gregory

A quiet revolution has taken place in the conveyor belt industry, Man-made materials, improved production facilities, better splicing techniques and emphasis on repair and maintenance have all contributed substantially to lowering material handling costs for the mining industry, It wasn't too many years ago that the rubber industry had only cotton for a belt carcass and tree grown rubber for the protective cover. Then came the development of monofilament rayon. This material had desirable elongation and elastic properties and was the first synthetic fiber to be used in place of cotton. But wet strength and other limitations restricted its use, and the conveyor belt industry turned to nylon. Initially, nylon was considered suitable only for the cross threads or filler threads of a belt carcass. Then technical advancements in heat setting and fabric weave created a major change in belt construction. As a result of these advances the industry was able to take advantage of the full tension strength of nylon cord. Another breakthrough in the use of synthetics was the tremendous increase in adhesion resulting from a chemical bond, rather than the limited physical bond available with cotton. But the advantages of nylon had a more Car-reaching effect, We were able to design a two-ply nylon belt that did the work of a four- or five-ply cotton or rayon belt. A six-ply nylon belt now replaces a twelve-ply cotton elevator belt. Arid nylon resists moisture, acid and mildew, It also has excellent resistance to impact and can be produced with controlled elongation and elastic properties that work to great advantage in reduced-ply belt constructions.

Jan 1, 1971