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By M. L. Liu

This work reports the results about the determination of mean activity coefficients and relative partial molar free energies for copper sulfide mineral bioleaching solutions by potentiometric method at 25ºC. The experimental potentiometric data were obtained by combining a solid state membrane-cupric ion selective electrode (Cu2+ ISE), containing a KNO3 filling solution, and an Ag/AgCl electrode. The measurements were performed in different series of copper sulfide mineral bioleaching solutions. The non-ideal behavior of the system was described on the base of the Pitzer ion-interaction model for mixed salts. Meanwhile, the relative partial molar free energies of bioleaching solution were investigated. The determination of the thermodynamic properties offers a basic data for the study of copper sulfide mineral bioleaching solutions.

Jan 1, 2014

By Karl E. Burgher

Since World War II, the need for the use of explosives with testing, construction, demolition, mining and quarrying near urban areas has increased dramatically. Once remote, testing areas have been encroached upon by commercial and residential areas. Evidence has been found that overpressure levels near these areas can be estimated using meteorological conditions. This paper reviews a study where 205 test shots were fired, meteorological conditions recorded, and over-pressure levels estimated using multiple regression techniques.

Jan 1, 1988

A method is proposed for the determination of antimony in ores. Antimony is volatilized as antimony iodide by heating with ammonium iodide at a controlled temperature.The fusion mixture is extracted with hydrochloric acid and the antimony content is measured by atomic absorption spectrophotometry using an air/ acetylene flame. The time taken for analysis when comparedwith existing fusion and separation procedures is considerably reduced. Cations and anions likely to be present in antimony ores were also studied for possible interference effects but were not found to interfere.

Jan 1, 1972

By Carlos M. Fontes Vieira, Ruben J. Sanchez Rodriguez, Carlos E. Gomes Ribeiro

"In this study we attempted to model a response surface for the apparent dry density of ternary blends of calcitic marble particles. The crushed marble was divided into three granulometric ranges. Simplex network methodology was used to determine the mathematical relation between granulometric ranges and apparent dry density (ADD) of particle mixtures. A highly significant regression was obtained and the simplex network methodology proved to be able to predict high packing particle compositions.IntroductionProblems with packing and expected porosity of particles are common and widely recognized to be important in terms of both fundamental physics and engineering applications. For example, densification of a powder mass is important in the shaping of solids in ceramics, powder metallurgy or composite synthesis; chemical processes such as solid-liquid separation (sedimentation, thickening and filtration), raw material handling (stockpiling, blending, drying, storage and transportation) and pyrometallurgical processes (agglomeration, coke making, ore sintering, blast furnace iron making and new iron making processes) [1,2].Many factors can affect particle packing, but in practice, there are three main factors: (dimensionless) particle size distribution, particle shape and absolute particle size [2].Geometrical and practical methods were developed to predict properties in mixtures. Zou, Gan and Yu [2] present a paper treating a prediction of the porosity of multi-component mixtures of cohesive (fine) and non-cohesive (coarse) particles. Bahiense et al. [3,4] used a simplex network to determine a mathematical model for obtain the optimal compositions between aggregates to a greater packing of a ternary particles mixture. Despite these techniques for predicting particle packing, some studies in particulate composites production don't present clear criteria for choice of particle distribution [5,6]. As the best particle packaging depends on the size, distribution and shape of these particles, individual models can be constructed for specific combinations of these factors."

Jan 1, 2014

By François Robert, Steve Green, Tyson Birkett, Dan Richardson

Abstract -Detailed sampling using a portable diamond drill, and interlaboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or Jess. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By Tyson Birketi, Françoi Robert, Steve Green, Dan Richardson

Detailed sampling using a portable diamond drill, and inter laboratory comparison of selected samples have been combined with statistical studies of truncated populations to establish the gold content of several outcrops in the Val d'Or area. The outcrops chosen are non-mineralized. The background gold concentration in the rocks of the region is 5 ppb or less. Gold is distributed relatively homogeneously within the outcrops studied except for slightly increased concentrations within quartz-tourmaline veinlets. Three samples, of which 20 grams of powder are analyzed for each, can adequately determine the gold concentration of a structurally simple outcrop in the Val d'Or area.

Jan 1, 1992

By Stanley D. Michaelson

THE selection of the proper size of grinding mill for a given installation has long been a subject of discussion by mill manufacturers, consulting engineers, and their clients. It would be presumptuous for the author to propose a simple cure-all. Instead this paper describes a method that has been used over a period of years to determine mill size with a reasonable degree of accuracy. Furthermore, this method claims no theoretical background, for ball milling, as practiced today, is still an art. The selection of the proper size and type of mill must, therefore, be made on an empirical basis. A ball mill, in order to grind, must deliver power through its grinding media to the material to be ground. Assuming that a mill is properly supplied with grinding media, ore pulp, and power, the amount of grinding done is closely proportional to the power expended. With this as a basic premise we can, for the moment, forget about type of mill (i.e., overflow, low-level mill, or other design) and base our calculation of mill size on the total power required to grind a ton of a particular ore from a given size of feed to a given size of product. When this is determined the type and size of mill, its speed, and the weight of the load of grinding media can be selected to absorb this amount of power. DEVELOPMENT OF TECHNIQUE Some years ago, W. L. Maxson, F. Cadena, and F. C. Bond, working in the Minerals Research Laboratory of Allis-Chalmers Co., Milwaukee, developed and described a laboratory technique for comparing grindability (or relative ease of grinding) of various ores at different mesh sizes of grind.1 Additional papers2 have described the work done since that time, and the most recent paper3 summarizes results for hundreds of tests on many ores and materials. The essentials of the testing method are: a I a by 12-in. laboratory mill operating at a constant speed of rotation, using a constant volume of ore, and a constant ball load having a relatively constant grinding surface. Tests are run at 250 per cent circulating load with the feed, circulating load and products screened on calibrated Tyler standard screens. Certain ores from operating mills, representing various mineralogical types, were selected for reference and designated "standard ores." In most cases, detailed studies of the grinding circuits were made when samples of mill feed were taken for grindability tests. Each analysis formed a basis for comparison of the grindability in the laboratory with actual power requirements for a particular grinding circuit. In addition, a critical study was made, to evaluate the differences in the various grinding circuits so that two or more field installations having different layouts (single-stage grinding, two-stage grinding, or others), and using mills of various diameters operating at various speeds with differing circulating loads, etc., could be compared. Large-scale tests by mill operators complemented by laboratory investiga-

Jan 1, 1945

By Anthony T. C. Goh

"For deep excavations in soft clay, it is common to use jet grouting piles (JGP) prior to excavation to minimize wall deflections and ground settlement, and to prevent basal heave instability. In this paper, finite element analyses were carried out to assess the basal heave factor of safety for excavations in soft clay supported by JGP. Comparison of the factor of safety from the finite element analyses with limit equilibrium methods was then performed. Subsequently, to account for the uncertainties in the soil and JGP properties, a simplified reliability analysis procedure is proposed to estimate the probability of basal heave failure for deep excavations supported by JGP.INTRODUCTIONJet grout piles (JGP) are often used to prevent basal heave instability and to minimize excessive wall and ground movements associated with deep excavations in soft clay deposits (Shirlaw 2003; Wen 2005; Ou 2006). The jet grouting process which is carried out prior to any excavation works produces a series of short overlapping grout columns resulting in a “continuous” base slab (commonly termed as jet grout pile or JGP) below the final excavation level that spans across the entire excavation (Gaba 1990; Hsieh et al. 2003; Ho and Hu 2006). Typically, the JGP thickness ranges from 2 m to 4 m.The focus of this paper is on the assessment of basal heave instability for deep excavations in clay stabilized with JGP. Finite element analyses were first conducted to determine the basal heave factor of safety for deep excavations in clay with JGP. Comparisons were then carried out with factors of safety based on conventional limit equilibrium methods. Since the conventional factor of safety approach does not explicitly reflect the uncertainties of the soil and JGP properties, it is demonstrated in this paper that a simple reliability based approach (Hasofer and Lind 1974) can be used to assess the probability of basal heave failure.LIMIT EQUILIBRIUM METHODFor excavations is clay, the Terzaghi (1943), Bjerrum and Eide (1956) and Eide et al. (1972) methods which are based on bearing capacity theory, are commonly used to determine the basal heave factor of safety. Another commonly adopted method in Japan and Taiwan is the slip circle method which involves taking moments about the lowest strut level (JSA 1988; Hsieh et al. 2008; Luo et al. 2012). The slip circle method has also been applied for excavations with a JGP at the base by incorporating the undrained shear strength of the JGP. In the slip circle method, the basal heave factor of safety FSslip is assessed by taking moments about the lowest strut level (Fig. 1)"

Jan 1, 1900

By Karl H. Brandt

In the Auguste Victoria mine a bolted rectangular roadway has been kept open for the first time in the seam D/C after retreat. The target of the project was to gain a basis for planning and experience for future mining layouts in the same scam in view of the reuse of boated rectangular roadways. For this the roadway was additionally secured in sections with longbolts before the influence of the retreating panel had taken place. On retreat a concrete sidepack was concurrently put in place on the face side. The installed monitoring systems consisted of endoscopic devices, multiple extensometers (Tell-Tales), shear-tales, extensometers and convergence measurements. The experience that was gained was carried over into a physical and numerical model.

Jan 1, 2001

By J. Wyn Prior

The seismic refraction technique is probably the most popular geophysical method of bedrock profiling in geotechnical site investigations but is somewhat restricted by the inherent assumptions in the method. This paper describes how Hales' method of profile interpretation is modified to overcome the assumptions of increasing velocity and layer thickness with depth when only first arrival data is available. A further expansion of Hales method enables presentation of refraction data in a form whereby bedrock features, such as changes in velocity, relief and dip in particular, are more readily recognized. Characteristic curves of the more common bedrock features are presented as an aid to bedrock feature recognition.

Jan 1, 1976

By Theophili CN, Kapenis AP

Seismic tomographic imaging has been applied to determine the blast induced damage zones in bauxite pillars in underground mining. At the retreating stage, when pillar dimensions are reduced from 8 x 8 m to approximately 5 x 5 m, the' seismic tomographies reveal, through measurements of the P-wave velocities which is a measure of the degree of fracturation of the pillar rock mass, the presence of three zones within each pillar. In the external zone, where velocities recorded are below 750 m/s. extensive pillar damage occurs which is attributed to both the growth and coalescence of pre-existing cracks and even the creation of new cracks in the rock mass. This effect is in agreement with literature, when considering the peak particle velocity as a criterion for rock failure in tunnels. In the intermediate zone, where velocities range between 7S0-1000 m/s, damage to a much lesser extent occurs which is due mostly to growth of pre-existing cracks and widening of their apertures. The inner zone, where velocities exceed 1000 m/s, is considered to be unaffected by blasting. Simple remedial measures of low cost, which are based on blasting mechanics are proposed to minimise the blast induced damage zone and consequently the transition zone.

Jan 1, 1995

By Adrian Moore, Alan Richards, Andrew Brodbeck

Structural blast vibration limits should be based on the strength of the structure, the stress induced by blasting, and a responsible factor of safety. In this paper a methodology that uses direct strain measurements to determine the stress induced by blasting is described. The methodology has been used to measure strain resulting from blasting, and establish appropriate blast vibration limits on a brick sewer tunnel, an underground mine heading, brick veneer houses, a water pipeline, and transmission tower foundations. An outline is given of the use of the methodology to establish limits for the main entry heading of an underground coal mine, and transmission tower footings. The methodology that is described has reduced uncertainty factors, and permitted the specification of higher blast vibration limits than had been previously used.

By Adrian Moore, Alan Richards, Andrew Brodbeck

Structural blast vibration limits should be based on the strength of the structure, the stress induced by blasting, and a responsible factor of safety. In this paper a methodology that uses direct strain measurements to determine the stress induced by blasting is described

Feb 1, 2020

By Frank W. Cole, Sharanjit S. Dhillonn

A new method has been developed for calculating flowing bottom hole pressure in a gas well, using as a basis the general energy equation. Fundamentally, the method shows that a plot of flowing pressure versus depth for a gas well can be represented as a series of incremental .straight lines, with the accuracy in-creasing as the number of increments increase. It is shown mathematically that for most cases the slope of the flowing pressure versus depth curve is essentially constant, in which case a single calculation based on surface conditions will yield acceptable results. In all cases studied no more than two iterations were required for very good accuracy, and in most cases only one iteration was necessary. Several example calculations are shown and the results are compared to other commonly used methods of calculating bottom hole pressures These examples show that the method provides answers which are at least as accurate as other methods usually used, and results in a considerable reduction in computation time.

Jan 1, 1960

By R M. Arellano, D M. W Harney, M Makhuvha

Mineral resource and ore reserve estimates are founded on two sources of data: tonnage and grade. The tonnage is a product of volume and density; both of which are estimates. Density impacts numerous operational factors, which include, but are not limited to, mine design, mine planning, equipment selection and operational performance. Hence, density is a significant parameter and its determination requires similar care as the measurement of grade. Selecting an appropriate method to determine density, and ensuring its rigorous application, thus reduces risk and can improve operational performance, which in turn increases profit margin.Different Anglo American sites use a variety of practices and protocols to determine density, which is highly dependent on the physical characteristics of the orebody, local conditions and historical practices. Also, individual sites sometimes execute the same method in a slightly different way, which may also affect the outcome of the measurements. In order to gain a better understanding of how density is determined at Anglo American projects and operations, a review of these techniques was undertaken. The objective of the study was to identify and share good practices across the company, as well as to look for improvement opportunities, where applicable. Ten different methods of measuring density, applied to nine different commodities, were identified and described. An additional technique was recently developed by Anglo American Technical Solutions. The core pycnometer is a large gas displacement pycnometer capable of measuring density at high accuracy on full pieces of intact core.This paper provides an overview of methods used to determine density within the Anglo American Group, including quality control and quality assurance aspects. It is not the purpose of this paper to identify a preferred method, but to highlight the importance of choosing the best suited practice for a project or mine site. In addition, a case study comparing two different density determination methods applied to the same rock samples from the Los Bronces Copper mine was undertaken and the results of that study are presented here.Selecting the most appropriate method to determine density and comparing results from two or more techniques against each other, together with other suitable quality control procedures, is considered to be of utmost importance for all mining operations and exploration projects.CITATION:Makhuvha, M, Arellano, R M and Harney, D M W, 2014. Determination of bulk density in Anglo American plc, methods and impacts, with a case study from Los Bronces Mine, in Proceedings Ninth International Mining Geology Conference 2014 , pp 85–96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By L. M. Pidgeon

Abstract The production of metallic calcium, by reduction of lime with aluminium, was investigated. Using a modified form of the effusion method, the vapour pressure of calcium above the reaction: 4CaO + 2Al ~ 3Ca + CaO.AI203 was determined and found to vary from 1.0 to 1.3 mm. Hg from 1,150° to l,200°C. From the magnitudes of the various thermodynamic quantities involved, together with a consideration of the known chemical characteristics of the reaction, it was suggested that the reaction proceeded by reduction of lime with aluminium vapour. INTRODUCTION The conventional production of metals by reduction of their ores by carbon (or carbon monoxide) may be represented by the equilibrium: MO+ R [] RO+ M . . . . . . . . . .(1) where MO represents the metal oxide, and R the reducing agent (carbon or carbon monoxide). The free energy change ?F° associated with the reaction is given by -?F° = RTlnKp . . . . . . . . ... . (2) where R is the gas constant, T the absolute temperature, and KP the equilibrium constant. It should be noted that ?F° represents ? the standard free energy gained by the system and hence -?F° is the free energy gained by the surroundings - and that as ?F° increases K must decrease, and conversely. For metals above manganese in the electromotive series, the ?F° associated with reaction would quantity and from it can be seen that this corresponds to a small fraction for K. The equilibrium pressure of the oxide of carbon represented by RO is then too near its concentration in the furnace gases for the reaction to proceed in an internally fired furnace. For the practical reduction of such metals, fuel fired furnaces are inadequate. Electric furnaces may be used to give higher temperatures with lower concentration of carbon oxides and the reaction may still proceed. However, for many metals such as calcium and aluminium the formation of stable carbides or acetylides may prevent production of the metal by this reaction. In this case, either electrolytic methods must be used, orrecourse must be had to reducing agents other than carbon. It is the latter method which is under consideration here.

Jan 1, 1948

By Andrew S. M’Creath

THE treatment which a steel receives, and the uses to which it may be applied, are frequently determined by the percentage of carbon which it contains; and especially is this the case in the different steel works in this country. The part which this element plays in the composition of steel is such an important one that a process for its accurate determination becomes an absolute necessity.

Jan 1, 1877

By Zongshu Zou, Qiang Li, Mingming Li, Mingxia Feng

The impingement onto the surface of bath by top-blown jets is a significant process characteristic in BOF and EAF steelmaking process. The cavity is one of the most important outcomes of the interaction and plays an important role on reaction kinetics and reactors performance. But to date, the understanding to cavity is still so limited. In present study, a water model for a BOF converter is established and the dimension of cavity profile is investigated. The effects of lance height, gas flow rate, nozzle inclination angle and the amounts of slag are discussed. The results show that penetration depth increases with the increase of gas flow rate and the amount of slag, and the decrease of lance height and nozzle inclination angle. Furthermore, a theoretical model of cavity dimension is proposed for multiply jets impinging liquid bath on the basis of energy balance at the stagnation point of cavity.

Jan 1, 2015

By Erdal Unal

In underground mining today, safety and economical aspects demand a better understanding of the rock-mass conditions, particularly for design of underground mine openings excavated in weak and stratified rock mass. The rock mass classification systems, in essence, are empirical approaches utilized during preliminary design stage. These systems have been developed for specific purposes and rock mass types, therefore, direct utilization of the classification systems in their original form, for characterization of complex rock-mass conditions is not always possible. This is probably one of the main reasons why designers continue to originate new systems, or modify and extend the ones already existing. RMR and Q systems, for example, although widely used in mining and tunnelling, can not fully describe the specifications of the weak, stratified and flay bearing rock mass. Consequently, the engineering applications that would be carried out based on original RMR and Q ratings could be inadequate for making design decisions even during the preliminary design stage.

Jan 1, 1990

By Kot F. v. Unrug

In spite of extensive research and accumulated experience from mining operations, appropriate coal strength values for pillar design remain debatable. Coal strengths determined in the laboratory on standardized samples vary widely among various coal seams with poor repeatability. Penetrometric in situ strength testing obtains multiple measurements at multiple horizons within the coal seam to provide a strength profile. Alliance Coal has used that method in many of its mines for pillar design. Pillars in these mines perform well. This paper presents a series of case studies and discussion of issues related to coal pillar design. The analysis demonstrates that the proposed default in situ strength of 900 psi is appropriate when no other data exist. However, in the case of appropriate strength measurements combined with analysis of pillar structural composition, differing values can be used successfully. In areas where the penetrometric derived in situ strength is greater than the standard 900 psi in situ strength, reserve recovery has been optimized as required by law without compromising safety.

Jan 1, 2009