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"In response to mine head grades declining and orebodies becoming more complex, Glencore Technology has developed an alternative method for recovering economic minerals once leached into solution, rather than relying on conventional flowsheet options. The method involves the precipitation and separation of base metals from solution with limestone or lime. The final grade of these precipitate is not usually high enough to attract favourable terms of sale due to dilution from gypsum and sulphate salts. A set of operating conditions have been developed to allow the separation of the base metal precipitate from gypsum by exploiting the difference in particle size. A high-grade oxide product can be easily separated from the gypsum stream at very low cost. This process was originally developed by Glencore for zinc and copper systems. This paper reports on the successful application to nickel and cobalt, and this process has significant advantages over the incumbent precipitation process utilising magnesia.INTRODUCTION During evaluation of transitional and oxide zinc ore deposits during the 1990’s, Noranda Inc. (now Glencore) developed a sulphate based ore leach process to extract zinc into solution. For flowsheet development, conventional schemes dictated that once the zinc was dissolved in an acidified solution it was recovered by means of purification or solvent extraction followed by electrowinning and casting to produce zinc ingots. The deposits Noranda evaluated were high grade but had a relatively short mine life (10 years) and economic analysis showed that the projects couldn’t sustain the investment of a full zinc refinery. Compounding this problem was the lack of power supply infrastructure and the high power cost in the region. Noranda then evaluated alternative means of recovering zinc from solution. Laboratory testwork showed that a high-grade zinc precipitate (+50 wt% Zn) could be produced as an oxide, carbonate or sulphide by contacting acidified zinc sulphate solution with a number of reagents including soda ash, sodium hydroxide, and sodium hydrogen sulphide. Economic evaluation showed that the cost of the reagents are prohibitive, especially when the final product is still a metal intermediate (ZnO, ZnCO3 or ZnS). Noranda then continued to focus on fine zinc oxide precipitation for supply into the automotive tyre industry as this product would attract favourable terms of sale as a premium on Special High Grade (SHG) zinc."

Jan 1, 2017

By Robert Boehnke, Bernd Mueller

This contribution presents an innovative, statistically supported method to predict blast vibrations in rock mass. For modelling the processes during and after detonation, a theory is employed which is based on linear momentum (so-called momentum theory), strongly supported by new measurement methods. During the course of the investigations, the following parameters have been found to dominantly influence vibrations: ! charge WB, includes geometrical factors such as borehole length and diameter (kg) ! detonation velocity cd of the explosives used (m/s) ! distance r between the points of emission and immission (m) and the statistically determined negative exponent n ! factor RM or RS of the rock mass which is related to the specific blast momentum and the drilling and blasting technique used and is statistically determined together with the exponent m (mm/kg or mms/kgm)

Jan 1, 2004

By R. Barbaroux, B. Dubreuil, D. Lemieux, K. Nasrallah, G. Garcia Curiel

"As conventional, base or precious metal ores are being depleted worldwide, the mining industry is being faced with an increasing exploitation of arsenical sulfidic ores. Enargite is a common example. The downstream processing of these ores poses several problems ranging from high smelter penalties to finding economical and environmentally acceptable means of disposing of the arsenic. Several hydrometallurgical processes have been proposed for extracting arsenic from enargite concentrates, notably using alkaline sulphide leaching (ASL). However, few alternatives exist for removing the arsenic from solution and stabilizing it in an approach that is both economical and environmentally acceptable.Dundee Sustainable Technologies (“DST”) has developed a technology for the sequestration of arsenic by vitrification. Originally optimized to cost-effectively stabilize arsenic trioxide (As2O3), DST has shown that vitrification could be successfully extended to the stabilization of other arsenical products, such as calcium arsenate (Ca3(AsO4)2) and sodium arsenate (Na3AsO4). In this paper, the vitrification of arsenic in the context of an enargite leaching was newly explored and demonstrated successfully.Two processing routes are being proposed by DST for the removal of arsenic from enargite concentrates and their stabilization by vitrification. In one route, arsenic is extracted by ASL and is then precipitated under atmospheric conditions and with minimal use of reagents and time. The resulting precipitate is an unstable hydrated ferric arsenate (FeAsO4•2H2O) that is then vitrified in a non-dilutive method, significantly increasing the stability of arsenic and meeting the TCLP guideline. Unlike is required for scorodite, stabilization was successfully achieved without concern for the crystallinity of the precipitate."

Jan 1, 2017

By M. England

A method for the analysis and prediction of single pile displacement behaviour is described. It is the displacement in time, under constant load, based on the use of hyperbolic functions to characterise individual constituents of the displacement-time behaviour. Extensive use of this technique has confirmed its validity in a variety of soils and that consolidation and creep settlement appear to be indistinguishable. The algorithms employed are suitable to model the displacement behaviour from the onset of load to infinite time for all types of piles and surface foundations. Until the advent of computer controlled static load testing, analysis of the displacement-time characteristic during pile load tests has been hindered by the quality of the data recorded and inconsistency of loading. This has hitherto made the development of suitable behavioural models very difficult. Understanding the soil deformation within a proper time framework allows the subject of pile instrumentation and testing to be developed. The equipment required is basically a computer controlled loading and pile head displacement measuring system which allows accurate analysis of the settlement characteristic in almost every situation.

Jan 1, 1993

By Kenneth M. Bravinder, Jonathan E. Koogle, Dean H. Sheldon

THE solution of subsurface geological problems requires an analysis of vertical and horizontal dimensional relationships. For many, the ability to visualize structures in three dimensions is not easily acquired, and for areas where the structural conditions are complicated by faulting the need arises for illustrative models. This has led to the many forms of peg models, in which the usual course of construction includes a peg for the well bore, and the suspension of strings from peg to peg to illustrate the formation correlation between wells, thus developing the usual folds and flexures. Such models proved unsatisfactory for the analysis of fault problems. Consideration was then given to the use of transparent materials. A model of the Dominguez oil field was constructed in 1935, which consisted of a series of glass panels from well to well on which the formations were shown in color. This model, though serving its purpose at the time, proved to be impractical from the standpoints of cost, breakage hazard, and extreme difficulty in maintenance. The cost of materials was estimated to be approximately $300, and the construction required the services of one man for a period of from 10 to 12 months. Maintenance after actual construction was an additional expense. Consideration was then given to the use of celluloid, and after some experimental work it was found that the advantages in its use were: (I) a short construction time, (2) ease of handling the material, (3) sections are easily reworked, (4) low cost. CONSTRUCTION It would be of little value to recount here the difficulties encountered in the building of the first celluloid model. The conclusions drawn, however, suggest the following procedure for those who contemplate the construction of such a model: I. Determination of the Scale.-Accurate geological interpretation requires the use of the same scale horizontally and vertically. It should be emphasized that the limited size of the celluloid sheets (20 by 48 in. maximum dimensions), the area to be studied, the maximum depths to be plotted, and area of possible future development are the controlling factors in adopting a scale to be used. 2. Construction of the Base.-A satisfactory base may be constructed by using two pieces of three-ply wood separated by strips of i by 2-in. material. This type of construction prevents warping of the base. The size of the base is determined by the dimensions of the area to be studied plus 5 in. on all sides. A map of the same scale as that adopted for the model, indicating the lines of section to be used, should be fastened to the base. 3. Construction of the Frame (Fig. I).-In the construction of the frame the use of 1/2-in. o.d. pipe welded in a box shape is suggested, with two horizontal rods on each of the four sides, top and bottom. The top rod should be at least I in. higher than the

Jan 1, 1941

By B. P. Verma, K. N. Sinha, N. M. Raju, B. Singh

The paper describes a new method of grouting bolts developed at the Central Mining Research Station at Dhanbad in India. This method makes use of wire-mesh sleeve instead of the expensive metal tube to insert the cement mortar into the drill hole. The field trials confirmed that the method is cheap and an effective system of support.

Jan 1, 1972

By Mukhopadhaya K. K, Cory A. H

The concept of using travelling magnetic fields created by linear motors was stimulated by Laithwaite who advanced ideas on motors with shaded poles (Laithwaite, 1968), rack and pinion motors (Laithwaite, 1970) as well as low speed, brushless motors and three dimensional motors (Laithwaite, 1973a and 1973b).Sudan (1963) and Sundberg (1969) had applied the concept to metallurgical processes. However, the use of travelling magnetic fields has not been used widely to produce conditions for the separation of magnetic from non-magnetic minera1s or even magnetic materials from non-magnetic materials, although some attempts were made by McCarthy (1922), Davis (1934), Dean, Gottschalk and Davis (1934) and Gottschalk (1934).Laithwaite (1973, a) while working with linear motors made suggestions for designing separators and in the work described here, the observations of Laithwaite and others are extended to determine the characteristics of the motor with a view to using it as a magnetic separator.

Jan 1, 1980

By Ellis Thomson

The microscope is now used extensively not only in the examination of solid ore but also in the determination of fragmental mill products. It has therefore become a matter of paramount importance to be able to mount and polish fragmental as well as solid specimens in the easiest and most efficient way, so that the minerals present may be readily determined. In the case of the solid ore the ordinary mount of plasticine set on a glass or metal slide serves for most practical purposes. An improvement on this is furnished by the small brass container inside of which the specimen is mounted in a cementing medium of sealing wax. The latter is the method in use at Harvard University. It has the advantage of uniform height, thus obviating the necessity of a slide of any sort. It is also easily catalogued as the brass holder may be stamped with a convenient series of letters and numbers that will serve as a label. Other advantages of this type are the ease with which any particular part of the section may be re-located, the excellent storing facilities afforded by mounts of uniform size, and the possibility of polishing ten or a dozen sections at the same time by means of a holder which is placed over the polishing wheel, is geared with it, but revolves the opposite way.

Jan 1, 1926

By Nikolaus Schneider

"Abstract: The combination of failure in joints of diaphragm walls and their exposure to water pressure may have far reaching effects ranging from water leakage to the risk of catastrophic loss of stability for the retaining wall and civil structures behind it. Investigations of imperfect joints in diaphragm walls have led to the development and testing of a quality tool to monitor the joint integrity of diaphragm walls during construction. By applying independent mechanical sensors (“joint inspector”) to the steel frame of hydraulic or mechanical grabs, it is now possible to record the surface conditions of exposed primary joints during the construction of secondary panels. This allows for the implementation of corrective action during the construction process should joint quality not indicate a watertight connection to the adjacent panel. The joint inspector, used for different types of stop ends, was tested on a full scale test field at several construction sites. The implementation of this new quality tool drives a new quality standard for deep excavations in inner city areas.General introduction to diaphragm wallsDiaphragm walls are reinforced concrete elements constructed using bentonite slurry to temporarily support an open trench in the ground. They are used in two main fields of application in civil construction, as foundation elements for vertical and horizontal loads (barrettes) and as retaining walls for excavation pits.Particularly for deep excavation pits in inner city areas, diaphragm walls are used as temporary or permanent walls of retaining walls. Alternative retaining wall systems would be secant pile walls, sheet piles or soldier piles, but these have disadvantages in structural strength when compared to diaphragm walls. If the vertical load of existing buildings next to the excavation pit has to be accommodated, the most practical solution can be found using diaphragm walls supported by prestressed anchors, steel struts or slabs."

Jan 1, 2014

By Gary Cavanough

The spontaneous exothermic reaction of ammonium nitrate explosives with sulphide-containing rocks, commonly referred to as reactive ground, is a site-specific condition that can lead to spontaneous detonations. Mine sites typically carry out regular assessment of ground for reactivity. In Australia, reactive ground testing is conducted according to the Australasian Explosives Industry Safety Group (AEISG) Code of Practice. This paper presents a new method to assess reactive ground. The new method can be completed on the mine site or in the laboratory. The new method allows samples to be tested in hours not weeks, as required when using the method prescribed in the AEISG Code of Practice. The new method also provides an explanation of why ground is reactive or not reactive, Whereas the AEISG Code of Practice provides a reactive, not reactive or marginal results with no understanding of reason for these results. Case studies on the use of weathering agents, pH, sulphide content and carbonate content will be reported. These case studies identify instances where the testing as per the AEISG Code of Practice provides false positive and false negative results. A false positive result will require the use of inhibited products when they are not actually required which increases costs and reduces productivity due to the need to used multiple explosive products. A false negative result increases the risk of an unplanned initiation of a blast hole.

Feb 6, 2023

By John Cowin, Dan McCutchen

Cowin & Company has specialized in underground construction since 1924. This paper reviews the sinking of two shafts in the Alabama coal fields using bulk-loaded explosives. Each shaft is eighteen hundred feet deep, and their diameters were twenty feet and twenty-three feet. The first consideration in changing to a new explosives system was safety. Safety began with the explosive supplier training the miners in the use of the new system, from explanation of the pumping unit on the surface to hands-on training in the shaft. The considerations covered include establishing a thunderstorm exit plan, and reducing exposure time of the crew to explosives while loading. The system consisted of a specialized pumping unit and an advance emulsion product. Eliminating the need for nitroglycerin based explosives, and reducing sensitivity to mechanical shock were goals that were met. Performance in the shaft and ease of use meant morale of the miners using the system remained high and positive. Performance benefits discussed include reducing the number of holes in the round, and cutting explosives loading time in half. Damage to the ribs of the shaft was greatly reduced, making it safer to work near the ribs on succeeding rounds. Cleaning the bottom before drilling the next round also showed marked improvement. The economics of the system became very apparent when cycle time saved was allocated against fixed cost of sinking these shafts.

Jan 1, 2000

By Eckley B. Coxe

(WITH FIGURES ON PLATES II, III, AND IV.) I DESIRE to call the attention of the Institute to two deep vertical shafts, which are now being sunk in Schuylkill County, Pennsyl¬vania, about 1 1/2 miles north of Pottsville. These shafts are of interest to the mining engineer, not only on account of the novelty of the method of sinking adopted, which promises to produce a revolution in that branch of mining engineering, but also as examples of the manner in which such work should be undertaken. GEOLOGICAL SKETCH OF THE TERRITORY TO BE WORKED BY THE SHAFTS AND REASON FOR SINKING THEM. The Mammoth or E Vein of the anthracite coal-measures in that part of the Schuylkill region near and north of the town of Pottsville lies at a great depth below the surface, and has, in consequence, never been worked in that locality.

Jan 1, 1873

By Xiyun Yang, Hui Xu, Xichang Shi, Xiang Xiao

"Rod-like magnetite particles were prepared by precipitation of iron salts with urea under the induction of magnetic field. Temperature and initial Fe3+/Fe2+ ratio have a significant effect on the composition of the product. Magnetite particles change from spherical into rod shape in the presence of a 0.35 T magnetic field, The addition of a small amount of spherical seeds increases the rod-like magnetite particles yield. The seeds are prepared by aging ferrous and ferric solution with sodium hydroxide as precipitator. The aspect ratio of the rod is controlled by varying the volume ratio of seed to iron salt.IntroductionMagnetite, an important member of magnetic materials, has attracted a lot of attentions for its super magnetic properties. The rod-like magnetite particles have high anisotropy and coercive force as well as super magnetic properties compared to other shapes, and are widely used as high magnetic density media, magnetic devices and microwave materials [1-4]. Recent studies have found that magnetic field can direct magnetite growing along easy magnetization axis to get one-dimension particles [5-6]. Chen et al. [7] synthesized single crystalline nanorod magnetite under magnetic field. Wang et al. [8] discovered that magnetite grew along easy-magnetization directions under 0.35T magnetic field. Vereda et al. [9-1 O] found that magnetic field had a dramatic effect on the morphology, inducing the aggregates to line along one direction to form rodlike particles.At present, most of the synthesis methods reported in the literature result in a low yield of rod particles and the aspect ratio are difficult to control. Recently, we developed a seed-mediated growth approach to making rod-like particles in an aqueous solution. The spherical magnetite generated by oxidation serves as a seed. These seeds are then added to a solution containing iron salt and urea, and provide nucleation sites for magnetite rod growth."

Jan 1, 2011

By G. Van Esbroeck

THE copper mines of the Katanga region in the Belgian Congo lie along the same mineralized belt as those of Northern Rhodesia. There are two distinct types of deposits in that belt, the dolomitic and the quartzitic. In the dolomitic type the metallic minerals are found in a dolomitic limestone country rock. Through oxidation and enrichment, large deposits of high-grade oxidized copper ores were formed, some of which are being worked by the Union Miniere du Haut Katanga. Such deposits are all in Katanga. The quartzitic deposits are found in Katanga and Northern Rhodesia. Here the primary mineralization occurred in sandstones and quartzites, in horizons stratigraphically lower than the dolomites. These rocks are not favorable to secondary enrichment and the oxidized zone is poorer than the sulphide zone, which alone contains the ore. There are also in Katanga a few ore-bearing veins. One of them is being worked in the Prince Leopold mine at Kipushi.

Jan 1, 1939

By M. Van Weyenbergh, G. Van Esbroeck

THE copper mines of the Katanga region in the Belgian Congo lie along the same mineralized belt as those of Northern Rhodesia. There are two distinct types of deposits in that belt, the dolomitic and the quartzitic. In the dolomitic type the metallic minerals are found in a dolomitic limestone country rock. Through oxidation and enrichment,, large deposits of high-grade oxidized copper ores were formed, some of which are being worked by the Union Miniére du Haut Katanga. Such deposits are all in Katanga. The quartzitic deposits are found in Katanga and Northern Rhodesia. Here the primary mineralization occurred in sandstones and quartzites, in horizons stratigraphically lower than the dolomites. These rocks are not favorable to secondary enrichment and the oxidized zone is poorer than the sulphide zone, which alone contains the ore. There are also in Katanga a few ore-bearing veins. One of them is being worked in the Prince Leopold mine at Kipushi. PRINCE LEOPOLD MINE The Kipushi ore body fills a fault vein and invades the wall rocks more or less extensively by metasomatic replacement. The vein strikes north-northeast and south-southwest and dips to the west. The variable dip averages 60ºto a depth of 300 ft., and more uniformly 80º below 400 ft. In the upper section the average width is 200 ft. and below the width is about 150 ft. The length of the ore body is 2300 feet. The eastern side of the vein-the footwall-is dolomitic and contains irregular masses of ore sometimes extending 100 ft. or more from the main

Jan 1, 1939

By J. G. Phillips

Introduction Throughout the Great Plains region (the provinces of Manitoba, Saskatchewan, and Alberta), numerous clay deposits of widely varying composition and character are to be found. These may be classified into two general types: (1) surface clays, and (2) shales. The surface clays consist of a heterogeneous mantle of silts and clays interspersed with grave! and sand deposits, and may belong to any of the following groups: (1) lake clays: (2) river-terrace or flood-plain deposits; (3) delta deposits . In most cases, the water from which these deposits were ' laid down was derived from the melting ice of the continental glaciers. These surface clays, in general, possess certain characteristics in common, being all more or less calcareous, often silty, and showing a tendency to 'check' in air-drying. The shales found in this region are of Cretaceous and Tertiary age. These deposits have a wide extent, but there is frequently such a heavy covering of drift material that the clays are accessible chiefly along the walls of stream valleys, or along the escarpments of uplands.

Jan 1, 1929

By Josiah Royce

To evaluate chemically the sample of rock obtained by diamond drilling, it has long been recognized that the analyses of the two components of the sample, core and sludge, must be given appropriate influence in computing the average analysis of any unit of depth. The purpose of this investigation is to set forth what means are available for apportioning the effect of core and sludge on the final analysis, what variables affect the problem, and what combination of applied mathematics will closest approximate the truth under each condition as these variables proceed within their limitations. A drill hole is bored in iron ore ex- ploration principally to test variations in rock composition with depth and is usually directed as nearly normal to the bedding of a horizon to be tested as possible. This practice has a tendency to minimize variation in composi- tion laterally which in any event is not likely to be great. It is obvious that the opportunity for change in analysis of a particular rock is not statistically as great radially in a diamond drill hole where the distance in which such a change may occur is from 0.719 in. (EX bit) to 1.469 in. (NX bit) as there would be longitudinally even in a run as short as 5 ft. Variations in composition of bedded or layered rocks are usually greater normal to the bedding than parallel thereto. Even in massive rocks, like porphyries, varia- tions are functions of distance. Hence, in either case, variations along the hole are of greater effect than across it.

Jan 1, 1949

Provide an effective method for "soft" soldering aluminum and aluminum alloys using conventional tin-lead solder alloys and flukes. The Problem In the past, it was virtually impossible to solder aluminum and aluminum alloys using standard tin-lead soldering systems (solder and flux) due to the presence of an aluminum oxide surface film which forms instantly on aluminum and aluminum alloys when these are exposed to air. The tenacious and stable oxide film enables aluminum-base materials to maintain their bright luster. But the film also prevents the required wetting and spreading of solder on the substrate, causing the loss of adhesion between the solder and the substrate. In addition, the heat produced during soldering increases

Jan 1, 1983

By Ruilin Yang

The vector sum peak particle velocity (PPV) of blast vibrations describes the blast vibration intensity more completely than the PPV of a single component waveform. It is more logical to use a vector sum PPV as a vibration limit than using a single component PPV. In 1980 the USBM recommended the frequency related peak particle velocity criterion. So far this method has been only applied to single component waveforms, but not to the vector sum PPV since there is no method available to associate a frequency to the vector sum PPV. The present paper describes a method to define a principal frequency associated with vector sum PPV. The method is based on the weighted average of the principal (zero-crossing) frequencies of the three tri-axial components at the time of the PPV.

Jan 1, 2015

By P Mackenzie, S Askraba

Pyritic black shales present several challenges to mining operations due to their reactivity. The risk of predetonation of explosives in blastholes, spontaneous combustion of fractured rock and the generation of acid rock drainage must be managed for safety, operational and environmental reasons. At the Mt Tom Price iron ore mine there is a need to differentiate between reactive and non-reactive shale in order to assess risk and make decisions on materials handling. The current approach uses a combination of stratigraphic information and sulfur analysis of blasthole samples. The time taken for sulfur analyses can be a constraining factor on mine production. A new instrument developed by ANSTO Minerals overcomes some of the current limitations on material characterisation. The IOR MeterÖ measures the intrinsic oxidation rate (IOR) of samples of broken rock by circulating air through a sample and monitoring the oxygen concentration over time. The intrinsic oxidation rate is given by the rate at which oxygen is consumed per unit mass of sample, in units of kg(oxygen) kg-1(sample) s-1. Up to eight samples can be measured simultaneously and the turn-around time can be less than 12 hours. Initial trials of the IOR MeterÖ were undertaken at the Mt Tom Price mine in July 2004. The measured IOR of samples from a blasthole pattern spanning different geological layers containing black shale, correlated strongly with the expected reactivity of those layers. The correlation between position in the geological sequence (detailed stratigraphy) and IOR MeterÖ results were much stronger than that between stratigraphy and sulfur content. The new characterisation technique offers the prospect of improving the ability to identify and predict the behaviour of reactive black shales and to differentiate more precisely between different materials. Mine planning, operations, safety and environment all stand to benefit from the success of further trials of the technique.

Jan 1, 2005