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By M. J. Latva-Kokko, CA Snyders, J. R. Peltola, M. K. Kostiainen

It is well known that carbon management is essential for minimising soluble gold losses in carbonin- leach (CIL) and carbon-in-pulp (CIP) circuits. Even so, carbon measurements remain predominantly a manual operation with a low amount of control and automation around CIL and CIP reactors. Carbon inventory, i.e. knowing the carbon concentration in each reactor, is crucial for good carbon management. CarbonSense, a novel in-situ measurement system, was therefore developed for continuous monitoring of the carbon concentration in each reactor and paves the way for more advanced control in gold operations. The carbon management and optimisation system is based on Outotec® HSC Sim dynamic process simulations where each process component is modelled in detail. Generated models are validated with real data from a particular operation. The simulator will allow for the carbon control sequence to be realistically tested and the efficiency optimised by controlling the feed and discharge pumps in a hazard- and risk-free process environment. Furthermore, by combining CarbonSense and Outotec® gold courier (online soluble gold measurements) continuous feed-forward and feedback information can be obtained. The optimiser will then define the best running parameters based on the cost function of gold production versus intrinsic factors such as utility costs and adsorption time. Eventually, the application can be installed parallel with a real process island and it can be continuously calibrated with real-time process data. The dynamic model will then create future predictions for the entire process island. The example case presents a CIL circuit, which is simulated using Outotec® HSC Chemistry Sim and operated through Outotec® ACT (Advanced Control Tool) application. Keywords: Carbon-in-leach, CIL, CarbonSense, carbon management, automated control, simulation

Jan 1, 2020

By J K. Claflin, S R. La Brooy

A case study from a current Ausenco project is presented to demonstrate the importance of maintaining high carbon activity to illustrate the driving force for plant improvements such as a carbon regeneration kiln upgrade.This paper revisits the factors that influence carbon activity for gold loading, with emphasis on deactivation by organic solution components such as flotation reagents.Kiln process design requirements for effective thermal regeneration are reviewed including the interaction of parameters such as temperature, kiln atmosphere and residence time.The different types of kilns that have been used for carbon reactivation are described. A check list is provided of what to look for when purchasing a carbon reactivation system for dealing with severely fouled carbon. This covers the ancillary equipment as well as the kiln itself.While the effectiveness of the carbon reactivation kiln is vital to maintenance of high carbon activity it needs to be remembered that this is only the end of pipe solution. It is also important to ensure that reagents such as frothers and flotation collectors are appropriately chosen to maximise recovery and at the same time minimise carbon deactivation.CITATION:La Brooy, S R and Claflin, J K, 2013. Carbon management in a high gold price environment, in Proceedings MetPlant 2013 , pp 455-467 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

Provide an instrument for continuous remote monitoring of carbon monoxide concentration in underground mines. Approach A carbon monoxide fixed? point continuous monitor consists of two modules. A line-powered control module is designed to power a remote transducer module; provide continuous readouts, visual and audible alarms, operational checks; and activate fans and equipment shutdown circuits if preset CO concentration levels are exceeded. How It Works The control module must be used in conjunction with a single transducer module. Developed under contract. the control module is a wall-mounted Instrument which contains a readout and alarm capability and power supply

Jan 1, 1981

By David Burgess, Hershiel H. Hayden

Experiments at the Somerset mine, Colo., under an agreement between US. Steel Corp. and the US. Bureau of Mines are described. A test was made of the tube bundle method of mine air sampling which was developed for European longwall mines; some 300,000 running feet of tubing provided continuous monitoring at 38 locations. Carbon monoxide concentrations were obtained with standard deviations of less than 1 ppm and oxygen concentrations with standard deviations of less than 0.2%. A base level of CO index (ppm CO evolved per percent 0, removed) was determined to be zero to 20 through most of the passageways of the mine. However, in one working section where the coal was initially hot (about 180°F within a pillar) the CO index was demonstrably higher, 120 trending upward to about 60 when smoke appeared and the section was sealed. The data are discussed in terms of laboratory experiments on CO evolution from coals.

Jan 1, 1977

By Pierre Auger, Benoit Levesque, Richard Martel, Guy Sanfacon, Louis-Charles Boutin, Marc-Andre Lavigne, Patrick Brousseau, Luc Trepanier, Louise Galarneau

Explosives used for blasting operations in civil engineering works, like construction of piping systems under roads, of pools, of houses and buildings can generate large volumes of carbon monoxide (CO). Carbon monoxide can represent between 1 to 3% of the gases produced by usual explosives. The production of 10 to 24 1 of CO by kg of explosives blasted is theoretically anticipated. CO is a gas that has no characteristic colour, smell or taste. It can migrate in the fractured rock of the blasted areas on fair distances, and then infiltrate in closed spaces like sewage systems, manholes, but also in basements of houses. In Quebec, in the last 10 years, 7 people were poisoned by CO in their houses to the point that they had to be treated in hyperbaric chambers. In the USA, many accidents have occurred and one worker died in a manhole. From the review of intoxication cases, the distance of migration of CO may reach 55 m if a conduit is present underground. Underground conduits broken by blast, tilling around underground conduits in road or house trenches, or fractured rock created by blasts between houses or between a house and a road, are the different pathways identified in the Quebec incidents. Field tests were performed at sites close to CO intoxication locations in order to evaluate the behaviour of CO in fractured rock following blasting operations. From these tests, the following conclusions may be drawn. The structural geology of the rock formation (schistosity, family of joints, fractures) plays a role in the direction and extent of gas migration in fractures generated when rock is blasted with explosives. The confinement of the rock can affect the quantity of gas migrating in the fractured rock. Significant concentrations of CO may persist in the fractured rock even 7 days after a blast. Advection is the initial mechanism of CO migration in fractured rock generated by the blasts or naturally occurring before the blast. The distance of migration with this mechanism is short (5 to 8 m). In trenches of muck (equivalent to tills under roads) the distance of CO migration by advection is 12 to 20 m. In the 2 to 3 days following the blasts, further CO migration up to 15 m is made by diffusion in the induced fractures, or up to 30 m in the trenches. To minimise CO production and migration in the fractured rock during blasting, special procedures can be applied by the blasting contractors: (1) do the complete excavation of the overburden before drilling and put mats for each blast; (2) do the complete excavation of the muck after each blast; (3) the last blasting should be the one for the private services entrance of the house and the excavation of the muck should begin at the junction between the road trench and the services entrance trench. Another technique consists in the pumping of interstitial air in the muck with a vacuum truck immediately after each blast.

Jan 1, 2002

By Thomas Kovalchuk, Kenneth Eltschlager, William Shuss

In April of 2000, two adults and their newborn infant, were poisoned by carbon monoxide in their home and received medical treatment at a Pennsylvania hospital. Carboxyhemoglobin levels were; child - 3 1%, father - 28Oh, and mother - 17%. Initially the furnace was blamed but after further review, blasting at a nearby coal mine was determined to be the source. All other sources of carbon monoxide were ruled out. The blasting was about 400 feet from the house. The conditions that led to the migration of gas include: the blasts were highly confined, the geologic structure contained fractures that served as conduits for the carbon monoxide to reach a hand-dug well outside the house, and the well was atmospherically connected to the basement floor drains.

Jan 1, 2001

By Nadya Michel, Daniel Gros-Jean

This is a true story. Names have been changed to illustrate the importance and impact of carbon monoxide risk management in explosive blast projects and the community « Honey I’m not feeling good…” “What is going on Michael?” – – Michael was not answering so Julia, who was on the third level of the magnificent house, hurried down the stairs to check up on him in the basement. Today was day 2 of the construction work of the bathroom, yesterday they had excavated all the space for the shower. She started to breathe heavily as she was approaching the bathroom and saw Michael unconscious on the floor. “Michael!” – Julia immediately dialed 911. She opened a window since the air was heavy and went by Michael to hear him breathe and take his pulse. The paramedics took Michael on a stretcher and rushed him to the hospital. “I’m feeling dizzy” she thought to herself a couple of hours after the incident, and heard Matthew say: “Mom, I’m feeling sick”. Suddenly, she felt like she would pass out and felt in danger but couldn’t move. She desperately searched for her cellphone and dialed 911 but couldn’t speak. The dispatcher sent the firefighters and paramedics to the GPS location that was appearing on the screen and the emergency team was alerted that it was a second call in hours at the same address. When the firefighters arrived, they had to force the door to enter and found Julia in her bedroom on the third floor and Anette and Matthew also unconscious in their bedroom, lying on their respective bed. There was no smoke but on their multigas meter, carbon monoxide (CO) peaked at 1500 ppm on every level of the house, which is abnormally high.

Feb 6, 2023

To provide for continuous remote sensing of carbon monoxide (CO) in underground mines. The Approach A transducer module has been developed as a wall-mounted, continuously operating instrument that will measure ambient levels of CO, and produce a signal that is proportional to the concentration.

Jan 1, 1982

By Dilermando Nagle Travessa

High strength-light weight materials are very attractive for the transportation sector, particularly to the aerospace industry. High strength-age hardenable aluminium alloys are widely used in airframes due to their unique combination of strength, density, toughness, corrosion resistance, cost and easy processing. However, the hardening capacity of such alloys is somehow saturated due to thermodynamic issues related to the conventional processing. The production of aluminum-matrix composites is a promising strategy to overcome this limitation, resulting in strength levels that cannot be reached by actual commercial aluminum alloys. In the present work, multiwall carbon nanotubes were used to reinforce the AA6061 aluminium alloy. 1 and 2% weight percent of MWCNT were mixed to the alloy powder by high-energy ball-milling process. The blended powder was consolidated by hot extrusion. The obtained composite bars were submitted to heat treatment for the T6 condition in order to combine both CNT dispersion and precipitation hardening effects. Optical and scanning electron microscopy, as well as hardeness testing, was used to characterize the bars. Typical wrought microstructure, free of defects, was observed on the extruded bars. Hardness of the composites was observed to increase by 20, 28 and 68% for 1% MWCNT 6 h milling, 2% MWCNT 6 h milling and 2% MWCNT 10 h milling, respectively, in the as-extruded condition. The better performance for the composites blended at higher milling time was attributed to a better nanotubes dispersion. Subsequent heat treatment to the T6 condition did not result in additional hardening.

Aug 8, 2018

By T. Yegulalp, M. Castaldi

As global energy demands increase, there will be a critical need to employ fuels that have minimal environmental impacts. While hydrogen is considered the ultimate fuel for that purpose, hydrocarbon based fuels will be in use for a considerable time and will probably be the first major source of hydrogen for next generation power systems. The best fuel for this transition will be natural gas because of the high hydrogen to carbon ratio. Natural gas hydrates have the potential to meet the global energy needs for the foreseeable future. The amount of energy stored in natural gas hydrates is significantly more than that of all the other fossil fuels combined. However, most proposed techniques for recovering the natural gas from the hydrate require too much energy input, raise safety concerns or can only recover a fraction of the gas. This paper discusses the technical feasibility of a novel method of gas production in hydrate reservoirs. The method is an in-situ process that creates a point heat source in the hydrate formation. This method not only significantly reduces the energy input, but also has the potential to sequester as much or more CO2 than would be produced from combustion of the natural gas produced, thus making this in-situ methane production technique virtually carbon neutral. Simulations using FEMLAB™ show that the method offers an energy efficient and environmentally friendly way to produce natural gas from hydrate reservoirs. Preliminary results indicate that it is possible to have an energy efficiency of nearly 90% for land based reservoirs for hydrate loadings of 20%. The simulation results also suggest that alternatives to a point source can be employed which may improve the process efficiency.

Jan 1, 2007

By D G. Rantucci

Organic carbon is a major ore contaminant at MMG’s Century mine. This carbonaceous matter is associated with shale hosted sphalerite mineralisation. It occurs as elongated lamellae and as inclusions in porous sphalerite aggregates which are fine grained and difficult to liberate from sphalerite. The carbon prefloat circuit was designed to remove the liberated organic carbon in order to mitigate excessive reagent consumption, contamination of the lead and zinc concentrates and poor flotation performance in the primary zinc circuit. The consequence of organic carbon removal is that sphalerite and galena minerals are lost to the prefloat concentrate. A Jameson Cell was installed in late 2005 as a prefloat cleaner cell. Operational experience showed that the cell became capacity limited during periods of high amounts of organic carbon in the feed and was subsequently bypassed.Reactive style operating strategies were implemented to manage the effects of insufficient organic carbon removal by the prefloat circuit but due to the relatively large circuit residence time, upstream changes meant hours before the downstream circuits were stabilised following a disturbance from excess carbon.This paper describes the modifications and testwork undertaken to enable the Jameson Cell to be operated during periods of high organic carbon in the float feed and the implementation of process control initiatives to proactively remove the required prefloat mass from the float feed to eliminate the reactive style operating strategy.The process control modifications centred on dynamically targeting a prefloat mass recovery determined by an equation relating the carbon to zinc ratio to the carbon prefloat mass as a percentage of the float feed. The equation was developed by analysing historical data. These improvements served to optimise the prefloat circuit and consequently stabilise the downstream lead and zinc circuits.

Aug 8, 2011

By G. S. Hume

In the transformation of carbonaceous materials, such as peat, to coals of various grades, the changes are known to be both physical and chemical and the grade of coal finally produced depends on the stage to which alteration proceeded. Those changes, which are frequently spoken of as the results of metamorphism, are due to pressure with accompanying heat and, according to the amount of metamorphism to which the sediments with the included carbonaceous beds have been subjected, there is a gradation from peat to anthracite coal, and even to graphite. The improvement in the quality of the coal as a result of metamorphism is due to an increase of the carbon content of the coal and a corresponding loss of the volatile materials. This rise in the quality of the coal according to the degree of metamorphism is well illustrated by the coals of western Canada. In the Plains area, where the deformation and the attendant metamorphism of the sediments is comparatively small, the coals are lignites, whereas in the mountains, where deformation has been severe, the coals are semi-anthracites. Sub-bituminous and bituminous coals occur in the intervening areas. The same general relationship between the quality of the coal and the degree of metamorphism holds true for the Appalachian basin of the United States, where there is a progressive improvement in the quality of the coals from west to east, that is, from an area of comparatively slight metamorphism to an area of marked deformation in the Appalachian Mountain region. But while it is true that this relationship holds in a general way, it has been found that the improvement in the quality of the coal is not always uniformly progressive, and there may be local variations such that an area containing coal with a carbon content indicating low or medium metamorphism may be surrounded by areas in which the coals are of higher grade. These local variations in many cases can be explained, and they in no way detract from the general rule that, in a region exhibiting a progressive betterment in the quality of the coal from an area of low metamorphism to one of more marked deformation, the quality of the coal, i.e., the amount of fixed carbon in the coal, may be taken as an index of the degree of metamorphism of the coal as well as of the sediments in which it occurs, It has been pointed out (') that certain coals, such as cannels, are unreliable indicators of the varying degree of metamorphism because of the nature of the material from which such coal was derived. Such coals, however, are not known in western Canada and their behaviour need not here be discussed.

Jan 1, 1927

By David Reger

THE value of carbon ratios in determining the boundaries of possible oil deposits appears to have passed the hypothetical stage. The theory that the ratio of fixed carbon in pure coals is an, invariable index of incipient metamorphism in both, surface and underground rocks and that it may be applied in defining the limits of petroleum, advanced by David White,1 has been received with keen interest by many petroleum geologists. Detailed isocarb maps have been prepared of the Pennsylvanian area of North Texas and Eastern Oklahoma by M. L. Fuller.2 A similar map of the coal-bearing area of West Virginia is given here. An isocarb3 is a line showing an equal fixed-carbon percentage, pure coal basis; the term has been proposed by David White to supersede a less expressive nomenclature. The term carbon ratio is applied to the percentage of carbon in pure coal after water and ash have been eliminated. As a comparatively small number of analyses have been made on this basis, it is usually necessary to compute the ratio by dividing the fixed carbon of the proximate analysis by the sum of the fixed carbon and volatile matter of the same analysis. Many thousands of proximate analyses have been made by the West Virginia Geological Survey, covering nearly every county in which coal is found. Numerous others have been made by the. U.S. Geological Survey and the U. S. Bureau of Mines, but as uniformity of results is

Jan 2, 1921

This treatise presents the application of the vertical furnace in a carbon regeneration system. Comparison is made to a rotary kiln. The construction, operation and control of the vertical furnace and system components are discussed. Advantages include high efficiency, fuel economy, minimal mechanical apparatus and maintenance, atmospheric and temperature control, ease of operation and reliability.

Jan 1, 1985

By P. J. Stewart, S. Tracy

This presentation describes the operation and features of the WCC Carbon Reactivation Kiln. Particular emphasis is placed on minimizing carbon losses, corrosion resistance, fuel efficiency and the fate of mercury during reactivation in the multiple-tube vertical retort. Detailed laboratory work indicates that there is complete vaporization of mercury in the kiln, no refluxing in the upper sections and distinct advantages in using this type of kiln when sizing collection equipment.

Jan 1, 1993

By Tianzu Yang, Weifeng Liu, Lin Chen, Wei Chen, DUCHAO ZHANG, HUI XIAO

Carbonaceous refractory materials are widely accepted in many reducing smelting processes such as iron and ferroalloys. Oxidizing processes such as copper concentrate smelting traditionally use magnesia and/or alumina/silica refractory materials. The main objection to the use of carbon-based refractories as the exposed working lining in oxidizing applications is the potential for free oxygen to react with the carbon at high temperature, which could rapidly degrade the refractory lining. In 2013, Outotec and GrafTech conducted joint trials of a thermally conductive, carbonaceous lining for smelting copper concentrates in the Outotec® pilot-scale top-submerged-lance (TSL) furnace in Dandenong, Australia. This testwork had two equally important goals; to demonstrate the ability of carbon refractories to withstand oxidizing process conditions, while ensuring that neither furnace operating conditions nor process stability were negatively affected by the refractory material. The paper discusses the input parameters of the trials, key observations during the testwork program, and the results and conclusions from both process and refractory design standpoints.

Jan 1, 2016

By Tom Bruington

This paper discusses the accuracy of determining the quantities of gold and silver on activated carbon in various stages of process for typical precious metals flowsheets. Accurate plant performance evaluation depends upon reliable estimates of carbon and precious metals inventories. The sources of sampling error are identified and methods of reducing them discussed. Several case studies illustrating the sensitivity of flowsheet performance to sampling error are presented.

Jan 1, 1991

By W. Lodge, G. Rasmussen

"The carbon-in-pulp (CIP) process has been the dominant gold recovery technology since the 1980s. During all this time carbon measurement, and control of the carbon transfer pumps has been largely manual in nature. Such manual operation inevitably limits process efficiency, potentially resulting in higher gold solution losses, and higher cost of circuit operation. Based on the authors’ experience, average plant solution loss is in the range of 0.02-0.03 ppm Au, as opposed to the general industry target of 0.01 ppm Au or less. Gekko Systems, in conjunction with Curtin University’s Gold Technology Group, has developed a carbon concentration meter, the ‘Carbon Scout’ meter. The meter automatically measures carbon concentration in all tanks, providing more frequent and more precise data. Combined with SIMCIL, a CIP circuit process model which is used to determine the optimum set points for the circuit, the meter should ensure lower gold solution losses, and more efficient operation of the carbon circuit. This paper will review they critical factors for good carbon management, the development of the meter and results from the first plant installation. Additional benefits of the Carbon Scout, including improved health and safety and the opportunity to measure other key variables in the leach/adsorption circuit from one central location will also be described.INTRODUCTION The carbon-in-pulp (CIP) process was first introduced to the gold industry in the early 1950s at the Carlton Mill in the USA (Fast, 1988), with the modern version of CIP becoming fully developed with large scale installations in South Africa in the late 1970s (Laxen, 1982). CIP quickly became the technology of choice for new operations, and for the retrofitting or upgrading of existing operations. In the 1980s the carbon-in-leach (CIL) circuit configuration became the process design of choice due mainly to its lower capital costs. With 40 years of operational experience, CIP/CIL for gold recovery is now mature a technology, whose operations and limitations are well understood. To extract further efficiencies from such technologies, by improving recoveries and/or reducing operating costs, is challenging and may require new approaches to circuit management. Gekko Systems, in association with the Gold Technology Group at Curtin University, has developed the Carbon Scout, an automated carbon measurement device. This device replaces manual measurement of carbon concentration in carbon adsorption tanks, providing more frequent and more accurate data for control of the CIP process. Data from the Carbon Scout can be used to automatically control the carbon forwarding pumps."

Jan 1, 2018

By S. Zaman, John Bulter, M. E. Defoe, Franklin T. Davis

This section deals with the carbon minerals and materials: graphite, tar sands, gilsonite, and diamond. as well as sulfur and the sulfides of mercury, arsenic, antimony, and bismuth. Table I contains the production figures for each of these commodities in the United States and in the world. Specifications for concentrates are also summarized as are prices for concentrates at the time the section was written. In each chapter an attempt has teen made to describe the more common commercial mineral involved with the commodity, the processes used to recover and concentrate the minerals, as well as geographical areas where these processes are utilized.

Jan 1, 1985

By H. L. Retcofsky

Carbon-13 nuclear magnetic resonance (18CNMR) spectra of nine 2-substituted pyridines, seven 3 -substituted pyridines, and nine 4-substituted pyridines have been obtained and analyzed. Substituents included both electron-releasing groups and electron-with hawing groups. Substituent effects on the magnetic shieldings of the ring carbons, except for those in the 2-positions of 2-substituted pyridines, were found to be quite similar to the effects reported for the monosubstituted benzenes, Thus, at least to a first approximation, the two classes of compounds have similar shielding mechanisms. Shieldings of the carbon atoms in the 5-positions of 2-substituted pyridines and those in the 6-positions of 3-substituted pyridines were found to reflect electron release or withdrawal by substituent groups, The pyridinium cation and the compounds 2,2'-dipyridyl and benzonitrile were also investigated.

Jan 1, 1969