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By Aleksandar D. Bugarski, Robert J. Timko

Despite extensive research efforts conducted in the past decades, occupational health risks associated with exposure to nano and ultrafine aerosols emitted by diesel power equipment are still not completely understood. The complexity of physical and chemical properties of diesel aerosols, constantly changing with the implementation of advanced diesel emissions control technologies, make this task rather challenging. The objective of this paper is to identify and characterize nanometer and ultrafine aerosols emitted by diesel engines in the underground environment and evaluate the effects of selected contemporary control technologies on physical properties, chemical composition, and in-vitro toxicology of diesel aerosols. The physical and chemical properties of the nanometer and ultrafine diesel aerosols are to be characterized through a test series in the NIOSH Lake Lynn Laboratory experimental mine. The crucial part of the study has been development of a facility that allows researchers to generate field results with precision and accuracy characteristics of a laboratory environment. The knowledge obtained from this study should strengthen our understanding of the health implications related to exposure to diesel particulate matter and aid in assessing the potential of various control technologies for reducing this exposure.

By M. Schreiner, J. Brune, D. Theisen, C. S. -J. Tsai

This study reports that routine mining activities could produce a high number of nanometer sized particles which have not been well characterized and may represent an unacknowledged exposure present in the mining environment. A preliminary survey of the particle emission from the feed-leg drilling activity was conducted in the excavations of an experimental mine. The level of particulate exposure was monitored by real time direct reading instruments include a NanoScan scanning mobility particle sizer (measurement range 10-420 nm) and an optical particle sizer (measurement range 0.3-10 μm). Particulate morphological and structural examination was conducted through transmission and scanning electron microscopy and x-ray dispersive analysis of samples collected by a thermophoretic sampler, and a novel nanoparticle sampler. The real time instrument data revealed high concentrations (> 3.5 x 106 particles/cm3) of ultrafine/nanoparticles generated from the drilling activity. Analysis of particle sampler specimens with energy-dispersive x-ray spectroscopy showed a large amount of submicron silica, spherical primary particles and agglomerated soot particles rich in carbon. Exposure to particles in the nanometer size from various sources within the mining environment may be associated with the poorly understood rise in respiratory and systemic disease among miners. INTRODUCTION Exposures to mine dust have been measured and evaluated for decades. Exposures to aerosolized dust such as coal or silica particles can cause lung and other diseases (1-7). One way that The Mine Safety and Health Administration (MSHA) characterizes inhalation exposures within the mining environment is through measuring the respirable dust mass concentration within the breathing zone of workers (8). Respirable particulate matter (RPM) is of great concern due to its ability to deposit in the alveolar region of the lungs (9-10) where it can affect respiratory function. Interventions championed by MSHA have greatly reduced the prevalence of coal workers pneumoconiosis (CWP) and progressive massive fibrosis (PMF). Although great progress has been made, the prevalence of CWP and PMF appears to be trending upwards and the measured increase in prevalence is not elucidated in RPM measurements (11-12). Though the presence and risk associated with ultrafine particles such as emission from diesel engine within the mining environment has been previously established (13-14). There is suspicion within the mining industry that this resurgence of lung disease may be due to very fine particulate matter from various source that is not properly characterized by current sampling methods. Nanometer sized particles, in the range of ultrafine particles, fall within the RPM size range and have been found to deposit in all regions of the respiratory tract (15). Nanoparticles are commonly accepted as particles that are greater than 1 nm in two or three dimensions but smaller than 100 nm (16). Once in the lungs, nanoparticles can enter the blood stream (17) and selectively affect other target organs such as the heart, liver, bone marrow, lymph nodes, spleen, and brain (15,18-19). The size of nanoparticles has been shown to correlate with their translocation behavior on secondary target organs (20-21). There is strong evidence that the clearance mechanisms used to rid the lungs of particulate matter are not as effective on nanometer sized particles, leading to a greater fraction of never-cleared particles which may enhance disease development (20). Research has demonstrated that nanometer sized particles have unique properties (22) whose adverse health impact is greater than what has been found with micrometer sized particles of the same type (23-26). The large ratio of surface area to mass compared to larger particles is believed to make nanoparticles a greater hazard. Utilizing mass to measure these types of exposure will be very difficult to accurately characterize the quantity of

Jan 1, 2019

By H. A. Hamza, N. E. Andersen

Emulsions have long occupied an important position in many industries. In the petroleum industry, where enhanced oil recovery techniques such as steam stimulation, flooding, etc. are being increasingly practiced, emulsions are very frequently produced. Characterization of these emulsions are an important prerequisite for monitoring and evaluation of the recovery processes. Emulsion properties will also determine the type of treatment required to separate and recover the oil phase. A variety of laboratory, pilot-scale and field-generated emulsions were characterized. Coulter technique results for size analysis are compared with microscopy (image analysis) and laser light scattering methods; Coulter determined oil contents are compared with gravimetric and volumetric methods of analysis.

Jan 1, 1980

By Fejes A. J

The U.S. Bureau of Mines installed surface and subsurface instruments at a mine site in Colorado to monitor and characterize the overburden response to longwall mining. Instrumentation included a time-domain reflectometry (TDR) cable, a multiple-point borehole extensometer (MPBX), vertical- deformation surface monuments, and in-mine pressure cells for monitoring abutment, pillar, and gob loads with respect to the longwall face position. The purpose of the study was to collect data that could be analyzed to correlate the design of the mine layout to the resulting overburden failure response. Determining the extent of caving and fracturing is important in the and and semiarid Western United States because of the possible consequences to the fragile underground hydrologic systems upon which the land owners and users depend. This study is unique from past investigations because the overburden contains massive sandstone members that impose special conditions on the caving process and pressure redistribution above the longwall panels. This paper presents the results of this correlation study.

Jan 1, 1992

By Khamis Y. Haramy

The U.S. Bureau of Mines installed surface and subsurface instruments at a mine site in Colorado to monitor and characterize the overburden response to longwall mining. Instrumentation included a time-domain reflectometry (TDR) cable, a multiple-point borehole extensometer (MPBX), vertical-deformation surface monuments, and in-mine pressure cells for monitoring abutment, pillar, and gob loads with respect to the longwall face position. The purpose of the study was to collect data that could be analyzed to correlate the design of the mine layout to the resulting overburden failure response. Determining the extent of caving and fracturing is important in the arid and semiarid Western United States because of the possible consequences to the fragile underground hydrologic systems upon which the land owners and users depend. This study is unique from past investigations because the overburden contains massive sandstone members that impose special conditions on the caving process and pressure redistribution above the longwall panels. This paper presents the results of this correlation study.

Jan 1, 1992

By R. Hogg, T. F. Dumm

A simple shape description scheme has been developed which has the specific aim of distinguishing between angular and more rounded particles. The procedure involves fitting a general polygon (usually about 20 sided) to the particle profile. Geometric shape descriptors have been defined based on variations in the angles between adjacent sides and their radial displacement from the particle centroid. A two-parameter shape description, incorporating an angular variabli1ity and an elongation index, has been shown to be clearly consistent with visual observations. A single-parameter angularity index has been shown to be very sensitive to small differences in particle roundness and seems to provide a better description of angularity than other approaches such as signature and fractal analyses. The scheme has been applied to three sets of fine quartz particles produced by different grinding procedures. The results indicate that the technique is capable of distinguishing between angular and re1atively rounded particles and can quantify their specific shape features.

Jan 1, 1991

By Hall J. S, Zuiderwyk M, Reid A. F

A prototype version of a computer controll- ed on-line scanning electron microscope image analyser, employing the real-time signals ob tamed by digital control of the electron beam has been used to obtain statistical quantificat lion of a wide range of mineral grain character istics, including composition, size distribut- ion, and degree of liberation. These propert lies have been determined for suites of whole particles of flotation concentrates, mounted without further preparation. The facility is also well adapted to the measurement of general Istereological parameters. The computer control software is based on an operating system which includes the device drivers and which is linked to FORTRAN programs [containing the procedural algorithms. The beam scanner provides a 4000 x 4000 point raster swept at a 10 Mhz rate in steps of 1 to 200 points and a set of up to 8 signal channels which respond to electron or energy dispersive X-ray signals to provide a digital attern.characterizing the sample composition. the beam is stepped at high speed until a part- 'cle or phase boundary is encountered; a longer well time is set if X-ray data is required. he digital scanner interrupts the computer

Jan 1, 1977

By Sergio Sanchez-Segado, Yuan Zhang, Animesh Jha, Ahmad Fahmi Ruzaidi

Niobium and tantalum are considered critical materials because the increasing demand in the energy sector which is reliant on limited abundance of these two metals in minerals. Traditionally, niobium and tantalum mineralsare digested using hydrofluoric acid at moderate temperatures, producing oxy-fluorides which are separated by solvent extraction, involving the use ofhazardous chemicals. The increasing environmental pressures are forcing the industry to search for alternative low carbon processing methods. In this paper alkali roasting based separation and beneficiation, which is not well understood in the literature, is proposed, for which the kinetics and thermodynamic equilibria for the formation of sodium tantalate and niobate with sodium hydroxide are analyzedat the temperature range of 400ºC to 700ºC. The apparent activation energy of formation,changes from 31.0±0.8 to 22.3±1.2 kJ mol-1 and from 23.8±1.2 to110.2±12.8 kJ mol-1, for tantalate and niobate, respectively. The reaction mechanism is examined on the basis of the analysis of reaction products using X-ray powder diffraction (XRPD) and X-ray fluorescence (XRF).

Jan 1, 2015

By A. Rojo, N. J. Ramirez, J. E. Salgado

"This work aims to characterize the plastics used in a handgrip located in the car interior body in order to improve its design process and be able to predict its behavior when the part is subjected to impact test involving human casualties.Through stress analyses at high speeds and a video camera set up (front and side view), the reduction of area of specimen was obtained from image analysis, allowing to get the stress-strain real curve of the material.Continuing the characterization process a set of impact test was developed, where standard lzod configurations were used in unnotched specimens. From these tests were gotten displacement curves and absorption energy estimations.The proposed testing procedure allowed the acquisition of force and displacement data through time at various strain rates which are indispensable for the characterization of dynamic events. Using a specimen with a special configuration has shown a more detailed dynamic behavior resulting into more accurate numerical analyses within the design process.IntroductionIn the design process, one of the many analyses which take place is the impact test of the designed part. Nowadays there are many software capable to do these kind of analysis and each industry use the one they think it is convenient for them, but also the selected software has mathematic models that help to find the solution and the simulation of the case of analysis. These are not the only considerations that a company has to take into account, other one is the type of information and data necessary to feed the software. For this study we are going to focus on the acquisition of these data.The mail reason of this work is that generally the supplier gives the card of the material with all the characteristics and information requested by the buyer, but all of that information is acquired by standard methods, but it is inconvenient when the materials are polymers."

Jan 1, 2011

By S. W. Kan, M. G. Kakarkis, J. Zelanco

Grouting has been used in underground mining for more than 20 years. Chemical grouting is often used as a remedial measure when the implemented ground-control program is unable to completely prevent structural failures or when there is a need for preventing a structural member from unraveling. The utilization of polyurethane grout is restricted by its limited range of physical and mechanical properties. To overcome some of the drawbacks of polyurethane, research is being conducted on a newly developed polyester based grout. The polyester resin, identified by Sandvik as Strata Grip, provides a number of features, including variable gel times and a much-reduced chemical hazard. Equally important are the mechanical properties of the product. The strength and deformability of any chemical grout must be compatible with the intended purpose of grouting and the expected deformation of the rock that is to be grouted The assessment of the mechanical properties of polyester grout is the focus of this work. Field experiences and laboratory research defined the properties of an effective grouting material. Experimental results indicate that the polyester grout meets or exceeds the recommended properties for many injection applications. Furthermore, the results suggest that the ability to adjust mechanical properties via resin formulation has the potential to expand the applicability of chemical grouting in ground control.

Jan 1, 1999

By M. G. Karfakis

Grouting has been used in underground mining for more than twenty years. Chemical grouting is often used as a remedial measure when the implemented ground control program is unable to completely prevent structural failures or when there is a need for preventing a structural member from unraveling. Utilization of the polyurethane grout currently being used is restricted by its limited range of physical and mechanical properties that restrict its utilization. To overcome some of the drawbacks of polyurethane, research has been conducted on a newly developed polyester based grout. The polyester resin, identified by Sandvik as StrataGrip, provides a number of features, including variable gel times and much reduced chemical hazard. Equally important are the mechanical properties of the product. The strength and deformability of any chemical grout must be compatible with the intended purpose of grouting and the expected deformation of the rock that is to be grouted. Assessment of the mechanical properties of polyester grout is the focus of this work. Field experiences and laboratory research have defined the properties of an effective grouting material. Experimental results indicate that the polyester grout meets or exceeds the recommended properties for many injection applications. Furthermore, the results suggest that the ability to adjust mechanical properties via resin formulation has the potential to expand the applicability of chemical grouting in ground control.

Jan 1, 1997

By Artur R. P. Junior Sergio, Pedro A. Netto, N. Monteiro, Foluke S. de Assis, Frederico M. Margem

Synthetic fibers are being replaced gradually by natural materials such as lignocellulosic fibers. Compared to synthetic fibers, natural fibers have shown advantages in technical aspects such as environmental and economic. So there is a growing international interest in the use of those fibers. The banana fiber presents significant properties to be studied, but until now few thermal properties on banana fiber as reinforcement of polyester matrix were performed. The present work had as its objective to investigate, by photoacoustic spectroscopy and photothermal techniques the thermal properties of diffusivity, specific heat capacity and conductivity for polyester composites reinforced with banana fibers. In the polyester matrix will be added up to 30% in volume of continuous and aligned banana fibers. These values show that the incorporation of banana fibers in the polyester matrix changes its thermal properties.

Jan 1, 2015

By John Fallavollita

Conventional gas atomization produces powders that vary widely in size distributions and microstructures, thus making it very costly to produce powders tailor made in a narrow size distribution and microstructure. Furthermore, it is difficult to determine the relationships between atomizer operating conditions and resulting powder characteristics. The Impulse Atomization Process (IAP) was developed at the Advanced Materials and Processing Laboratory to produce powders with narrow size distributions. Powders produced by the IAP were reproducible and their sizes could be easily controlled by adjusting experimental conditions. Characteristics of Zn, Sn-Pb, AI-Cu, and Cu powders will be described to illustrate the flexibility of the process to tailor-make powders.

Jan 1, 1994

By L. Béjar-Gómez

The aim of this research work is to study and characterize the precipitates in structural microalloyed steel by transmission electron microscopy and analysis by low resolution. Microalloyed steel with niobium was produced by casting in an electrical induction oven of 25 Kg capacity. Carbon content in steel was less than 0.1 % and 0.036% of niobium. Steel was processed thermomechanically; reheated to 1250 °C and hot rolled on a laboratory mill to a 13.0 mm thick plate with a finish rolling temperature of 900ºC and a thickness reduction of 80% . This work shows what precipitates are present in steel, the type of precipitates and their morphology. Analysis by transmission electron microscopy of low resolution was applied to obtain the chemical analysis of precipitates and the matrix. Spectroscopy of dispersive energy (STEM - EDS) was applied to obtain the element profile of precipitates. Particles of precipitates of NbC were found; with cubic morphology and size from 70 to 130 nm, circular morphology and size from 10 to 70 nm, polygonal morphology and size from 10 to 80 nm.

Jan 1, 2006

By L. Béjar-Gómez

The aim of this research work is to study and characterize precipitates in structural microalloyed steel by transmission electron microscopy and analysis by high resolution (HRTEM). Microalloyed steel with titanium was produced by casting in an electrical induction oven of 25 Kg. capacity. Carbon content in steel was less than 0.1 % and titanium content of 0.04%. Steel was processed thermomechanically; reheated to 1250ºC and hot rolled on a laboratory mill to a 13.0 mm thick plate with a finish rolling temperature of 900ºC and thickness reduction of 80%. Analysis by High Resolution Transmission Electron Microscopy (HRTEM) identified precipitates in the steel; type and morphology. Energy Dispersive Spectroscopy (EDS) analysis was applied to obtain the chemical composition of precipitates and the matrix. STEM-EDS analysis was also applied to obtain the element profile of precipitates. The results showed the presence of carbonitride precipitates of titanium, Ti (CN), with a circular morphology and size of 10 nm and less.

Jan 1, 2006

By Yi Yang, Xiuzhu Su, Wei Sung Ng, Shuiping Zhong, Miao Chen

With over 260 tons of gold reserves, the Shuiyindong gold mine is one of the largest Carlin-type gold deposits in China. A particular challenge in the processing of the ore is the presence of carbonaceous compounds, which can cause substantial losses in recoveries via the preg-robbing and adsorption of gold. To investigate the structural properties of the native carbon and to compare between different characterization techniques for such compounds, pre- and post-flotation mineral samples containing 0.9–4.8% non-carbonate carbon from the Shuiyindong mine have been examined via mineralogical and thermogravimetric approaches, as well as spectroscopic techniques, including X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine edge structure spectroscopy (NEXAFS), solid-state 13C nuclear magnetic resonance (NMR) spectroscopy, diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, Raman spectroscopy and preg-robbing measurements. NEXAFS and DRIFT yielded the most reliable results, indicating that 60–75% of the organic carbon in all samples consist of aliphatic alkenes with substantial unsaturated content, highly similar to activated carbon, with the remainder being graphitic and humic. Speciation by XPS was sub-optimal due to spectral overlaps between graphitic and aliphatic carbon, and between carboxylic and carbonate functionalities, while NMR spectroscopy could not provide reliable speciation of the carbon groups. The preg-robbing strength was strongly correlated to the aliphatic content and structural disorder in the carbon, while no such relationship was found with the graphitic and humic content.

Nov 29, 2021

By Flávia Paulucci Cianga Silvas, Otávio da Fonseca Martins Gomes, Viviane Tavares de Moraes, Denise Crocce Romano Espinosa, Jorge Alberto Soares Tenorio, Guilherme Apostólico Bortolini, Stoyan Gaydardzhiev

"Printed circuit boards (PCB) are particularly problematic to recycle because of the heterogeneous mix of organic materials, metals, and glass fiber. PCBs are found in almost every electroelectronic equipment and their recycling process involves a pre-treatment to separate the products which contain targeted metals. In this work, a physical processing involving sequential shredding and hanuner milling were used to obtain a comminuted sample from scrap printers PCBs. The thus prepared sample was analyzed for particle size distribution and by optical microscopy as well was subjected to pyrolysis, leachabilty and chemical composition determination by XRF. The metals concentration was determined by ICP and AAS. The PCBs have been also analyzed by SEM-EDS (micro-analysis and X-ray mapping). The results show that the studied PCBs are lead free, multilayer with 4 copper layers, have 45% of metals and the copper is present in significantly higher concentration than the rest of the metals.IntroductionThe global generation of e-waste (electrical and electronic equipment waste - WEEEs) grows at a rate of about 40 millions of tons per year [ l].Among this e-waste there are PCBs that are present in almost all electronic equipment. Their composition is heterogeneous and varies according to several factors, including: kind of EEE, when and where it was produced, fabrication technology [2], etc. In printers, the PCBs represent about 6.6- 8 wt.% [3].The PCBs treatment may include physical, pyrometallurgical, hydrometallurgical, ectrometallurgical and more recently bio-hydrometallurgical process. Normally there is a combination between these processes [2, 4, 5, 6, 7, 8, 9, 10].The diversity between the different PCBs composition complicates the recycling process since the composition of metal and others materials can vary according to the models. So characterization is an indispensable step before any processing of PCB to begin. Owing to the above said, the main goal of this work has been set to characterize representative samples of PCBs from printers through physical, chemical and microstructural analyses."

Jan 1, 2014

By M. C. Esposito

Seven pyrite samples purified from coal sources and one ore source pyrite (for comparative purposes) have been characterized by chemical and mineralogical analyses, inherent floatability, apparent specific gravity, surface area, semiconductor type, optical anisotropy, dissolution and oxidation rate. The data clearly demonstrate that pyrites from various coal sources differ not only from ore pyrite but from each other as well.

Jan 1, 1987

By Miguel N. Herrera, Abbas H. Mirza, Fiona M. Doyle

The standard test methods used to determine the pyrite content of coal and mineral wastes, and their propensity to release acidic drainage, are critically reviewed. In addition to analysis of total sulfur by combustion, test methods using selective oxidation of pyrite by HNO3 and H2O2 are available. The oxidation kinetics of pyrite vary appreciably from sample to sample, and it is difficult to ascertain whether complete dissolution has occurred in heterogeneous materials. The reliability, reproducibility and suitability of different standard test methods were studied, using well characterized ore and coal pyrite samples. The kinetics of pyrite dissolution were also investigated. The results are discussed in terms of the fundamental chemical and physical characteristics of each sample, and the implications for waste characterization are considered.

Jan 1, 1992

By A-A. Bogno, Ch. -A. Gandin, A. Maitre, H. Henein

Most metallic materials are produced from their liquid state. In order to control the properties of industrial products, it is very important to understand their solidification path and the resulting microstructures which can be significantly affected by melt undercooling. High undercooling results in rapid solidification and a refined microstructure with minimal microsegregation. This paper reports on the analysis of rapidly solidified Al-Cu droplets obtained by a single fluid atomization process, Impulse Atomization. A quantitative analysis by Rietveld refinement method of the Neutrons Diffraction data was carried out to determine the fraction of the intermetallic Al2Cu. Knowing the fraction of Al2Cu, the eutectic fractions and corresponding dendritic and eutectic undercoolings were estimated using the metastable extensions of solidus and liquidus lines of the Al-Cu system calculated by Thermo-Calc. In addition to this work, a model of microsegregation coupled with ThermoCalc software via TQ (application programming interface of ThermoCalc) and the Wang-Beckerman model for dendritic growth velocities has been developed for binary alloys. This has led to the development of a phenomenological relationship between primary phase undercooling and initial growth velocity. A comparison of estimated primary undercoolings using a coarsening model with the adiabatic undercoolings for each alloy composition has confirmed that solidification occurs under adiabatic conditions during recalescence.

Jan 1, 2014