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By C. Coetzee

Additives are commonly used in copper electrowinning to improve cathode morphology. Polysaccharides such as guar are generally favoured as additives due to their compatibility with solvent extraction. Polyacrylamides are, however, being considered as possible alternatives. Understanding the influence of the structural chemistry of additives on electrowinning performance is critical to utilise them efficiently. This paper investigated polyacrylamide additives which are structurally different; their effects on copper electrodeposition were characterized and compared to that of guar. Electrochemical impedance spectroscopy (EIS) were used to characterize the effects of molecular weight and ionic charge of the polyacrylamides on electrodeposition. The findings were compared against results obtained with an industrially used guar product. Equivalent circuit modelling of EIS data indicated that an increase in polyacrylamide concentration and a decrease in additive molecular weight increased the overall system resistance.

By R. Trottier, B. H. Kaye

Characterizing the structure of such open-structured dusts such as diesel soot and those present in welding fumes plus any other dusts which were initially formed by precipitation or agglomoration of subsidiary units in a flame process has always been a difficult task. Recently, scientists have been able to use the concepts of fractal geometry to model the growth of diesel soot and fume fine particles and characterize their structure using fractal dimensions. The measured fractal dimension of a diesel exhaust at various levels of scrutiny can be used to study the health hazards posed by the soot. Thus, the fractal dimensions of the overall structure can be related to the dynamics of the dust both empirically and theoretically. In this communication, the use of fractal dimensions to describe the structure of smoke and fine particles which pose a respirable hazard are reviewed. Experimental studies linking the measured fractal dimensions of the fine particles to dynamics of the fine particles in respirators and in the lung are outlined.

Jan 1, 1987

By Ashu Garg, Anirban Bhattacharya

"Friction stir spot welding of aluminum alloy AA6061-T6 sheets was performed with circular (plunge depths 0.4 and 0.6 mm), square and triangular tool pin (plunge depth 0.4 mm) with constant 0.2 mm shoulder penetration to characterize various zones of weld nugget. It was observed that the depth of the stir zone formed below the tool pin is comparatively similar for different tool pins but wider for circular tool pin. The size of another stir zone formed at the interface of tool pin and a tool shoulder is observed to be larger for triangular and square tool pin due to the higher swept rate. Predicted strain from finite element analysis, calculated strain rate using Zener-Hollomon relationship and experimentally measured grain size distribution indicates severe amount of plastic deformation in-and-around the nugget/spot region. Finer grains in various stir zones were observed than thermo-mechanically and heat affected zones. Grain size (at distribution peaks) in stir zones varied around 2.54 µm to 3.69 µm for different tool pin profiles as compared to base metal grain size of 20 µm. Microhardness results indicate that the welded region is quite softened than base metal and maximum hardness is mostly observed around the thermo-mechanically affected zone.INTRODUCTION Friction stir spot welding (FSSW) is widely used for joining the sheets of materials like aluminum, copper, magnesium, etc. The process begins by plunging a rotating tool (generally having a pin and a shoulder) into the sheets to be welded. Continuous stirring of the tool and downward plunging force generates localized heat due to friction at the tool-sheet interface and plastic deformation of the sheet metal. The material gets softened and the plasticized material adjacent to the tool pin starts flowing due to the action of tool rotation and tool plunge thereby causing intermixing and bonding between the overlapped sheets. The tool stirring also promotes grain refinement in the weld nugget associated with high strain, strain rate and thermal cycle. The formation of new microstructure also affects the mechanical properties and efficiency of FSSW joints. Studies also showed that the tool pin design and tool shoulder feature exerts a noteworthy influence on the material flow and intermixing during the FSSW process (Reilly et al., 2015; Hirasawa et al., 2010). Sarkar et al. (2016) studied the material flow and intermixing during FSSW using tracer material method and reported that the size and width of flow zone increases with tool penetration depth. The influence of tool rotational speed on microstructure and stir zone temperature was investigated during FSSW of dissimilar AA6061-AA5754 alloys (Gerlich et al., 2007). They reported that the average grain size in stir zone of AA6061 weld increases with increase in tool rotational speed. In another work, Gerlich et al. (2008) studied the local melting and tool slippage during FSSW of Al alloys. Tool slippage was investigated by calculating the strain rate using Zener-Hollomon relation. Garg and Bhattacharya (2017a) studied the effect of dwell time, tool pin profiles and tool rotational speed on shear strength, microstructure, temperature and strain distribution during FSSW of AA6061. In another work, Garg and Bhattacharya (2017b) analyzed the effect of different tool pins and pinless tools on the shear strength and microstructure during similar and dissimilar FSSW of AA6061-T6 and pure Cu. Chang et al. (2004) proposed mathematical relationship between the average grain size and Zener-Hollomon parameter during friction stir processing of Mg alloy. Solhjoo (2010) presented a mathematical approach to determine the critical strain as a function of peak strain required for initiation of dynamic recrystallization in austenitic stainless steel. Fratini and Buffa (2005) also proposed the numerical model to determine the grain size during continuous dynamic recrystallization phenomenon."

Jan 1, 2018

By R. H. Sweetser

THERE are SO many conditions affecting blast-furnace results that it is hard to get satisfactory comparative data on the working of two furnaces, and much more difficult to get comparable results from the use of two entirely different fuels. The several advantages of charcoal over coke as a blast-furnace fuel have doubtless been apparent to many managers; but probably the conditions for comparative tests of the two were never so favorable as during the year 1905, at the works of the Algoma Steel Co., Sault Ste. Marie, Ontario, which comprise two modern blast-furnaces, well equipped, though of comparatively small capacity. For four consecutive months one of these furnaces was run with charcoal and the other with coke. Then the charcoal-furnace ran for a while with part charcoal and part coke; and, still later, with coke only. The ore-mixtures were about the same in the two furnaces, and, of course, all the climatic conditions were identical. The dimensions of the two furnaces, and their work with the different fuels, are given in Table I.

Jan 5, 1908

By B. VISWANATH

T HE Mysore iron works, at Bhadravati, about 2000 ft. above sea level in the Shimoga district of Mysore, British India, is served by a meter gage branch line of the Mysore State Railways. The works which were designed and erected by Perin & Marshall, who still act as consulting engineers, are surrounded by a thickly wooded country which sup- plies about 400 tons per day of wood for fuel. The ore deposits lie 20 miles to the south, and limestone quarries are close by the works. The Bhadra river sup- plies the works and the town with the necessary quantity of water. Dwelling houses for the employees

Jan 1, 1930

By Davi Silva Braga, Alexssander Lopes Sampaio, Rodrigo Carneiro de Oliveira

Vallourec was world pioneer in the deployment, development and consolidation of technology for the use of pulverized charcoal as the main energy source on the first Grate-kiln pelletizing plant in Brazil. The objective of this work was to delve into the subject and to bring more information about this innovative practice of Vallourec that has been attracting the attention of other companies in the steel industry. Industrial tests confirmed the technical feasibility, taking Vallourec ahead in the project of adaptation and investment. With consolidated data of two years and five months from the beginning of the implementation, the main benefits are the average reduction of CO₂e emissions by 50%, cost reduction higher than expected and return on investment in just 19 months.

Oct 1, 2019

By M. Tangstad, B. Monsen, H. Midtgaard, R. Ishak, M. Syvertsen, I. Solheim

Charcoal is an interesting reducing agent because it is produced from growing wood which is renewable and does not contribute to global warming, provided that there is a balance between the felling of timber and growth of trees. In the biocarbon project the possibilities for using charcoal is investigated as well as other biological based and renewable reductants for ferroalloy production. The background for the project is that the Norwegian ferroalloy producers wish to contribute to reduction of CO2- emissions. This paper focuses on the use of charcoal instead of coke for the production of manganese alloys, and the consequences of doing so. Results from practical SiMn smelting experiments on a pilot scale have previously been reported, where only 12-14 % Si in the metal was obtained when charcoal was used. Recently we have attained satisfactory 18 %Si also for charcoal, but good results are indeed dependant on good furnace performance. There is no tradition for using charcoal for manganese production in Norway. A change from using mainly coke to the use of some charcoal will demand new routines for furnace operation, raw material and off-gas handling. Hence, characteristic properties of charcoal, which may cause change of furnace operation, have been measured and are compared to coke. The following results are presented: ?Thermal abrasion strength together with CO2- reactivity; important parameters for the performance of the upper part of the furnace. ?Coke-bed resistance; it will increase with the use of charcoal (a review of new results). ?Slag reactivity; a relevant method for testing slag reactivity of industrial reductants is of interest. The suggested method can serve for comparing slag reactivities towards graphite.

Jan 1, 2007

By Ralph H. Sweetser

AT the end of 1943 the charcoal pig iron capacity of the United States was at the lowest point in over 1110 years, with only one strictly charcoal blast furnace in operation, and all others permanently out of blast except one in Tennessee d reported to he running on part charcoal and part coke. Such a decrease in production has taken place in spite of the O.P A.'s high-premium price on charcoal pig iron of +34 per ton f.o.b. furnace in Michigan. Depletion of the hardwood supply within fifty mlles or inure of the blast furnace is the reason why; the deplorable lack of reforesting is the cause.

Jan 1, 1944

By Roger Holmberg

INTRODUCTION The driving of drifts is a very important aspect of underground mining. It is not unusual for the percent¬age of rock broken during development in a mine using sublevel caving, for example, to be as much as 25% of the total. If one also considers the amount broken for transport, ventilation, and exploration drifts, one can easily understand that the planning and excavation of drifts play a major part in the total economics of the mine (Fig. 1). Increasing mechanization in mining demands larger tunnel areas for transport and mining equipment. With modern machines the hard work involved in using hand¬held pushers is gone, and a better environment is achieved. More rational methods could be used, but much of the experience the working man acquired by working close to the rock face (such as utilizing the natural weak planes in the rock when he placed the drill¬ing holes) has unfortunately been lost. By having sepa¬rate shifts for drilling, loading, and hauling, more atten¬tion has to be placed upon a well-designed drilling pattern. Some reduction in the number of holes required can be achieved with mechanized drilling because of the larger holes that can be produced. On the other hand, it is probably not possible to achieve the same precision as with pneumatic pushers, and it is difficult to utilize the larger holes because these cause more damage to the re¬maining rock. Recently, however, the precision has be¬come very good with the parallel booms and automatic devices for setting the lookout angle (Fig. 2). A larger arch of the drift roof requires a more carefully executed blasting procedure than before in order to prevent rock fall and to insure a sufficiently long stand-up time. In this chapter, empirical relationships that can be used to design an economic and optimal drift blasting design will be presented. The principles of the calcula¬tion method are based upon the earlier work of Langefors and Kihlström (1963) and Gustafsson (1973). COMPARISON OF EXPLOSIVES To provide for the use of various explosives it is necessary to have a basis of comparison. Several meth¬ods have been developed to characterize the strength of an explosive. Some examples are comparison of values given by (1) calculated explosion energies; (2) the ballistic mortar test; (3) the Trauzl lead block test; (4) the brisance test; (5) the weight strength concept; and (6) the underwater test. However, most of these meth¬ods should be used carefully when stating the breaking

Jan 1, 1982

Efficient performance of pulp lifters to discharge ground rock is critical to the effective performance of SAG and AG mills. The paper covers developments in the design of pulp lifters and associated grates, of both conventional straight-radial and curved types, and of the inner discharge cone. Issues covered include the discharge performance of both the slurry and rock components of the discharge, reverse flow back into the mill through open grates and backflow down the pulp lifters of material that fails to discharge from the mill. The design experience is interpreted in the light of developments in particle flow modelling of the flow of charge in pulp lifters.

Jan 1, 2004

By Joshua Hoffman, Braden Lusk, Kyle Perry

Shock tubes are used to simulate large-scale arena explosions without the use of full-scale arena sites that utilize large quantities of explosives. Instead, small explosive charges can be used to drive shock tubes. When this is done, the geometries of the explosive charges can alter the resulting pressure time curve. A common geometry chosen for the explosive charge is a sphere in order to be congruent with the spherical shockwave that emanates symmetrically in three dimensions from the detonation point. This paper reports on the findings from experiments that study the effects of altering the charge geometries and explosive types while keeping the TNT equivalency constant. Peak pressures and durations were affected by these changes. Directional phenomena are exaggerated by the use of certain charge shapes and detonation points. The speed of the detonation front in the explosive being greater than the speed of the shockwave in air played a critical role in the resulting pressure time waveforms. Waveform manipulation can be used to generate job specific waveforms that ultimately benefit the shock tube operators and their clients.

Jan 1, 2010

By D. W. Li

Due to the ultrasonic testing and mechanical wind speed sensor have high requirement for the environmental of the coal mine, the charge induction wind speed detection method based on wavelet analysis is proposed. The same wavelet disturbance detection method is used at a fixed distance to obtain an induction signal to obtain a pass time, and then calculate the magnitude and speed of the wind. Simulation and verification experiments show that the method has application across a wide range of test speeds (up to 60 m/s). The metal probe causes little pipeline flow field interference. The method is particularly well-suited to dusty environment, and does not cause dust deposition through long-term operation. It can be widely used in coal mines for point wind speed continuous online testing.

Aug 1, 2013

By P. A. Mascaró, N. Chacon, A. A. Cecchi

"This document shows the development of a system called the “On-line charge level determination in SAG mills” (abbreviated as Jc). The Jc variable has certainly been difficult to measure due to the relevant number of factors and variables that affect the grinding phenomena inside semi autogenous (SAG) mills. To assess the feasibility stage of the proposed system, it was necessary to carry out two tests in different sized SAG mills, 38´ × 22´ and 36´ × 15´, respectively. In each test, the system was configured with a battery of sensors of the following types: (1) strain gauge, (2) accelerometer, and (3) gyroscope. The first step involved for charge level determinations was to determine kidney foot and shoulder by means of a study of the energy-impacts on shell structures. The second step consisted of correlating the measured grinding operational variables with the actual charge levels obtained from SAG mill crash stops. This system development is extremely useful and relevant for providing approximations about mass balances inside SAG mills. It will be a suitable tool for explaining “tonnes per hour” variations and determining optimal points under various operating conditions.INTRODUCTIONThere has been a growing necessity for technologies capable of obtaining “on-line data” of the main comminution variables in order to increase throughput. Computer systems have taken an important role in providing important solutions by means of processing on-line device signals (commonly referred to as monitoring). In semi autogenous (SAG) milling, there are many examples of monitoring devices that allow the operational staff to obtain detailed information both mechanically and electronically inside a grinding circuit. In this context, a new technology has been developed to obtain “Jc total charge (%) online” in two different SAG mills called Vibro-Energy® System.As part of the analysis performed by JKsimMet® the Jb/Jc was estimated because it has an important impact on SAG mill throughput. Different scenarios were simulated and contrasted at various theoretical Jb/Jc values in a baseline circuit (Figure 1)."

Jan 1, 2016

By J. A. Herbst, Z. Rogovin

In order to develop more accurate procedures for scale-up and design of semi-autogenous grinding mills through detailed mathematical models, a better understanding of the charge motion and rocklball segregation is needed. To achieve this a 0.61 m (2.0 ft) diam by 0.305m (1 .0ft) length plexiglas mill was constructed as a scale model of a commercial SAG mill. Rock motion in the rotating mill was simulated using various sizes of ceramic balls. Quantitative measurements of dynamic angle of repose, water and slurry motion, holdup and size segregation of the charge were taken. In addition, a video presentation (available to the public) was prepared to elucidate charge and water motion at various mill speeds, charge volumes, rocksize distribution, and flow rates.

Jan 1, 1990

By Z. Rogovin

In order to develop more accurate procedures for scale-up and design of semi-autogenous-grinding mills through detailed mathematical models, a better understanding of the charge motion and rock/ball segregation is needed. To achieve this a 0.61 m (2.0 ft) diameter x 0.305 m (1.0 ft) length plexiglas mill was constructed as a scale model of a commercial SAG mill. Rock motion in the rotating mill was simulated using various sizes of ceramic balls. Quantitative measurements of dynamic angle of repose, water and slurry motion, holdup and size segregation of the charge were taken. In addition, a video-presentaiton (available to the public) was prepared to elucidate charge and water motion at various mill speeds, charge volumes, rock size distribution and flow rates.

Jan 1, 1985

By M. S. Duffy

To exploit the mineral resources of fine grained ore bodies the minerals processing industry is turning to fine grinding technology, of which tower milling has become an established part. However, compared to other mills relatively little is known about the operating mechanisms in tower mills. In all milling processes one of the keys to understanding how they work is in knowing how their grinding media move. To investigate the ball motion in tower mills a glass unit was therefore constructed and measurements taken of the movement of the grinding media. This paper describes the results from this study.

Jan 1, 1998

By I. Stavrakas

This work studies the variations of the electric current caused by the application of an electric field on marble samples when they are subjected to continuously increasing mechanical stress at a constant rate up to fracture. The external electric field is applied in a direction perpendicular to the applied mechanical stress. An increase of the level of the electric current was observed when micro-damages started to occur in the samples. The increase of the electric current was approximately 14%. Consequently, the current started to decay abruptly and the sample failed. This electric current recording is compared with the corresponding electric recording without applying the external electric field (Pressure Stimulated Current technique). Both recordings show similar qualitative characteristics. The most obvious of these characteristics are that the electric current starts to develop when microcrack structures start to form due to the externally applied stress. Both recordings show a maximum in the vicinity of fracture.

Jan 1, 2008

By H. Senoh

For the purpose of clarifying the reason caused a drastic decrease of discharge capacity for MmNi3.6Mn0.4Al0.3Co0.7 electrode at relatively low temperatures, various factors influencing the charge-discharge processes were investigated in the temperature range of 25°C to -40°C. The charge efficiency obviously decreased at low temperatures less than 0°C due to a decrease in the rate of the charge-transfer reaction on the electrode surface. Moreover, both the rate of the hydrogen diffusion from the alloy bulk to surface and the rate of the charge-transfer reaction significantly influenced the high-rate dischargeability. The addition of Mo to MmNi3.6Mn0.4Al0.3Co0.7 alloy was found to be effective for improving the electrocatalytic activity, leading to the improvements of the charge efficiency and the high-rate dischargeability at relatively low temperatures.

Jan 1, 2002

CHARGING of an open-hearth heat is begun as soon as possible after the previous heat has been tapped. Ordinarily, about 40 min. is required to drain and dress the furnace hearth, make up the tap hole, and perform routine repairs of the banks. Repairs to the upper back wall and to the front wall and jambs can ordinarily be done while the first scrap charge is being heated and are therefore allowed to wait in order to save furnace time. Any major repairs required on the hearth or other parts of the furnace necessitate longer delays, because such repairs must be made while the furnace is empty. Although charging practice varies considerably in detail with the type and proportions of scrap and iron used, many factors are common to all varieties of' charge. Such general considerations are dealt with first. GENERAL CHARGING PRACTICE Charge materials are discussed in detail in Chapter IV; the present chapter is concerned with the charging, melting, and proportioning of the raw materials in the various types of furnace practice. Charging Equipment and Stock Handling. The physical equipment available for loading and weighing the stock, transporting it to the furnace, and charging it may have a major effect on charging practice. Limestone, scrap, and all other solid melting stock are charged mechanically by means of equipment described in Chapter I (see also Fig. 18, page 33). It is generally desirable to charge the scrap about as fast as the physical volume can be got into the furnace. A limiting factor may be the height to which the scrap may be piled in the furnace without deflecting the flame to such an extent that it will impinge on the roof or walls and thus damage the refractories, but light scrap may often be piled up near the roof since the flame usually "cuts it down" rapidly before impingement on any roof area can persist long enough to do appreciable harm. When the nature of the scrap and the handling facilities are adequate to meet the aim of rapid charging, little thought is given to this feature of operation. Unfortunately, at times

Jan 1, 1944

CHARGING of an open-hearth heat is begun as soon as possible after the previous heat has been tapped. Ordinarily, about 40 min is required to drain and dress the furnace hearth, make up the taphole, and perform routine repairs of the banks. Repairs to the upper back wall and to the front wall and jambs can ordinarily be done while the first scrap charge is being heated and are therefore allowed to wait in order to save furnace time. Any major repairs required on the hearth or other parts of the furnace necessitate longer delays because such repairs must be made while the furnace is empty. Although charging practice varies considerably in detail with the type and proportions of scrap and iron used, many factors are common to all varieties of charge. Such general considerations are dealt with first. CHARGING EQUIPMENT AND STOCK HANDLING The physical equipment available for loading and weighing the stock, transporting it to the furnace, and charging it, may have a major effect on charging practice. Limestone, scrap, and all other solid melting stock are charged mechanically by means of equipment illustrated in Fig 2-1. The charging of hot metal is shown in- the background of this figure. Mechanical equipment and plant layout for stock handling are described in Chapter 1. It is generally desirable to charge the scrap about as fast as the physical volume can be put into the furnace. Charging scrap that is too heavy or adding the charge too rapidly (less than 45 min) may be detrimental to melting rate because of excessive chilling of the entire furnace system and also because of poor conduction of heat to the lower layers in the furnace; but the more common problem is the reverse one of charging light scrap fast enough to maintain a normal heat time. A limiting factor may be the height to which the scrap may he piled in the fur-

Jan 1, 1964