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By Jean-Pierre Birat, François Hanrot, Gérard Danloy

Global warming presents an enormous challenge to the steel industry, which is both carbon-intensive and energy efficient. Lean production can provide some short-term emission mitigation, at the level of the Kyoto requirements. In the middle term, more use of scrap will also help alleviate emissions. But to reach much larger reductions in GHG emissions, on a par with the likely targets that will be set after the Kyoto period, the steel industry will have to imagine new production paradigms, which constitutes its most formidable challenge for the years to come. Carbon capture and sequestration, processes leaner in carbon use, electricity and hydrogen from green sources will have to be added together in a patchwork of process routes, which will have to be developed at great risk in the next decade, hopefully through broad international cooperation.

Jan 1, 2004

By Kanchan Mondal

"Methanol, lower hydrocarbons, CO, and HCOOH formation have been by the reduction of CO2 with H2. Un-catalyzed electro-reduction requires a significant overvoltage. An alternate route has been conceptualized. Production of hydrogen from water can be achieved by chemical oxidation of a metal in water followed by oxidation of the hydronium ion by the released electrons to form hydrogen radical. It is hypothesized that circumventing the problem of the formation of hydrogen molecule is essential while having the hydrogen radical to react with CO2 forming methanol, etc. This may be possible by a bimetallic catalyst acting as a galvanic couple, wherein one metal acts as the electron donor for the production of hydrogen radical while the other acts as a catalyst for the reduction of CO2. This may enhance the reaction rates. The current concept circumvents the need for an external electric field unlike the electrochemical process.IntroductionUtilization of carbon dioxide as a raw material, not only as carbon sources but also as useful chemical feedstock is a more holistic approach to reduce air pollution by flue gases (1-3). Several methods have been proposed to maintain the concentration of atmospheric CO2 or to reduce and recycle it. One of these is the chemical fixations using catalysts. The conversion of CO2 to methanol by hydrogenation over copper containing catalysts is one of the most widely studied subjects in this area. The limitation in this reaction is the low conversion of CO2."

Jan 1, 2008

By Dolf Gielen

This paper discusses the results of a Western European energy and materials systems engineering study that analyses the impact of greenhouse gas (GHG) emission reduction on the future of the steel and aluminum industry. he technology selection will be significantly affected by future CO2 policies. The avail- ability of C02 removal and storage technology and the social acceptance of this strategy for GHG emission reduction is of key importance for the strategy selection. The use of coal based smelting reduction technologies is optimal in case of weak C02 policies or in case of strong C02 policies and low CO2 removal and storage costs. The selection of CCF or Corex technology depends on the penalty regime. However, if C02 removal proves to be problematic, CCF development fails and strong C02 policies are introduced, the gas based DRI production processes will become more attractive. In both cases, the energy efficiency of the iron and steel industry will further increase in the next decades. The impact of GHG emission reduction on aluminum prices and aluminum use can be significant. However contrary to common notions the aluminum production will be positively affected by GHG emission reduction, notwithstanding the currently high emissions in aluminum production. A combination of emission mitigation in production and significant GHG emission reduction effects further down the product chain cause this effect. A significant potential exists for improved materials efficiency. This potential is generally neglected in energy efficiency and CO2 reduction studies. However improved steel qualities are of similar importance for C02 emission reduction as increased energy efficiency. It remains to see if this potential will be used to its full extent in the next decades. Model calculations indicate that the impact of C02 policies on the competition with other materials will be limited. Greenhouse gas emission mitigation will have much more impact on materials production and waste handling than on materials consumption.

Jan 1, 1999

By M. K. Patel, K. A. Pericleous, M. Molaei

"The future trading of carbon credits and increased financial cost necessitates substantial cuts in incidental C02 emissions in the production of metals (iron, steel, aluminum, zinc, lead). Although greener methods of production are being developed, in the short term the use of point-source C02 extraction using existing technology remains attractive. Accelerated natural carbonation, in a fluidized bed is a feasible technological route investigated in this research. CFD modelling has been used to study the efficiency of C02 capture in a fluidized bed reactor containing a CaO solid sorbent. A Lagrangian/Eulerian scheme describes describe CaO particle trajectories and exchange of mass, momentum and energy with the carrier gas, with a typical off-gas composition. Different reactor geometries are considered (with uniform, stepped and gradually expanding cross-section), to maximize conversion for a given particle loading and size distribution (100-200 microns). Removal efficiencies of up to 80% are demonstrated, making this a viable process.IntroductionBased on Intergovernmental Panel on Climate Change (IPCC) reports, the major cause of climate change and global warming is due to a high level of C02 concentration in the atmosphere resulting from fossil fuel combustion, particularly in coal-fired power plants [1]. Carbon capture and storage is therefore the most important action proposed to reduce C02 from combustion flue gases. In this process, carbon dioxide is captured and may then be regenerated as pure C02 and conducted to a permanent storage, or simply stored as a solid carbonate [2]. Capture and storage of C02 has an economic penalty and the main cost of this penalty is associated with the capture plant. Capturing C02 with a lime-based solid sorbent (CaO) is a very promising technique, due to the low cost and the wide availability of the reactant. In this process, the CaO reacts with C02 based on the following reaction in a reactor called a Carbonator:"

Jan 1, 2012

By G. M. Bond

Reduction of the emissions of greenhouse gases, such as CO,, is currently the subject of extensive research. A novel strategy is put forward here, based on a biomimetic approach providing accelerated deposition into carbonate form for long-term sequestration. It offers the advantages of a process that: does not require concentration of CO, from flue gases; could potentially be used in an on-site scrubber to provide a plant-by-plant solution to reducing CO, emissions; is an environmentally benign procss with an environmentally benign product; and is based on readily available, low-cost reagents (except perhaps the catalyst).

Jan 1, 1999

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By R. E. Whitehead

"The earliest gold-mining operations in Ontario included the Cordova, Deloro, and Sophia mines north of Lake Ontario (see for example, Miller and Knight, 1914). The Cordova deposit, worked intermittently between 1891 and 1940, is reported to have yielded 22 774 oz of gold from 127 670 tons of ore averaging 0.19 oz/ton Au (Gordon et al., 1979). The property remained inactive for many years. In 1988, Gunnar Gold Inc. and Mill City Gold Inc. conducted a drilling program along the main Cordova vein. The present study is based on core from three drill holes through the Cordova gabbro (Fig. 1) and the carbonate alteration zones enveloping the quartz-carbonate veins. The relatively narrow width of the alteration zone and the availability of continuous sections of core provided an opportunity to conduct a compact mineralogical-chemical study of carbonate alteration and its effect on the redistribution of rare earth elements (REEs). Although the Cordova deposit is not of great economic importance, this study has revealed a number of interesting features which are interpreted as resulting from processes that may be applicable to gold-bearing quartz vein deposits elsewhere.The Cordova gabbro is layered in places, varying from fine-to coarse-grained and in color from light gray (feldspathic) to dark gray-green (amphibolitic). However, layering within the section of the gabbro considered here and which hosts the Cordova gold deposit is mainly textural rather than compositional. Samples of unaltered gabbro selected for analyses were medium- to coarse-grained; amphibolitic and anorthositic phases were avoided as being less representative of the general chemical composition of the gabbro.The Cordova intrusion has undergone regional metamorphism and consists dominantly of actinolite and saussuritized plagioclase with smaller amounts of granular clinozoisite and flaky chlorite; minor quartz, ilmenite, titanite, apatite, and calcite are typically present. Some actinolite grains have irregular rims of pleochroic green hornblende that is optically continuous with the actinolite. Both chlorite and clinozoisite occur in two modes. Chlorite occurs as an alteration product of actinolite and as separate grains in the groundmass. Clinozoisite and albite occur together as regional metamorphic alteration products of original plagioclase crystals and as discrete grains in the matrix.The main gold-bearing quartz-carbonate occurrence occupies an easterly trending, steeply southward-dipping carbonatized shear zone up to 15 m wide and 700 m long. The gold occurs principally in irregular lenses and veins of quartz-carbonate up to a foot thick occupying the lower part of the schistose shear zone within the gabbro. This zone consists of chlorite, biotite, and carbonate and is flanked on both sides by chlorite-carbonate schist lacking biotite. The chlorite-carbonate schist in turn grades into regionally metamorphosed actinolite-bearing undeformed gabbro.The dominant sulfide within the quartz-carbonate lenses and in the surrounding schist is pyrite which occurs mainly as small cubes (1 mm to 2 mm) generally making up less than 10% of the rock. Rare blebs of chalcopyrite are present. Magnetite is common throughout the schist."

Jan 1, 2001

By B Hooper

Deep cuts in CO2 emissions will be required to stabilise and, in the long term, decrease CO2 concentrations in the atmosphere. Technologies for capturing CO2 from major stationary sources (power stations, industrial plants, etc) and storing that CO2 for long periods of time is one of few near term options for decreasing CO2 emissions. This transition to low carbon intensity energy and possibly the hydrogen economy through renewables and in the long-term technological developments such as artificial photosynthesis.Capture of CO2 from post combustion emissions can be done using a range of technologies though costs are currently high and dependent on the concentration of CO2 in the emissions. Techniques include solvents, pressure swing adsorption and the use of membranes. Options for decreasing capture costs by increasing the concentration of CO2 in the emission stream include the use of oxyfuels (in pulverized fuel types boilers) and by moving to integrated gasification combined cycle (IGCC) operations either simply for power generation or for poly-generation opportunities. Once the CO2 has been captured it can be stored using a variety of methods. Storage in the ocean has been suggested but is considered an unlikely option because of environmental uncertainties and political opposition. Mineral storage is a niche opportunity. The greatest potential lies in geological storage of CO2 and this option is commanding increased attention from the Australian and international community.In Australia, the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) is an important new initiative that will support energy companies and energy intensive industries in meeting challenges posed by greenhouse gas issues and assist them in their efforts to reduce their emissions profile.The progress of geo-sequestration and the challenges in the capture and separation of CO2 in the process industries are discussed.

Jan 1, 2004

Coagulation-Neutralisation Technology to Treat Wastewater from Lead-Zinc Concentrator

Sep 13, 2010

By Price E. R.

The coal industry was beset with work stoppages and strikes throughout the year, and there was some loss in markets to oil and gas. These conditions, along with the mild decline in industrial activity, the steel strike, and the reduction in exports, contributed to an unfavorable year for the industry. All coal mines are working three days a week at the time of writing, and in estimating production for the year, it will be assumed that the mines will continue to work on that basis through December. Total production of bituminous coal in 1949 is estimated at 420 million tons, which is 179,518,229 tons under the production in 1948. Anthracite production is expected to reach 39,400,000 tons as compared with 57,139,948 tolls in 1948, a loss of 17,739,948 tons. Coal stocks, as of January 1, 1949, were 69,373,000 tons but at the end of the year will have dropped to approximately 22 million tons. Regardless of the difficulties during the current year, the industry has made substantial

Jan 1, 1950

By F. Freme

Coal production in the United States increased in2004 by 36 Mt (39.7 million st) to end the year at 1 Gt(1.11 billion st), according to the U.S. Energy Information Administration (EIA). This was a 3.7-percent in-crease from 2003’s 971.6 Mt (1.07 billion st) (Table 1).(All percentage change calculations are done at the short-tons level.) Although U.S. coal consumption rose in 2004, not all coal-consuming sectors had increased consumption for the year. Coal consumption increased in the electric power sectors by 1 percent and declined slightly in the other industrial sector, while coking coal consumption dropped by 2.4 percent. U.S. coal exports rose for the second consecutive year, while coal imports again increased to record levels. Coal stocks declined during the year, as electric generators used their stockpiles to helpmeet increased demands and missed shipments. Coal producers used their stockpiles to supplement their production levels.

Jan 1, 2005

By D. R. Mitchell

Accent is on mechanization, more preparation plants - Competition from other fuels remains biggest problem.

Jan 2, 1953

The North American Coal Corp. Increasing demand for coal, stimulated by the national energy shortage, and complicating and often conflicting, demands by government and ecology groups for better land reclamation methods continued to propel advances in surface mining technology during 1974. To meet current demands for coal (estimated at more than 700 million t for 1975 and 1.5 billion t in 19851, equipment manufacturers and coal operators concentrated on increasing the productivity of all surface mining equipment. The trend towards larger equipment, particularly in overburden removal, loading, and haulage machinery, prevailed during the year, notwithstanding the perennial debate over the economics and practicality of using large, inflexible equipment. Increasingly, the industry called on computers to monitor productivity and help design more efficient production systems

Jan 2, 1975

By C. F. Hardy, D. R. Mitchell

Bolts held up roofs as mining machines went on to set new records, but rising labor costs still plagued operators.

Jan 2, 1951

By George R. Eadie

As 1972 slipped through our grasp, coal industry adjustments to health and safety laws, environmental restrictions, rising costs and higher production targets left many mine operators groping for a new grip. The industry adopted a defensive attitude in 1972 as it faced the onslaught of inspectors. With rigid demands for improving safety and instituting environmental programs, the industry worked hard and watched production figures stagger upward while operating costs zoomed. In an effort to determine how to meet the goals that were established for fewer ignitions, fewer accidents, less respirable dust, lower noise levels, fewer law violations, better reclamation, less pollution, lower costs and higher production, industry representatives attended numerous technical meetings.

Jan 2, 1973

By Marke Wong

? Vietnam?s economy is growing so fast that gross domestic product (GDP) growth remained above 8% in 2005 and exports are rising steadily at 25% per year. ? Demand for electricity is expected to increase 18% per year through 2010 requiring an additional estimated 7,547 MW before 2010 ? Domestic coal demand is expected to be over 45 Mt by 2010. ? The Quang Ninhcoal deposits are estimated at 6.5-7 billion tons (350m) Vietnam News Agency. Saturday, May, 6, 2006. ? National resources are now estimated at 10 billion tonnes; not including a relative new coal bed discovery estimated at 210 billion tonnesin the Red River Basin.

May 1, 2006

With the dawning of a new century came the beginning of a new era in the coal industry. Instead of the traditional practice of only buying and selling produced coal in the United States, a coal futures market was established. The New York Mercantile Exchange began trading coal futures in July 2001. But, even in this new era, many of the old is-sues that have beset the coal industry still remain, as was evident in2001. Coal production increased to are cord level during 2001, according to preliminary data from the US Energy Information Administration(EIA). Production in 2001 rose by4% to 1.01 Gt (1.12 billion st), compared with 2000 (Table 1). This barely surpassed the previous record level of 1 Gt (1.11 billion st)set in 1998. Coal consumption remained unchanged. The additional production was used to replenish the depleted stockpiles that had resulted after two years of declining coal production and increasing coal consumption.

Jan 1, 2002

By Suresh P. Babu, Joseph W. Leonard, Richard Muter, D. P. Sen

OUTLOOK FOR COAL UTILIZATION In 1975, about 650 million tons of bituminous coal and lignite mined in the United States was used to meet 55% of the primary energy input for electric power generation and 26% of the total industrial consumption.1 Even though this amounts to only 21% of the total energy requirements, it is believed that with the declining natural gas resources and uncertainty of liquid fuel imports, coal will assume a more dominant role in suppplying our future energy needs. A regional breakdown of the coal reserves of the United States along with their characteristics is shown in Table I. At present the United Stares Energy Research and Development Administration (ERDA) and the US Bureau of Mines (USBM) are financing extensive research programs in advanced mining methods and energy conversion processes. The increased demand for wal which may result from these research programs may also create large-scale environmental protection problems. As more and more coal is mined the production of undesirable coal fines and dust also increases proportionally. The USBM and the Environmental Protection Agency (EPA) research in this field includes development in the areas of instrumentation for qualitative and quantitative analysis of wal dust, protective devices, and dust collectors. Dust control by water sprays, steam, and foam are also being investigated. Other aspects of safety in mining include developing methane drainage techniques prior to coal mining, fire and explosion prevention, and neutralization and disposal of acid mine waters. It is the belief of coal technologists that when the emphasis shifts to coal as the primary source of energy. the existing methods of mining and preparation of coal must be improved considerably to supply large quantities of quality coal for energy conversion. It is the objective of the present large-scale research financed by ERDA to produce substitute fuels from coal. Large-scale gasification pilot plants are being constructed by Bituminous Coal Research, Consolidation Coal Co., Institute of Gas Technology, and the Pittsburgh Energy Research Center to produce coal gas of natural gas standards at 1,000 psig. The processes being adopted by these pilot plants are oriented towards recovering most of the sulfur from coal by absorbing H2S and its subsequent conversion to elemental sulfur. The environmental protection standards will be strictly followed in using the results of these pilot plants to construct large-scale coal gasification plants in the latter part of the 1970's. With the increasing awareness of the need for air pollution control, considerable research is being done to minimize sulfur dioxide emission from thermal power plants. Utilization of limestone and dolomite scrubbing systems and caustic treatment of stack gases have proved to reduce sulfur and nitric oxide emissions by about 90 to 96%.3 Currently, about 22 scrubbers are in use in the United States to reduce sulfur in stack gas emission. In the long-term, it appears that optimal combinations will be developed involving both advanced coal preparation technology and wet scrubbing. The sulfur compounds are converted either to elemental sulfur of sulfuric acid. Besides the sulfur compounds, the major byproduct of the coal utilization industry is the large amount of coal ash. The Coal Research Bureau at West Virginia University has developed a practical use for coal ash as a structural material. The coal industry will undergo revolutionary changes when coal becomes the primary source of energy. New coal mining and preparation processes will be introduced to meet the ever-increasing per capita energy requirements. 2. BENEFICATION Introduction Coal preparation, like the beneficiation of ores, is also aimed at the separation of values from associated waste. Even though the unit operations involved when enriching ores and coal are similar, there are certain characteristics unique to coal preparation. Unlike the scattered and concentrated veins of underground minera1 ores, coal is distributed uniformly and very much in abundance in the coal mines. Coal occurs as the metamorphosed sedimentary deposits of vegetable matter, while metal and mineral deposits occur in great varieties of forms, structures, and origin-from igneous to sedimentary and metamorphic. The mined coal, being much more friable than mineral ores, is subjected to less intensive size reduction operations. Ores are usually ground to a very fine size for subsequent concentration, while coal is crushed to a coarser size, since considerably less liberation is needed to achieve the desired degree of separation. Since mineral matter is to a great extent discretely distributed in coal, concentration is mainly achieved by taking advantage of differences in specific gravity between clean coal and associated waste. In general, about 90% of coal is concentrated using specific gravity separation and about 10% by froth flotation. In contrast, these operations are frequently reversed in the beneficiation of ores. In coal preparation almost all fractions separated during various stages are made use of. while large amounts of gangue material are rejected in the concentration of ores. Hence, coal generally has a much lower ratio of concentration than ores. Since ore deposits are frequently more variable and mineralogically complex than coal, beneficiation of ore may require more plant flexibility and point-to-point quality control. This characteristic difference between the mineral ores and coal is attributed to the generally used one-step processing in coal as compared to the multiple-step processing of ores. Dewatering to enhance the energy content of coal is usually considered a major unit operation. Even though thickening and filtration are common for dewatering ore concentrates and cleaned coal, vibrating centrifuges and disk filters find unique application in the coal industry for achieving these types of solid-fluid separation. In coal preparation, thermal drying is carried out in separate units at the mine. While ore concentrates are usually dried at the smelter. Although the drying of ores is seldom considered dangerous, volatile matter and combustible dust are reasons why the thermal drying of coal can be hazardous. Open air storage of ores and mined coal results in partial oxidation. Unlike the oxidation of ores, the oxidation of the pyritic and carbonaceous constituents of coal together with the heat of condensation of moisture contribute to spontaneous heating and the subsequent combustion of coal in storage. Among the other significant difference between concentration of ores and coal are the weight and capacity of processing equipment. Coal processing employs less cumbersome, higher capacity units while the beneficiation of ores usually requires much more massive and frequently lower capacity equipment. Properties of Coal Which Influence Design The widely varying and heterogeneous composition of coal, due to metamorphism, determines the preparation design and uses of the resulting products. Petrography serves as a useful system of classification to identify the coal types present and their distribution. Early

Jan 1, 1985

By H. W. Ahrenholz

Seven weeks of 1971 were devoted to a nationwide coal walkout resulting in lost production of some 70 million tons and leaving 1971 coal production at about 550 million tons. Compounding the problem, consumption of coal in 1971 by electric utilities rose by about 5% to 336 million tons. In the mean- time, numerous contracts were awarded for coal R&D including $24.8 million given by the Office of Coal Research to Bituminous Coal Research for the construction of a coal-to-gas pilot plant using the BIGAS process. Exports declined mainly due to Japan's decrease in steel production and to that country's increase in coal imports from Canada and Australia. The advances in equipment design and mining procedures made 1971 a noteworthy year. Introduction of the variable pitch I dipper, the trend toward wheeled vehicles, the greater use of scrapers in reclamation and battery-operated vehicles and oscil-mining, and the increased activity in the areas of ventilation and dust control were given widespread approval. There were also strides made in computerization, longwall mining, roof bolting, rock dusting, mine haulage and methane detection.

Jan 2, 1972

By B. Tönjes

In the course of the last decade, the concept of sustainability has turned from a catchword into a vision - a vision to which politics and industry feel increasingly committed. In terms of the energy industry, the key criteria for sustainable development are supply security, economic efficiency and social responsibility. Coal is able to meet all these criteria if it is produced in conformity with high safety standards through the use of modern mining technology and converted into electricity with the aid of environmentally friendly methods. Among the fossil energy resources, coal will, according to the vast majority of global energy scenarios, continue to be the most important input energy in power generation for the foreseeable future. Coal is therefore today, and will in future continue to be, an important element in ensuring sustainable energy and raw material supply, worldwide, in Europe and also in Germany.

Jan 1, 2005