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A knowledge of the mechanics of wave propagation through the earth is essential if reliable communication systems are to be designed for coal mine environments. To obtain a reliable basis from which accurate propagation predictions could be drawn, a series of theoretical studies have been prepared for the US Bureau of Mines by Mr. Ramsay Decker of Spectra Associates, Inc. through a subcontract with Collins Radio Group. These reports formulate the analytical techniques from which we may derive frequencies and antenna configurations that yield the optimum signal-to-noise ratios over the greatest distances in mine environments. The reports of sections 2 and 4 deal with analytical techniques for determining the signal-to- noise ratio within a mine environment for loop-to-loop and line source-to-loop antenna con- figurations. The analytical results of these reports were then implemented into computer programs to obtain predictions concerning through-the-earth signal propagation. These preliminary predictions are based on noise data compiled by Bensema, Maxwell and Stone, and WVU prior to the extensive research conducted by the National Bureau of Standards (NBS). These initial measurements indicated a 20- to 30-dB lower noise level than that measured recently by NBS. The recent NBS data is that used by Collins in the final predictions. The following outline indicates the order and subject matter treated in the subsequent sections: Section 2 - Signal-to-Noise Analysis for Loop-to-Loop Mine Communications Section 3 - The Horizontal Electric Dipole Section 4 - Signal-to-Noise Analysis for Down-Link Line Source Mine Communications Section 5 - LF Communication Section 6 - The Application of Recent NBS Noise Data to Mine Communications Section 7 - Analysis of Mine Communication Propagation Programs

Nov 15, 1974

This report summarizes the results of several field tests conducted by Collins for the Bureau of Mines under contract SO122076 and contract H0232056. The field projects represent a part of Collins continuing effort on a broad study of coal mine communications. These experiments analyze the propagation characteristics of radio signals in a working coal mine environment. The intent of the program is to provide basic propagation loss characteristics by which we may evaluate various approaches to an integrated mine communications system. The goal of such a system is to satisfy both operational and emergency communications needs in the mine. Field testing was conducted during the last week of November 1972, at a coal mine operated by Inland Steel Company, near Sesser, Ill, and in the Robena No. 1 Mine, Waynesburg, Pa, on 12 March 1974. The tests included uhf propagation losses and noise (200 MHz to 1 GHz) in the Sesser, I11 mine location and vlf propagation loss and noise (1 to 200 kHz) in both of the above locations. The basic experimental parameters were frequency, polarization, antenna type/orientation, and distance. The following reports treat the various aspects of the test programs in detail. Since different antenna configurations were used in the two mines, each report contains its own experimental predictions drawn from its corresponding test activities. A test equipment list and block diagrams of typical experimental setups for the tests of section 2 are contained in appendix A.

Jan 1, 1974

This report is a compilation of all information obtained in accordance with the requirements of contracts SO122076 and H0232056. A series of eight coal mines were visited to determine their communications usage and requirements. Presently available equipment was surveyed and evaluated to determine its applicability to the needs of the mines. The equipment studied includes that made by the following companies : Anaconda Telecommunications Division Andrew Antenna Bendix Communications Division Collins Radio Group of Rockwell International Executone Communication and Sound Systems Gau-tronics Mine Safety Appliances Company Motorola Communications and Electronics, Inc National Mine Service Company Plessey Communications Systems Corp Pye Electronics Limited Reach Electronics Set Com Corporation Sonex Incorporated Mine visits and in-depth interviews were made alt the following sites: Robena No. 4, Pennsylvania Greenwich Colliery Mines, Pennsylvania Somerset Coal Mine, Colorado Keystone No. 1, West Virginia Harris Mine No. 1, West Virginia Baldwin Underground No. 1 Mine, Illinois Lovilia No. 4 Coal Mine, Iowa Orient No. 3 Coal Mine, Illinois

Nov 15, 1974

A working understanding of present coal mine communications equipment and its usage is an essential prerequisite to the determination of future communications systems needs. As a means of gaining this understanding, a field survey program was planned and implemented. The plan formulated called for obtaining both qualitative and quantitative data from three main areas of interest: the types, physical condition, and performance characteristics of equipment presently used in the sample of mines to be visited; the relationship present communications has to safety and productivity; and the practical, future communications needs as de- rived through interviews with present mine management. In compliance with the original plan, the type and physical condition of equipment in use was found through at-mine interviews of personnel responsible for installation and maintenance. Further evaluation was made through the review of equipment instruction books and maintenance manuals and through in-mine inspection of communications equipment and signal distribution networks. The performance characteristics were determined through listening to conversations and noise levels and by talk-testing from randomly selected stations throughout each mine. System operation was evaluated by asking communication system users their opinions and by noting any difficulties personnel had using the systems. Plans in the second area of interest--that of relating communications to mining operations-- were to observe mining operations and usage of communications; to gain insight through interviews with mine management, from mine superintendents to section foreman; and to look for correlation between communications, production, and safety. Lastly the communication systems needs and requirements were determined from first hand interviews of mine personnel, from the analysis that lead to the individual reports on the eight mines, and from an overview of all of the mines studied. The latter was done to find commonality between the needs of the individual mines such that system requirements having the greatest universal value could be derived, thus lowering per-mine cost of equipment through economics of scale. Armed with tape recorders, backgrounds in communications technology, and with an interview questionnaire that was improved as experience was gained, engineers visited the eight mines to obtain the raw data from which the needs and requirements could be developed through analysis. During the first part of the program two days were spent at each mine so that interviews and tours could be completed, and so that full eight hour shift phone usage recordings could be obtained for statistical analysis. One day visits were sufficient for those trips where tape recordings were not made. During the later trips less attention was given to the statistical nature of communications, and more to how communications relates to the total mining operation.

Nov 15, 1974

By K. Eckert, A. E. Sommer, S. Heitkam

One highly relevant challenge in flotation is the recovery of fine particles. Due to their low inertia, these particles are mostly pushed aside by rising bubbles. Consequently, they typically exhibit low probability for bubble-particle collision and thus, a poor recovery rate. In this work, the trajectories of fine particles in the vicinity of rising bubbles were investigated. The measurements considered a chain of millimetric bubbles in a rectangular container filled with deionized water. The flow field near the bubbles was measured by tomographic particle image velocimetry (TPIV), employing fluorescent tracer particles of 33μm diameter. Subsequently, trajectories of larger particles and bubble-particle collision events are recorded with 4D particle tracking velocimetry using a high temporal and spatial resolution. The results reproduce the well-known collision of particles on the leading edge of a rising bubble. Additionally, collisions on the tailing edge were observed in cases with a low Stokes number. The TPIV results demonstrate, that the high turbulent kinetic energy in the bubble wake allows particles to divert from the fluid streamlines and collide with the tailing edge of the bubble. The tailing edge collision probability increases with the bubble Reynolds number and decreased particle inertia. Overall, the investigation shows that the collision of fine particles in the bubble wake should be considered for the development of further collision probability models. Furthermore, the importance of turbulence on the fine particle flotation was demonstrated. Keywords: 4D Particle tracking velocimetry (PTV), tomographic particle image velocimetry (TPIV), fine particle flotation, collision probability, bubble-particle interaction, wake induced collision

Jan 1, 2020

It is well established that the results of emulsion flotation in which water-insoluble oily collectors are utilized depend critically on the emulsification of the collector and on its conditioning with the pulp prior to flotation. The flotation tests carried out with magnesite and fluorite using sodium oleate as collector confirmed acidic and alkaline ranges of good flotation. While the flotation results in the acidic solutions depend strongly on the conditioning time and can be very much improved when longer conditioning times are utilized, the tests in the alkaline environment do not exhibit any significant dependence on conditioning. The results obtained with sodium salts of myristic and lauric acids confirm these findings. The observed effects provide additional evidence for the role of the colloidal species which appear in the acidic solutions of weak electrolyte type surfactants, such as fatty acids. The flotation properties of sodium oleate in the pH region in which it appears in the form of oleic acid droplets are mainly determined by the properties of such droplets. The flotation in this pH region closely resembles an emulsion flotation.

Jan 1, 1993

By Rainer Köster, Tobias Wagner, Markus Delay, Fritz Hartmann Frimmel, Wolfgang Ferstl, Wolfgang Höll

"The mobilization of contaminants from industrial residues like ashes from municipal solid waste incinerators in case of leaching is investigated world wide. In classical leach tests only soluble species are considered. In addition the geochemical behaviour of residues has to be completed by assessing the mobilization via colloidal particles. This transport is well known from natural aquatic systems. Quantification of aquatic colloids is associated with considerable difficulties, because they are often found in low concentrations and in a size distribution where small particles with diameters below 0.1 µm predominate. In the past years, the Laser-induced Breakdown Detection (LIBD) has been developed as a novel sensitive method for quantifying colloids. Column leaching experiments with directly coupled LIBD were used to quantify the release of heavy metals and colloids out of bottom ashes. Some typical colloid bound heavy metal concentrations in the leachate are in some cases exceeding the limits defined by German authorities. The LIBD with a flow-through cell allowed to assign absolute values to colloid size and concentration."

Jan 1, 2008

By K. V. S. Sastry, A. J. Hunt, K. D. Lofftus

Sol-gel processing is rapidly becoming an important process for producing such advanced materials as high activity catalysts, fiber optics and ceramic precursors. These materials can be tailor made with properties unique to sol particles as well as the gel aggregates by controlling production of the sol, the formation of the gel, and the removal of the interstitial fluids. This paper presents colloidal and kinetic principles of sol generation and gel formation. Hydrolysis of alkoxides provides the best means of controlling sol production and electrostatic stabilization enables the formation of the most homogeneous gels. Gelation occurs by hierarchial aggregation which produces inhomogeneities much larger than the sol particles. Colloidal and kinetic principles can be applied to reduce the size of the inhomogeneities and obtain high performance transparent insulation and new ceramic composites.

Jan 1, 1990

By James Pollock

SUMMARY THE possibility of colloidal deposition of cinnabar has been neglected. In opalite deposits cinnabar exists in particles within or near the colloidal size range. Colloidal processes have been admitted to be operative in hot springs and low-temperature deposits similar to most cinnabar deposits. Mercuric sulphide sols are stable to elevated temperature and pressure, and in nature probably are chiefly affected by the electrolytes in solution, dilution of colloid, and presence of protective colloids as silica. The stability of mercuric sulphide sols to electrolyte is measured, and shown to be greatly increased by dilution and by the protective action of silica. Mercuric sulphide sols follow the Schulze-Hardy valency rule, therefore the precipitating power of complex mixtures of electrolytes can be computed roughly. The stability of mercuric sulphide sols is shown to be greater than the equivalent precipitating power of the electrolytes in a hot spring depositing mercuric sulphide. It is concluded that finely divided or earthy types of cinnabar are colloidally deposited. POSSIBILITY OF COLLODIAL DEPOSITION While colloidal solution has been suggested as a means of transport for a number of minerals, such as the sulphides of antimony, arsenic, and iron, it has been neglected in connection with mercury. This is surprising because there exists positive evidence that cinnabar is present in certain deposits in particles of colloidal or near colloidal size. Colloidal transport could result from either the rapid dilution or neutralization of alkaline sulphide solution bearing mercury coming in contact with deep ground waters, or from colloidal solution near the original source and subsequent flow to the point of deposition unchanged. That the dilution of a mercuric alkaline sulphide solution will precipitate mercury sulphide in colloidal form has been demonstrated a number of times and is easily confirmed. The dilution hydrolyzes the alkaline sulphide Na2S to the corresponding hydroxide and hydrosulphide NaOH and NaHS, and the diminution of the concentration of alkaline sulphide reduces the solubility. It is not the contention of this writer that colloidal deposition is the mode of transport of mercuric sulphide in all mercury deposits, but that the stability of a mercuric sulphide sol, as demonstrated below, in waters that are similar to those that have deposited mercuric sulphide necessitates consideration of this possibility in many deposits, especially those of the hot-spring and so-called opalite type. EVIDENCE OF COLLOIDAL DEPOSITION Ross1 has shown that most deposits of quicksilver are formed at low temperatures and pressures, and probably by solutions that have relatively simple chemical compositions. In most cases the solutions are probably similar to those observed in hot springs, and in two instances-at Steamboat Springs, Nevada, and Sulphur Bank, California-hot springs have been reported by Becker as actually depositing cinnabar.2 Opalite deposits were believed by early investigators to be surface phenomena

Jan 1, 1944

Adsorption isotherms, zeta potential and coagulation techniques have been used to exa- mine the mechanism of metal activation on SiO2 and ZnS surfaces. The importance of surface nucleation or precipitation of metal hydroxide coatings is'established and identified-by characteristic charge reversal patterns. The significance of surface coatings in sulphide and non-sulphide flotation is discussed.

Jan 1, 1973

By R. C. Bunge

Many minerals float best with fatty acids in the intermediate pH range. For example, fluorite, a semi soluble salt mineral, exhibits a maximum contact angle and a maximum flotation recovery in the pH range of 6-8 after conditioning in a palmitate solution (fig. 1). The maximum in flotation coincides roughly, as many researchers have observed, with the boundary of bulk precipitation of the fatty acid. According to fig. Z this boundary is in the above case of 5xl0-7 M palmitate approximately at pH 6.3. For assessing the phenomena occurring at the bulk precipitation boundary of fatty acids, the surface tensions of carboxylate solutions have been measured under various conditions. Fig. 3 shows the surface tension development of palmitate and myristate solutions of increasing concentration at pH 12. Also shown are the bulk precipitation edges (BPE) of the respective solid species that is stable under these conditions, that is the potassium acid soap, HKAZ. Both curves display a similar behavior. As the concentration of carboxylat,e increases, the surface tension decreases, until a minimum is reached at which the curves level off. The decrease of surface tension with increasing carboxylate concentration is generally taken to indicate the surface excess of the carboxylate ion. The point where the curve suddenly levels off has not yet been explained. While it is well known that the onset of micellization (CMC) may cause such an inflexion of the surface tension curve, this cannot be the case here because the position of this point depends, as shown in fig. 4 for palmitate, on pH (the CMC is generally independent of pH). We believe that this point indicates the precipitation of a colloidal acid soap (colloidal precipitation edge, CPE) before the bulk precipitation of this species sets in (BPE).

Jan 1, 1994

By Martin Rudolph

"Flotation is without a doubt one of the major processes for the separation of fine minerals and it has been applied for more than a century. A key task of a successful flotation separation is to find the proper chemical treatment to selectively hydrophobize and thus float a certain mineral phase using molecules or ions referred to as collectors, depressants, regulators and frothers. Commonly floatability is determined by microflotation tests using the Hallimond tube with pure mineral phases. This method however requires the pure mineral phase which is very often not even taken from the same deposit which is going to be processed. In this paper we present a new approach to in-situ determine and even map the floatability of finely disseminated mineral phases within cross-sections of an ore. It is based on measuring hydrophobic effects using colloidal probe atomic force microscopy with a hydrophobic polystyrene probe based on force spectroscopy with a lateral resolution of only a few nanometers. Coupled confocal Raman spectroscopy on the same locality enables the identification of the mineral phase. We present the working principles of the method and show which signals in the force spectra characteristic for hydrophobic interactions can be used to define floatability and which can then be mapped as single quantities, e.g. jump-into-contact events due to nanobubble occurrence or parameters of the long range interaction curves most probably due to capillary effects. A finely grained silicate ore containing the valuable rare earth mineral eudialyte from southern Sweden as well as pure samples of magnetite are presented as substrates to demonstrate the capability of this new approach. This method will not only help to find the proper flotation chemistry but it can furthermore help in researching and unravelling problems of floatability within similar mineral phases."

Jan 1, 2014

By David McGregor, Ashoke SenGupta, Jerry Darlington

The stability of bentonite clay suspensions against flocculation in the presence of certain anionic polymers was investigated. These polymers included a purified sodium lignosulfonate, a sodium oxylignosulfonate, a potassium salt of humic acid, and a sodium polyacrylate. The polymers differed from one another in molecular weight as well as in carboxylic, phenolic, and sulfonate group contents. The scope of this study is in evaluating the extent of thinning achievable in a bentonite clay suspension in the presence of these anionic polymers under varying electrolyte concentration, presumably as a result of deflocculation of the clay platelets by the polymers. Under certain conditions of polymer dosage and electrolyte concentration, the lignosulfonate seemed to have flocculated the clay suspension, while the other polymers served fairly well as a deflocculating/dispersing agent. The lignosulfonate, however, showed some deflocculating ability when the electrolyte concentration of the suspending medium (water) was increased by adding sodium chloride to the clay suspension. Among the four polymers tested, the polyacrylate was found to be the most effective in deflocculating clay particles, followed by the humate and the oxylignosulfonate.

Jan 1, 2003

By Jerome Alexander

THE object of this paper is to show that many of the important phenomena of metals and alloys are due to the facts that, at some stage, metals and alloys, or some of their constituents, are in a colloidal state and that a portion of the metal or alloy tends to remain in this state. The so-called amorphous phase in pure metals is an isocolloid, consisting of colloidal groups of metal molecules that may be dispersed in still more finely subdivided metal; these colloidal particles are not truly amorphous, but may consist, in part, if not entirely, of ultramicroscopic crystals; as a result the expressions amorphous phase and amorphous theory might be replaced by the expressions colloidal phase and colloidal theory. Any substance is in the colloidal state when the constituent particles consist of molecular or atomic groups, whose size varies approximately from about 100µµ down to about 5µµ, that is from just below the limit of microscopic resolvability to the dimensions commonly ascribed to the larger molecules. Colloidality involves no assumption as to the shape, internal structure, or orientation of the colloidal particles; size alone is the critical factor. A colloidal system may therefore contain crystalline groups, or amorphous groups (non-crystalline, random or haphazard clusters), or a mixture of the two. All colloids consist of at least two phases, the subdivided substance, or dispersed phase, and the substance into which this is subdivided, the dispersion medium. It is not necessary that there be any chemical difference between the dispersed phase and the dispersion medium. As molecular forces are extremely powerful, their application may produce marked changes in the physical properties of metals. It is doubtful whether metal in the interior, especially of large masses, possesses the same properties as that on or near the surface, which alone is open to, inspection.

Jan 10, 1920

A Colloquium and General Meeting was held jointly with the Mine Ventilation Society of S.A. in Kelvin House, Johannesburg, on 17th November, 1971, the theme being "The Economics of Mine Ventilation". Professor D. Howat (President) was in the chair. The Colloquium was attended by 150 delegates and was opened by the President at 9.00 a.m. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following Grades: Fellows: Frederich-Wilhelm Volk, Peter Bennet Columbine. Members: Allan Colin Lawrence, Karel Anton van Gessel, Christopher Robert Harrison, Christopher Michael George Wartley, Frank Heinrich Deist, Ralph Morris, Benjamin Johannes Nolte. Associates: Wolf gang Freidrich Gottsman. TRANSFERS From Member to Fellow: Hugh Edward Keith Alien. From Graduate to Member: Errol Vincent Bosman, Christopher Roderick Stewart Needes, Bernard Wessels Holthousen. From Student to Graduate: David Robert Fleming. I welcome the new members to the Institute and congratulate them on their election. CO-OPTION TO COUNCIL The President announced that at the Council meeting held on 5th October, 1971, it was agreed, in terms of Rule 3.9 to co-opt Dr T. B. Beeton to Council. COLLOQUIUM The President welcomed visitors and members. He stressed that the discussion would be informal and that any contributor requiring publication should submit his contribution in writing. He then thanked the authors for providing pre-prints of the papers. After the President had concluded his opening remarks, he asked Professor J. de V. Lambrechts to act as Colloquium Chairman for the day and he, in turn, introduced the three Session Chairmen namely, Dr A. Whillier (Chamber of Mines and President of the Mine Ventilation Society); Mr M. Barcza (Managing Director, Corner House Laboratories); and Mr L. W. P. v.d. Bosch (Chief Consulting Engineer, Union Corporation). The following papers were presented: "Fan efficiency investigation on mines of the Union Corporation, Ltd." by J. A. Drummond. Published in the Journal Feb. 1972. "The design of underground cooling towers" by A. Whilliel'. Published in the Journal, Oct. 1971. "Some aspects of the design of cooling plant installations" by R. Hemp. Published in the Journal, Nov. 1971. "The planning of ventilation and refrigeration requirements in deep mines" by D. F. H. Grave and R. M. Stroh. Published in the Journal, Dec. 1971. "Cooling power of underground environments" by D. Mitchell and A. Whillier. Published in the Journal, Oct. 1971. At the conclusion of the three technical sessions the Symposium Chairman commented as follows, indicating that he would prepare a written summing up at a later stage: "The tone of the colloquium has had a sincerely practical note about it. It would have been a pity if the ventilation experts talked only theory and little practice. This practical theme has, I am sure, made the colloquium interesting to both ventilation men and others whose daily tasks do not touch so closely on this fascinating subject. This practical theme was in evidence through all the papers and contributions. Some of you may have felt that there was not enough emphasis on the word 'economics' as advertised in the broad title of the colloquium. I do not think this was really a valid criticism because as someone said 'it all boils down to Rands in the end!' So whether it was a case of low fan efficiency, poor design of cooling towers, wrong planning or low human efficiency due to high heat stress. . . it all boils down to money saving and therefore economics, whenever improvements are forthcoming. The title of the colloquium was thus not misplaced. The views of senior mining men on the production side are appreciated. Let us say that this exchange of views between ventilation engineers and those who have to take the final decisions and spend the money, should prove to be most rewarding." Professor Lambrechts finally thanked the Session Chairmen and everybody who had helped to make the colloquium a success and the meeting closed at 4.0 p.m. In a subsequent written summing up, the Colloquium Chairman gave the following as his impressions of some of the highlights which emerged from the papers and discussion thereof: (The names indicate the authors only). Drummond: It was hinted that the time had arrived to consider the introduction of a South African fan test code which would be better suited to local conditions than the currently acknowledged B.S.S. code which, however, is seldom enforceable in practice. In this connection also, there was prominent reference to the thermodynamic approach of McPherson. Wide variations in the quality of maintenance of, and repair work on, fans were stressed. It was mooted that ventilation engineers responsible for estimating the basic duty specifications for large fans, frequently played safe by overestimating the pressure required, thus ensuring that there would not be a shortfall in air volume delivered. This usually meant reduced fan efficiency and it was suggested that decision makers seemed to lay more emphasis on volume of air delivered than on real eco-

By P. W. J. van Rensburg

COLLOQUIUM AND GENERAL MEETING A General Meeting and Colloquium on comminution was held on March 13th, 1974, at Kelvin House, Johannesburg. Mr P. W. J. van Rensburg (President) was in the chair. The Colloquium was attended by 140 delegates and was opened by the President at 9.15 a.m. MINUTES The minutes of the general meeting held on November 14th, 1973, as published in the December issue of the Journal, were confirmed.

Jan 5, 1974

Colloquium And General Meeting - Trackless Mining in Underground Metal Mines A General Meeting and Mining Colloquium on the above topic was held on Wednesday, May 16th, 1973, at Kelvin House. Dr J. P. Hugo (President) was in the chair. The colloquium wasattended by approximately 200 delegates, and was opened by the President at 9.15 a.m. OBITUARIES The President: It is my sad duty to announce the death of the following: W. A. Schwezoff and L. G. S.

By SAIMM Journal

COLLOQUIUM ON COMMINUTION The Institute has arranged a colloquium on the above topic to be held on 13th March, 1973, at Kelvin House. The following papers will be presented: 'Peripheral Discharge Mill', by A. H. Mokken, Union Corporation Limited

Jan 1, 1974

By D. G. Davies

Colloquium on the construction of Slimes dams The following contributions to the discussion at the above Colloquium were received for publication. D. G. DAVIES* This contribution is really a follow up on Mr H. E. Cross's paper on the conversion of a uranium plant to the recovery of zinc (published in the Journal, November 1973). Ecological aspects of slimes-dam construction by H. T. CLAUSEN C. M. VAN STADEN* Published in the Journal, December 1973 I should like to thank Mr Clausen for his paper and to congratulate the Research Laboratories and the Vegetation Unit of the Chamber of Mines on the excellent work they have done in the past, are still doing at present, and, we hope, will continue to do in future, on the testing of various methods for the covering of slimes dams and specifically on the vegetation of dams. The impact of slimes-dam formation on water quality and pollution by R. T. RUDD* C. M. VAN STADEN Published in the Journal, December 1973 I should like to congratulate Mr Rudd on the paper he presented. Congratulations are also due to the Department of Water Affairs for the practical attitude they have taken in implementing the Water Act. Slimes-dam construction in the gold mines of the Anglo American Group by W. T. RUHMER W. R. FLOOK* Published in the Journal, February 1973 Methods for the construction and operation of slimes dams in the gold-mining industry do not appear to have changed much for some considerable number of years.

Jan 3, 1974

By Gaston Giuliani, Jérome Massot, Didier Bourlès, Lionel Siame

"Abstract - We present a new approach for the evaluation of the potential of emerald reserves in gem projects using beryllium (Be) mobility. The distribution of Be in the different phases of hydrothermally altered (albitized) black shale hosting Colombian emerald deposits indicates that Be mobility is associated with the breakdown of Fe-Mn oxyhydroxide phases. The amount of Be that can be mobilized (~0.7 x 10-6 g/g; i.e., 0.7 ppm) may represent up to 18 wt% of the total Be contained in the black shale. A mass balance calculation applied to a well-constrained alteration zone of the Chivor mines, and based on the quantification of Be that can be mobilized under hydrothermal conditions, gives an estimate of the total gem reserves of these mines. Resumé - Une nouvelle approche, basée sur la mobilité du béryllium (Be) pour l’évaluation des réserves d’émeraude dans des projets d’exploitation de gemmes est présentée. La distribution du Be dans les différentes phases minérales de schistes noirs hydrothermalisés (albitisés) qui contiennent les gisements d’émeraude colombiens, indique que le Be mobilisable se trouve dans les oxyhydroxydes de fer et de manganèse. La quantité de Be potentiellement mobilisable (~0,7 x 10-6 g/g; soit 0,7 ppm) constitue jusqu’à 18% poids du Be global contenu dans le schiste noir. Un bilan de masse appliqué à la zone d’altération hydrothermale des mines de Chivor et basé sur la quantification du Be mobilisable, donne une première estimation des réserves à émeraude de ces mines. rieur."

Jan 1, 1999