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By Riyad N. Ahmad-Bitar, Shadia J. Ikhmayies

"CdS/CdTe solar cells were built by depositing a 200 nm layer of Sn02:F on glass substrates by the spray pyrolysis (SP) technique, a 500 nm CdS:In layer by the same technique and a 1-1.5 µm CdTe layer by vacuum evaporation. The cells were CdCh heat-treated in nitrogen atmosphere for 30 minutes at 350 -.C. The photoluminescence (PL) spectra were measured at the CdS/CdTe interface for two cells with different values of the CdTe layer's thickness at temperature T = 60 K. A deconvolution peak fit was performed from which it is found that the peaks are characteristic of the solid solution CdSxTei-x· The parabolic relation that relates the bandgap energy with the composition was used to estimate x, where xis [S]/([Te]+[S]) and [Te], [S] are the concentrations of Te and S atoms respectively. The results show that the interface is smooth and the change of the bandgap occurs gradually.IntroductionCdS/CdTe heterojunctions represent a combination of materials promising various applications, and for solar energy conversion in the first place [1]. In photovoltaic cells the CdS material acts as a wide bandgap window. Direct bandgap CdTe with high optical absorption coefficient is used as an absorber [1]. Solar cells with efficiencies of 10 to 16% have been obtained with CdTe grown by close space sublimation, electrodeposition, vacuum evaporation and rf sputtering methods [2]. In this work the CdTe layer was prepared by vacuum evaporation because it results with films of minimum impurities, while the Sn02:F and CdS:In layers were deposited by the spray pyrolysis technique because it is a low cost method which enables intentional doping and large area thin films."

Jan 1, 2011

By M. S. Delibalta, S. Kahraman, R. Comakli

The block cutting machine is one of the most important noise sources in the stone processing factories. In this study, the assessability of the noise from the block cutting machines in the stone processing factories using the P-wave velocity was investigated. The noise levels of some block cutting machines were firstly measured during the cutting of the three different rocks. Then, core samples of the same rocks were cut by an automatic cutting machine in the laboratory and noise levels were measured. A conversion factor was obtained by dividing the site noise levels by the laboratory noise levels. Then, thirty seven different rocks were cut by an automatic cutting machine in the laboratory and noise levels were measured. The P-wave velocity of rock samples were also measured in the laboratory. A strong relation between the laboratory noise levels and the P-wave velocity was found. The noise level from the block cutting machines can be assessed using the derived relation and the conversion factor.

Jan 1, 2011

By Tom Watts

The practice of pumping bulk blasting agents is regulated by many agencies around the world. The explosives manufacturers have done an excellent job of hazard and operability studies allowing criteria to be established for the safe pumping of water based blasting agents. The challenge of a Bulk Trucks or Mobile Manufacturing Units (MMUs) manufacturer is to take the objectives of the regulatory agencies and the explosives manufacturers and responsibly design and build MMUs that are safe, compliant, and cost effective without compromising serviceability.

Jan 1, 2011

By Lucas L. da Costa, Sergio N. Monteiro, Romulo L. Loiola, Tammy G. Rodrigues Portela

"The fibers extracted from the petiole of the buriti palm tree are relatively strong as compared to other lignocelluloses fibers, with a potential for composite reinforcement. In this work, polyester matrix composites incorporated with these fibers were investigated for their flexural behavior. Specimens with up to 40% in volume of continuous and aligned buriti petiole fibers were bendtested until rupture. The results showed an increase in both the composite mechanical strength and the stiffness with incorporation of these fibers. A fractograph analysis by SEM disclosed a moderate adhesion mechanism between the buriti petiole fiber and the polyester matrix. This mechanism is apparently responsible for the improved performance of the composites.IntroductionIn recent years, the substitution of energy-intensive synthetic materials for natural ones is being considered in many industrial sectors including automobile, packing and textile [1]. A typical case is that of natural fibers, mainly those obtained from cellulose-based plants also known as lignocelluloses fibers. They have being investigated in the past two decades, aiming to replace synthetic fibers, particularly the glass fiber, commonly used as polymer composite reinforcement [2-8]. From the engineering point of view, lignocellulosic fibers present today important environmental, economical, societal and technological advantages already discussed [7-8]. Moreover, several lignocellulosic fibers are known since the beginning of our civilization and still cultivated or naturally extracted all over temperate and tropical regions of the world. According to Kalia et al [1 ], these fibers can be classified by their origin, as shown in Table 1."

Jan 1, 2011

By A. Consigny

New "clean technologies" to treat mining and metallurgical effluents containing dissolved metals have been successfully applied at mine sites in North America and Asia, treating water flows up to 24,000 m3/day. These clean technologies offer significant benefits compared to conventional alternatives and provide a sustainable solution that eliminates residual waste sludge, improves water conservation, generates revenues from wastewater, and delivers overall improvements to the environment. This paper will profile these technologies, and provide best practice case study examples of their application at mining operations, including data for water chemistry, flows, water quality, capital and operating costs, and life cycle costs of treatment.

Jan 1, 2011

By A. Hekmat-Ardakan

Conventional hypereutectic Al-Si alloys such as A390 are used principally for the casting of components used in wear applications requiring abrasive resistance such as in engine or compressor blocks. A comprehensive study was undertaken to investigate the potential of improving the mechanical properties of these alloys by the addition of magnesium. A thorough thermodynamic study of the effect of the addition of Mg to the conventional A390 alloy showed that Mg2Si starts to form as a primary phase at 4.2% Mg as well as in the products of the binary and ternary eutectic reactions forming the matrix. Experiments were carried out in producing castings with different cooling and solidification rates of alloys with up to 10% Mg. Mg additions were found to increase the hardness over the as cast alloy due to solid solution strengthening. Also, T6 heat treatment greatly improved the tensile properties of these alloy compositions due to the strengthening effect of the theta-Al2Cu phase. The elongation of these alloys generally decreases marginally with Mg content. The most significant property improvement of the alloys with higher Mg content is the substantial increase in wear resistance. This is attributed to the dispersion of smaller particles of Mg2Si and their coherence with the matrix as compared to the large Si particles in the conventional alloy. A new rheoforming process for A390 is presented that improves the processing of the semi-solid slurry. Structure modification elements were also added to refine the primary and eutectic silicon greatly improving the processing of the semi-solid slurry.

Jan 1, 2011

By Tetsuya Yumoto, Toshikazu Shiratori

Information on the elements contained in E-Waste is important from the viewpoint of recycling. We analyzed several components of waste electrical and electronic equipment (WEEE) collected from citizens. The distributions of the minor metals in WEEE were determined with elemental mapping and chemical analyses. The annual change in elemental composition was investigated by analyzing equipment manufactured in different years. The information will be of use for separation techniques required for future advanced recycling.

Jan 1, 2011

By F. Bourgouin

Thirty-one years ago, African leaders met in Lagos for the drafting of the Lagos Plan of Action for the Economic Development of Africa, 1980?2000. The main objective of the plan was to increase Africa?s self-sufficiency and in this regard, the plan had a section pertaining specifically to redressing the ills of an unproductive mining and minerals industry and harnessing its potential for socio-economic development. However, if we look at the nature of this sector on the continent today, its characteristics resemble the diagnosis of the sector given in the plan back in 1980: lack of information on endowments of minerals; lack of value added in the sector; low development and use of those endowments that are not of interest to transnational corporations (TNCs); and most importantly, low contribution to socio-economic development. The primary consequence of the lack of visible benefits to African states, despite growth and development of the sector in terms of increased mining activity led by Foreign Direct Investment is that countries with mining industries are characterized by dysfunctional internal processes. Improvements in governance, monitored with indices such as those set out in the Extractive Industries Transparency Initiative, the Millennium Development Goals, and other such ?good governance? agendas, are being asserted. However, before we prescribe the introduction of initiatives or guidelines based upon highly subjective norms which we believe to fit this diagnosis, it is necessary to review how it is that we got to this situation that we are in today. How is it that, 31 years after the Lagos Plan of Action, we have not seen any major changes in the role the industry can play in socio-economic development, despite the vast increase in mining activity on the continent?

Jan 1, 2011

By Bruno Gemmi

The objective of the ? 200 million ($280 million) project Parma Railways Station-Urban Transformation was the reconnection of the North and South parts of the town by constructing an 80 m (250 ft) wide sunken artery passing under the four double railway tracks of the station without any impact on train traffic. The site of the project, adjacent to the Parma River, presented water seepage problems at any excavation depth. The use of conventional large diameter bored pile machinery was not allowed by the Railway Authority because equipment dimension and construction phases do not comply with train traffic safety regulations. Foundations for the bypass were thus constructed by minipiles nested into jet-grouted soil using machinery operating within the existing head room and at a safe distance from the tracks. Jet-grouting treatment reached depths of 25 to 28 m (80 to 90 ft) from tracks? grade and embedded minipile-heads were terminated at 2 to 3 m (6.6 to 10 ft) below grade. Load tests on minipiles were pushed to failure. Failure occurred at a 240 t (265 t) load without breakage of the bond between the jet grouted soil and the minipiles. A 0.93 MPa (135 psi) shear resistance ??? between minipile steel casing and the jet grouted soil was measured prior to the failure of the steel casings. Overall measured foundation settlements were well within expected values and were considered insignificant.

Jan 1, 2011

By Ki-Hyune Kim

The Korea Ocean Research and Development Institute conducted its first exploration for deepsea mineral resources in 1983, and began a systematic deepsea prospecting in 1989 among Micronesian islands and in central and eastern parts of Carion-Clipperton fracture zones of eastern Pacific. With the arrival of R/V Onnuri in 1992, KORDI commenced a full-scale national program for nodule exploration. The total area surveyed by KORDI covers more than 1,500,000 km2. At the end of 1993, based on the collected data, Korea designated 300,000 km2 in the Clarion-Clipperton fracture zone as prospective mining area for manganese nodules, and accordingly, the government of Korea submitted the application in January of 1994 to the United Nations for registration as a pioneer investor and for the allocation of a pioneer area. This application was approved by the General Committee of the Preparatory Commission in August 1994. As a result, Korea became the 7m pioneer investor under the United Nations Convention on the Law of the Sea. KORDI is now carrying out detailed exploration survey and environmental studies in the registered area to fulfill required obligations to UN, and Korea will continue exploring the last frontier on earth. It is KORDI's unshaken calling to be successful in exploiting deepsea resources to provide our nation resources it lacks. It is not only a challenge to explore deepsea, but it is also our national mission to explore and succeed in our endeavor for future generation.

Jan 1, 2011

By D. Yuan, L. Yan, R. Kalanchey, M. J. Collins, I. M. Masters

Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project located in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Since the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The "lime boil" process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95 to 98%; silver extraction was up to 94%.

Jan 1, 2011

By Guolin Zheng, Jian Pan, Deqing Zhu, Xianlin Zhou

"In ferronickel production, nickel oxide and part of the iron oxide are reduced to metal by agglomeration and smelting in blast furnace. Due to the physical and chemical properties of the laterite ores, a large fraction of fines is generated during the pre-treatment stages and the strength of agglomeration is weakened, which results in low productivity and bad quality. In this paper, the process of pelletization of nickel laterite was developed, and some parameters to strengthen the pelletization of nickel laterite have been optimized. The results show that the compressive strength of fired nickel laterite pellet can reach over 2000 Newton per pellet while firing at the temperature of 1220 °C~1250 °C in 12 min. The product pellet can be used as high-quality burden for blast furnace to manufacture ferronickel.IntroductionIn recent years, the global stainless steel market was developed exuberantly, which greatly promoted the needs of the basic raw material of stainless steel smelting - metal nickel. Currently nickel sulfide ores are only 40% of global nickel reserves, but offer 60% of all the nickel production. However, with the deficit of resources, the nickel sulfide ore (high grade ore) is depleting, so there is an increasing focus on the utilization of low-grade nickel laterite. Recent research has focused on the wet treatment process to utilize nickel laterite, and less on the use of other technologies [1-8]. The economical and efficient technology relies on the reduction of nickel oxide and part of the iron oxide metal by agglomeration and smelting in blast furnace in China. Some domestic steel companies have adopted this process [9, 10]. Unfortunately a large fraction of fines is generated during the pre-treatment stages and the strength of agglomeration is weakened, which results in low productivity and bad quality of fired pellets. In this study, the process of pelletization of nickel laterite was developed firstly, and some parameters to strengthen the pelletization of nickel laterite have been optimized, and the product pellet can be used to produce stainless steel and ferronickel alloy by blast furnace."

Jan 1, 2011

By Adrian Moore, Bryan Goodwin, David Fales, David Lam

This paper describes the development of blasting protocols used to successfully create a 450m long blast fractured permeable trench in a basalt aquifer up to 20m thick, at a petrochemical facility in Australia, to enable the remediation of contaminated groundwater.

Jan 1, 2011

By Helvio P. G. Santafé Jr., Ruben J. S. Rodriguez, Sergio N. Monteiro, Teresa E. Castillo

"The coir fiber extracted from the husk of the coconut fruits are worldwide available in tropical regions as a low cost lignocellulosic by-product for many applications including composite filler in automobile parts. Possible uses above room temperature require information on the thermal behavior of these coir fiber composites. Therefore, the objective of this work was to perform thermogravimetric, TGA and DTG, analysis on polyester matrix composites incorporated with different volume fractions of coir fiber. In general, it was found that thermal degradation associated with weight loss occurred in three stages. Changes were also observed in the DTG peaks that could be attributed to the coir fiber participation through the decomposition of its lignocellulosic structure.IntroductionThe development of new materials has always been motivated by the need of improved properties. This was the case of modem composites with combination of properties that surpass those of conventional monolithic metallic alloys, ceramic or polymers, from which composites are made. A typical example is the synthetic fiber reinforced composite with specific strength i. e, ultimate stress divided by density, higher than any other monolithic material. Today, however, our global society is concerned with serious environmental problems and thus demanding that new materials be developed with distinct characteristics. They are known as environmentally correct and are expected to be sustainable, which corresponds to the condition of being biodegradable, renewable, recyclable and neutral with respect to C02 emission, considered the main responsible for global warning [1]. Synthetic fiber composites cannot meet these requirements. Consequently, new composite reinforced with cellulose-based natural fiber are being developed [2-8] and are already replacing the synthetic ones in several engineering fields including the automobile industry [9-11]. These composites have additional advantages owing to the lignocellulosic fiber benefits of being diversified, abundant, less expensive, lighter and of societal interest [8]. In some cases even technical advantages such as non-abrasive effect to processing equipments and more flexibility exist in comparison to synthetic fibers."

Jan 1, 2011

By Kerina Taylor

Due to their high amount of stored energy, explosives have been the cause of many serious injuries and fatalities over the last centuries. Despite safety advances and awareness in the last decades, injuries and fatalities continue to occur at mining operations due to blasting. According to the National Institute for Occupational Safety and Health, from 1978 to 2001, blasting incidents claimed 106 lives and were responsible for over 1000 injuries in mines in the US. The main causes of incidents found today are flyrock, blast area security and premature detonations. The concerted efforts of the mining and explosives industries and labour and government agencies have greatly improved the safety record of blasting in mines.

Jan 1, 2011

By Somasundaran P., M. Vasudevan, Z. Dai, D. R. Nagaraj, T. Bhambani, P. Patra

Historically, efficient beneficiation of ultramafic ores has been challenging, partly due to a lack of clear scientific understanding of the effects of Mg silicates, particularly fibrous serpentines, on selective Ni recovery. Recent research at Columbia-Cytec as a part of a Vale JDP project has led to new insights into the mechanistic aspects of the adverse effects of Mg silicates. Our research has provided strong evidence to support the hypothesis that the adverse effects of Mg silicates are mediated through their large influence on pulp rheological properties, far more than any other pathway. The severity of the effect of Mg silicates is predominantly dependent on the aspect ratios of Mg silicates. For example, the pulp viscosity increases dramatically with increase in the fibrous nature of the gangue mineral leading to poor Ni separation. Various ways by which the suspension rheology affects flotation sub-processes, with implications for remedy are discussed. The insights and results have served to develop (or construct) a phenomenological model to adequately explain all of the ore flotation data, particularly the Mg silicate transport to the froth phase and the concentrate.

Jan 1, 2011

By John N. Cunningham

Despite the wide use of micropiles for rehabilitating and retrofitting existing structures, little is known regarding the load-transfer distribution of grouted micropiles in various soil deposits. The rehabilitation of a concrete-frame warehouse in Portland, Oregon, required provisions for the seismic restraint of a new shear wall; the installation of two micropiles was specified to meet project requirements. The micropiles were uncased, 19-m (63-ft) long, 200-mm (8-in) nominal diameter, and reinforced full-length with a 64-mm (No. 20) diameter hardened steel threadbar. Due to space limitations, a sacrificial, instrumented micropile was installed near the two production piles to verify design assumptions. This paper describes the geologic setting of the project within the unsaturated Missoula Flood deposits, instrumentation, load-displacement behavior, load transfer, and Beta-coefficients for the sacrificial micropile.

Jan 1, 2011

By J. G. Pippenger

The mining industry has been Australia?s major economic driver over the past decade, contributing 8% to Australia?s Gross Domestic Product and 26% of Australian Stock Exchange Market capitalisation. Australia is the world's leading exporter in coal, iron ore, alumina, lead and zinc; and second largest in gold and uranium. While driving the economy, this resource boom has also created a demand for professional and operating talent that has far outstripped the capacity of Australia?s 21 million residents. I moved to Australia some 10 years ago and have not looked back. This unique island continent with its mix of Indigenous and diverse immigrants ? many still proud of their convict ancestry ? has offered life long memories both professionally and personally.

Jan 1, 2011

By Frederic Masse

With widespread acceptance in the market place, many engineers are choosing ground improvement techniques to provide suitable foundation subgrade at sites that would have traditionally required deep foundations. This paper discusses the Controlled Modulus Columns (CMC) ground improvement technique and some case histories highlighting the use of this technique for retail development sites. CMC are a sustainable and cost-effective ground improvement technology that transmit load from the foundation to a lower bearing stratum through a composite CMC/soil matrix. The CMC installation is also an attractive option from an environmental perspective because it utilizes reverse flight augers, which displace the soil laterally. This installation technique achieves two goals: it densifies the soil around the CMC, which improves load transfer into the element and avoids spoil and its disposal. Through the introduction of two cases histories, we will present the key benefits of the CMC technology. Each case history will clearly illustrate how a CMC solution can reduce the overall cost of a project when compared to a more traditional type of deep foundations. They will also show how the use of CMCs has benefits that relate to the overall sustainability of the project. While CMCs are an attractive financial and sustainable option, they have also demonstrated that the performance of the system is comparable to that of deep pile foundations. Because CMCs are a relatively new technology many potential users are not aware of its benefits. While we discuss the use of CMCs to support buildings in this paper, CMCs also have been used for a variety of other applications including foundations for tanks, mechanically stabilized earth (MSE) walls, and embankments

Jan 1, 2011

By R. B. Krog

Airflow patterns in longwall bleeder systems are affected by gob permeability and porosity and the condition of the gateroad entries after mining. As longwall panels are mined, areas of the caved zone and portions of the remaining gateroad entries become inaccessible, making direct ventilation measurement impossible. Mine operators are left to estimate direction and amount of airflow in the gob and the surrounding gateroads. The most readily available locations are where air enters the worked-out area, approved measurement point locations (MPLs) and/or evaluation points such as bleeder evaluation points, intake evaluation points, and the outer bleeder entry. Ventilation models (network or Computational Fluid Dynamics, CFD) can model the gob and the surrounding bleeder system but calibrating these models is difficult without field data. NIOSH installed a tube sampling system ahead of a longwall face and, as the face retreated, released a slug of tracer gas (SF6) to determine transportation times and flow rates in the inaccessible gateroads. The data was used to calibrate both network and CFD ventilation models for a longwall panel. Both model types were used to predict the airflow patterns in the gob and to determine the airflow rate from the longwall tailgate corner back to the bleeders.

Jan 1, 2011