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By Edgar Schach, Tom Leistner, Markus Buchmann, Urs A. Peuker, Martin Rudolph, Marius Kern

"In this study, the flotation characteristics of a cassiterite-bearing fine-grained and complex skarn ore from a deposit in the Ore Mountains is investigated. The tests are performed using an oil-assisted column flotation approach to process very fine ore fractions and avoid losses of cassiterite into the tailings. First, process parameters are obtained for a finely ground artificial mixture of quartz, magnetite and cassiterite, simulating the real ore. Thereby, magnetite is used, as iron oxides can have a detrimental effect on the flotation due to a similar flotation behavior. In addition, they can act as a source of multivalent ions, which are known to reduce the concentration of collector molecules, active for flotation. Based on the results, selected parameters are further tested for cassiterite skarn ore from the Hämmerlein deposit including a pre-conditioning and a water exchange step to remove ionic contaminants. The process response is analyzed in detail by XRF (X-ray fluorescence) and MLA (mineral liberation analysis) to get a better understanding of the behavior of the single ore components. Sulfosuccinamate type surfactant is utilized as the collector, emulsifier and to reduce the froth destabilization through nonpolar oil. Sodium hexafluorosilicate is added as the depressant.INTRODUCTION Complex skarn ore deposits containing considerable amounts of tin, indium and other metals are located in the Ore Mountains region (Germany). In this study, a skarn ore from the Hämmerlein deposit was investigated. Due to the finely disseminated nature of this ore, past beneficiation attempts failed, and the ore was considered economically unprocessable. However, increasing resource demands brings it back into focus (Schuppan and Hiller, 2012). Cassiterite is the main tin bearing mineral in this ore. Due to its high density (~7 g/cm³), the predominant beneficiation technique is gravity separation (Angadi et al., 2015). Tin ores from disseminated deposits have to be extensively comminuted to reach a sufficient degree of liberation of the cassiterite grains. As cassiterite has a brittle nature, it is preferable enriched in small size fractions, during comminution (Angadi et al., 2015). Gravity separation methods become more and more inefficient for particles smaller 40 µm (Falcon, 1982), causing tin losses of up to 30 to 40wt.-% (Angadi et al., 2015). Thus, froth flotation of cassiterite was first utilized in Altenberg in the Ore Mountains as an additional processing step to reduce the cassiterite losses into gravity separation tailings (Bulatovic, 2010; Gruner and Bilsing, 1992). Although the reported lower size limits for an effective cassiterite floatability are often smaller compared to other minerals, the flotation performance is in general decreasing for small particle sizes < 10 µm (Trahar and Warren, 1976). Therefore, different approaches have been already investigated for the flotation of such fine cassiterite fractions to overcome the limits in particle size. Bilgen et al. investigated the shear flocculation of cassiterite with a sulfosuccinamate collector (Bilgen et al., 1994). The agglomeration flotation of cassiterite has been tested by Schubert et al. (Schubert et al., 1966), in which the selective coagulation of fine hydrophobic particles and oil droplets leads to an increase of the effective particle size. Recently, Leistner at al. investigated an oil-assisted agglomeration flotation for ultra-fine cassiterite ore fractions (Leistner et al., 2016). However, a poor response due to an increased concentration of Fe and Ca ions, unselective oil/gangue coagulation and froth instability, that is caused by oil/frother interactions, has been observed."

Jan 1, 2018

By A. V. Bogdanovich, S. A. Urnysheva

"Gravity and X-ray luminescent separation methods are generally used in processing of diamond ores. X-ray luminescent separators are applied for separation of diamonds from feed ore size fractions from 100 to 10-15 mm size and for final treatment of gravity concentrates over 1 mm size. Gravity separation machines used for diamond ores separation are heavy medium cyclones and pneumatic jigs. One of the most important parameters, to a large extent affecting diamonds recovery from ore, as well as processing costs and specific energy costs, is size of dumped final tailings. That was exactly the purpose of the studies, the results of which are described in this paper. The studies performed on different ores showed that in order to achieve high recovery results, it is necessary to dump heavy medium separation tailings below 3 mm size. Separation of final tailings of -6+1 mm size by jigging is also possible. However, with a view to exclude extra diamond losses, it is necessary to maintain jigging concentrate yield approximately at 25% from starting feed, with its subsequent cleaning in heavy medium cyclones. In addition to that, it is necessary to separate 20-25% of middling with diamonds content at feed ore level and subject it to grinding. This will complicate flow sheet, but reduce load on heavy medium cyclones. In order to develop optimal flow sheet for gravity concentration of a specific diamond ore, large-scale investigations are required, including technical-and-economic assessment of separation alternatives. INTRODUCTION In processing of diamond ores, gravity and X-ray luminescent separation methods are generally used. It is common practice to apply X-ray luminescent separators for separation of diamonds from feed ore size fractions from 50 (100) to 20 (10) mm size and for final treatment of gravity concentrates over 1 mm size. With that, X-ray luminescent separation tailings larger than 3-6 mm size are reground and delivered to gravity concentration processing stage. Middling products circulation volumes are large, not infrequently necessitating decrease in concentrating plants capacity, especially with mining in deep workings of deposits, where ore strength is higher (Goryachev, 2010; Vaginov, 2000; William, 1988). Diamond ores preparation before processing is accomplished by means of roll-screw crushers and autogenous grinding mills, minimizing probability of free diamonds damage in liberation from barren rock. In re-crushing of size fractions that are “difficult” in autogenous grinding, high pressure grinding rollers are applied (Burchardt, 2014; Fedotov, 2011a, 2006b)."

Jan 1, 2018

By Francisco Sena Leite, Vinicius Miranda

Mine blasting is directly associated with ground vibration. If these affect critical structures (buildings pit walls, etc.) they must be mitigated to reduce the environment and social impacts. Vibration monitoring and control is one of the most important procedures in blasting because it will impact short and long term incidents associated with this blast effect. Technology moves ever forward, and today we have personal devices that are equipped with an array of sensors, for that reason the authors decided to investigate the possibility of using a personal device to do vibration control. This case study compares the same blast measured with a traditional seismograph and a smartphone. To validate this new methodology, attenuation laws were built with data from a traditional seismograph and a smartphone application. Predictions were also made prior to a set of blasts. Residual analysis was used for data validation from the two different sources. From the performed analysis, to prove the validity of this new methodology, the normality tests for statistics residues analysis proves that it is possible to infer that the model has a null residual mean and a small residual error. The achieved results show the accuracy of these devices, the authors pretend to show the potential of this equipment and open a completely new door for vibration analysis.

Jan 1, 2018

By Isobel Yeo, Florent Szitkar, Sven Petersen, Sebastian Graber, Meike Klischies

Technological advances and the shift towards green energies in the last decades have led to a substantial increase in the demand for metal resources. With rising political tension, and quasi-monopolistic production of some key metals, a secured supply chain cannot be guaranteed [1]. Therefore, the focus of the international research community and mining companies has expanded to the seafloor, looking for additional resources. The seafloor may have the potential to contribute significantly to a secure metal supply in the future. However, we have only investigated a fraction of our oceans in sufficient detail to assess the global resource potential. A detailed exploration of the vast seafloor is currently economically not feasible, due to its extremely time-consuming and costly nature. Seafloor massive sulfides generally form along the active plate boundaries and at active volcanoes in arc settings. However, the resources are not evenly distributed on the seafloor. Large deposits tend to be more common along slow-spreading and ultra-slow- spreading ridges that make up the majority of the global mid-ocean ridge system [2]. Therefore, it is important to establish geological models and exploration criteria in order to narrow down the permissive areas, which are likely to accommodate economically interesting deposits. Based on a detailed study of the TAG hydrothermal field in the central Atlantic Ocean, hosting a large active mound as well as several inactive mounds, we develop exploration methods and criteria to define areas of potential massive sulfide occurrences along slow-spreading sections.

Jan 1, 2018

By J. A. Dos Santos

"INTRODUCTION Dramatic reduction in energy use and environmental impact can be achieved with sandwich belt high angle conveyors that serve as the vital link in any IPCC (In-pit Crushing and Conveying) system. These high angle conveyors are not new at all, but have not found wide use in IPCC systems where they can realize the greatest advantage. Reduced energy consumption and environmental impact, with IPCC systems, was already realized in the 1970s. With the bulk material haulage limited to conventional open trough conveyors the most direct path out of the open pit was precluded, requiring low angle spiral ramps and/or deep slots and/or tunnels through the high wall of the open pit. These excavations, to accommodate the low angle limitations, represented undesirable impact on cost and on the environment. Against this backdrop, a major study in 1979 sought to develop high angle conveying systems that could continuously haul the mined bulk material directly out of the pit, along the high wall – the shortest distance between the two end points. Between 1979 and 1982, that study developed sandwich belt high angle conveying systems that utilized all conventional conveyor equipment including smooth surfaced rubber belts that could be continuously scraped clean. These systems had all of the positive features of conventional conveyors but overcame the angle limitation. By hugging the bulk material between two belts, the material’s internal friction could be developed to facilitate conveying at any high angle up to 90 degrees (vertical). After an intense testing period (about one year) on the first large scale prototype system, commercialization began in 1983 with the installation of a 60 degree incline system at a western United States coal mine, elevating 2000 t/h of coal to a train load out system. It did not take a long period of scrutiny and acceptance before this high angle conveyor found use in the most rugged requirements of an IPCC system. This was only the second commercial sale, and after more than 150 commercial installations, it remains arguably the most significant high angle conveying system. In 1984, a copper mine in Serbia, already using pit perimeter crushing and conveying, decided to move their primary crusher deep into the pit and to use a sandwich belt high angle conveying system to elevate the ore continuously, directly out of the pit, along the high wall to the pit perimeter where it then transferred to a conventional conveyor for the remaining haul to the plant. The system had significant features including 2000mm wide belts that elevated 250mm coarse ore, at 4000 t/h, over six 15-meter high benches for a total 90 meters of net lift. The system was able to reduce the truck haulage fleet by ten 200 ton trucks realizing great cost savings, zero emissions to the air and greatly reduced traffic congestion in the pit. The system operated successfully until 2002 when the mine shut down. Many successful sandwich belt high angle conveyors followed with the current count of commercial installations at more than 150. Despite the great success with this system, its use has not been repeated as part of an IPCC system."

Jan 1, 2018

By Elisabetta Tedeschi, Razieh Nejati Fard

Deep-sea mining is in the future perspective of mining industry and it is currently in the technological development phase. The focus of this study is on the electrical power system that provides sufficient energy for the mining equipment at the seafloor, excavating Seafloor Massive Sulfide (SMS) deposits. SMS deposits usually exist at water depths between 1500 m and 4000 m. Despite the similarities of SMS deposits excavation to the open-pit terrestrial mines, more energy is required to drill and crush the ores in the hyperbaric conditions [1], which can be done whether by static trench cutters [1] or by mobile mining crawlers [2]. In addition, the ores vertical transportation by subsea pumps requires several MW electrical power that can be supplied by all-electric subsea motors or hydraulically from water injection motors located on the surface. The power requirements can be fulfilled by an offshore or subsea power network. As the SMS mines are usually in remote locations, the straightforward solution will be an isolated offshore grid mounted on a vessel or platform similar to the most of offshore Oil & Gas projects. These power systems resemble the onshore microgrids for industrial purposes operating in island mode. However, in contrast with the onshore power networks, there are space and weight limitations in offshore infrastructures, which impose the design compactness to be a priority. In addition, having a very high reliability is necessary in the design approach of the offshore projects due to the extraordinary high expenses corresponding to repair and maintenance. The other design criterion is to improve the power system efficiency in order to reduce the size of the power equipment cooling apparatus, operational costs and CO2 emissions produced by diesel/LNG onboard generators. There are a few studies considering power system distribution for seafloor mining industry. Among them, [3] has investigated the AC and DC alternatives for SMS mining in 2400 m water depth by considering Solwara 1 project scenario introduced by Nautilus Minerals Inc. [2]. In this study, a power system design tool will be presented taking into account various water depth, power consumption levels, different distribution configurations (AC and DC) and the aforementioned design criteria.

Jan 1, 2018

By L. E. Veki, S. M. Luukkanen, J. P. Karvonen, J. O. Leppinen

Today there is a consensus that xanthate adsorption on sulfide minerals is primarily controlled by redox reactions occurring at specific potentials on these semi-conductive minerals. Consequently, it is possible to control xanthate adsorption by controlling electrochemical conditions in the system by using oxidizing and reducing agents. The scope of this study was to investigate the possibilities to increase the selectivity of Cu-Fe-Zn ore flotation by applying electrochemical control in the conditioning of the flotation feed. In this work, mild steel grinding in a nitrogen atmosphere was used as the basis to provide a negative starting potential and minimize the amount of oxidation products on sulfide mineral surfaces. To study how different potential levels affect flotation results, a controlled conditioning procedure was utilized maintaining potential at a desired level by titrating the pulp with air. Xanthate adsorption kinetics during conditioning was examined by taking pulp samples for spectrophotometric analysis and laboratory flotation tests were conducted for samples that underwent the controlled conditioning procedure in the potential range of -200mV to +200mV vs. SHE. A clear correlation was detected between chalcopyrite recovery and the potential during controlled conditioning indicating that there was a constant increase in chalcopyrite recovery when the potential was shifted to more anodic values. It is possible that utilizing potential control in the conditioning stage, a smelter grade copper concentrate can be achieved directly in rougher flotation without cleaning stages. Conditioning in favorable conditions had significant positive effects on flotation selectivity of chalcopyrite. The improvement in copper concentrate grade being predominantly caused by the depression of pyrite. By applying the controlled conditioning procedure pyrite recovery in rougher flotation was reduced even low as under 1%, while in the tests without controlled conditioning, pyrite recovery varied between 7.5 – 65.7%. The result of this work indicate that affecting collector adsorption by electrochemical control in the conditioning stage can provide significant improvement in sulfide mineral flotation and industrial applications could lead to decreased chemical consumption, reduced equipment and maintenance costs.

Jan 1, 2018

By C. A. C. Sequeira, G. N. Anastassakis

"The separation of fine or even smaller size mineral particles with conventional methods is inefficient due to the specific properties of fines (small mass, high specific surface area, and high surface energy per unit area). Hence, the production of high-grade concentrate with high recovery is very difficult to impossible and a significant share of mineral values is lost to the tailings. The aim of the current research is to investigate the possibility to efficiently separate value minerals from gangue of fine particle size. The objective of the current work is to develop separation schemes of fine mineral particles by combining an initial stage of particles agglomeration with the use of collectors (hydrophobic agglomeration) with a subsequent conventional separation method. In the current research, magnesite was used as mineral value to be separated: a) from quartz, and b) from mineral mixture (serpentine, ilmenite, and olivine). In each case, tests on single minerals and artificial mixtures were carried out. After hydrophobic agglomeration, the separation of magnesite from quartz was achieved by settling; in the second case (gangue: serpentine, ilmenite, and olivine), magnetic separation of the co-agglomerated gangue was applied. In both cases, the results of the preliminary tests on single minerals suggest that the separation of mineral value is feasible and efficient. These findings were also confirmed from the results of the tests on artificial mixtures of magnesite and gangue, either quartz only or mineral mixture. Both separation schemes provided with magnesite concentrates of commercial grade (95% magnesite) with high recovery. INTRODUCTION The generation of fine particles is inevitable in many operations of mineral commodities processing. Especially in the case of low-grade ores, the mineral value is finely disseminated in the ore, and considerable liberation occurs at a fine size range. Although there is not a uniform classification system with respect to mineral particles size, fines are usually characterized the particles with a size range of -100µm+20µm, very fines those of -20µm+5µm, ultra fines of -5µm+1µm, and colloids smaller than 1µm (Sivamohan, 1990)."

Jan 1, 2018

By Matt Slezak, Tristan Worsey, Nathan Rouse, Kyle Hall

As everyone knows, blasters are required to file blast reports of every blast for regulatory purposes. To this day, the authors see many handwritten blast reports. Handwritten blast reports are notorious for containing errors or omissions. This is not because the blaster intends to misreport information. It is because blasters have many tasks to complete in a day, are sometimes in a rush, and could accidentally miscalculate data, omit items, or record incorrect data. In most cases, blasters do not suffer consequences to these errors because blast reports are seldom reviewed in detail. In some cases, such as when a blasting operation undergoes some sort of litigation process, the reports are reviewed in detail and the blaster is ultimately held responsible. If the reports contain errors, the blaster can be fined, have his/her license revoked, or worse. Electronic blast reporting and centralized data management can help reduce or eliminate the potential for accidental blast reporting errors to occur. This paper presents many ways that electronic blast reporting can reduce or eliminate blast reporting errors, decrease time and extra costs spent reporting, and improve efficiencies in the field and the office.

Jan 1, 2018

By O. Jerez, A. Novoselov, L. Gutiérrez, J. Morales, U. Kelm

"In Chile, the evaluation to reprocess tailings for elements other than the traditional Cu, Mo, Au, and Ag, as well as projects to implement long-term monitoring of mining residue sites are key elements of the government’s roadmap laid out for the mining industry for the next two decades. Characterization routines for tailings and mining residues in general have to be adapted from traditional ore and gangue mineral and micro-chemical studies. This contribution summarizes key aspects for the regional mining industry for a basic characterization of tailings with emphasis on small- to medium-size operations with limited in-house facilities and funds to carry out extensive characterization programs. The oldest tailings in Chile were deposited almost a century ago; this fact gives importance to the recovery of past ore /gangue feed information, process circuits and changes (e.g. acid to alkaline flotation), process water provenance and recovery, meteorological registers, and routines of filling a tailings impoundment. Basic characterization should include X-ray fluorescence spectrometry combined with laser diffraction (LD) granulometry followed by X-ray diffraction (XRD), optical microscopy (OM) and automated mineral analysis (AMA) on a reduced set of samples identified by hierarchical cluster analysis. For this detailed stage, only coarse tailings are recommended for direct a study by microscopy and automated mineralogy (P80 >100 µm); for fine tailings (P80 ~30 µm) a combination of XRD and deposit type adapted sequential extraction are more informative options. In particular, for XRD of clay phases, losses of crystallinity may result in deviation of spectra from standard reference phases due to prolonged storage. To monitor surface alteration, scanning electron microscopy can be complemented by Raman spectroscopy to detect residual reagents on mineral surfaces. For reactivity modeling BET measurements are essential."

Jan 1, 2018

By L. A. Nemchinova, M. A. Arustamian

"For a long time tailings piles of mining and smelting complexes have met the eye being a prospecting feedstock source for many industries. Nowadays, 6.5 million tons of copper and cooper-zinc processing tailings are stockpiled in the Urals annually, as there is no technology of its processing to provide a full and complex metal extraction within mining and processing operations. In spite of large volumes of mining wastes, not more than 20% of annual overburden, approx. 10% of processing wastes, approx. 40% slags (1) are involved into processing.Based on today’s complex of economic, environmental and social challenges of ore processing, waste processing technology using existing capacities is a burning issue. Mining wastes characteristics (including fine dissemination, variability of physical and chemical properties of mineral surfaces under impact of oxidizing, leaching, etc.) predetermine challenges arising out of its involving into processing and justify high capital intensity of new construction or reconstruction projects followed by replacement of existing processing lines with new ones.In this paper, the authors propose flotation technology for mature tailings of copper, copper-zinc and polymetallic ore processing. The technology developed provides for upgrade of existing process flowsheet diagrams at minimum costs to produce additional saleable products including low-grade copper concentrate, saleable zinc concentrate and gold concentrate thus facilitates sustainable use of depleting minerals and operational efficiency due to cost-efficient processing of already mined materials, being in fact, final semi-products located near existing operations. This is particularly important for operations with standby capacities and not engaged workforce."

Jan 1, 2018

By A. P. Chaves, D. Jose Neto, M. G. Bergerman, E. S. Mano

"More complex ore comminution and concentration operations have found increasing application in the mining industry due to lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. They allow removing a significant mass of material with little or no content of the relevant mineral before the ore is fed into the processing plant, with the consequent reduction in the mass to be processed in downstream operations. Significant benefits arise out of the use of pre-concentration, such as higher contained metal output without the need to increase the grinding or flotation capacity, and longer mine life. The grade of marginal ores could be enhanced to a level that would make their exploration economically feasible, which would result in increasing exploitable reserves. Nevertheless, few studies to date have assessed the resulting impacts on ore grinding energy consumption and wear after the gangue is removed through pre-concentration operations. This study evaluated the energy consumption and wear of grinding circuits in Brazilian mining operations in which the feed has gone through a pre-concentration stage. Such assessment was based on different samples of sulfide and oxide ores. Laboratory tests were carried out to investigate the power consumption and wear of grinding circuits with and without a pre-concentration stage. Laboratory test results were used to simulate industrial grinding circuits based on both alternatives and illustrate the environmental and economic benefits of each one.INTRODUCTION Increasingly complex ore concentration operations in several stages have found broadening application in recent years in view of lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. Different ore processing technologies can be used for that purpose, such as magnetic separation, density segregation, and separation methods based on high-tech sensors (ore sorting). Currently, the most common methods are gravimetric processes, in view of their low cost, particularly jigging and dense medium separation methods, such as the drum and cone separators manufactured by Western Machinery Company, Teska, Drewboy, Norwalt, Dynawhirlpool and Tri-flo, and dense medium cyclones (CAMPOS; LUZ; BRAGA, 2010). The use of dry ore sorters has also grown significantly in recent years (Jose Neto et al. 2017). The selection of the separator type depends essentially on the ore particle size, required flows, and operating density ranges. All these methods may even be used after preferential blasting in mining (Grigg & Delemontex, 2015)."

Jan 1, 2018

By S. A. Kubyshkin, A. A. Agafonov, A. L. Shakhnin, S. M. Sukharzhevsky, A. A. Komlev, N. V. Vorob’ev-Desyatovskii, A. Pichugina

Cyanidation of gold ore results in formation not only of Na[Au(CN)2], but also cyanometallate complexes of some transition metals. During subsequent gold extraction from such solutions and pulps, using activated carbons (??), a number of problems arise. An effective solution of the problem is not possible without detailed knowledge of the interaction mechanism of transition metals cyanide complexes with AC particles. The chemical properties of AC particles and graphene, saturated with [?u(CN)n](n-1)- (n=2, 3), were studied by XPS, ESR, SQUID, and DFT. The obtained results were compared with the data on AC adsorption of anionic form of Ag(I), Au(I), Cd(II), Hg(II), Cr(III), Fe(II), Fe(III), Co(III), Rh(III), Ni(II), Pd(II), Pt(II) and Pt(IV) cyanide complexes. The adsorption of [?u(CN)n](n-1)- (n=2, 3) on AC from aqueous solutions in air is accompanied with oxidation of ?u(I) atoms. Besides, Cu(II) and Cu(III) compounds were found on AC surface. Quantum-chemical calculations confirmed the possibility of formation of Cu(I) complex with carbene-like sites of AC. The reactions of [?u(CN)n](n-1)- (n=2, 3) complexes and aromatic carbenes and their cation-radical were theoretically studied at DFT PBE level to obtain the information on adsorption of cyanometallate complexes on AC. Carbenes with different fragments were regarded as a model of activated carbons, which have free edge sites with paired o and n electrons. It was shown that [Cu(CN)2]- bounds firmly with triplet carbene, if one Cu-CN bond breaks. The dissociation process occurs through a multi-step spin-crossing mechanism to reduce total spin multiplicity of the metal-carbene complex. The behavior of transition element complexes in contact with AC in aqueous solutions is determined by the following characteristics: geometrical structure of ionic complexes; nature of ligands bonded to the central atom; concentration of reactive oxygen species in solution and its pH; nature of binding sites of AC.

Jan 1, 2018

By S. Nakamura, K. Fujiwara, S. Hirosawa, S. Tsukamoto, Y. Koshino, Y. Aruga

"In this study, hardness test, differential scanning calorimetry(DSC)and transmission electron micros copy were carried out to investigate the age-hardening behavior of Al-Mg-Si alloy with a Mg+Si concentration of 1.5mass%, and a Mg/Si ratio of 1.0. Pre-aging treatment was conducted for the solution-treated and then water-quenched specimen at 100, 80, 60, 40, 20 (natural aging), 0 and -20°C for 20min or 5h, followed by artificial aging at 170°C for 20min. It was found that when pre-aging time is prolonged from 20min to 5h, the bake-hardening response is deteriorated irrespective of the pre-aging temperature. In particular, the specimens subjected to pre-aging at 20-40°C for 5 h hardly increased the hardness with the subsequent artificial aging. From the results of DSC measurement, it was suggested that as pre-aging temperature is lowered, the amount of solute clusters formed during pre-aging, i.e. Mg-Si clusters and Si-rich clusters, is decreased, but the ratio of Si-rich clusters is increased, resulting in the deteriorated bake-hardening response.INTRODUCTIONIn recent years, Al-Mg-Si alloys have been widely used forautomotive body panels due to their excellent characteristics such as high strength-to-weight ratio and good formability. Their strength is increased not only by artificial aging during paint-bake treatment; i.e. “bake-hardening”, but also when kept at room temperature(RT);i.e. “natural aging”, in association with the suppressed bake-hardening response. Such a “negative effect of two-step aging” has been a serious problem because Al-Mg-Si alloy coils are unavoidably maintained at RT in the manufacturing process of body panels; e.g. shipping and storage. However, it was reported that pre-aging above 70°C before the two-step aging can restore the bake-hardening response, and such an improvement is related to the formation of solute clusters(Sato, 2006; Abidet al., 2010; Takaki et al., 2014; Zandbergen et al., 2015). From the comprehensive analysis by three-dimensional atom probe (Aruga et al., 2014 and 2015), it is believed that Mg-Si clusters formed during pre-aging transform into the strengtheningß"" phase, whereas Si-rich clusters formed during pre-aging act as a detrimental precursor of ß""phase. In this study, it was aimed to investigate the effect of pre-aging conditions, especially pre-aging temperature and time, on the formation of solute clusters during pre-aging, in order to elucidate the mechanism of the age-hardening behavior of an Al-Mg-Si alloy."

Jan 1, 2018

By Peter Zhang, Daniel Su, Essie Esterhuizen, Mark Van Dyke, Berk Tulu, Dave Gearhart

"Roof falls in longwall headgate can occur when weak roof and high horizontal stress are present. To prevent roof falls in the headgate under high horizontal stress, it is important to understand the ground response to high horizontal stress in the longwall headgate and the requirements for supplemental roof support. In this study, a longwall headgate under high horizontal stress was instrumented to monitor stress change in the pillars, deformations in the roof, and load in the cable bolts. The conditions in the headgate were monitored for about six months as the longwall face passed by the instrumented site. The roof behavior in the headgate near the face was carefully observed during longwall retreat. Numerical modeling was performed to correlate the modeling results with underground observation and instrumentation data and to quantify the effect of high horizontal stress on roof stability in the longwall headgate. This paper discusses roof support requirements in the longwall headgate under high horizontal stress in regard to the pattern of supplemental cable bolts and the critical locations where additional supplemental support is necessary.INTRODUCTIONLongwall mining is the primary underground coal mining method in the United States and currently accounts for more than 60% of the underground coal production. The longwall headgate, as a passageway for the longwall crew, intake air, material supplies, and coal belt transportation, is critical for both safety and continuous production of the longwall panel. A roof fall in the longwall headgate would not only result in substantial interruption of production but could potentially cause injuries or fatalities. Rehabilitation of failed roof in the headgate would also expose miners to the risk of injuries. Roof falls in the headgate, though infrequent, mostly occur in the belt entry near the face. Considerable research has been conducted to determine the effects of various factors on headgate roof stability, as well as effective measures to support the roof in longwall mines in the Pittsburgh seam (Mark, Mucho, and Dolinar, 1998; Chen et al., 1998; Su and Hasenfus, 1995; Su, Thomas, and Hasenfus, 1999; Su, Morris, and McCaffrey, 2002; Su, Draskovich, and Thomas, 2003; Hasenfus and Su, 2006; Van Dyke et al., 2015). Previous studies have demonstrated that high horizontal stress and transitional roof geology are primary factors that cause headgate roof failure. These studies also showed that panel orientation, retreat direction, pillar sizes, and roof support played an important role in the stability of a headgate.In underground coal mines located in the eastern United States, the magnitude of the maximum horizontal stress is typically three times greater than the vertical stress, and about 40% greater than the minimum horizontal stress. Mark, Mucho, and Dolinar (1998) studied seven cases of headgate failures caused by high horizontal stress in different coal seams in the United States and stated that roof stability is affected, to a large extent, by rock type, entry orientation, and longwall orientation. The effects of horizontal stress can be summarized in these statements: (1) A laminated roof is very vulnerable to high horizontal stress. (2) Entries that are aligned with the maximum horizontal stress will suffer less damage on development than those perpendicular to it. (3) Horizontal stress concentration and relief depends on panel orientation, the direction of retreat, and the sequence of longwall panel extraction."

Jan 1, 2018

By Bret N. Lingwall, Byron Foster

The problem of reliable extreme event modeling of large diameter piles under enormous structural or kinematic loads has gained more attention in recent years. In particular, the soil response around the foundation and impacts to buried adjacent infrastructure has gained interest. One of the principal shortcomings with analysis of large diameter pile foundations under extreme event lateral loading is the reliance on conventional beam on elastic foundation methods, which do not model the soil field response around the pile. These methods are limited for large displacement problems, and for large diameter piles. However, the fundamental interactions between steel and concrete, and structure to soil are difficult to constrain, especially in large strain problems where the structural elements become inelastic. The non-linear interaction of the structural materials and soil is desirable so that assessment of stress changes in the field and effects on adjacent facilities can be modeled. A numerical modeling methodology that addresses these shortcomings has been developed. This method utilizes the interaction of brittle concrete with discrete steel reinforcing and casing in a robust manner capturing inelastic non-linearity in both soil and structure. This paper presents a comparison study of the method, wherein three different validation studies were made to data from full scale laterally loaded pile testing. INTRODUCTION Extreme event lateral loading of deep foundations comes in many forms including earthquakes, landsliding, tsunamis, hurricanes, surface fault rupture, liquefaction induced lateral spreads and many more. These extreme events induce loads on foundations far greater than service or strength loads. Perhaps the most dangerous extreme event loads are those of large soil displacements such as landslides, lateral spreads, and surface fault rupture, wherein the soil surrounding the foundations can move laterally 100 mm to 3 m! In these extreme event loading scenarios, small diameter foundations are pushed past their limits and many engineers prefer large diameter deep foundations for these situations. These deep foundations of diameter 900 mm or greater may be auger cast in place piles, cast in drilled hole piles, cast in steel shell piles, cased or uncased drilled shafts, bored precast piles, etc. For convenience in this paper, large diameter deep foundations will be referred to as Large Diameter Shafts (LDS). In LDS, steel may or may not used as a shell around the perimeter of the concrete and/or as internal tensile reinforcement. The interaction between brittle concrete and ductile steel within and/or along the perimeter of the LDS is critical to understanding the non-linear inelastic behavior of LDS for problems of large lateral displacements from extreme events.

Jan 1, 2018

By S. Corrent, F. A. V. Guimarães, M. G. Barbosa

"INTRODUCTION Moisture can be a villain, so new technologies have been explored to make more viable the production of high moisture iron ores. The current work presents the attempt of the utilization of a superabsorbent polymer (SAP) to aid in the screening process and in the ore handling process, such as stockpiles reclaiming and vessels/trains discharge in sub-zero temperature conditions. The results have shown that the polymer can be used in certain cases to improve productivity and increase safety in the process of handling the material (by increasing the TML). However, for size separation no advantages were found upon the use of the polymers. WATER ADSORPTION MECHANISMS The use of water in mineral processing is constant as its utilization brings an increase in the efficiency of separation. Although we have better results in the processing with water, materials with a high content of “natural” moisture can be very difficult to be treated by the conventional methods of separation. Nowadays many studies have been conducted in order to understand the effect of adsorption of water in the particles of complex minerals. Those studies have being divided in many different lines of research such as contact angle of a drop of water and the surface of the mineral to determine hydrophobicity, the particle size distribution and the porosity of particles. Mainly two forms of adsorption of water by the particles are possible: one the water is retained inside porosity of the particles. Laboratory tests developed in China have showed that capillary adsorption is faster in coarser particles that achieve the saturation degree earlier than finer particles (Xuewei Lv et al., 2011). The so called non-porous model considers the effect of water in the bulk sample of iron ores, in a physical connection when all the water works as a binder between particles as shown in the figure 1.If we take into account the compressibility of the system and compaction due to the weight of the bed over the particles, the thickness of the water film between particles is the same but the volume inside different particle size systems is much higher than in a system with particles of same size."

Jan 1, 2018

By S. Patra, R. Venugopal

"The quality of pellets produced is affected by quality anssastd quantity of green pellets, amount of addition of binders, type of binders added, amount of moisture added along with the other variables like rotation, inclination and fineness of feed. The green pellet quality depends upon chemistry, mineralogy and granulometry of fines used for pellet making, the feed size, its moisture content and porosity. During firing of green pellets ingredients present within reacts to form different phases and microstructure. So in turn physical and metallurgical properties of pellets are influenced by amount and type of binder and flux addition, induration time and temperature. During iron making process, the metallurgical properties of fired pellets are decided by the type and amount of these phases and their chemistry. Green pelletizing and induration studies have been already carried out with hematite ore fines. Indian iron ores of high alumina content showing different pelletizing characters, these studies can’t be directly interpreted. The main objective of proposed research work is to understand the green pelletizing process and determine the water bentonite interaction at different levels. Detailed investigation on swelling behavior of bentonite and microstructure of the green pellets of iron ore fines from SAIL captive iron ore fines from the Barsua in the state of Odisha. To convert these ore fines into pellets, the key raw material, additives and process variables that influence the pellet quality needs to be identified.INTRODUCTION Pelletization is the unit operation of agglomerating iron bearing fines (generally below 150µ with 65-80% passing 40µ) by tumbling in horizontal rotating drums or inclined discs, (Sivrikaya and Arol, 2013; Bhuiyan et al., 2011; Forsmo et al., 2006; Sastry et al., 2003) and the pellets are approximately spherical lumps formed by this process in presence of water and binder, on subsequent induration at 1300°c (Sivrikaya and Arol, 2014; Sivrikaya and Arol, 2013; Sivrikaya and Arol, 2012; Sivrikaya and Arol, 2010; Sastry et al., 2003; Kawatra and Ripke, 2003; Iveson, 2001a; Iveson, 2001b)."

Jan 1, 2018

By D. G. Lynch, M. R. Martin, R. J. Coutts

"Broadmeadow Mine is an underground longwall mine located in Central Queensland, Australia. The mine introduced a top coal caving (TCC) longwall face in 2013 but since then has experienced severe convergence events at the start of each panel after 60–70m of retreat, resulting in equipment damage and the longwall almost becoming iron bound. A significant geotechnical monitoring effort during LW10 and LW11 to characterise the caving mechanics and operational changes during LW11 were successful in mitigating the risk posed by these initial convergence events. This paper describes the geotechnical monitoring programme undertaken during LW11, the operational methods used to mitigate these initial convergence events, and the contribution to these events of the TCC technique.A thick sandstone unit close to the extraction roof was likely the cause of the convergence events at the start of each longwall panel. However, stress change monitoring cells, surface extensometers, an inclinometer, and the blockage of holes designed for pre-conditioning using hydraulic fracturing indicated that the convergence events were not caused by the sudden collapse of sandstone bridging across the goaf. Rather, they were caused by the propping action of strong units within the overburden strata. Equipment design modifications were made to allow the longwall to remain operational during the convergence events and an operational strategy was implemented to mitigate convergence in LW11. The initial convergence event was successfully negotiated, and Broadmeadow went on to be the highest producing longwall for CY16 in Australia.INTRODUCTIONBroadmeadow Mine is an underground longwall mine located in Central Queensland, Australia, owned and operated by BHP Mitsubishi Alliance (BMA). The mine is a punch longwall mine using open cut pit access provided by Goonyella/Riverside Mine. Broadmeadow commenced longwall operations in 2005 using a conventional high reach longwall, but later changed to the top coal caving (TCC) method of extraction. Broadmeadow extracts the easterly dipping 5.5–7.5m-thick Goonyella Middle Seam in ranging in depth from 90m to 330m. The coal is washed and blended at the adjacent Goonyella/Riverside open cut mine to produce a premium coking coal product for export."

Jan 1, 2018

By S. M. Bradshaw, C. Dorfling, F. Ngandu

"Selenium removal and platinum group metal (PGM) recovery from copper sulfate leach solutions form an integral part of platinum producers’ base metal refinery operations. Recent studies found that substantially higher PGM recoveries can be achieved if excess thiourea instead of sulfurous acid is used as precipitation reagent; however, the impact of the proposed process on downstream processes was unknown. The objective of the current study was therefore to investigate the effects that excess thiourea and residual selenium present in the rich copper sulfate electrolyte have on copper electrowinning. This was achieved by performing cyclic voltammetry tests using a platinum rotating disk as working electrode, a graphite auxiliary electrode and a saturated calomel reference electrode. A synthetic copper sulfate electrolyte containing 0.01 M Cu2+, 1 M H2SO4 and varying amounts of selenium (20 – 150 mg/L) and thiourea (10 mg/L and 100 – 300 % excess) was used. The results obtained have shown that both thiourea and selenium interact with the cupric ion cathodic reduction reaction. Thiourea polarized the working electrode and lowered the efficiency of the cupric reduction reaction. Tests on the solutions with high selenium concentration showed simultaneous reduction of copper and selenium, which led to copper selenide formation. Nodule formation on the deposit surface also became significant at higher selenium concentrations. Based on these results, it was concluded that precipitation of PGMs from the copper sulfate solution with excess thiourea is not feasible due to the detrimental effect on downstream electrowinning operations.INTRODUCTION During the high pressure oxidative leaching stage in a typical base metal refinery (BMR) circuit, selenium, tellurium and some platinum group metals (PGMs) are dissolved along with the desired copper ions. The impurities (selenium and tellurium) may pass to the copper electrowinning circuit where it can result in the formation of nodular copper electrodeposits or reduced current efficiency. The presence of PGMs in solution, on the other hand, increases the precious metal inventory and potential losses of the operation. Currently, sulfurous acid is widely used for selenium and tellurium precipitation from copper sulfate leach solutions. Sulfurous acid is capable of reducing cupric ions to cuprous ions; the generated cuprous ions then react with Se4+ and Se6+ to precipitate selenium as a copper selenide (Bello, Dorfling, 2014). Recent studies have, however, proposed the use of excess thiourea as a precipitating agent for the removal of selenium and tellurium; it has the advantage of improved PGM recovery in the Se/Te precipitation step (Lottering, Eksteen et al., 2012; Mulwanda, Dorfling, 2015)."

Jan 1, 2018